CN104291761A - Antique brick and applications thereof - Google Patents
Antique brick and applications thereof Download PDFInfo
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- CN104291761A CN104291761A CN201410492069.0A CN201410492069A CN104291761A CN 104291761 A CN104291761 A CN 104291761A CN 201410492069 A CN201410492069 A CN 201410492069A CN 104291761 A CN104291761 A CN 104291761A
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- imitation tiles
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Abstract
The invention discloses an antique brick and applications thereof. The antique brick comprises the following active ingredients in parts by weight: 100-200 parts of mineral powder, 20-50 parts of pulverized coal ash, 5-20 parts of excitant, 1-10 parts of iron oxide black, 250 parts of sand, 500 parts of stones and 25-39 parts of water. The antique brick has the properties of early strength, durability, permeability resistance, corrosion resistance, freezing and thawing resistance, low heat of hydration, good crack resistance, environment-friendliness and the like, and can replace cement products to be applied to restoration engineering of historic buildings.
Description
Technical field
The invention belongs to building material technical field, specifically, the present invention relates to a kind of Antique Imitation Tiles and application thereof.
Background technology
Cement products in the application of building every field widely in recent years, but because the feature of cement own makes it be not suitable for application in ancient architecture engineering is repaired in ancient architecture recovery project, the floor tile in some ancient buildings, wall brick, through erosion for many years, are damaged very serious.This just needs a kind of novel good endurance, and the Antique Imitation Tiles of environmental protection again substitutes and in ancient architecture recovery project.
Summary of the invention
The present invention is intended to solve one of technical problem in correlation technique at least to a certain extent.For this reason, one object of the present invention is to propose a kind of Antique Imitation Tiles and application thereof, this Antique Imitation Tiles have early strong, durable, impervious, anticorrosive, freeze-thaw-, hydration heat are low, splitting resistance good and the performance such as environmental protection.
In one aspect of the invention, the present invention proposes a kind of Antique Imitation Tiles, contain:
The breeze of 100 ~ 200 weight parts;
The flyash of 20 ~ 50 weight parts;
The exciting agent of 5 ~ 20 weight parts;
The iron oxide black of 1 ~ 10 weight part;
The sand of 250 weight parts;
The stone of 500 weight parts; And
The water of 25 ~ 39 weight parts.
Use industrial waste breeze and flyash as raw material according to the Antique Imitation Tiles of the embodiment of the present invention, the Antique Imitation Tiles of environmental protection can be prepared, and the effectuation that can realize resource utilizes, simultaneously by breeze, flyash and exciting agent mix at normal temperatures can react generation gelling material, more traditional Antique Imitation Tiles can save cement, thus significantly can reduce the raw materials cost of Antique Imitation Tiles, and by adding iron oxide black as tinting material, due to stable Steel Gray goods can be formed after its oxidation, therefore the Antique Imitation Tiles prepared can be applied to the reparation to ancient building.
In addition, Antique Imitation Tiles according to the above embodiment of the present invention can also have following additional technical characteristic:
In some embodiments of the invention, described breeze is blast-furnace slag.Thus, the Antique Imitation Tiles of environmental protection can be prepared, and the effectuation realizing resource utilizes.
In some embodiments of the invention, the fineness of described blast-furnace slag is greater than 350m
2/ kg.Thus, the uniformity coefficient of raw material can be significantly improved.
In some embodiments of the invention, described flyash quality grade is secondary.Thus, the over-all properties of Antique Imitation Tiles can be significantly improved.
In some embodiments of the invention, described exciting agent is the mixture containing water glass and additive.Thus, can react generation gelatinous material, comparatively traditional technology can save cement, thus significantly reduces the raw materials cost of Antique Imitation Tiles.
In some embodiments of the invention, described additive is sodium hydroxide.Thus, the raw materials cost of Antique Imitation Tiles can be reduced further.
In some embodiments of the invention, the modulus of described water glass is 1.0 ~ 1.8.Thus, the over-all properties of Antique Imitation Tiles can be improved further.
In the present invention in another, the present invention proposes a kind of method of repairing ancient building, the method adopts Antique Imitation Tiles described above to repair ancient building.Thus, by adopt above-mentioned have early strong, durable, impervious, anticorrosive, freeze-thaw-, hydration heat are low, splitting resistance good and the Antique Imitation Tiles of the performance such as environmental protection, and it has early strength development soon, the feature that later strength is high, therefore can substitute cement products and be applied to ancient building recovery project.
Additional aspect of the present invention and advantage will part provide in the following description, and part will become obvious from the following description, or be recognized by practice of the present invention.
Embodiment
Be described below in detail embodiments of the invention, the logical embodiment described is exemplary below, is intended to for explaining the present invention, and can not be interpreted as limitation of the present invention.
In one aspect of the invention, the present invention proposes a kind of Antique Imitation Tiles.According to embodiments of the invention, this Antique Imitation Tiles comprises: the breeze of 100 ~ 200 weight parts; The flyash of 20 ~ 50 weight parts; The exciting agent of 5 ~ 20 weight parts; The iron oxide black of 1 ~ 10 weight part; The sand of 250 weight parts; The stone of 500 weight parts; And 25 ~ 39 water of weight part.
Contriver finds, use industrial waste breeze and flyash as raw material, the Antique Imitation Tiles of environmental protection can be prepared, and the effectuation that can realize resource utilizes, breeze, flyash and exciting agent are mixed at normal temperatures simultaneously, Si-O, Al-O key in the aluminium of the potential hydraulically active had in slag, magnesium, lime glass body structure is ruptured under the effect of water-soluble exciting agent, SiO
4and AlO
4tetrahedron Fast Stripping, there is the inorganic polymer that polycondensation generates-O-Si-O-Al-O skeleton, generation gelling material can be reacted, the cement that high energy consumption has pollution can be saved compared with in the Antique Imitation Tiles raw material that cement makes, thus the present invention significantly can reduce the raw materials cost of Antique Imitation Tiles and energy consumption and pollution, and by adding iron oxide black as tinting material, due to stable Steel Gray goods can be formed after its oxidation, caesious brick body therefore can be prepared.In addition, the Antique Imitation Tiles that the present invention obtains does not need to fire, but by directly carrying out as required after raw material is mixed stirring, shapingly can obtain Antique Imitation Tiles, thus pollution and energy consumption can be reduced further.And contriver passes through great many of experiments, adopt Antique Imitation Tiles formula of the present invention can prepare early strong, durable, impervious, anticorrosive, freeze-thaw-, hydration heat are low, splitting resistance good and the Antique Imitation Tiles of the performance such as environmental protection, such as, 3d ultimate compression strength can reach 45MPa, 28d ultimate compression strength can reach 85MPa, and it is fast to have early strength development, the feature that later strength is high, therefore can substitute cement products and be applied to ancient building recovery project, also can use as floor tile or wall brick.
According to embodiments of the invention, the source of breeze is also not particularly limited, and according to a particular embodiment of the invention, breeze can be blast-furnace slag.Contriver finds, uses industrial waste blast-furnace slag as raw material, can prepare the Antique Imitation Tiles of environmental protection, and the effectuation that can realize resource utilizes.
According to embodiments of the invention, the fineness of blast-furnace slag is also not particularly limited, and according to a particular embodiment of the invention, the fineness of blast-furnace slag can be greater than 350m
2/ kg.Contriver finds, the breeze of different fineness, and different volumes can obtain the goods of different performance; If the meticulous meeting of the fineness of breeze makes the contraction of finished product become large, thus affects the performance of Antique Imitation Tiles.
According to embodiments of the invention, flyash quality grade is also not particularly limited, and according to a particular embodiment of the invention, flyash quality grade can be secondary.Concrete, the technical indicator of second class powered coal ash is: water demand ratio is not more than 105%, and fineness is not more than 20%, and loss on ignition is not more than 8%; , select second class powered coal ash can play skeleton thus and fill, thus improve Antique Imitation Tiles performance.
According to embodiments of the invention, the particular type of exciting agent is also not particularly limited, and according to a particular embodiment of the invention, exciting agent can for the mixture containing water glass and additive, and according to concrete example of the present invention, additive can be sodium hydroxide.Contriver finds, is mixed at normal temperatures by this exciting agent and can react generation gelling material, can save cement, thus significantly can reduce the raw materials cost of Antique Imitation Tiles in more traditional Antique Imitation Tiles raw material with breeze and flyash.
According to embodiments of the invention, in exciting agent water glass modulus and be not particularly limited, according to a particular embodiment of the invention, the modulus of water glass can be 1.0 ~ 1.8.Concrete, water glass is the soluble alkali metal silicate material by alkalimetal oxide and silica bound, and also known as sodium silicate, its molecular formula is respectively Na
2onSiO
2, the coefficient n in formula is called modulus of water glass, is the molecular ratio (or mol ratio) of silicon oxide in water glass and alkalimetal oxide.Contriver finds, modulus scope 1.0 ~ 1.8 water glass along with the increasing of modulus, its intensity also increases within the specific limits, and the too high Strength Changes that makes of modulus is little.
As mentioned above, can have according to the Antique Imitation Tiles of the embodiment of the present invention and be selected from following advantage one of at least:
Be all industrial waste according to the Antique Imitation Tiles starting material breeze of the embodiment of the present invention and flyash, thus achieve the recycling of resource;
According to the Antique Imitation Tiles of the embodiment of the present invention by adding iron oxide black as tinting material, can obtain with Concrete in Natural drying after fade and form stable color caesious modelled after an antique, the Antique Imitation Tiles therefore prepared can be applied to the reparation to ancient building;
According to the Antique Imitation Tiles of the embodiment of the present invention breeze, flyash and exciting agent mixed at normal temperatures and can react generation gelling material, comparatively cement makes in Antique Imitation Tiles raw material and can save cement, thus significantly can reduce raw materials cost and the energy consumption of Antique Imitation Tiles, and environmental pollution is little, there is green environmental protection;
According to the Antique Imitation Tiles good mechanical performance of the embodiment of the present invention, 3d ultimate compression strength can reach 45MPa, and 28d ultimate compression strength can reach 85MPa, and it is fast to have early strength development, the feature that later strength is high.
In another, a kind of method of repairing ancient building is the present invention proposes in the present invention.According to embodiments of the invention, above-mentioned Antique Imitation Tiles is adopted to repair ancient building.Contriver finds, above-mentioned Antique Imitation Tiles have early strong, durable, impervious, anticorrosive, freeze-thaw-, hydration heat are low, splitting resistance good and the performance such as environmental protection, and it has early strength development soon, the feature that later strength is high, thus, as required Antique Imitation Tiles can be made external form is desired shape, therefore can substitute cement products and be applied to ancient building recovery project.
Below with reference to specific embodiment, present invention is described, it should be noted that, these embodiments are only descriptive, and do not limit the present invention in any way.
Embodiment 1
Composition of raw materials: the water of the iron oxide black of the breeze of 100 weight parts, the flyash of 20 weight parts, the exciting agent of 15 weight parts, 10 parts of weight parts, the sand of 250 weight parts, the stone of 500 weight parts and 25 weight parts;
Preparation method: mixed according to predetermined proportion at normal temperatures by above raw material, through stirring, building or dry-pressing formed and maintenance makes discharging and obtains Antique Imitation Tiles, its 3d ultimate compression strength is 45MPa, 28d ultimate compression strength is 85MPa.
Embodiment 2
Composition of raw materials: the water of the exciting agent of the breeze of 200 weight parts, the flyash of 50 weight parts, 20 weight parts, the iron oxide black of 10 weight parts, the sand of 250 weight parts, the stone of 500 weight parts and 39 weight parts;
Preparation method: with embodiment 1, its 3d ultimate compression strength is 48MPa, 28d ultimate compression strength is 88MPa.
Comparative example 1
Composition of raw materials: the water of the exciting agent of the breeze of 95 weight parts, the flyash of 25 weight parts, 13 weight parts, the iron oxide black of 10 weight parts, the sand of 250 weight parts, the stone of 500 weight parts and 23 weight parts;
Preparation method: with embodiment 1, its 3d ultimate compression strength is 43MPa, 28d ultimate compression strength is 74MPa.
Comparative example 2
Composition of raw materials: the water of the exciting agent of the breeze of 205 weight parts, the flyash of 25 weight parts, 17 weight parts, the iron oxide black of 10 weight parts, the sand of 250 weight parts, the stone of 500 weight parts and 42 weight parts;
Preparation method: with embodiment 1, its 3d ultimate compression strength is 38MPa, 28d ultimate compression strength is 60MPa.
In the description of this specification sheets, specific features, structure, material or feature that the description of reference term " embodiment ", " some embodiments ", " example ", " concrete example " or " some examples " etc. means to describe in conjunction with this embodiment or example are contained at least one embodiment of the present invention or example.In this manual, to the schematic representation of above-mentioned term not must for be identical embodiment or example.And the specific features of description, structure, material or feature can combine in one or more embodiment in office or example in an appropriate manner.In addition, when not conflicting, the feature of the different embodiment described in this specification sheets or example and different embodiment or example can carry out combining and combining by those skilled in the art.
Although illustrate and describe embodiments of the invention above, be understandable that, above-described embodiment is exemplary, can not be interpreted as limitation of the present invention, and those of ordinary skill in the art can change above-described embodiment within the scope of the invention, revises, replace and modification.
Claims (8)
1. an Antique Imitation Tiles, is characterized in that, contains:
The breeze of 100 ~ 200 weight parts;
The flyash of 20 ~ 50 weight parts;
The exciting agent of 5 ~ 20 weight parts;
The iron oxide black of 1 ~ 10 weight part;
The sand of 250 weight parts;
The stone of 500 weight parts; And
The water of 25 ~ 39 weight parts.
2. Antique Imitation Tiles according to claim 1, is characterized in that, described breeze is blast-furnace slag.
3. Antique Imitation Tiles according to claim 2, is characterized in that, the fineness of described blast-furnace slag is greater than 350m
2/ kg.
4. Antique Imitation Tiles according to claim 1, is characterized in that, described flyash quality grade is secondary.
5. Antique Imitation Tiles according to claim 1, is characterized in that, described exciting agent is the mixture containing water glass and additive.
6. Antique Imitation Tiles according to claim 5, is characterized in that, described additive is sodium hydroxide.
7. Antique Imitation Tiles according to claim 5, is characterized in that, the modulus of described water glass is 1.0 ~ 1.8.
8. repair a method for ancient building, it is characterized in that, adopt the Antique Imitation Tiles described in any one of claim 1 ~ 7 to repair ancient building.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410492069.0A CN104291761B (en) | 2014-09-23 | 2014-09-23 | Antique Imitation Tiles and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410492069.0A CN104291761B (en) | 2014-09-23 | 2014-09-23 | Antique Imitation Tiles and application thereof |
Publications (2)
| Publication Number | Publication Date |
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| CN104291761A true CN104291761A (en) | 2015-01-21 |
| CN104291761B CN104291761B (en) | 2016-11-30 |
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ID=52311754
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| CN201410492069.0A Expired - Fee Related CN104291761B (en) | 2014-09-23 | 2014-09-23 | Antique Imitation Tiles and application thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105967760A (en) * | 2016-05-05 | 2016-09-28 | 华若延 | Archaized brick manufacturing method |
| CN107244862A (en) * | 2017-07-11 | 2017-10-13 | 合肥尚涵装饰工程有限公司 | Environmentally friendly Antique Imitation Tiles of a kind of weather-resistant and high-strength and preparation method thereof |
| CN109020452A (en) * | 2018-10-09 | 2018-12-18 | 河南能工巧匠网络科技有限公司 | A method of utilizing the clay standby Antique Imitation Tiles of saw |
| CN109053057A (en) * | 2018-10-09 | 2018-12-21 | 河南能工巧匠网络科技有限公司 | A method of romote antiquity brick is prepared using loess |
| CN109279852A (en) * | 2018-10-09 | 2019-01-29 | 河南能工巧匠网络科技有限公司 | A kind of gold tailing slag Antique Imitation Tiles and preparation method thereof |
| CN112047702A (en) * | 2020-09-01 | 2020-12-08 | 贵州城晖环保科技有限公司 | Baking-free antique blue brick based on electrolytic manganese slag and preparation method and application thereof |
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| JPH0977530A (en) * | 1995-09-08 | 1997-03-25 | Chichibu Onoda Cement Corp | Vitreous hardened body and its production |
| CN101289310A (en) * | 2008-03-24 | 2008-10-22 | 昆明理工大学 | Low-temperature ceramic permeable bricks and production method thereof |
| CN101700672A (en) * | 2009-10-16 | 2010-05-05 | 中国铝业股份有限公司 | Method for preparing copy stone floor tile by mineral processing tailing of bauxite |
| CN102701641A (en) * | 2012-06-25 | 2012-10-03 | 重庆龙者低碳环保科技有限公司 | Building finish material, composite raw material and dosage proportion |
| CN103011733A (en) * | 2012-12-24 | 2013-04-03 | 济南大学 | Waste base polymer building block and fabrication method thereof |
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2014
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Patent Citations (5)
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| JPH0977530A (en) * | 1995-09-08 | 1997-03-25 | Chichibu Onoda Cement Corp | Vitreous hardened body and its production |
| CN101289310A (en) * | 2008-03-24 | 2008-10-22 | 昆明理工大学 | Low-temperature ceramic permeable bricks and production method thereof |
| CN101700672A (en) * | 2009-10-16 | 2010-05-05 | 中国铝业股份有限公司 | Method for preparing copy stone floor tile by mineral processing tailing of bauxite |
| CN102701641A (en) * | 2012-06-25 | 2012-10-03 | 重庆龙者低碳环保科技有限公司 | Building finish material, composite raw material and dosage proportion |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105967760A (en) * | 2016-05-05 | 2016-09-28 | 华若延 | Archaized brick manufacturing method |
| CN105967760B (en) * | 2016-05-05 | 2018-08-10 | 江门市华陶陶瓷有限公司 | A kind of production method of Antique Imitation Tiles |
| CN107244862A (en) * | 2017-07-11 | 2017-10-13 | 合肥尚涵装饰工程有限公司 | Environmentally friendly Antique Imitation Tiles of a kind of weather-resistant and high-strength and preparation method thereof |
| CN109020452A (en) * | 2018-10-09 | 2018-12-18 | 河南能工巧匠网络科技有限公司 | A method of utilizing the clay standby Antique Imitation Tiles of saw |
| CN109053057A (en) * | 2018-10-09 | 2018-12-21 | 河南能工巧匠网络科技有限公司 | A method of romote antiquity brick is prepared using loess |
| CN109279852A (en) * | 2018-10-09 | 2019-01-29 | 河南能工巧匠网络科技有限公司 | A kind of gold tailing slag Antique Imitation Tiles and preparation method thereof |
| CN112047702A (en) * | 2020-09-01 | 2020-12-08 | 贵州城晖环保科技有限公司 | Baking-free antique blue brick based on electrolytic manganese slag and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104291761B (en) | 2016-11-30 |
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