CN109704617A - A kind of building waste wallboard crack resistance modifier and preparation method thereof - Google Patents

A kind of building waste wallboard crack resistance modifier and preparation method thereof Download PDF

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Publication number
CN109704617A
CN109704617A CN201910027019.8A CN201910027019A CN109704617A CN 109704617 A CN109704617 A CN 109704617A CN 201910027019 A CN201910027019 A CN 201910027019A CN 109704617 A CN109704617 A CN 109704617A
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building waste
crack resistance
resistance modifier
mixture
waste wallboard
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CN109704617B (en
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班良民
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Shenpeng Environmental Protection Engineering Co ltd
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Shenpeng Environmental Protection Engineering Co ltd
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Abstract

The present invention discloses a kind of building waste wallboard crack resistance modifier and preparation method thereof, wherein by mass percentage, the building waste wallboard crack resistance modifier includes: 20~30% light calcined magnesia;12~20% calcium oxide-calcium sulphoaluminate class clinker;30~42% filler;9~15% silica flour;And 5~10% light calcium carbonate powder.The present invention has selected the raw material as building waste wallboard crack resistance modifier such as light calcined magnesia, calcium oxide-calcium sulphoaluminate class clinker, filler, silica flour, light calcium carbonate powder, sodium gluconate, polyvinyl alcohol and inorganic gel, and the proportion of each raw material is optimized, to obtain final formula, building waste wallboard crack resistance modifier prepared by the present invention, it has larger improvement to the cracking resistance of regeneration wallboard, and it is at low cost, preparation process is simple.

Description

A kind of building waste wallboard crack resistance modifier and preparation method thereof
Technical field
The present invention relates to the field of building materials more particularly to a kind of building waste wallboard crack resistance modifier and its preparation sides Method.
Background technique
According to alleged building waste in " urban building waste administrative provisions ", refer to that construction unit, unit in charge of construction create, change Spoir caused by building, extend and remove during all kinds of buildings, structures, pipe network etc. and resident's decorations house, Rejected material and other wastes.Construction refuse regenerated to utilize product, the huge market demand, governments at all levels issue various government decrees, encourage With require government-works and business development engineering to use renewable building material.
Construction refuse regenerated to utilize product, mainstream kind has currently on the market: recycled aggregate, regenerated construction material two major classes.Its In: recycled aggregate is divided into regenerated coarse aggregate and recycled fine aggregate etc..Regenerated construction material is mainly regeneration brick and regenerates wallboard, extensively For building, road, bridge construction in.
And in the prior art, the cracking resistance of construction refuse regenerated wallboard is poor, is unfavorable for regenerating the popularization and application of wallboard.
Therefore, the existing technology needs to be improved and developed.
Summary of the invention
In view of above-mentioned deficiencies of the prior art, the purpose of the present invention is to provide a kind of building waste wallboard crack resistance modifiers And preparation method thereof, it is intended to solve the problems, such as that regeneration wallboard cracking resistance is to be improved in the prior art.
Technical scheme is as follows:
A kind of building waste wallboard crack resistance modifier, wherein by mass percentage, comprising:
12~18% light calcined magnesia;
25~30% calcium oxide-calcium sulphoaluminate class clinker;
18~30% filler;
8~12% silica flour;
6~9% light calcium carbonate powder;
1~3% sodium gluconate;
2~5% polyvinyl alcohol;
3~6% inorganic gel;
Surplus is water.
The building waste wallboard crack resistance modifier, wherein the inorganic gel is lithium magnesium silicate gel.
The building waste wallboard crack resistance modifier, wherein the mesh number of the light calcium carbonate powder is 1000~1200 mesh.
The building waste wallboard crack resistance modifier, wherein the filler is fine powder material.
The building waste wallboard crack resistance modifier, wherein the specific surface area of the fine powder material is greater than 450m2/kg。
The building waste wallboard crack resistance modifier, wherein the mesh number of the fine powder material is 200~400 mesh.
The building waste wallboard crack resistance modifier, wherein by mass percentage, comprising:
15% light calcined magnesia;
28% calcium oxide-calcium sulphoaluminate class clinker;
25% filler;
10% silica flour;
8% light calcium carbonate powder;
2% sodium gluconate;
4% polyvinyl alcohol;
5% inorganic gel;
Surplus is water.
A kind of preparation method of building waste wallboard crack resistance modifier as described above, wherein comprising steps of
By light calcined magnesia, silica flour, light calcium carbonate powder, sodium gluconate, polyvinyl alcohol and a part of water be pre-mixed One mixture;
And by calcium oxide-calcium sulphoaluminate class clinker, filler, inorganic gel and remaining a part of water be pre-mixed second Mixture;
The first mixture and the second mixture are stirred mixing again, obtain building waste wallboard crack resistance modifier.
The preparation method, wherein the incorporation time of the first mixture and the second mixture is 6~8 minutes.
The preparation method, wherein the first mixture and the second mixture are mixed in spiral ribbon mixer.
The utility model has the advantages that the present invention has selected light calcined magnesia, calcium oxide-calcium sulphoaluminate class clinker, filler, silica flour, light The raw material as building waste wallboard crack resistance modifier such as calcium powder, sodium gluconate, polyvinyl alcohol and inorganic gel, and to each original The proportion of material is optimized, so that final formula has been obtained, building waste wallboard crack resistance modifier prepared by the present invention, It has larger improvement to the cracking resistance of regeneration wallboard, and at low cost, and preparation process is simple.
Specific embodiment
The present invention provides a kind of building waste wallboard crack resistance modifier and preparation method thereof, to make the purpose of the present invention, skill Art scheme and effect are clearer, clear, and the present invention is described in more detail below.It should be appreciated that tool described herein Body embodiment is only used to explain the present invention, is not intended to limit the present invention.
A kind of building waste wallboard crack resistance modifier provided by the present invention, by mass percentage, comprising:
12~18% light calcined magnesia;
25~30% calcium oxide-calcium sulphoaluminate class clinker;
18~30% filler;
8~12% silica flour;
6~9% light calcium carbonate powder;
1~3% sodium gluconate;
2~5% polyvinyl alcohol;
3~6% inorganic gel;
Surplus is water.
The sum of mass percent of each raw material is 100%.
The reason of regeneration wallboard cracking, mainly has: dehydration drying shrinkage and temperature difference shrinkage are shunk one is generating in hydration process, The second is tensile strength is small, limit elongation is low.When shrinkage value is more than concrete ultimate extension, concrete, which will crack, to be caused to leak.It can See that " splitting " is the major reason of " infiltration ", concrete is not permeable without splitting, and the premise of antiseepage is anticracking.
Building waste wallboard crack resistance modifier in the present invention is added in building waste concrete mix water after generate a large amount of expansions Property crystallization hyrate-hydrated calcium aluminate sulfate, i.e. entringite makes concrete generate appropriateness expansion, constraint of the expansive concrete in reinforcing bar and ortho position Under the compression established in the structure, this compression can offset the contraction pressure or keep its small that concrete generates in hardening process In the limit of stretch of concrete to prevent concrete shrinkage cracking.
It can be seen that the addition of building waste wallboard crack resistance modifier, changes answering in concrete hardening process since expansion compensation is shunk Stress-strain state splits infiltration so fundamentally overcoming the fault in material of concrete to solve the problems, such as concrete material.
Specifically, light calcined magnesia is a kind of by magnisite stone, shepardite and the hydrogen by extracting in seawater or brine Magnesia Mg (OH)2, through 700~1000 DEG C of temperature lower calcinations, it is made to decompose discharge CO2Or H2O to get arrive light-burning magnesium powder (Caustic calcined magnesia), also referred to as light calcined magnesia, caustic magnesia or magnesia unslacked, are commonly called as magnesia.It is light-burned Magnesium powder quality is loose, chemical activity is big, not only can be used for manufacturing magnesium cement, magnesite building material, heat-insulating heat-preserving material etc., but also be The intermediate product of two step calcination methods production quality magnesia.2852 DEG C of light calcined magnesia fusing point, 3600 DEG C of boiling point, it is dissolved in acid and ammonium Salt is insoluble in water and ethyl alcohol.Specific surface area is 180m at 400 DEG C of calcination temperature2/g.Specific surface area is only 3m at 1300 DEG C2/g。 It easily deliquesces in air, it belongs to the cementing material of air-setting.
Calcium oxide-calcium sulphoaluminate class clinker is using lime stone, alumina and chemical industry anhydrous gypsum as raw material, by CaO:Al2O3: CaSO4(mole ratio)=4:1:3 is burnt through glue, and regrinding into fineness is 1500~2300cm2The powder of/g specific surface area.It is this ripe Material is using C4A3S and C3S as main mineral constituent.General mixing expansive concrete volume (presses swelling agent/cement+swelling agent Weight %) 7.0~11.0%.Mixing self-stressing concretes is 13~17%.
Filler refers to the material being filled in other objects.Filler is also known as filler, refer to improve processing performance, Mechanical Properties of Products simultaneously (or) reduce the solid material of cost.Fine powder material is the small material of the thin quality of particle, and generally chemistry is used Product or building material.
Further, the filler is preferably fine powder material.
The fine powder material is the small material of the thin quality of particle, generally chemical article or building material.It is mixed in coarse granule In fine powder material to it is coarse grained movement play the role of reduce friction, be conducive to the rolling and flowing of material.While fine powder material In the presence of the refinement for also helping product surface and article section porosity is reduced, improves quality of item.The fine powder material specifically may be used To be talcum powder etc..
Further, the specific surface area of the fine powder material is greater than 450m2/kg.Fine powder material can be improved in biggish specific surface area With the contact area of other raw materials, so that fine powder material be enable to be sufficiently mixed with other raw materials.Further, the mesh of the fine powder material Number is 200~400 mesh, and the even particle size of such fine powder material and moderate can be improved the stability of product.
The silica flour is also known as silicon powder.Silica flour is a kind of hard, wear-resisting, stable chemical performance silicate mineral, Its main mineral constituent is SiO2, color be milky or semi-transparent clear shape, hardness 7, the crisp no cleavage of property, conchoidal fracture, Greasy luster, density 2.65, bulk density (20-200 mesh is 1.5), chemistry, calorifics and mechanical performance have apparent different Tropism is slightly soluble in KOH solution insoluble in acid, and 1650 DEG C of fusing point.After the quartz gone out from mining is processed, general fineness Product more than 120 mesh is known as silica flour.Further, the mesh number of the silica flour is 325~400 mesh, the quartz of above-mentioned mesh number Powder can come into full contact with other raw materials and uniformly mix.
The light calcium carbonate powder is also known as precipitated calcium carbonate, is that (main component is oxidation by the raw materials section such as lime stone burning generation lime Calcium) and carbon dioxide, it adds water digestion lime and generates milk of lime (main component is calcium hydroxide), be then passed through carbon dioxide again The milk of lime that is carbonized generates precipitation of calcium carbonate, crushes and is made through lime flour mill after being most dehydrated, dried afterwards, or first uses carbonic acid Sodium and calcium chloride carry out metathesis reaction and generate precipitation of calcium carbonate, are then made through dehydration, drying and crushing.Due to light calcium carbonate powder Settling volume (2.4-2.8mL/g) than dicalcium powder settling volume (1.1-1.4mL/g) greatly, so referred to as light calcium carbonate powder.Into One step, the mesh number of the light calcium carbonate powder are 1000~1200 mesh, the even particle size of such light calcium carbonate powder and moderate, can be improved production The stability of product.
The sodium gluconate can increase the plasticity and intensity of building waste wallboard, and have retardation.It postpones mixed The initial and final solidification period of solidifying soil.Plasticity and the initial solidification time is delayed to be very important problem, such as in high-temperature In season construction and the engineer operation of large size, delaying the initial solidification time then is a problem, and sodium gluconate can satisfactorily resolve this A problem.In addition when high temperature be glued oil well be it is relatively difficult, it is plastic within several hours after being added to sodium gluconate.
The polyvinyl alcohol is important industrial chemicals, for manufacturing Pioloform, polyvinyl acetal, resistance to gasoline pipeline and vinylon Synthetic fibers, fabric-treating agent, emulsifier, paper coating, adhesive, glue etc..Polyvinyl alcohol in the present invention specifically can be with It is PVA17-99, PVA20-99 or highly viscous PVA24-99, PVA26-99 etc. of medium viscosity.Its application in the present invention, has There is the characteristic of high clayization, there is significant cracking resistance effect.
The inorganic gel is preferably lithium magnesium silicate gel, and artificial synthesized lithium magnesium silicate gel essential mineral composition is lithium Saponite.Artificial synthesized hectorite is trioctahedron layer silicate mineral as natural hectorite.Unit cell is by two layers Si-O tetrahedron presss from both sides one layer of Mg- (O.OH) trioctahedron composition.It observes under an electron microscope, crystal grain is in irregular sheet, piece Long and wide about (0.3~2.5) μm, piece thickness about (15~230) nm is typical artificial synthesized two-dimensional nano mineral material.Silicic acid The crystal structure unit of magnesium lithium gel is small thin slice of the thickness in terms of nanometer.The surface of small pieces be covered with it is tradable sun from Son, wherein predominantly Na+.When gel particle is mixed with water, water and Na+Contact is adsorbed to the surface of thin slice, by gel along thin Piece struts, and at this moment particle expands rapidly until thin slice separates.Since thin slice level is negatively charged, end face is positively charged, after separation Thin slice end face be attracted to the level of another thin slice, to quickly form the colloform texture of three-dimensional space, i.e. card palace structure, Increase the viscosity of system, and suspension, thickening property, thixotropy and good compatibility and chemical stability with height.
Further, by mass percentage, the building waste wallboard crack resistance modifier includes:
15% light calcined magnesia;
28% calcium oxide-calcium sulphoaluminate class clinker;
25% filler;
10% silica flour;
8% light calcium carbonate powder;
2% sodium gluconate;
4% polyvinyl alcohol;
5% inorganic gel;
Surplus is water.
The sum of mass percent of each raw material is 100%.
The sum of the mass percent of each raw material is similarly 100% in subsequent embodiment.
Tests prove that above-mentioned specific formula, obtained building waste wallboard crack resistance modifier effect of prestressed is more preferable.
The present invention also provides a kind of preparation methods of building waste wallboard crack resistance modifier as described above comprising step It is rapid:
By light calcined magnesia, silica flour, light calcium carbonate powder, sodium gluconate, polyvinyl alcohol and a part of water be pre-mixed One mixture;
And by calcium oxide-calcium sulphoaluminate class clinker, filler, inorganic gel and remaining a part of water be pre-mixed second Mixture;
The first mixture and the second mixture are stirred mixing again, obtain building waste wallboard crack resistance modifier.
The present invention is to carry out light calcined magnesia, silica flour, light calcium carbonate powder, sodium gluconate, polyvinyl alcohol and a part of water Mixing, and calcium oxide-calcium sulphoaluminate class clinker, filler, inorganic gel and remaining a part of water are mixed;It in this way can be with Respectively obtain the first mixture and the second mixture.Finally the two mixtures are mixed, to obtain building waste wall Plate crack resistance modifier.The advantage of doing so is that the similar raw material of shape can first be mixed, make raw material mixing more evenly.
Further, the incorporation time of the first mixture and the second mixture is 6~8 minutes.Incorporation time is too long, will lead to The property of raw material changes, and effect of prestressed is caused to decline, and incorporation time is too short, then will lead to raw material mixing unevenly, respectively It can not influence each other and mutually promote between raw material, cracking resistance is caused to decline.
Further, the first mixture and the second mixture are mixed in spiral ribbon mixer.Spiral ribbon mixer Blade is helical ribbon, and the quantity of ribbon is two to three, is installed on the screw rod in blender center, the spiral shell of spiral ribbon mixer Away from the outer diameter for determining ribbon.Above-mentioned blender is suitable for the stirring of each raw material in the building waste wallboard crack resistance modifier, Mixing effect can be improved, reduce stirring cost.
Further, the speed of agitator of the first mixture and the second mixture is 60~80rpm.Speed of agitator is too fast, raw material Property can change, the product stirred to get can not play original performance, and speed of agitator is excessively slow, and raw material is unable to fully mix It is even, so currently preferred speed of agitator is 60~80rpm.
In following embodiment, filler is specially fine powder material, and the fine powder material is specially talcum powder, the ratio table of the fine powder material Area is greater than 450m2/ kg, the mesh number of the fine powder material are 300 mesh, and the mesh number of the silica flour is 375 mesh, the light calcium carbonate powder Mesh number is 1000 mesh, and the inorganic gel is preferably lithium magnesium silicate gel.
Embodiment 1
A kind of building waste wallboard crack resistance modifier, by mass percentage, comprising: 12% light calcined magnesia;30% Calcium oxide-calcium sulphoaluminate class clinker;18% filler;8% silica flour;9% light calcium carbonate powder;1% sodium gluconate; 2% polyvinyl alcohol;6% inorganic gel;Surplus is water.
The preparation method is as follows:
By light calcined magnesia, silica flour, light calcium carbonate powder, sodium gluconate, polyvinyl alcohol and a part of water (such as whole water Half, subsequent embodiment are identical) it is pre-mixed to obtain the first mixture;
And by calcium oxide-calcium sulphoaluminate class clinker, filler, inorganic gel and remaining a part of water be pre-mixed second Mixture;
The first mixture and the second mixture are stirred mixing in spiral ribbon mixer again, incorporation time is 6 points Clock, speed of agitator 80rpm obtain building waste wallboard crack resistance modifier.
Embodiment 2
A kind of building waste wallboard crack resistance modifier, by mass percentage, comprising: 18% light calcined magnesia;25% Calcium oxide-calcium sulphoaluminate class clinker;30% filler;12% silica flour;6% light calcium carbonate powder;3% sodium gluconate; 5% polyvinyl alcohol;3% inorganic gel;Surplus is water.
The preparation method is as follows:
By light calcined magnesia, silica flour, light calcium carbonate powder, sodium gluconate, polyvinyl alcohol and a part of water be pre-mixed One mixture;
And by calcium oxide-calcium sulphoaluminate class clinker, filler, inorganic gel and remaining a part of water be pre-mixed second Mixture;
The first mixture and the second mixture are stirred mixing in spiral ribbon mixer again, incorporation time is 8 points Clock, speed of agitator 60rpm obtain building waste wallboard crack resistance modifier.
Embodiment 3
A kind of building waste wallboard crack resistance modifier, by mass percentage, comprising: 17% light calcined magnesia;28% Calcium oxide-calcium sulphoaluminate class clinker;19% filler;10.5% silica flour;7.5% light calcium carbonate powder;2% gluconic acid Sodium;3% polyvinyl alcohol;4% inorganic gel;Surplus is water.
The preparation method is as follows:
By light calcined magnesia, silica flour, light calcium carbonate powder, sodium gluconate, polyvinyl alcohol and a part of water be pre-mixed One mixture;
And by calcium oxide-calcium sulphoaluminate class clinker, filler, inorganic gel and remaining a part of water be pre-mixed second Mixture;
The first mixture and the second mixture are stirred mixing in spiral ribbon mixer again, incorporation time is 8 points Clock, speed of agitator 80rpm obtain building waste wallboard crack resistance modifier.
Embodiment 4
A kind of building waste wallboard crack resistance modifier, by mass percentage, comprising: 13% light calcined magnesia;26% Calcium oxide-calcium sulphoaluminate class clinker;22% filler;9% silica flour;7% light calcium carbonate powder;1.5% sodium gluconate; 3% polyvinyl alcohol;4% inorganic gel;Surplus is water.
The preparation method is as follows:
By light calcined magnesia, silica flour, light calcium carbonate powder, sodium gluconate, polyvinyl alcohol and a part of water be pre-mixed One mixture;
And by calcium oxide-calcium sulphoaluminate class clinker, filler, inorganic gel and remaining a part of water be pre-mixed second Mixture;
The first mixture and the second mixture are stirred mixing, incorporation time 6.5 in spiral ribbon mixer again Minute, speed of agitator 65rpm obtains building waste wallboard crack resistance modifier.
Embodiment 5
A kind of building waste wallboard crack resistance modifier, by mass percentage, comprising: 14% light calcined magnesia;29% Calcium oxide-calcium sulphoaluminate class clinker;26% filler;11% silica flour;8% light calcium carbonate powder;2.5% gluconic acid Sodium;4.5% polyvinyl alcohol;5% inorganic gel;Surplus is water.
The preparation method is as follows:
By light calcined magnesia, silica flour, light calcium carbonate powder, sodium gluconate, polyvinyl alcohol and a part of water be pre-mixed One mixture;
And by calcium oxide-calcium sulphoaluminate class clinker, filler, inorganic gel and remaining a part of water be pre-mixed second Mixture;
The first mixture and the second mixture are stirred mixing, incorporation time 7.5 in spiral ribbon mixer again Minute, speed of agitator 75rpm obtains building waste wallboard crack resistance modifier.
Embodiment 6
A kind of building waste wallboard crack resistance modifier, by mass percentage, comprising: 15% light calcined magnesia;28% Calcium oxide-calcium sulphoaluminate class clinker;25% filler;10% silica flour;8% light calcium carbonate powder;2% sodium gluconate; 4% polyvinyl alcohol;5% inorganic gel;Surplus is water.
The preparation method is as follows:
By light calcined magnesia, silica flour, light calcium carbonate powder, sodium gluconate, polyvinyl alcohol and a part of water be pre-mixed One mixture;
And by calcium oxide-calcium sulphoaluminate class clinker, filler, inorganic gel and remaining a part of water be pre-mixed second Mixture;
The first mixture and the second mixture are stirred mixing in spiral ribbon mixer again, incorporation time is 7 points Clock, speed of agitator 70rpm obtain building waste wallboard crack resistance modifier.
Then the building waste wallboard crack resistance modifier that various embodiments of the present invention obtain is added in building waste, and made Standby building waste wallboard (i.e. construction refuse regenerated wallboard can also claim construction refuse regenerated wallboard).Blank expression, which is not added, builds Building refuse wallboard crack resistance modifier.
The cracking resistance of building waste wallboard is tested: according to " Standard for quality control of concrete " (GB50164-2011) into Row.
The anti-permeability performance of building waste wallboard is tested: according to " Standard for quality control of concrete " (GB50164-2011) into Row.
By the building waste wallboard crack resistance modifier of each embodiment, the anti-permeability performance of prepared building waste wallboard is such as Shown in following table one.
Table one
By the building waste wallboard crack resistance modifier of each embodiment, the cracking resistance of prepared building waste wallboard is such as Shown in following table two.
Table two
Total area of cracks (the mm of unit2/m2)
Blank 487
Embodiment 1 352
Embodiment 2 287
Embodiment 3 201
Embodiment 4 268
Embodiment 5 198
Embodiment 6 124
Wherein electric flux value is lower, represents that seepage-resistant grade is higher, and the total area of cracks of unit is smaller, and cracking resistance is better.It can See, building waste wallboard crack resistance modifier of the invention can improve the waterproof performance of building waste wallboard, can also mitigate and build The bleeding of building refuse wallboard improves building waste wallboard later strength, building waste wallboard aquation can also be promoted complete, ties Structure is more closely knit.
The embodiment of the present invention 6, obtained building waste wallboard crack resistance modifier is for the impervious, anti-of building waste wallboard The improvement of fragility is better than other embodiments, and is apparently higher than blank group.
It should be understood that the application of the present invention is not limited to the above for those of ordinary skills can With improvement or transformation based on the above description, all these modifications and variations all should belong to the guarantor of appended claims of the present invention Protect range.

Claims (10)

1. a kind of building waste wallboard crack resistance modifier, which is characterized in that by mass percentage, comprising:
12~18% light calcined magnesia;
25~30% calcium oxide-calcium sulphoaluminate class clinker;
18~30% filler;
8~12% silica flour;
6~9% light calcium carbonate powder;
1~3% sodium gluconate;
2~5% polyvinyl alcohol;
3~6% inorganic gel;
Surplus is water.
2. building waste wallboard crack resistance modifier according to claim 1, which is characterized in that the inorganic gel is silicic acid Magnesium lithium gel.
3. building waste wallboard crack resistance modifier according to claim 1, which is characterized in that the mesh number of the light calcium carbonate powder is 1000~1200 mesh.
4. building waste wallboard crack resistance modifier according to claim 1, which is characterized in that the filler is fine powder material.
5. building waste wallboard crack resistance modifier according to claim 4, which is characterized in that the specific surface of the fine powder material Product is greater than 450m2/kg。
6. building waste wallboard crack resistance modifier according to claim 4, which is characterized in that the mesh number of the fine powder material is 200~400 mesh.
7. building waste wallboard crack resistance modifier according to claim 1, which is characterized in that by mass percentage, packet It includes:
15% light calcined magnesia;
28% calcium oxide-calcium sulphoaluminate class clinker;
25% filler;
10% silica flour;
8% light calcium carbonate powder;
2% sodium gluconate;
4% polyvinyl alcohol;
5% inorganic gel;
Surplus is water.
8. a kind of preparation method of building waste wallboard crack resistance modifier as described in any one of claims 1 to 7, feature exist In, comprising steps of
Light calcined magnesia, silica flour, light calcium carbonate powder, sodium gluconate, polyvinyl alcohol and a part of water are pre-mixed first to mix Close object;
And calcium oxide-calcium sulphoaluminate class clinker, filler, inorganic gel and remaining a part of water are pre-mixed to obtain the second mixing Object;
The first mixture and the second mixture are stirred mixing again, obtain building waste wallboard crack resistance modifier.
9. preparation method according to claim 8, which is characterized in that the incorporation time of the first mixture and the second mixture It is 6~8 minutes.
10. preparation method according to claim 8, which is characterized in that the first mixture and the second mixture are in helical-ribbon type It is mixed in blender.
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110143802A (en) * 2019-06-17 2019-08-20 山东凯勒蓝房家居文化发展有限公司 Magnesium oxysulfide melamine paper facing negative oxygen ion rock porcelain non-combustible plate and preparation method thereof
CN111393172A (en) * 2020-02-19 2020-07-10 佛山市山有海科技有限公司 Inorganic green body reinforcing agent based on silicate system
CN111393134A (en) * 2020-02-19 2020-07-10 佛山市山有海科技有限公司 Silicate system-based modified bentonite body reinforcing agent
CN111777349A (en) * 2020-07-28 2020-10-16 陕西科技大学 Shrinkage-resistant and crack-resistant additive for cement-based composite material and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU974818A1 (en) * 1981-05-08 1994-06-15 А.Ф. Мирошкин Flux for electric-slag remelting of steel
CN105837153A (en) * 2016-03-28 2016-08-10 北京中晶环境科技股份有限公司 Sulfur magnesium oxychloride foam cement exterior wall insulation board and preparation method thereof.
CN105837154A (en) * 2016-03-28 2016-08-10 北京中晶环境科技股份有限公司 Hollow partition board
CN106365486A (en) * 2016-08-31 2017-02-01 武汉三源特种建材有限责任公司 Concrete compaction anti-cracking agent
CN107140915A (en) * 2017-06-20 2017-09-08 和县明生环保材料有限责任公司 A kind of light heat-resisting tailings hollow brick and its preparation

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU974818A1 (en) * 1981-05-08 1994-06-15 А.Ф. Мирошкин Flux for electric-slag remelting of steel
CN105837153A (en) * 2016-03-28 2016-08-10 北京中晶环境科技股份有限公司 Sulfur magnesium oxychloride foam cement exterior wall insulation board and preparation method thereof.
CN105837154A (en) * 2016-03-28 2016-08-10 北京中晶环境科技股份有限公司 Hollow partition board
CN106365486A (en) * 2016-08-31 2017-02-01 武汉三源特种建材有限责任公司 Concrete compaction anti-cracking agent
CN107140915A (en) * 2017-06-20 2017-09-08 和县明生环保材料有限责任公司 A kind of light heat-resisting tailings hollow brick and its preparation

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
杨春平等主编: "《工业固体废物处理与处置》", 30 June 2017, 河南科学技术出版社 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110143802A (en) * 2019-06-17 2019-08-20 山东凯勒蓝房家居文化发展有限公司 Magnesium oxysulfide melamine paper facing negative oxygen ion rock porcelain non-combustible plate and preparation method thereof
CN111393172A (en) * 2020-02-19 2020-07-10 佛山市山有海科技有限公司 Inorganic green body reinforcing agent based on silicate system
CN111393134A (en) * 2020-02-19 2020-07-10 佛山市山有海科技有限公司 Silicate system-based modified bentonite body reinforcing agent
CN111393172B (en) * 2020-02-19 2022-12-20 佛山市山有海科技有限公司 Inorganic green body reinforcing agent based on silicate system
CN111777349A (en) * 2020-07-28 2020-10-16 陕西科技大学 Shrinkage-resistant and crack-resistant additive for cement-based composite material and preparation method thereof
CN111777349B (en) * 2020-07-28 2022-05-10 陕西科技大学 Shrinkage-resistant and crack-resistant additive for cement-based composite material and preparation method thereof

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