CN104212398B - A kind of macromolecule resin laminated glass glue and preparation method thereof - Google Patents
A kind of macromolecule resin laminated glass glue and preparation method thereof Download PDFInfo
- Publication number
- CN104212398B CN104212398B CN201410422219.0A CN201410422219A CN104212398B CN 104212398 B CN104212398 B CN 104212398B CN 201410422219 A CN201410422219 A CN 201410422219A CN 104212398 B CN104212398 B CN 104212398B
- Authority
- CN
- China
- Prior art keywords
- laminated glass
- glass glue
- polyester resin
- resin laminated
- macromolecule resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Abstract
The present invention relates to a kind of macromolecule resin laminated glass glue, it is made up of the raw material of following percentage by weight: urethane modified polyester resin 40 ~ 65%, isophthalic unsaturated polyester resin 10 ~ 30%, hardness regulator 5 ~ 10%, viscosity reduction diluent 10 ~ 30%, firming agent 0.5 ~ 4%, curing accelerator 0.1 ~ 3%, ultraviolet (UV) resistant agent 0.5 ~ 2% and defoamer 1 ~ 3%, and preparation method comprises the following steps: in urethane modified polyester resin and isophthalic unsaturated polyester resin are added container cartridge and stir mixing；Take again in hardness regulator, viscosity reduction diluent, curing accelerator, ultraviolet (UV) resistant agent, defoamer addition reactor, under normal temperature condition, start stirring rod stirred for several minute；Add firming agent, and be sufficiently mixed.The invention have the benefit that normal temperature and pressure can be fully cured, colloid viscosity is low simultaneously, it is easy to release bubble, simplifies the technological operation on convenient production, and the intensity of cured glue layer each side and weather resistance are superior to acrylics doubling water.
Description
Technical field
The present invention relates to glass working arts field, particularly relate to a kind of macromolecule resin laminated glass glue and preparation side thereof
Method.
Background technology
Laminated glass is the composite that glass separates with glass intermediate layer and makes it be bonded as one by process, typically
For manufacturing the purposes such as safety glass, bulletproof glass, architectural decorative glass, art glass.Macromolecule resin laminated glass glue
Can be as middle separate layer after solidification.Laminated glass production method has dry technology for production and wet process technique, uses glue
The technique of solidification is alternatively referred to as wet glass glue in wet processing, macromolecule resin laminated glass glue.
The application technology performance requirement of laminated glass has optical property, and (visible transmission ratio, visible light reflectance, part is produced
Product require ultraviolet transmission ratio and infra-red transmittance), mechanical property (impact strength, peel strength), weather resistance is (heat-resisting
Property, moisture-proof, radioresistance).Although acrylics, epoxy resin, polyurethanes, organosilicon can be used in theory
The high molecular polymers such as resin, unsaturated polyester esters, Merlon or compound prepare macromolecule resin folder as matrix resin
Layer glass glue, but limited by laminated glass every application technology performance, the most little several polymer or chemical combination
Thing can be selected.
The most wide variety of macromolecule resin laminated glass glue typically uses acrylate base polymer plus increasing
Mould the components such as agent, cross-linking agent, coupling agent, firming agent, light (hot) initiator and be made into glue.As used methyl methacrylate
(PMMA), butyl acrylate, o-phthalic acid dibutyl ester, Ethylene glycol dimethacrylate, toluene acrylic acid acyloxy silicon
The compositions such as alkane (KH-550), benzoyl peroxide, benzoin ethyl ether coordinate by certain formula, mix after can produce macromolecule
Resin sandwich glass glue.Add glue (or shining 3-8 hour in the sun) solidification under ultraviolet irradiates of light trigger；
The glue adding thermal initiator solidifies in the baking oven being heated to 80-120 degree.
Although acrylate base polymer goods transparency is good, excellent optical performance, but acrylate base polymer (as
PMMA) hardness own is big, and property is crisp, can reduce hardness but owing to migration of plasticizer causes product after being added into plasticizer
Use that middle cementability is bad, transparency declines.Curing process needs ultraviolet (sunlight) or firing equipment to carry out causing crosslinking,
Thus curing process is complicated, quality control difficulty is big, and production cost is higher.Acrylics glue is at weather resistance, mechanical property
Aspect can be limited by chemical compositions such as auxiliary agents in formula, be also at relatively low level.
Summary of the invention
It is an object of the invention to provide a kind of macromolecule resin laminated glass glue and preparation method thereof, to overcome prior art
Above shortcomings.
It is an object of the invention to be achieved through the following technical solutions:
A kind of macromolecule resin laminated glass glue, it is made up of the raw material of following percentage by weight: urethane modified polyester resin
40～65%, isophthalic unsaturated polyester resin 10～30%, hardness regulator 5～10%, viscosity reduction diluent 10～30%, firming agent
0.5～4%, curing accelerator 0.1～3%, ultraviolet (UV) resistant agent 0.5～2% and defoamer 1～3%.
Further, described hardness regulator is methacrylic acid, butyl acrylate, Hydroxypropyl acrylate, vinyl acetate
One or more in ester.
Further, described viscosity reduction diluent is one or more in vinylacetate, acrylic acid, styrene.
Further, the one during described firming agent is benzoyl peroxide, isopropyl benzene hydroperoxide, methyl ethyl ketone peroxide
Or it is several.
Further, one or more during described curing accelerator is cobalt naphthenate, cobalt iso-octoate, dimethylaniline.
Further, described ultraviolet (UV) resistant agent be Octabenzone (UV-531) or 2-(2-hydroxyl-
5-aminomethyl phenyl) BTA (UV-P).
Further, the model of described defoamer is BYK-555 or BYK-560.
The preparation method of above-mentioned macromolecule resin laminated glass glue, comprises the following steps:
1) in urethane modified polyester resin and isophthalic unsaturated polyester resin being added container cartridge and stir mixing；
2) take in hardness regulator, viscosity reduction diluent, curing accelerator, ultraviolet (UV) resistant agent, defoamer addition reactor again, often
Stirring rod stirred for several minute is started under the conditions of temperature；
3) in step 2) middle addition firming agent, and be sufficiently mixed.
The invention have the benefit that
1, the glass sandwich glue that prepared by the present invention, compared with the most widely used acrylics doubling water, will not produce
Auxiliary agent migrate cause foaming, haze, transparency decline, delamination, the use problem such as come unglued；
2, normal temperature and pressure can be fully cured, and can simplify production technology greatly, reduces control of product difficulty, reduces and produces into
This；
3, colloid viscosity is low, it is easy to release bubble, simplifies the technological operation on convenient production；
4, after described glass sandwich glue curing, the power such as glue-line tensile break strength, impact strength, peel strength, percentage elongation
Learn index and be superior to acrylics doubling water, and the every weather resistance of glue-line such as moisture-proof, radioresistance, heat resistance etc. are equal
It is better than acrylics doubling water.
Detailed description of the invention
Embodiment 1:
A kind of macromolecule resin laminated glass glue described in the embodiment of the present invention 1, by the urethane modified polyester resin of 52kg,
The isophthalic unsaturated polyester resin of 20kg, the Hydroxypropyl acrylate liquid of 6kg, 15kg styrene liquid, 2kg cobalt naphthenate are molten
Liquid, the Octabenzone (UV-531) of 1kg, the peroxidating of defoamer BYK-555,3kg of 1kg
Butanone is made.
The preparation method of a kind of macromolecule resin laminated glass glue described in the embodiment of the present invention 1 comprises the following steps:
The isophthalic unsaturated polyester resin of the urethane modified polyester resin and 20kg that take 52kg puts into stirring mixing in container cartridge；Add again
Enter the Hydroxypropyl acrylate liquid of 6kg, 15kg styrene liquid, 2kg cobalt naphthenate solution, the ultraviolet (UV) resistant agent of 1kg and
The defoamer BYK-555 of 1kg, under normal temperature condition, starts driven stirring rod and stirs 20-30 minute；Add the mistake of 3kg
MEKP, is sufficiently mixed.
Using method is: filled by glue in sheet glass, within normal temperature and pressure 5-10 hour, can be fully cured, can obtain after solidification
To the glass sandwich glue that shore hardness is 80.
Embodiment 2:
A kind of macromolecule resin laminated glass glue described in the embodiment of the present invention 2, by the urethane modified polyester resin of 45kg,
The isophthalic unsaturated polyester resin of 25kg, the Hydroxypropyl acrylate liquid of 6kg, 17kg styrene liquid, 1.5kg cobalt naphthenate
Solution, ultraviolet (UV) resistant agent 2-(the 2-hydroxy-5-methyl base phenyl) BTA (UV-P) of 1.5kg, the defoamer of 2kg
The methyl ethyl ketone peroxide of BYK-555,2kg is made.
The preparation method of a kind of macromolecule resin laminated glass glue described in the embodiment of the present invention 2 comprises the following steps:
The isophthalic unsaturated polyester resin of the urethane modified polyester resin and 25kg that take 45kg puts into stirring mixing in container cartridge；Add again
Enter the Hydroxypropyl acrylate liquid of 6kg, 17kg styrene liquid, 1.5kg cobalt naphthenate solution, the ultraviolet (UV) resistant agent of 1.5kg
With the defoamer BYK-555 of 2kg, under normal temperature condition, start driven stirring rod and stir 20-30 minute；Add 2kg's
Methyl ethyl ketone peroxide, is sufficiently mixed.
Using method is: filled by glue in sheet glass, within normal temperature and pressure 5-10 hour, can be fully cured, can obtain after solidification
To the glass sandwich glue that shore hardness is 80.
Embodiment 3:
A kind of macromolecule resin laminated glass glue described in the embodiment of the present invention 3, by the urethane modified polyester resin of 60kg,
The isophthalic unsaturated polyester resin of 18kg, the Hydroxypropyl acrylate liquid of 8kg, 10kg styrene liquid, 2kg cobalt naphthenate are molten
Liquid, the ultraviolet (UV) resistant agent Octabenzone (UV-531) of 1.7kg, the defoamer BYK-555 of 1.3kg,
The methyl ethyl ketone peroxide of 1kg is made.
The preparation method of a kind of macromolecule resin laminated glass glue described in the embodiment of the present invention 3 comprises the following steps:
The isophthalic unsaturated polyester resin of the urethane modified polyester resin and 18kg that take 60kg puts into stirring mixing in container cartridge；Add again
Enter the Hydroxypropyl acrylate liquid of 8kg, 10kg styrene liquid, 2kg cobalt naphthenate solution, the ultraviolet (UV) resistant agent of 1.7kg and
The defoamer BYK-555 of 1.3kg, under normal temperature condition, starts driven stirring rod and stirs 20-30 minute；Add 1kg's
Methyl ethyl ketone peroxide, is sufficiently mixed.
Using method is: filled by glue in sheet glass, within normal temperature and pressure 5-10 hour, can be fully cured, can obtain after solidification
To the glass sandwich glue that shore hardness is 80.
The performance of the macromolecule resin laminated glass glue prepared according to the method described in embodiment 1-3 has a following characteristics:
1, thermostability: at 120 DEG C, in 2 hours, bubble-free produces；
2, moisture-proof: under conditions of 50 DEG C of relative humiditys are 95%-99%, in 14 days, bubble-free produces；
3, radioresistance: (be equivalent at outdoor environment by irradiation 5-8 for 100 hours according to the test method that GB15763-2009 specifies
Year), without notable variable color, bubble and turbid phenomenon；
4, tensile break strength: 20-30MPa；
5, tearing strength: 4-5MPa；
6, elongation at break: 120-150%.
The present invention is not limited to above-mentioned preferred forms, and anyone can draw other various shapes under the enlightenment of the present invention
The product of formula, no matter but in its shape or structure, make any change, every have same as the present application or akin technical side
Case, within all falling within protection scope of the present invention.
Claims (8)
1. a macromolecule resin laminated glass glue, it is characterized in that, it is made up of the raw material of following percentage by weight: urethane modified polyester resin 40 ~ 65%, isophthalic unsaturated polyester resin 10 ~ 30%, hardness regulator 5 ~ 10%, viscosity reduction diluent 10 ~ 30%, firming agent 0.5 ~ 4%, curing accelerator 0.1 ~ 3%, ultraviolet (UV) resistant agent 0.5 ~ 2% and defoamer 1 ~ 3%.
Macromolecule resin laminated glass glue the most according to claim 1, it is characterised in that: described hardness regulator is one or more in methacrylic acid, butyl acrylate, Hydroxypropyl acrylate, vinylacetate.
Macromolecule resin laminated glass glue the most according to claim 1, it is characterised in that: described viscosity reduction diluent is one or more in vinylacetate, acrylic acid, styrene.
Macromolecule resin laminated glass glue the most according to claim 1, it is characterised in that: described firming agent is one or more in benzoyl peroxide, isopropyl benzene hydroperoxide, methyl ethyl ketone peroxide.
Macromolecule resin laminated glass glue the most according to claim 1, it is characterised in that: described curing accelerator is one or more in cobalt naphthenate, cobalt iso-octoate, dimethylaniline.
Macromolecule resin laminated glass glue the most according to claim 1, it is characterised in that: described ultraviolet (UV) resistant agent is Octabenzone or 2-(2-hydroxy-5-methyl base phenyl) BTA.
Macromolecule resin laminated glass glue the most according to claim 1, it is characterised in that: the model of described defoamer is BYK-555 or BYK-560.
8. the preparation method of the macromolecule resin laminated glass glue described in any one of claim 1-7, it is characterised in that comprise the following steps:
1) in urethane modified polyester resin and isophthalic unsaturated polyester resin being added container cartridge and stir mixing；
2) take again in hardness regulator, viscosity reduction diluent, curing accelerator, ultraviolet (UV) resistant agent, defoamer addition reactor, under normal temperature condition, start stirring rod stirred for several minute；
3), under room temperature, add firming agent, and be sufficiently mixed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410422219.0A CN104212398B (en) | 2014-08-26 | 2014-08-26 | A kind of macromolecule resin laminated glass glue and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410422219.0A CN104212398B (en) | 2014-08-26 | 2014-08-26 | A kind of macromolecule resin laminated glass glue and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104212398A CN104212398A (en) | 2014-12-17 |
| CN104212398B true CN104212398B (en) | 2016-08-17 |
Family
ID=52094315
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410422219.0A Active CN104212398B (en) | 2014-08-26 | 2014-08-26 | A kind of macromolecule resin laminated glass glue and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104212398B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104629670A (en) * | 2015-02-04 | 2015-05-20 | 江苏大力士投资有限公司 | Shadowless glue with high adhesion and preparation method thereof |
| CN107011849A (en) * | 2017-06-05 | 2017-08-04 | 合肥聪亨新型建材科技有限公司 | A kind of glass cement and preparation method thereof |
| CN108276946A (en) * | 2017-12-27 | 2018-07-13 | 天长市墨缘玻璃建材有限公司 | A kind of water resistance polyurethane glass glue |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4035439A (en) * | 1975-10-17 | 1977-07-12 | Scm Corporation | Low-shrink thermosetting polyesters |
| CN1712449A (en) * | 2005-08-10 | 2005-12-28 | 北京玻钢院复合材料有限公司 | Unsaturated polyester/polyurethane/organic montmorillonite composite material and production thereof |
| CN101767611A (en) * | 2008-12-26 | 2010-07-07 | 沈阳理工大学 | Composite material closed boxcar |
| CN102516922A (en) * | 2011-11-28 | 2012-06-27 | 中国铁道科学研究院金属及化学研究所 | Embedded sleeve anchoring adhesive, and preparation method and application thereof |
-
2014
- 2014-08-26 CN CN201410422219.0A patent/CN104212398B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4035439A (en) * | 1975-10-17 | 1977-07-12 | Scm Corporation | Low-shrink thermosetting polyesters |
| CN1712449A (en) * | 2005-08-10 | 2005-12-28 | 北京玻钢院复合材料有限公司 | Unsaturated polyester/polyurethane/organic montmorillonite composite material and production thereof |
| CN101767611A (en) * | 2008-12-26 | 2010-07-07 | 沈阳理工大学 | Composite material closed boxcar |
| CN102516922A (en) * | 2011-11-28 | 2012-06-27 | 中国铁道科学研究院金属及化学研究所 | Embedded sleeve anchoring adhesive, and preparation method and application thereof |
Non-Patent Citations (1)
| Title |
|---|
| 高强度高伸长率聚氨酯改性不饱和聚酯;丁学文;《纤维复合材料》;20051231(第4期);第15-17页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104212398A (en) | 2014-12-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104030613B (en) | A kind of porcelain tendre and preparation method thereof | |
| CN106433537A (en) | Modified epoxy adhesive and preparing method thereof | |
| CN104212398B (en) | A kind of macromolecule resin laminated glass glue and preparation method thereof | |
| CN102994016A (en) | Multipolymer type waterproof sealant for construction | |
| CN103074010A (en) | Waterproof glue for building and preparation method thereof | |
| CN108752514B (en) | Epoxy modified acrylic emulsion and preparation method thereof | |
| CN101412591A (en) | Preparation of PET and PVC composite film for decorating glass | |
| CN104371508A (en) | Weather-resistant coating composite film | |
| CN101906282A (en) | Epoxy resin structural adhesive and preparation method thereof | |
| CN105176375B (en) | A kind of LED UV woodenware repairing transparent matt top coat top coat and preparation method | |
| CN108753022A (en) | A kind of UV-LED solidification repairing putty and preparation method thereof | |
| WO2017066905A1 (en) | Fluorine-containing (meth)acrylate polymer and preparation method therefor | |
| CN104559750A (en) | UV hand feeling coating based on elastic urethane acrylate and preparation method of UV hand feeling coating | |
| CN102676064B (en) | Matte adhesive and preparation method thereof | |
| CN103601870A (en) | Epoxy resin for low-gloss powder paint, and preparation method and application thereof | |
| CN102732072B (en) | Preparation method and product of high-adhesion polishing-free PE (Poly Ethylene) top-coat | |
| CN104211852A (en) | Preparation method of acrylate emulsion for waterborne printing ink | |
| CN104293119A (en) | High-intensity scratching-resistant ultraviolet light polymerization water paint and preparation method thereof | |
| CN102391440B (en) | Polycarbonate modified acrylic resin and preparation method thereof | |
| CN108504314A (en) | A kind of high-performance interior decoration plate sealing bonded adhesives and preparation method thereof | |
| KR101723406B1 (en) | Reusable resin composition to fabricate mock marble | |
| CN107286616A (en) | A kind of new lucite and preparation method thereof | |
| CN113583249A (en) | High-temperature-resistant epoxy modified acrylic resin and preparation method thereof | |
| CN102040796A (en) | Acrylic plate with natural coral patterns and method for producing same | |
| CN110760281A (en) | Aqueous acrylate emulsion type adhesive and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |