CN103074010A - Waterproof glue for building and preparation method thereof - Google Patents
Waterproof glue for building and preparation method thereof Download PDFInfo
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- CN103074010A CN103074010A CN2013100442106A CN201310044210A CN103074010A CN 103074010 A CN103074010 A CN 103074010A CN 2013100442106 A CN2013100442106 A CN 2013100442106A CN 201310044210 A CN201310044210 A CN 201310044210A CN 103074010 A CN103074010 A CN 103074010A
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Abstract
The invention provides waterproof glue for a building and a preparation method thereof. The waterproof glue for the building comprises the raw materials in parts by weight: 200-250 parts of vinyl acetate, 25-30 parts of organic silicone monomers containing unsaturated double bonds, 100-120 parts of vinyl versatate, 90-100 parts of butyl acrylate, 120-130 parts of butyl methacrylate, 70-85 parts of crylic acids, 40-60 parts of tackifying resins, 5-7 parts of sodium chelating agents, 200-250 parts of non-phthalic plasticizers, 25-45 parts of polyvinyl alcohol, 4-6 parts of silane coupling agents, 6-12 parts of anionic emulsifiers, 6-9 parts of nonionic emulsifiers, 450-550 parts of de-ionized water, 1-5 parts of corrosion removers and 1.3-3.3 parts of initiators. The waterproof glue for the building has the advantages that the product is wide in application scope, long in service life and high in stability; the storage period at 5-35 DEG C exceeds 12 months; and the waterproof glue for the building is convenient during a construction period.
Description
Technical field
The present invention relates to a kind of building marine glue and preparation method thereof.
Background technology
Our usually said building marine glue means a class water-based adhesive of building, decorations and building maintenance industry universal, gains the name because its bonding scope is wide, easy to use.The main component of early stage building waterproofing glue is chloroprene rubber, pitch, polyurethane etc., general toluene, dimethylbenzene, methylene dichloride, the trichloromethane of adopting is as solvent, because these materials are harmful to health, abroad ban use of, but domesticly also can not withdraw from indoor decorating market in a short time.
Along with GB18583-2008 compulsory standard that country promulgates, closed down for the tackiness agent of indoor decorating take benzene as solvent, and toluene and total volatile organic matter have also been made strict limiting the quantity of.For satisfying the needs of interior decoration, various water base adhesives are also arranged in the prior art, such as aqueous-based adhesives such as vinyl acetate between to for plastic homopolymerization emulsion, acrylate copolymer emulsions, but all can only satisfy the part service requirements, all there is such or such deficiency,, work-ing life narrow such as applicable surface is short, and the product construction is not very convenient etc.
Summary of the invention
The present invention proposes a kind of building marine glue and preparation method thereof, and it can overcome deficiency of the prior art effectively, and it is widely applicable, long service life, be good stability, and surpass 12 months the storage period under 5-35 ℃ storage requirement, also very convenient in construction.
Technical scheme of the present invention is achieved in that a kind of building marine glue, it is made by the raw material of following weight part: vinyl acetate 200-250 part, the organosilane monomer 25-30 part that contains unsaturated double-bond, tertiary ethylene carbonate 100-120 part, butyl acrylate 90-110 part, butyl methacrylate 120-130 part, vinylformic acid 70-85 part, tackifying resin 40-60 part, the sodium salt agent 5-7 part that boils together, non-o-benzene plasticiser 200-250 part, polyvinyl alcohol 25-45 part, silane coupling agent 4-6 part, anionic emulsifier 6-12 part, nonionic emulsifying agent 6-9 part, deionized water 450-550 part, sanitas 1-5 part, initiator 1.3-3.3 part.
Further, it is made by the raw material of following weight part: vinyl acetate 220-240 part, the organosilane monomer 26-28 part that contains unsaturated double-bond, tertiary ethylene carbonate 110-115 part, butyl acrylate 95-105 part, butyl methacrylate 122-128 part, vinylformic acid 75-80 part, tackifying resin 45-55 part, the sodium salt agent 5.5-6.5 part that boils together, non-o-benzene plasticiser 220-240 part, polyvinyl alcohol 30-40 part, silane coupling agent 4.5-5.5 part, anionic emulsifier 8-10 part, nonionic emulsifying agent 7-8 part, deionized water 505-545 part, sanitas 2-4 part, initiator 1.5-2.5 part.
Further, it is made by the raw material of following weight part: 230 parts of vinyl acetates contain 25 parts of the organosilane monomers of unsaturated double-bond, 113 parts of tertiary ethylene carbonates, 100 parts of butyl acrylates, 125 parts of butyl methacrylate, 6.0 parts of the agent that boil together of 77 parts in vinylformic acid, 50 parts of tackifying resins, sodium salt, 230 parts of non-o-benzene plasticisers, 35 parts of polyvinyl alcohol, 5.0 parts of silane coupling agents, 9 parts of anionic emulsifiers, 7.8 parts of nonionic emulsifying agents, 525 parts of deionized waters, 3 parts of sanitass, 2 parts of initiators.
Further, it also comprises defoamer 0.6-5.1 part, and this defoamer can be silicone antifoam agent.
Wherein, the described organosilane monomer that contains unsaturated double-bond is methyl ethylene chlorosilane or vinyl trichloro silane.
Wherein, described tackifying resin is mixed by weight portion rate 1:1.5 by Gum Rosin and rosin glycerol resin and makes.
Wherein, the agent that boils together of described sodium salt is disodium EDTA, tetrasodium ethylenediamine tetraacetate or trisodium hydroxyethylene diamine triacetate.
Wherein, described non-o-benzene plasticiser is tributyl citrate or Ethylhexyl stearate.
Wherein, described silane coupling agent is γ-aminopropyl triethoxysilane, γ-(methacryloxy) propyl trimethoxy silicane, vinyltrimethoxy silane or vinyltriethoxysilane.
Wherein, described initiator is the aqueous solution of ammonium persulphate or Potassium Persulphate.
The preparation method of above-mentioned a kind of building marine glue, it comprises the steps:
(1) with for subsequent use after non-o-benzene plasticiser heating and the dissolving of adding tackifying resin;
(2) in reactor, put into deionized water, add the polyvinyl alcohol rising temperature for dissolving, be cooled to 75-85 ℃;
(3) even with putting into the dropping in-tank mixing after reaction monomers vinyl acetate, the organosilane monomer that contains unsaturated double-bond, tertiary ethylene carbonate, butyl acrylate, butyl methacrylate and the vinylformic acid metering, drip for subsequent use as mix monomer;
(4) in reactor, add silane coupling agent, the agent that boils together of anionic emulsifier, nonionic emulsifying agent, sodium salt, defoamer;
(5) begin to drip mix monomer, drip simultaneously initiator, and in 3-5 hour, be added dropwise to complete;
(6) be warming up to 85-95 ℃ of slaking 40-60min after being added dropwise to complete;
(7) be cooled to 35-45 ℃, add non-o-benzene plasticiser and tackifying resin solution, sanitas and mix rear discharging filtration, packing.
Beneficial effect of the present invention is:
(1) product of the present invention is widely applicable, can be used for the brushing of the material surfaces such as cement components, pottery, glass, clamping plate, shaving board, brown fine plate, bamboo slag plate, paper slag plate, composition board, aluminium-plastic panel, PVC plate, PLASTIC LAMINATED, metal, plastics, leather, rubber, and have the bonding strength that other water-proof materials can not be accomplished;
(2) long product lifecycle of the present invention, i.e. good stability, and the storage period under 5-35 ℃ storage requirement was above 12 months;
(3) product easy construction of the present invention, because building marine glue of the present invention have nontoxic free from extraneous odour, pollution-free, do not burn, be coated with the advantages such as not wire drawing without burn into, the problem such as inflammable, staging life weak point, gluing wire drawing, the atmospheric pollution that has solved that the materials such as solvent-borne type, polyester type occur in application is serious.
Embodiment
The below will be clearly and completely described the technical scheme in the embodiment of the invention, and obviously, described embodiment only is wherein several embodiment of the present invention, rather than whole embodiment.Based on the embodiment among the present invention, those of ordinary skills belong to the scope of protection of the invention not making the every other embodiment that obtains under the creative work prerequisite.
Embodiment 1
A kind of building marine glue, it is made by the raw material of following weight part: 220 parts of vinyl acetates, 28 parts of organosilane monomers that contain unsaturated double-bond, 115 parts of tertiary ethylene carbonates, 90 parts of butyl acrylates, 122 parts of butyl methacrylate, 85 parts in vinylformic acid, 5 parts of the agent that boil together of 45 parts of tackifying resins, sodium salt, 220 parts of non-o-benzene plasticisers, 40 parts of polyvinyl alcohol, 6 parts of silane coupling agents, 10 parts of anionic emulsifiers, 7 parts of nonionic emulsifying agents, 545 parts of deionized waters, 2 parts of sanitass, 2.5 parts of initiators, 1.0 parts of defoamers.
Wherein, the described organosilane monomer that contains unsaturated double-bond is the methyl ethylene chlorosilane; Tackifying resin is mixed by weight portion rate 1:1.5 by Gum Rosin and rosin glycerol resin and makes; The sodium salt agent that boils together is disodium EDTA; Non-o-benzene plasticiser is tributyl citrate; Silane coupling agent is γ-aminopropyl triethoxysilane; Initiator is the aqueous solution of ammonium persulphate; Defoamer is silicone antifoam agent.
The consumption of producing concrete each raw material that uses of building marine glue of 2000kg is: vinyl acetate 285.1Kg, methyl ethylene chlorosilane 36.3Kg, tertiary ethylene carbonate 149.0g, butyl acrylate 116.6Kg, butyl methacrylate 158.1g, vinylformic acid 110.1g, Gum Rosin 23.3g, rosin glycerol resin 35.0Kg, disodium EDTA 6.5Kg, tributyl citrate 285.1Kg, polyvinyl alcohol 51.8g, γ-aminopropyl triethoxysilane 7.8Kg, anionic emulsifier 13.0Kg, nonionic emulsifying agent 9.1Kg, deionized water 706.2Kg, sanitas 2.6Kg, the aqueous solution 3.2Kg of ammonium persulphate, silicone antifoam agent 1.3Kg.
Its preparation method comprises the steps:
(1) with tributyl citrate heating and add and mix after the tackifying resin dissolving of making for subsequent use by weight portion rate 1:1.5 by Gum Rosin and rosin glycerol resin;
(2) in reactor, put into deionized water, add the polyvinyl alcohol rising temperature for dissolving, be cooled to 75 ℃;
(3) even with putting into the dropping in-tank mixing after reaction monomers vinyl acetate, methyl ethylene chlorosilane, tertiary ethylene carbonate, butyl acrylate, butyl methacrylate and the vinylformic acid metering, drip for subsequent use as mix monomer;
(4) in reactor, add γ-aminopropyl triethoxysilane, anionic emulsifier, nonionic emulsifying agent, disodium EDTA and silicone antifoam agent;
(5) begin to drip mix monomer, drip simultaneously the aqueous solution of ammonium persulphate, and in 5 hours, be added dropwise to complete;
(6) be warming up to 85 ℃ of slaking 55min after being added dropwise to complete;
(7) be cooled to 35 ℃, add tributyl citrate and tackifying resin solution, sanitas and mix rear discharging filtration, packing.
Embodiment 2
A kind of building marine glue, it is made by the raw material of following weight part: 240 parts of vinyl acetates, 26 parts of organosilane monomers that contain unsaturated double-bond, 110 parts of tertiary ethylene carbonates, 95 parts of butyl acrylates, 128 parts of butyl methacrylate, 75 parts in vinylformic acid, 6.5 parts of the agent that boil together of 55 parts of tackifying resins, sodium salt, 240 parts of non-o-benzene plasticisers, 30 parts of polyvinyl alcohol, 4.5 parts of silane coupling agents, 8 parts of anionic emulsifiers, 8 parts of nonionic emulsifying agents, 505 parts of deionized waters, 4 parts of sanitass, 2 parts of initiators, 3.0 parts of defoamers.
Wherein, the described organosilane monomer that contains unsaturated double-bond is vinyl trichloro silane; Tackifying resin is mixed by weight portion rate 1:1.5 by Gum Rosin and rosin glycerol resin and makes; The sodium salt agent that boils together is tetrasodium ethylenediamine tetraacetate; Non-o-benzene plasticiser is Ethylhexyl stearate; Silane coupling agent is γ-(methacryloxy) propyl trimethoxy silicane; Initiator is the aqueous solution of ammonium persulphate; Defoamer is silicone antifoam agent.
The consumption of producing concrete each raw material that uses of building marine glue of 2000kg is: vinyl acetate 311.7Kg, vinyl trichloro silane 33.8Kg, tertiary ethylene carbonate 142.9g, butyl acrylate 123.9g, butyl methacrylate 166.2g, vinylformic acid 97.4g, Gum Rosin 28.6g and rosin glycerol resin 42.8g, tetrasodium ethylenediamine tetraacetate 8.4Kg, Ethylhexyl stearate 311.7Kg, polyvinyl alcohol 39.0Kg, γ-(methacryloxy) propyl trimethoxy silicane 5.8Kg, anionic emulsifier 10.4Kg, nonionic emulsifying agent 10.4Kg, deionized water 655.8Kg, sanitas 5.2Kg, the aqueous solution 2.6Kg of ammonium persulphate; Silicone antifoam agent 3.9Kg.
Its preparation method comprises the steps:
(1) with Ethylhexyl stearate heating and add and mix after the tackifying resin dissolving of making for subsequent use by weight portion rate 1:1.5 by Gum Rosin and rosin glycerol resin;
(2) in reactor, put into deionized water, add the polyvinyl alcohol rising temperature for dissolving, be cooled to 80 ℃;
(3) even with putting into the dropping in-tank mixing after reaction monomers vinyl acetate, vinyl trichloro silane, tertiary ethylene carbonate, butyl acrylate, butyl methacrylate and the vinylformic acid metering, drip for subsequent use as mix monomer;
(4) in reactor, add γ-(methacryloxy) propyl trimethoxy silicane, anionic emulsifier, nonionic emulsifying agent, tetrasodium ethylenediamine tetraacetate and silicone antifoam agent;
(5) begin to drip mix monomer, drip simultaneously the aqueous solution of ammonium persulphate, and in 4 hours, be added dropwise to complete;
(6) be warming up to 80 ℃ of slaking 45min after being added dropwise to complete;
(7) be cooled to 40 ℃, add Ethylhexyl stearate and tackifying resin solution, sanitas and mix rear discharging filtration, packing.
Embodiment 3
A kind of building marine glue, it is made by the raw material of following weight part: 230 parts of vinyl acetates, 25 parts of organosilane monomers that contain unsaturated double-bond, 113 parts of tertiary ethylene carbonates, 100 parts of butyl acrylates, 125 parts of butyl methacrylate, 77 parts in vinylformic acid, 6.0 parts of the agent that boil together of 50 parts of tackifying resins, sodium salt, 230 parts of non-o-benzene plasticisers, 35 parts of polyvinyl alcohol, 5.0 parts of silane coupling agents, 9 parts of anionic emulsifiers, 7.8 parts of nonionic emulsifying agents, 525 parts of deionized waters, 3 parts of sanitass, 1.5 parts of initiators, 5.0 parts of defoamers.
Wherein, the described organosilane monomer that contains unsaturated double-bond is vinyl trichloro silane; Tackifying resin is mixed by weight portion rate 1:1.5 by Gum Rosin and rosin glycerol resin and makes; The sodium salt agent that boils together is trisodium hydroxyethylene diamine triacetate; Non-o-benzene plasticiser is tributyl citrate; Silane coupling agent is vinyltriethoxysilane; Initiator is the aqueous solution of Potassium Persulphate; Defoamer is silicone antifoam agent.
The consumption of producing concrete each raw material that uses of building marine glue of 2000kg is: vinyl acetate 297.3Kg, vinyl trichloro silane 32.3Kg, tertiary ethylene carbonate 146.1Kg, butyl acrylate 129.3Kg, butyl methacrylate 161.6Kg, propylene 99.5Kg, Gum Rosin 25.8Kg, rosin glycerol resin 38.8g, trisodium hydroxyethylene diamine triacetate 7.8Kg, tributyl citrate 297.3Kg, polyvinyl alcohol 45.2Kg, vinyltriethoxysilane 6.5Kg, anionic emulsifier 11.6Kg, nonionic emulsifying agent 10.1Kg, deionized water 678.6Kg, sanitas 3.9Kg, the aqueous solution 1.9Kg of ammonium persulphate; Silicone antifoam agent 6.5Kg.
Its preparation method comprises the steps:
(1) with tributyl citrate heating and add and mix after the tackifying resin dissolving of making for subsequent use by weight portion rate 1:1.5 by Gum Rosin and rosin glycerol resin;
(2) in reactor, put into deionized water, add the polyvinyl alcohol rising temperature for dissolving, be cooled to 85 ℃;
(3) even with putting into the dropping in-tank mixing after reaction monomers vinyl acetate, vinyl trichloro silane, tertiary ethylene carbonate, butyl acrylate, butyl methacrylate and the vinylformic acid metering, drip for subsequent use as mix monomer;
(4) in reactor, add vinyltriethoxysilane, anionic emulsifier, nonionic emulsifying agent, trisodium hydroxyethylene diamine triacetate and silicone antifoam agent;
(5) begin to drip mix monomer, drip simultaneously the aqueous solution of Potassium Persulphate, and in 3.5 hours, be added dropwise to complete;
(6) be warming up to 90 ℃ of slaking 50min after being added dropwise to complete;
(7) be cooled to 45 ℃, add tributyl citrate and tackifying resin solution, sanitas and mix rear discharging filtration, packing.
The building marine glue performance index of gained are as follows among the embodiment of the invention 1-3:
Detection method: performance index can be with reference to GB/T23445-2009, and the nuisance pledge is limited the quantity of with reference to GB18583-2008 and JC1066-2008.
The above only is preferred embodiment of the present invention, and is in order to limit the present invention, within the spirit and principles in the present invention not all, any modification of doing, is equal to replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (10)
1. building marine glue, it is characterized in that: it is made by the raw material of following weight part: vinyl acetate 200-250 part, the organosilane monomer 25-30 part that contains unsaturated double-bond, tertiary ethylene carbonate 100-120 part, butyl acrylate 90-110 part, butyl methacrylate 120-130 part, vinylformic acid 70-85 part, tackifying resin 40-60 part, the sodium salt agent 5-7 part that boils together, non-o-benzene plasticiser 200-250 part, polyvinyl alcohol 25-45 part, silane coupling agent 4-6 part, anionic emulsifier 6-12 part, nonionic emulsifying agent 6-9 part, deionized water 450-550 part, sanitas 1-5 part, initiator 1.3-3.3 part.
2. a kind of building marine glue according to claim 1, it is characterized in that: it is made by the raw material of following weight part: vinyl acetate 220-240 part, the organosilane monomer 26-28 part that contains unsaturated double-bond, tertiary ethylene carbonate 110-115 part, butyl acrylate 95-105 part, butyl methacrylate 122-128 part, vinylformic acid 75-80 part, tackifying resin 45-55 part, the sodium salt agent 5.5-6.5 part that boils together, non-o-benzene plasticiser 220-240 part, polyvinyl alcohol 30-40 part, silane coupling agent 4.5-5.5 part, anionic emulsifier 8-10 part, nonionic emulsifying agent 7-8 part, deionized water 505-545 part, sanitas 2-4 part, initiator 1.5-2.5 part.
3. a kind of building marine glue according to claim 2, it is characterized in that: it is made by the raw material of following weight part: 230 parts of vinyl acetates, 25 parts of organosilane monomers that contain unsaturated double-bond, 113 parts of tertiary ethylene carbonates, 100 parts of butyl acrylates, 125 parts of butyl methacrylate, 77 parts in vinylformic acid, 50 parts of tackifying resins, sodium salt 6.0 parts of the agent that boil together, 230 parts of non-o-benzene plasticisers, 35 parts of polyvinyl alcohol, 5.0 parts of silane coupling agents, 9 parts of anionic emulsifiers, 7.8 parts of nonionic emulsifying agents, 525 parts of deionized waters, 3 parts of sanitass, 2 parts of initiators.
4. a kind of building marine glue according to claim 3, it is characterized in that: it also comprises defoamer 0.6-5.1 part.
5. according to the described a kind of building marine glue of any one among the right 1-4, it is characterized in that: the described organosilane monomer that contains unsaturated double-bond is methyl ethylene chlorosilane or vinyl trichloro silane.
6. according to the described a kind of building marine glue of any one among the right 1-4, it is characterized in that: described tackifying resin is mixed by weight portion rate 1:1.5 by Gum Rosin and rosin glycerol resin and makes.
7. according to the described a kind of building marine glue of any one among the right 1-4, it is characterized in that: the agent that boils together of described sodium salt is disodium EDTA, tetrasodium ethylenediamine tetraacetate or trisodium hydroxyethylene diamine triacetate.
8. according to the described a kind of building marine glue of any one among the right 1-4, it is characterized in that: described non-o-benzene plasticiser is tributyl citrate or Ethylhexyl stearate.
9. according to the described a kind of building marine glue of any one among the right 1-4, it is characterized in that: described silane coupling agent is γ-aminopropyl triethoxysilane, γ-(methacryloxy) propyl trimethoxy silicane, vinyltrimethoxy silane or vinyltriethoxysilane.
10. according to the preparation method of the described a kind of building marine glue of any one in the right 4, it is characterized in that: comprise the steps:
(1) with for subsequent use after non-o-benzene plasticiser heating and the dissolving of adding tackifying resin;
(2) in reactor, put into deionized water, add the polyvinyl alcohol rising temperature for dissolving, be cooled to 75-85 ℃;
(3) even with putting into the dropping in-tank mixing after reaction monomers vinyl acetate, the organosilane monomer that contains unsaturated double-bond, tertiary ethylene carbonate, butyl acrylate, butyl methacrylate and the vinylformic acid metering, drip for subsequent use as mix monomer;
(4) in reactor, add silane coupling agent, anionic emulsifier, nonionic emulsifying agent, sodium salt boil together agent, defoamer;
(5) begin to drip mix monomer, drip simultaneously initiator, and in 3-5 hour, be added dropwise to complete;
(6) be warming up to 85-95 ℃ of slaking 40-60min after being added dropwise to complete;
(7) be cooled to 35-45 ℃, add non-o-benzene plasticiser and tackifying resin solution, sanitas and mix rear discharging filtration, packing.
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| CN104371612A (en) * | 2014-10-29 | 2015-02-25 | 广东巴德士化工有限公司 | Multiplex polymerized adhesive for adhering polyester foam with chemical fiber fabric |
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| CN105273225A (en) * | 2014-07-12 | 2016-01-27 | 卢桂才 | Methacryloxy silane waterproof bridging agent for asphalt and cement, and waterproof product and application thereof |
| CN105273230A (en) * | 2014-07-12 | 2016-01-27 | 卢桂才 | Diamino silane waterproof bridging agent for asphalt and cement, and waterproof product and application thereof |
| CN105273227A (en) * | 2014-07-12 | 2016-01-27 | 卢桂才 | Methacryloxyalkoxy silane waterproof bridging agent for asphalt and cement, and waterproof product and application thereof |
| CN105273233A (en) * | 2014-07-12 | 2016-01-27 | 卢桂才 | Isocyanate chlorosilane waterproof bridging agent for asphalt and cement, and waterproof product and application thereof |
| CN105273226A (en) * | 2014-07-12 | 2016-01-27 | 卢桂才 | Alkenyltrichlorosilane waterproof bridging agent for asphalt and cement, and waterproof product and application thereof |
| CN105273228A (en) * | 2014-07-12 | 2016-01-27 | 卢桂才 | 3-(2,3-Epoxypropoxy)trialkoxy silane waterproof bridging agent for asphalt and cement, and waterproof product and application thereof |
| CN105273231A (en) * | 2014-07-12 | 2016-01-27 | 卢桂才 | Amino silane waterproof bridging agent for asphalt and cement, and waterproof product and application thereof |
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| CN107459888A (en) * | 2017-08-18 | 2017-12-12 | 佛山市永恒达新材料科技有限公司 | A kind of water-base cement gluing for aluminium leather |
| CN108034017A (en) * | 2018-01-18 | 2018-05-15 | 保定光普化工研究所 | A kind of redwood jigsaw latex solution and preparation method thereof |
| CN111500241A (en) * | 2020-04-27 | 2020-08-07 | 上海善治环境技术有限公司 | Permeable adhesive applied to pipeline repair and preparation method thereof |
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| CN105273231A (en) * | 2014-07-12 | 2016-01-27 | 卢桂才 | Amino silane waterproof bridging agent for asphalt and cement, and waterproof product and application thereof |
| CN105273226A (en) * | 2014-07-12 | 2016-01-27 | 卢桂才 | Alkenyltrichlorosilane waterproof bridging agent for asphalt and cement, and waterproof product and application thereof |
| CN105273225A (en) * | 2014-07-12 | 2016-01-27 | 卢桂才 | Methacryloxy silane waterproof bridging agent for asphalt and cement, and waterproof product and application thereof |
| CN105273230A (en) * | 2014-07-12 | 2016-01-27 | 卢桂才 | Diamino silane waterproof bridging agent for asphalt and cement, and waterproof product and application thereof |
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Application publication date: 20130501 |