CN106221627A - A kind of water-based adhesive with high insulating property and preparation method thereof - Google Patents
A kind of water-based adhesive with high insulating property and preparation method thereof Download PDFInfo
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- CN106221627A CN106221627A CN201610651917.7A CN201610651917A CN106221627A CN 106221627 A CN106221627 A CN 106221627A CN 201610651917 A CN201610651917 A CN 201610651917A CN 106221627 A CN106221627 A CN 106221627A
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- vinyl acetate
- acetate resin
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- based adhesive
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J151/06—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
- C08F255/026—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms on to ethylene-vinylester copolymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F263/00—Macromolecular compounds obtained by polymerising monomers on to polymers of esters of unsaturated alcohols with saturated acids as defined in group C08F18/00
- C08F263/02—Macromolecular compounds obtained by polymerising monomers on to polymers of esters of unsaturated alcohols with saturated acids as defined in group C08F18/00 on to polymers of vinyl esters with monocarboxylic acids
- C08F263/04—Macromolecular compounds obtained by polymerising monomers on to polymers of esters of unsaturated alcohols with saturated acids as defined in group C08F18/00 on to polymers of vinyl esters with monocarboxylic acids on to polymers of vinyl acetate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The water-based adhesive with high insulating property of the present invention, including following raw material: vinyl acetate resin, ethylene vinyl acetate resin, deionized water, organic silicon monomer containing unsaturated double-bond, polyvinyl alcohol, butyl acrylate, tertiary ethylene carbonate, silane coupler, wherein vinyl acetate resin, ethylene vinyl acetate resin, the weight of three kinds of components of deionized water accounts for the 45%～65% of binding agent gross weight, and vinyl acetate resin, ethylene vinyl acetate resin, the mass ratio of deionized water is 0.3～0.7:1:2～3, fluorinated graphene accounts for the 30%～50% of binding agent gross weight, it is widely applicable is applicable to PP, PET, PVC, between BOPP composite back plate material, each layer is compound.The good stability of binding agent, storage period >=12 month of 5～50 DEG C, have nontoxic free from extraneous odour, pollution-free, corrosion-free, do not burn, be coated with the advantages such as not wire drawing, it is possible to increase solaode is combined the adhesion firmness of backboard, high-temperature stability, high mechanical properties, toughness, anti-ultraviolet radiation performance.
Description
Technical field
The application relates to a kind of water-based adhesive, in particular to a kind of water-based adhesive with high insulating property,
Belong to adhesive field.
Background technology
Bonding agent generally has critically important impact, in early days Laminating adhesive to the performance of the coalition formed between adhesive substance
Be mainly composed of butadiene-styrene rubber, toluene, dimethylbenzene, dichloromethane, chloroform as solvent, carcinogenic due to these materials
Property and easily health is damaged, the most prohibitted the use of, along with country promulgate GB18583-2008 mandatory standard,
Close down for the adhesive with benzene as solvent, and the content of toluene and volatile organic matter has been made that strict restriction.Therefore,
Aqua type Laminating adhesive will be increasingly becoming the leading of Laminating adhesive market.
At present, the water base adhesive of domestic market, such as water based adhesive such as vinyl acetate homopolymerization emulsion, acrylate copolymer emulsions
Agent, owing to existing, bonding strength is low and shortcoming by aspects such as high temperature xanthochromias, it is impossible to be the most well employed, although poly-
Compound itself there are certain insulating properties, but be typically due to thickness when binding agent uses, occasion etc. and limit, can cause gluing
The decreasing insulating of mixture, or in order to ensure that the insulating properties of adhesive layer uses substantial amounts of binding agent, thus cause binding agent
The waste used, it is also possible to cause adhesive layer cohesiveness too high or too low thus cause adhesive phase inefficacy or material to break, therefore
Needs find a kind of binding agent, can either provide required cohesive force, the most do not waste material and have high insulating property simultaneously.
Summary of the invention
For solving above-mentioned technical problem, the present invention provides water-based adhesive with high insulating property and preparation method thereof,
It can provide required cohesive force, and the fluorinated graphene owing to wherein adding has higher resistivity, again can be by each
Compact siro spinning technology between component, does not the most waste material and has high insulating property technical characterstic simultaneously.
For achieving the above object, the technical solution used in the present invention is as follows:
A kind of water-based adhesive with high insulating property, it includes following raw material: vinyl acetate resin, ethyl vinyl acetate
Vinyl, deionized water, fluorinated graphene, the organic silicon monomer containing unsaturated double-bond, polyvinyl alcohol, butyl acrylate, uncle
Ethylene carbonate, silane coupler, wherein vinyl acetate resin, ethylene vinyl acetate resin, the weight of three kinds of components of deionized water
Amount accounts for the 45%～65% of binding agent gross weight, and the quality of vinyl acetate resin, ethylene-vinyl acetate resin, deionized water
Ratio is 0.3～0.7: 1: 2～3, and fluorinated graphene accounts for the 30%～50% of binding agent gross weight.
Above-mentioned binding agent can also include: anion emulsifier, nonionic emulsifier, sodium salt chelating agen, defoamer, initiation
Agent preservative, and anion emulsifier, nonionic emulsifier, sodium salt chelating agen, defoamer, the weight of initiator preservative accounts for
Binding agent gross weight is less than 3%.
The described organic silicon monomer containing unsaturated double-bond is ethylene methacrylic base silane or vinyl tris silane one therein.
Described silane coupler is γ-2 propyl-triethoxysilicane, γ-(methacryloxy) propyl-trimethylsilicane
Alkane, vinyltrimethoxy silane or VTES one therein.
Shown anion emulsifier is NP-40.
Described nonionic emulsifier is OP-10.
Described sodium salt boils together agent for from disodium EDTA, tetrasodium ethylenediamine tetraacetate or hydroxyethylethylene diamine
Triacetic acid trisodium one therein.
Described defoamer is silicone defoamer.
Described initiator is inorganic peroxide initiator, preferred mass mark of the present invention be 1～the Ammonium persulfate. of 5% or
1～5% aqueous solution of potassium peroxydisulfate.
Described preservative is Kazon, can selectively add as required in the present invention, and Main Function is to optimize effectively to use
Time limit.
The preparation method of the water-based adhesive that the present invention has high insulating property is as follows:
(1) adding deionized water in reactor, polyvinyl alcohol, stirring is warming up to 95 DEG C, treats that polyvinyl alcohol is completely dissolved
After, it is cooled to 75～85 DEG C；
(2) by reaction monomers vinylacetate, ethylene-vinyl acetate resin, fluorinated graphene, having containing unsaturated double-bond
Machine silicon monomer part, polyvinyl alcohol, butyl acrylate, tertiary ethylene carbonate add reactor interior also mix homogeneously, wherein acetic acid second
Olefine resin, ethylene-vinyl acetate resin, the mass ratio of deionized water are 0.3～0.7: 1: 2～3, and the weight of three kinds of components accounts for
The 45%～65% of binding agent gross weight, fluorinated graphene accounts for the 30%～50% of binding agent gross weight；
(3) in reactor, be sequentially added into silane coupler, anion emulsifier, nonionic emulsifier, sodium salt boil together agent,
Defoamer；
(4) drip mix monomer under stirring condition, be simultaneously added dropwise the 0.1 of total monomer weight～the initiator over cure of 0.2%
Acid ammonium or persulfate aqueous solution, and be added dropwise to complete in 3～5h；
(5) 85～95 DEG C of ripenings 40～60min it are warming up to after being added dropwise to complete；
(6) being then cooled to 35～45 DEG C, add preservative, after mix homogeneously, discharging filters and packages.
Compared with prior art, the present invention has an advantage that
(1) water-based adhesive with high insulating property of the present invention, widely applicable, it is adaptable to PP, PET, PVC, BOPP
Between composite back plate material, each layer is compound.
(2) good stability of binding agent, storage period >=12 month of-5～50 DEG C.
(3) water-based adhesive with high insulating property of the present invention has nontoxic free from extraneous odour, pollution-free, corrosion-free, no
Burn, be coated with the advantages such as not wire drawing, required cohesive force can either be provided, the most do not waste material and there is high-insulativity simultaneously
Energy.
The water-based adhesive performance indications that the present invention a kind of has high insulating property are as follows:
Detection method: performance indications can refer to GB/T 27573-2011.
Detailed description of the invention
The present invention is made in detail below in conjunction with embodiment, clearly illustrates.
Following example are only the preferred embodiments of the present invention, it is noted that for the ordinary skill of this area
For personnel, under the premise without departing from the principles of the invention, it is also possible to make some improvement and deduction, these changes all should belong to
In protection scope of the present invention.
Embodiment 1
Described a kind of water-based adhesive with high insulating property, it prepares by the following method:
(1) adding deionized water in reactor, polyvinyl alcohol, stirring is warming up to 95 DEG C, treats that polyvinyl alcohol is completely dissolved
After, it is cooled to 75 DEG C；
(2) by reaction monomers vinylacetate, ethylene-vinyl acetate resin, fluorinated graphene, having containing unsaturated double-bond
Machine silicon monomer part, polyvinyl alcohol, butyl acrylate, tertiary ethylene carbonate add reactor interior also mix homogeneously, wherein acetic acid second
Olefine resin, ethylene-vinyl acetate resin, the mass ratio of deionized water are 0.3: 1: 2, and the weight of three kinds of components to account for binding agent total
The 45% of weight, fluorinated graphene accounts for the 50% of binding agent gross weight；
(3) in reactor, be sequentially added into silane coupler, anion emulsifier, nonionic emulsifier, sodium salt boil together agent,
Defoamer；
(4) drip mix monomer under stirring, be simultaneously added dropwise the ammonium persulfate aqueous solution that initiator mass fraction is 1%, and
It was added dropwise to complete in 3～5 hours；
(5) 85～95 DEG C of ripenings 40～60min it are warming up to after being added dropwise to complete；
(6) being cooled to 35 DEG C, add preservative, after mix homogeneously, discharging filters and packages.
Embodiment 2
Described a kind of water-based adhesive with high insulating property, it prepares by the following method:
(1) adding deionized water in reactor, polyvinyl alcohol, stirring is warming up to 95 DEG C, treats that polyvinyl alcohol is completely dissolved
After, it is cooled to 85 DEG C；
(2) by reaction monomers vinylacetate, ethylene-vinyl acetate resin, fluorinated graphene, having containing unsaturated double-bond
Machine silicon monomer part, polyvinyl alcohol, butyl acrylate, tertiary ethylene carbonate add reactor interior also mix homogeneously, wherein acetic acid second
Olefine resin, ethylene-vinyl acetate resin, the mass ratio of deionized water are 0.7: 1: 3, and the weight of three kinds of components to account for binding agent total
The 65% of weight, fluorinated graphene accounts for the 30% of binding agent gross weight；
(3) in reactor, be sequentially added into silane coupler, anion emulsifier, nonionic emulsifier, sodium salt boil together agent,
Defoamer；
(4) drip mix monomer under stirring, be simultaneously added dropwise the ammonium persulfate aqueous solution that initiator mass fraction is 5%, and
It was added dropwise to complete in 5 hours；
(5) 95 DEG C of ripenings 40～60min it are warming up to after being added dropwise to complete；
(6) being cooled to 45 DEG C, add preservative, after mix homogeneously, discharging filters and packages.
The described organic silicon monomer containing unsaturated double-bond is vinyl trichlorosilane.
Described silane coupler is γ-(methacryloxy) propyl trimethoxy silicane.
The agent that boils together of described sodium salt is tetrasodium ethylenediamine tetraacetate.
Embodiment 3
Described a kind of water-based adhesive with high insulating property, it prepares by the following method:
(1) adding deionized water in reactor, polyvinyl alcohol, stirring is warming up to 95 DEG C, treats that polyvinyl alcohol is completely dissolved
After, it is cooled to 75 DEG C；
(2) by reaction monomers vinylacetate, ethylene-vinyl acetate resin, fluorinated graphene, having containing unsaturated double-bond
Machine silicon monomer part, polyvinyl alcohol, butyl acrylate, tertiary ethylene carbonate add reactor interior also mix homogeneously, wherein acetic acid second
Olefine resin, ethylene-vinyl acetate resin, the mass ratio of deionized water are 0.3: 1: 3, and the weight of three kinds of components to account for binding agent total
The 55% of weight, fluorinated graphene accounts for the 40% of binding agent gross weight；
(3) in reactor, be sequentially added into silane coupler, anion emulsifier, nonionic emulsifier, sodium salt boil together agent,
Defoamer；
(4) drip mix monomer under stirring, be simultaneously added dropwise the ammonium persulfate aqueous solution that initiator mass fraction is 4%, and
It was added dropwise to complete in 4 hours；
(5) 90 DEG C of ripenings 40～60min it are warming up to after being added dropwise to complete；
(6) being cooled to 40 DEG C, add preservative, after mix homogeneously, discharging filters and packages.
The described organic silicon monomer containing unsaturated double-bond is ethylene methacrylic base silane.
The agent that boils together of described sodium salt is trisodium hydroxyethylene diamine triacetate.
Described silane coupler is vinyltrimethoxy silane.
Embodiment 4
Described a kind of water-based adhesive with high insulating property, it prepares by the following method:
(1) adding deionized water in reactor, polyvinyl alcohol, stirring is warming up to 95 DEG C, treats that polyvinyl alcohol is completely dissolved
After, it is cooled to 80 DEG C；
(2) by reaction monomers vinylacetate, ethylene-vinyl acetate resin, fluorinated graphene, having containing unsaturated double-bond
Machine silicon monomer part, polyvinyl alcohol, butyl acrylate, tertiary ethylene carbonate add reactor interior also mix homogeneously, wherein acetic acid second
Olefine resin, ethylene-vinyl acetate resin, the mass ratio of deionized water are 0.7: 1: 2, and the weight of three kinds of components to account for binding agent total
The 50% of weight, fluorinated graphene accounts for the 45% of binding agent gross weight；
(3) in reactor, be sequentially added into silane coupler, anion emulsifier, nonionic emulsifier, sodium salt boil together agent,
Defoamer；
(4) drip mix monomer under stirring, be simultaneously added dropwise the ammonium persulfate aqueous solution that initiator mass fraction is 3%, and
It was added dropwise to complete in 3 hours；
(5) 85 DEG C of ripenings 40～60min it are warming up to after being added dropwise to complete；
(6) being cooled to 35 DEG C, add preservative, after mix homogeneously, discharging filters and packages.
The described organic silicon monomer containing unsaturated double-bond is ethylene methacrylic base silane.
The agent that boils together of described sodium salt is tetrasodium ethylenediamine tetraacetate.
Described silane coupler is VTES.
The water-based adhesive with high insulating property of the present invention, widely applicable, it is adaptable to PP, PET, PVC, BOPP are compound
Between back veneer material, each layer is compound.The good stability of binding agent, storage period >=12 month of-5～50 DEG C, there is nontoxic being as good as
Taste, pollution-free, corrosion-free, do not burn, be coated with the advantages such as not wire drawing, required cohesive force can either be provided, do not waste simultaneously
Material and there is high insulating property.
Claims (9)
1. a water-based adhesive with high insulating property, it is characterised in that include following raw material: vinyl acetate resin, second
Alkene-vinyl acetate resin, deionized water, fluorinated graphene, the organic silicon monomer containing unsaturated double-bond, polyvinyl alcohol, acrylic acid
Butyl ester, tertiary ethylene carbonate, silane coupler, wherein vinyl acetate resin, ethylene vinyl acetate resin, three kinds of groups of deionized water
The weight divided accounts for the 45%～65% of binding agent gross weight, and vinyl acetate resin, ethylene-vinyl acetate resin, deionized water
Mass ratio be 0.3～0.7:1:2～3, fluorinated graphene accounts for the 30%～50% of binding agent gross weight.
2. water-based adhesive as claimed in claim 1, it is characterised in that also include: anion emulsifier, non-ionic emulsifier
Agent, sodium salt chelating agen, defoamer, initiator preservative, and anion emulsifier, nonionic emulsifier, sodium salt chelating agen, disappear
Infusion, the weight of initiator preservative account for binding agent gross weight less than 3%.
3. water-based adhesive as claimed in claim 2, it is characterised in that the described organic silicon monomer containing unsaturated double-bond is first
Base vinyl silanes or vinyl tris silane one therein.
4. water-based adhesive as claimed in claim 2, it is characterised in that described silane coupler is γ-2 propyl triethoxy
Silane, γ-(methacryloxy) oxypropyl trimethyl silane, vinyltrimethoxy silane or VTES
One therein.
5. water-based adhesive as claimed in claim 2, it is characterised in that shown anion emulsifier is NP-40, described non-from
Sub-emulsifying agent is OP-10.
6. water-based adhesive as claimed in claim 2, it is characterised in that described sodium salt boils together agent for from ethylenediaminetetraacetic acid
Disodium salt, tetrasodium ethylenediamine tetraacetate or trisodium hydroxyethylene diamine triacetate one therein.
7. water-based adhesive as claimed in claim 2, it is characterised in that described defoamer is silicone defoamer.
8. water-based adhesive as claimed in claim 2, it is characterised in that described initiator is inorganic peroxide initiator,
Mass fraction is 1～the Ammonium persulfate. of 5% or 1～5% aqueous solution of potassium peroxydisulfate, and described preservative is Kazon, as required
Selectively adding, effect is to optimize effective life.
9. the preparation method of the water-based adhesive with high insulating property as according to any one of claim 1～8, its feature
It is, including step:
(1) adding deionized water, polyvinyl alcohol in reactor, stirring is warming up to 95 DEG C, after polyvinyl alcohol is completely dissolved, and fall
Temperature is to 75～85 DEG C；
(2) by reaction monomers vinylacetate, ethylene-vinyl acetate resin, fluorinated graphene, organosilicon containing unsaturated double-bond
Monomer part, polyvinyl alcohol, butyl acrylate, tertiary ethylene carbonate add reactor interior also mix homogeneously, wherein vinyl acetate tree
Fat, ethylene-vinyl acetate resin, the mass ratio of deionized water are 0.3～0.7:1:2～3, and the weight of three kinds of components accounts for bonding
The 45%～65% of agent gross weight, fluorinated graphene accounts for the 30%～50% of binding agent gross weight；
(3) be sequentially added into silane coupler in reactor, anion emulsifier, nonionic emulsifier, sodium salt boil together agent, froth breaking
Agent；
(4) drip mix monomer under stirring condition, be simultaneously added dropwise the 0.1 of total monomer weight～the initiator ammonium persulfate of 0.2%
Or persulfate aqueous solution, and it is added dropwise to complete in 3～5h；
(5) 85～95 DEG C of ripenings 40～60min it are warming up to after being added dropwise to complete；
(6) being cooled to 35～45 DEG C, add preservative, after mix homogeneously, discharging filters and packages.
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| CN201610651917.7A CN106221627B (en) | 2016-08-10 | 2016-08-10 | A kind of water-based adhesive with high insulating property and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106675435A (en) * | 2016-12-30 | 2017-05-17 | 吴建平 | Adhesive |
| CN107118703A (en) * | 2017-06-06 | 2017-09-01 | 合肥月煌新型装饰材料有限公司 | A kind of decoration adhesive and preparation method |
| CN107513121A (en) * | 2017-08-18 | 2017-12-26 | 佛山市永恒达新材料科技有限公司 | A kind of adhesive bonded for iron plate with artificial leather |
| CN109054696A (en) * | 2018-08-04 | 2018-12-21 | 厦门力嘉诚防水工程有限公司 | A kind of graphene ceramic tile gum |
| CN109133797A (en) * | 2018-09-25 | 2019-01-04 | 厦门力嘉诚防水工程有限公司 | A kind of graphene concrete interface agent |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10204399A (en) * | 1997-01-24 | 1998-08-04 | Sekisui Chem Co Ltd | Pressure-sensitive adhesive acrylic composition |
| CN101225271A (en) * | 2008-02-04 | 2008-07-23 | 唐浩 | Water-based all-purpose adhesive and method for preparing same |
| CN103074010A (en) * | 2013-02-03 | 2013-05-01 | 四川诺施建材有限公司 | Waterproof glue for building and preparation method thereof |
| CN104371612A (en) * | 2014-10-29 | 2015-02-25 | 广东巴德士化工有限公司 | Multiplex polymerized adhesive for adhering polyester foam with chemical fiber fabric |
| CN104449483A (en) * | 2014-11-11 | 2015-03-25 | 哈尔滨工业大学无锡新材料研究院 | Fluorine-containing conductive pressure-sensitive adhesive and preparation method thereof |
| CN105504134A (en) * | 2015-12-24 | 2016-04-20 | 广东巴德士化工有限公司 | Water-based vinyl acetate-silicone-acrylate polymerized emulsion with wide application range |
-
2016
- 2016-08-10 CN CN201610651917.7A patent/CN106221627B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10204399A (en) * | 1997-01-24 | 1998-08-04 | Sekisui Chem Co Ltd | Pressure-sensitive adhesive acrylic composition |
| CN101225271A (en) * | 2008-02-04 | 2008-07-23 | 唐浩 | Water-based all-purpose adhesive and method for preparing same |
| CN103074010A (en) * | 2013-02-03 | 2013-05-01 | 四川诺施建材有限公司 | Waterproof glue for building and preparation method thereof |
| CN104371612A (en) * | 2014-10-29 | 2015-02-25 | 广东巴德士化工有限公司 | Multiplex polymerized adhesive for adhering polyester foam with chemical fiber fabric |
| CN104449483A (en) * | 2014-11-11 | 2015-03-25 | 哈尔滨工业大学无锡新材料研究院 | Fluorine-containing conductive pressure-sensitive adhesive and preparation method thereof |
| CN105504134A (en) * | 2015-12-24 | 2016-04-20 | 广东巴德士化工有限公司 | Water-based vinyl acetate-silicone-acrylate polymerized emulsion with wide application range |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106675435A (en) * | 2016-12-30 | 2017-05-17 | 吴建平 | Adhesive |
| CN107118703A (en) * | 2017-06-06 | 2017-09-01 | 合肥月煌新型装饰材料有限公司 | A kind of decoration adhesive and preparation method |
| CN107513121A (en) * | 2017-08-18 | 2017-12-26 | 佛山市永恒达新材料科技有限公司 | A kind of adhesive bonded for iron plate with artificial leather |
| CN109054696A (en) * | 2018-08-04 | 2018-12-21 | 厦门力嘉诚防水工程有限公司 | A kind of graphene ceramic tile gum |
| CN109133797A (en) * | 2018-09-25 | 2019-01-04 | 厦门力嘉诚防水工程有限公司 | A kind of graphene concrete interface agent |
| CN109133797B (en) * | 2018-09-25 | 2021-10-15 | 厦门力嘉诚防水工程有限公司 | Graphene concrete interface agent |
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