CN104292969A - Offset UV varnish printing ink with mirror surface effect and preparation method of offset UV varnish printing ink - Google Patents

Offset UV varnish printing ink with mirror surface effect and preparation method of offset UV varnish printing ink Download PDF

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Publication number
CN104292969A
CN104292969A CN201410547743.0A CN201410547743A CN104292969A CN 104292969 A CN104292969 A CN 104292969A CN 201410547743 A CN201410547743 A CN 201410547743A CN 104292969 A CN104292969 A CN 104292969A
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CN
China
Prior art keywords
printing ink
offset
glycol diacrylate
epoxy acrylate
propylene glycol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201410547743.0A
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Chinese (zh)
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CN104292969B (en
Inventor
胡爱军
徐执一
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ZHEJIANG MINONG CENTURY GROUP Co.,Ltd.
ZHEJIANG MINONG MATERIAL TECHNOLOGY Co.,Ltd.
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ZHEJIANG MINONG GROUP CO Ltd
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Priority to CN201410547743.0A priority Critical patent/CN104292969B/en
Publication of CN104292969A publication Critical patent/CN104292969A/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

The invention relates to an offset UV varnish printing ink with mirror surface effect and a preparation method of the offset UV varnish printing ink. The offset UV varnish printing ink with mirror surface effect is characterized by comprising the following compositions in percentage by weight: 19%-23% of standard bisphenol A epoxy acrylate, 61%-65% of dipropylene glycol diacrylate, 3%-7% of p-benzoyl polyethylene glycol benzoate, and 9%-13% of reactive tertiary amine. According to the invention, the offset UV varnish printing ink with mirror surface effect has good levelness and transparency without addition of auxiliaries such as a leveling agent and a defoaming agent, the offset and polished product has a mirror-like effect, and the smooth, level and transparent effects of a mirror can be simulated on a paper package by means of printing. No reaction auxiliaries are added in the printing ink, so that the curing resistance can be reduced, and the influence on the transparency and compatibility of the printing ink can be reduced. The printing ink is less in side reaction in curing reaction, low in migration rate and volatility, thus having high environment-friendly property; and the Vocs smell can completely achieve the national standard requirement.

Description

A kind of offset printing UV gloss oil ink with mirror effect and preparation method thereof
Technical field
The present invention relates to a kind of offset printing UV gloss oil ink with mirror effect and preparation method thereof.
Background technology
In offset printing; common offset printing UV gloss oil mainly carries out a provide protection to product; be difficult to form mirror effect at product surface; the present invention aims to provide one can realize a kind of mirror effect at common printed paper surface, reflect external light, realizes mirror function; make human consumer can be used as a simple and easy mirror to use; thus make product have extremely strong sales counter effect and visual effect, and there is certain practicality, and meet the feature of environmental protection requirement of cigarette package.
Summary of the invention
For problems of the prior art, the object of the present invention is to provide the technical scheme of a kind of offset printing UV gloss oil ink with mirror effect and preparation method thereof.
Described a kind of offset printing UV gloss oil ink with mirror effect; it is characterized in that being made up of the component of following weight percent: standard Bisphenol-A epoxy acrylate 19%-23%; propylene glycol diacrylate 61%-65%; o-benzoyl yl benzoic acid macrogol ester 3%-7%, response type tertiary amine 9%-13%.
Described a kind of offset printing UV gloss oil ink with mirror effect; it is characterized in that being made up of the component of following weight percent: standard Bisphenol-A epoxy acrylate 20%-22%; propylene glycol diacrylate 62%-64%; o-benzoyl yl benzoic acid macrogol ester 4%-6%, response type tertiary amine 10%-12%.
Described a kind of offset printing UV gloss oil ink with mirror effect; it is characterized in that being made up of the component of following weight percent: standard Bisphenol-A epoxy acrylate 21%; propylene glycol diacrylate 63%, o-benzoyl yl benzoic acid macrogol ester 5%, response type tertiary amine 11%.
The described preparation method with the offset printing UV gloss oil ink of mirror effect, it is characterized in that: be proportionally equipped with raw material, first the standard Bisphenol-A epoxy acrylate of the propylene glycol diacrylate of 1/5th and 1/5th is added in a mixing bowl, open high speed dispersor, rotating speed 400 revs/min, o-benzoyl yl benzoic acid macrogol ester is added after stirring and dissolving, stirring velocity is increased to 800-1000 rev/min, stirring and dissolving is to transparent in particle, add remaining propylene glycol diacrylate and remaining standard Bisphenol-A epoxy acrylate again, stir, after being cooled to room temperature, add response type tertiary amine, middling speed 800 revs/min stirs after 10 minutes, filter with filter, namely the offset printing UV gloss oil ink that this has mirror effect is obtained.
Namely ink of the present invention have fabulous planeness and transparency without the need to adding the auxiliary agent such as flow agent, defoamer, the product after offset printing glazing is made to have effect as mirror, meet the imagination that design field all the time thinks to add on the packaging other functions, in papery packaging, simulate smooth, smooth, the transparent effect of mirror by printing means.Owing to not adding various reaction promoter in this ink, decrease resistance during solidification, and reduce the impact on ink transparency, intermiscibility.The more craft feature of product and cultural connotation are given in the use of ink of the present invention; Meanwhile, the side reaction when curing reaction of this ink is few, and mobility, volatility are very low, and thus this printing-ink has the very high feature of environmental protection, the residual requirement that is up to state standards completely of its Vocs smell.
Embodiment
Embodiment 1
First be equipped with following raw material: standard Bisphenol-A epoxy acrylate 210g, propylene glycol diacrylate 630g, o-benzoyl yl benzoic acid macrogol ester 50g, response type tertiary amine 110g.
Preparation method: first the standard Bisphenol-A epoxy acrylate (UV resin) of the propylene glycol diacrylate (monomer) of 1/5th and 1/5th is added in a mixing bowl, open high speed dispersor (unit type F250, Jiangsu mighty torrent chemical industry is bought), rotating speed 400 revs/min, o-benzoyl yl benzoic acid macrogol ester (initiator) is added after stirring and dissolving, stirring velocity is increased to 800-1000 rev/min, so that rising temperature for dissolving initiator, stirring and dissolving is to transparent in particle, add remaining propylene glycol diacrylate (monomer) and remaining standard Bisphenol-A epoxy acrylate (UV resin) again, stir, after being cooled to room temperature, add response type tertiary amine (aided initiating), middling speed 800 revs/min stirs after 10 minutes, filter with filter, namely the offset printing UV gloss oil ink that this has mirror effect is obtained, then check, packaging.
Raw material is equipped with according to aforementioned proportion during batch production.
Embodiment 2
Standard Bisphenol-A epoxy acrylate 190g, propylene glycol diacrylate 640g, o-benzoyl yl benzoic acid macrogol ester 70g, response type tertiary amine 100g.
Be equipped with raw material according to aforementioned proportion during batch production, preparation technology is with reference to embodiment 1.
Embodiment 3
Standard Bisphenol-A epoxy acrylate 200g, propylene glycol diacrylate 650g, o-benzoyl yl benzoic acid macrogol ester 60g, response type tertiary amine 90g.
Be equipped with raw material according to aforementioned proportion during batch production, preparation technology is with reference to embodiment 1.
Embodiment 4
Standard Bisphenol-A epoxy acrylate 230g, propylene glycol diacrylate 610g, o-benzoyl yl benzoic acid macrogol ester 40g, response type tertiary amine 120g.
Be equipped with raw material according to aforementioned proportion during batch production, preparation technology is with reference to embodiment 1.
Embodiment 5
Standard Bisphenol-A epoxy acrylate 220g, propylene glycol diacrylate 620g, o-benzoyl yl benzoic acid macrogol ester 30g, response type tertiary amine 130g.
Be equipped with raw material according to aforementioned proportion during batch production, preparation technology is with reference to embodiment 1.
Embodiment 6
Standard Bisphenol-A epoxy acrylate 205g, propylene glycol diacrylate 618g, o-benzoyl yl benzoic acid macrogol ester 61g, response type tertiary amine 116g.
Be equipped with raw material according to aforementioned proportion during batch production, preparation technology is with reference to embodiment 1.
In above-mentioned ink, the matrix resin during standard Bisphenol-A epoxy acrylate (EBECRYL 600) forms as ink, mainly because itself and monomer reaction rapidly, make ink film be formed fast; And surface tension is moderate, inherently can at stock surface levelling well when there is no auxiliary agent; Have outstanding solvent resistance, modest viscosity, glossiness is high, and transparency is high, therefore can form outstanding mirror effect.This resin can commercially be buied, and manufacturer is the special extraordinary chemical industry (the Asian-Pacific area) of cyanogen.
Propylene glycol diacrylate (Oxybis (methyl-2,1-ethanediyl) diacrylate, molecular formula C 12h 18o 5) be monomer in ink composition, its dilution capacity is strong, and have fabulous intermiscibility with matrix resin, viscosity, surface tension are moderate, contribute to the levelling on stock surface, makes layer of ink have the excellent transparency and planeness; And high-polymer molecular interchain can form multiple hydrogen bond when reacting, make layer of ink have excellent mechanical endurance, this resin can commercially be buied, and manufacturer is the special extraordinary chemical industry (the Asian-Pacific area) of cyanogen.
O-benzoyl yl benzoic acid macrogol ester (Benzoylbenzoate esters with branched polyols) is a kind of polyfunctional group Benzophenone macromolecular photoinitiator; its formula consistency is good, efficiency of initiation is high; and no coupling product etc. after solidification; the effect having fast setting to react in the radical polymerization of UV UV-light; and have and refuse water main chain and fantabulous solvency power; aim at require low smell, low migration ink and design; and easily by the synergy of amine auxiliary agent; can commercially directly buy, Beijing Yingli Technology Development Co., Ltd of manufacturer.
6420 response type tertiary amine aided initiatings (Reation Amine Synergist response type tertiary amine aided initiating) are as the aided initiating in ink composition, surface cure is fast, side reaction product is few, transparency is high, effectively can reduce that the surface of amine is floating to be moved, therefore contribute to the mirror effect after improving ink setting.Can commercially directly buy, manufacturer is Guangzhou Han Dong trade Co., Ltd.

Claims (4)

1. one kind has the offset printing UV gloss oil ink of mirror effect; it is characterized in that being made up of the component of following weight percent: standard Bisphenol-A epoxy acrylate 19%-23%; propylene glycol diacrylate 61%-65%; o-benzoyl yl benzoic acid macrogol ester 3%-7%, response type tertiary amine 9%-13%.
2. a kind of offset printing UV gloss oil ink with mirror effect according to claim 1; it is characterized in that being made up of the component of following weight percent: standard Bisphenol-A epoxy acrylate 20%-22%; propylene glycol diacrylate 62%-64%; o-benzoyl yl benzoic acid macrogol ester 4%-6%, response type tertiary amine 10%-12%.
3. a kind of offset printing UV gloss oil ink with mirror effect according to claim 1; it is characterized in that being made up of the component of following weight percent: standard Bisphenol-A epoxy acrylate 21%; propylene glycol diacrylate 63%; o-benzoyl yl benzoic acid macrogol ester 5%, response type tertiary amine 11%.
4. the preparation method with the offset printing UV gloss oil ink of mirror effect as described in claim 1 or 2 or 3, it is characterized in that: be proportionally equipped with raw material, first the standard Bisphenol-A epoxy acrylate of the propylene glycol diacrylate of 1/5th and 1/5th is added in a mixing bowl, open high speed dispersor, rotating speed 400 revs/min, o-benzoyl yl benzoic acid macrogol ester is added after stirring and dissolving, stirring velocity is increased to 800-1000 rev/min, stirring and dissolving is to transparent in particle, add remaining propylene glycol diacrylate and remaining standard Bisphenol-A epoxy acrylate again, stir, after being cooled to room temperature, add response type tertiary amine, middling speed 800 revs/min stirs after 10 minutes, filter with filter, namely the offset printing UV gloss oil ink that this has mirror effect is obtained.
CN201410547743.0A 2014-10-16 2014-10-16 A kind of offset printing UV gloss oil ink with mirror effect and preparation method thereof Active CN104292969B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104650646A (en) * 2015-03-12 2015-05-27 山东德创喷墨科技有限公司 Low-migration UV flexible printing ink and preparation method thereof
CN109082156A (en) * 2018-08-28 2018-12-25 苏州安洁科技股份有限公司 A kind of imitative metal red ink and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0350216A (en) * 1989-07-17 1991-03-04 Sony Corp Photopolymer composition
CN1526770A (en) * 2003-03-03 2004-09-08 珠海东诚化工有限公司 Visible light cured plastic paint
CN1693385A (en) * 2005-05-11 2005-11-09 中国乐凯胶片集团公司 UV photocureable magnetic offset lithography printing ink
CN103224731A (en) * 2012-10-24 2013-07-31 北京印刷学院 Pinkish red UV ink-jet ink for high-speed ink-jet printing and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0350216A (en) * 1989-07-17 1991-03-04 Sony Corp Photopolymer composition
CN1526770A (en) * 2003-03-03 2004-09-08 珠海东诚化工有限公司 Visible light cured plastic paint
CN1693385A (en) * 2005-05-11 2005-11-09 中国乐凯胶片集团公司 UV photocureable magnetic offset lithography printing ink
CN103224731A (en) * 2012-10-24 2013-07-31 北京印刷学院 Pinkish red UV ink-jet ink for high-speed ink-jet printing and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104650646A (en) * 2015-03-12 2015-05-27 山东德创喷墨科技有限公司 Low-migration UV flexible printing ink and preparation method thereof
CN109082156A (en) * 2018-08-28 2018-12-25 苏州安洁科技股份有限公司 A kind of imitative metal red ink and preparation method thereof

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Effective date of registration: 20200622

Address after: Three 310030 Hangzhou Road, Zhejiang province Xihu District three Town Xiyuan No. 6

Co-patentee after: ZHEJIANG MINONG MATERIAL TECHNOLOGY Co.,Ltd.

Patentee after: ZHEJIANG MINONG CENTURY GROUP Co.,Ltd.

Address before: Three 310030 Hangzhou Road, Zhejiang province Xihu District three Town Xiyuan No. 6

Patentee before: ZHEJIANG MINONG CENTURY GROUP Co.,Ltd.