CN104292969B - A kind of offset printing UV gloss oil ink with mirror effect and preparation method thereof - Google Patents

A kind of offset printing UV gloss oil ink with mirror effect and preparation method thereof Download PDF

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Publication number
CN104292969B
CN104292969B CN201410547743.0A CN201410547743A CN104292969B CN 104292969 B CN104292969 B CN 104292969B CN 201410547743 A CN201410547743 A CN 201410547743A CN 104292969 B CN104292969 B CN 104292969B
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China
Prior art keywords
ink
offset printing
gloss oil
propylene glycol
mirror
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CN201410547743.0A
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CN104292969A (en
Inventor
胡爱军
徐执
徐执一
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ZHEJIANG MINONG CENTURY GROUP Co.,Ltd.
ZHEJIANG MINONG MATERIAL TECHNOLOGY Co.,Ltd.
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ZHEJIANG MINONG GROUP CO Ltd
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

The present invention relates to a kind of offset printing UV gloss oil ink with mirror effect and preparation method thereof。It is characterized in that being made up of following components in percentage by weight: standard Bisphenol-A epoxy acrylate 19%-23%, propylene glycol diacrylate 61%-65%, o-benzoyl yl benzoic acid macrogol ester 3%-7%, response type tertiary amine 9%-13%。Namely the present invention has fabulous flatness and transparency without adding the auxiliary agent such as levelling agent, defoamer so that the product after offset printing glazing has the effect as mirror, has simulated, on papery is packed, the effect that mirror is smooth, smooth, transparent by printing means。Owing to this ink not adding various reaction promoter, decrease resistance during solidification, and reduce the impact on ink transparency, intermiscibility。The side reaction when curing reaction of the ink of the present invention is few, and mobility, volatility are very low, thus have the significantly high feature of environmental protection, and its Vocs abnormal smells from the patient residual is fully achieved national standard requirement。

Description

A kind of offset printing UV gloss oil ink with mirror effect and preparation method thereof
Technical field
The present invention relates to a kind of offset printing UV gloss oil ink with mirror effect and preparation method thereof。
Background technology
In offset printing; product is mainly carried out a protective effect by common offset printing UV gloss oil; it is difficult to form mirror effect at product surface; it is desirable to provide one can realize a kind of mirror effect at common printed paper surface, reflect extraneous light, realize mirror function; make consumer can use as a simple and easy mirror; so that product has extremely strong sales counter effect and visual effect, and there is certain practicality, and meet the feature of environmental protection requirement of cigarette package。
Summary of the invention
For problems of the prior art, it is an object of the invention to provide the technical scheme of a kind of offset printing UV gloss oil ink with mirror effect and preparation method thereof。
Described a kind of offset printing UV gloss oil ink with mirror effect; it is characterized in that being made up of following components in percentage by weight: standard Bisphenol-A epoxy acrylate 19%-23%; propylene glycol diacrylate 61%-65%; o-benzoyl yl benzoic acid macrogol ester 3%-7%, response type tertiary amine 9%-13%。
Described a kind of offset printing UV gloss oil ink with mirror effect; it is characterized in that being made up of following components in percentage by weight: standard Bisphenol-A epoxy acrylate 20%-22%; propylene glycol diacrylate 62%-64%; o-benzoyl yl benzoic acid macrogol ester 4%-6%, response type tertiary amine 10%-12%。
Described a kind of offset printing UV gloss oil ink with mirror effect; it is characterized in that being made up of following components in percentage by weight: standard Bisphenol-A epoxy acrylate 21%; propylene glycol diacrylate 63%, o-benzoyl yl benzoic acid macrogol ester 5%, response type tertiary amine 11%。
The preparation method of the described offset printing UV gloss oil ink with mirror effect, it is characterized in that: be proportionally equipped with raw material, first the standard Bisphenol-A epoxy acrylate of the propylene glycol diacrylate of 1/5th and 1/5th is added in a mixing bowl, open high speed dispersor, rotating speed 400 revs/min, o-benzoyl yl benzoic acid macrogol ester is added after stirring and dissolving, mixing speed is increased to 800-1000 rev/min, stirring and dissolving is to transparent in granule, add remaining propylene glycol diacrylate and remaining standard Bisphenol-A epoxy acrylate, stir, after being cooled to room temperature, add response type tertiary amine, after middling speed 800 revs/min stirs 10 minutes, filter with filter, namely this offset printing UV gloss oil ink with mirror effect is prepared。
Namely the ink of the present invention have fabulous flatness and transparency without adding the auxiliary agent such as levelling agent, defoamer, the product after offset printing glazing is made to have the effect as mirror, meet design field all the time and think to add on the packaging the imagination of other functions, simulated, on papery is packed, the effect that mirror is smooth, smooth, transparent by printing means。Owing to this ink not adding various reaction promoter, decrease resistance during solidification, and reduce the impact on ink transparency, intermiscibility。The use of ink of the present invention gives the more craft feature of product and cultural connotation；Meanwhile, the side reaction when curing reaction of this ink is few, and mobility, volatility are very low, thus this printing-ink has the significantly high feature of environmental protection, and its Vocs abnormal smells from the patient residual is fully achieved national standard requirement。
Detailed description of the invention
Embodiment 1
First it is equipped with following raw material: standard Bisphenol-A epoxy acrylate 210g, propylene glycol diacrylate 630g, o-benzoyl yl benzoic acid macrogol ester 50g, response type tertiary amine 110g。
Preparation method: first the standard Bisphenol-A epoxy acrylate (UV resin) of the propylene glycol diacrylate (monomer) of 1/5th and 1/5th is added in a mixing bowl, open high speed dispersor (unit type F250, Jiangsu mighty torrent chemical industry is bought), rotating speed 400 revs/min, o-benzoyl yl benzoic acid macrogol ester (initiator) is added after stirring and dissolving, mixing speed is increased to 800-1000 rev/min, so as rising temperature for dissolving initiator, stirring and dissolving is to transparent in granule, add remaining propylene glycol diacrylate (monomer) and remaining standard Bisphenol-A epoxy acrylate (UV resin), stir, after being cooled to room temperature, add response type tertiary amine (aided initiating), after middling speed 800 revs/min stirs 10 minutes, filter with filter, namely this offset printing UV gloss oil ink with mirror effect is prepared, then check, packaging。
It is equipped with raw material according to aforementioned proportion during batch production。
Embodiment 2
Standard Bisphenol-A epoxy acrylate 190g, propylene glycol diacrylate 640g, o-benzoyl yl benzoic acid macrogol ester 70g, response type tertiary amine 100g。
Being equipped with raw material according to aforementioned proportion during batch production, preparation technology is with reference to embodiment 1。
Embodiment 3
Standard Bisphenol-A epoxy acrylate 200g, propylene glycol diacrylate 650g, o-benzoyl yl benzoic acid macrogol ester 60g, response type tertiary amine 90g。
Being equipped with raw material according to aforementioned proportion during batch production, preparation technology is with reference to embodiment 1。
Embodiment 4
Standard Bisphenol-A epoxy acrylate 230g, propylene glycol diacrylate 610g, o-benzoyl yl benzoic acid macrogol ester 40g, response type tertiary amine 120g。
Being equipped with raw material according to aforementioned proportion during batch production, preparation technology is with reference to embodiment 1。
Embodiment 5
Standard Bisphenol-A epoxy acrylate 220g, propylene glycol diacrylate 620g, o-benzoyl yl benzoic acid macrogol ester 30g, response type tertiary amine 130g。
Being equipped with raw material according to aforementioned proportion during batch production, preparation technology is with reference to embodiment 1。
Embodiment 6
Standard Bisphenol-A epoxy acrylate 205g, propylene glycol diacrylate 618g, o-benzoyl yl benzoic acid macrogol ester 61g, response type tertiary amine 116g。
Being equipped with raw material according to aforementioned proportion during batch production, preparation technology is with reference to embodiment 1。
In above-mentioned ink, standard Bisphenol-A epoxy acrylate (EBECRYL600), as the matrix resin in ink composition, is primarily due to it with monomer reaction rapidly, makes ink film quickly be formed；And surface tension is moderate, inherently can at stock surface levelling well when there is no auxiliary agent；Having outstanding solvent resistance, modest viscosity, glossiness is high, and transparency is high, therefore can form outstanding mirror effect。This resin is commercially available, and manufacturer is cyanogen spy's special type chemical industry (the Asian-Pacific area)。
Propylene glycol diacrylate (Oxybis (methyl-2,1-ethanediyl) diacrylate, molecular formula C12H18O5) it is the monomer in ink composition, its dilution capacity is strong, has fabulous intermiscibility with matrix resin, and viscosity, surface tension are moderate, contribute to the levelling on stock surface so that layer of ink has the transparency and the flatness of excellence；And high-polymer molecular interchain can form multiple hydrogen bond when reacting so that layer of ink has the mechanical endurance of excellence, and this resin is commercially available, and manufacturer is cyanogen spy's special type chemical industry (the Asian-Pacific area)。
O-benzoyl yl benzoic acid macrogol ester (Benzoylbenzoateesterswithbranchedpolyols) is a kind of polyfunctional group Benzophenone macromolecular photoinitiator; its formula compatibility is good, efficiency of initiation is high; and no coupling product etc. after solidifying; UV ultraviolet light radical polymerization has the effect that fast setting reacts; and have and refuse water main chain and fantabulous dissolving power; aim at and require low abnormal smells from the patient, the ink of low migration and design; and easily by amine auxiliary agent potentiation; can commercially directly buy, Beijing Yingli Technology Development Co., Ltd of manufacturer。
6420 response type tertiary amine aided initiatings (ReationAmineSynergist response type tertiary amine aided initiating) are as the aided initiating in ink composition, surface cure is fast, side reaction product is few, transparency is high, the floating shifting in surface of amine can be efficiently reduced, hence help to the mirror effect after improving ink setting。Can commercially directly buying, manufacturer is Guangzhou Han Dong trade Co., Ltd。

Claims (1)

1. the preparation method of an offset printing UV gloss oil ink with mirror effect; offset printing UV gloss oil ink is made up of following components in percentage by weight: standard Bisphenol-A epoxy acrylate 21%; propylene glycol diacrylate 63%, o-benzoyl yl benzoic acid macrogol ester 5%, response type tertiary amine 11%；It is characterized in that: be proportionally equipped with raw material, first the standard Bisphenol-A epoxy acrylate of the propylene glycol diacrylate of 1/5th and 1/5th is added in a mixing bowl, open high speed dispersor, rotating speed 400 revs/min, o-benzoyl yl benzoic acid macrogol ester is added after stirring and dissolving, mixing speed is increased to 800-1000 rev/min, stirring and dissolving is to transparent in granule, add remaining propylene glycol diacrylate and remaining standard Bisphenol-A epoxy acrylate, stir, after being cooled to room temperature, add response type tertiary amine, after middling speed 800 revs/min stirs 10 minutes, filter with filter, namely this offset printing UV gloss oil ink with mirror effect is prepared。
CN201410547743.0A 2014-10-16 2014-10-16 A kind of offset printing UV gloss oil ink with mirror effect and preparation method thereof Active CN104292969B (en)

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Families Citing this family (2)

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Publication number Priority date Publication date Assignee Title
CN104650646A (en) * 2015-03-12 2015-05-27 山东德创喷墨科技有限公司 Low-migration UV flexible printing ink and preparation method thereof
CN109082156A (en) * 2018-08-28 2018-12-25 苏州安洁科技股份有限公司 A kind of imitative metal red ink and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1526770A (en) * 2003-03-03 2004-09-08 珠海东诚化工有限公司 Visible light cured plastic paint
CN1693385A (en) * 2005-05-11 2005-11-09 中国乐凯胶片集团公司 UV photocureable magnetic offset lithography printing ink
CN103224731A (en) * 2012-10-24 2013-07-31 北京印刷学院 Pinkish red UV ink-jet ink for high-speed ink-jet printing and preparation method thereof

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0350216A (en) * 1989-07-17 1991-03-04 Sony Corp Photopolymer composition

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1526770A (en) * 2003-03-03 2004-09-08 珠海东诚化工有限公司 Visible light cured plastic paint
CN1693385A (en) * 2005-05-11 2005-11-09 中国乐凯胶片集团公司 UV photocureable magnetic offset lithography printing ink
CN103224731A (en) * 2012-10-24 2013-07-31 北京印刷学院 Pinkish red UV ink-jet ink for high-speed ink-jet printing and preparation method thereof

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Effective date of registration: 20200622

Address after: Three 310030 Hangzhou Road, Zhejiang province Xihu District three Town Xiyuan No. 6

Co-patentee after: ZHEJIANG MINONG MATERIAL TECHNOLOGY Co.,Ltd.

Patentee after: ZHEJIANG MINONG CENTURY GROUP Co.,Ltd.

Address before: Three 310030 Hangzhou Road, Zhejiang province Xihu District three Town Xiyuan No. 6

Patentee before: ZHEJIANG MINONG CENTURY GROUP Co.,Ltd.