CN104286015A - Insecticidal composition containing thiamethoxam and diazinon - Google Patents
Insecticidal composition containing thiamethoxam and diazinon Download PDFInfo
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- CN104286015A CN104286015A CN201410458106.6A CN201410458106A CN104286015A CN 104286015 A CN104286015 A CN 104286015A CN 201410458106 A CN201410458106 A CN 201410458106A CN 104286015 A CN104286015 A CN 104286015A
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- diacloden
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Abstract
The invention discloses an insecticidal composition containing thiamethoxam and diazinon. The insecticidal composition comprises a first active ingredient thiamethoxam, a second active ingredient diazinon and commonly-used auxiliary ingredients, wherein weight ratio of thiamethoxam to diazinon is 40:1-1:40, preferably 10:1-1:20. Through a lot of indoor and outdoor tests, it shows that the insecticidal composition has an obvious synergic effect, has a good effect of controlling homopteran pests, lepidopteran pests and underground pests on crops, and especially has a more obvious effect of controlling aphid, leafhopper, rice planthopper, Chilo suppressalis, tryporyza incertulas, mole cricket, grub and the like than a separately-used single dosage. Meanwhile, usage amount of pesticides is reduced, residual quantity of pesticides on crops is minimized, environmental pollution is mitigated, and generation of pest resistance to insecticide is delayed.
Description
Technical field
The present invention relates to agricultural insecticide composition and application thereof, specifically with Diacloden and diazinon for active ingredient Pesticidal combination, be mainly used in the control of homoptera pest on crops, lepidoptera pest and soil insect.
Background technology
Diacloden belongs to second generation nicotinoids efficient pesticides, and the mechanism of action for suppressing insect CNS nicotinic acetylcholine esterase acceptor, and then blocks the normal conduction of insect CNS, and paralysis is dead to cause insect to occur.Its not only have tag, stomach toxicity, systemic activity, and there is active high, the feature such as safety good, insecticidal spectrum is wide and speed of action is fast, the lasting period is long.Can effectively prevent and treat the various pests such as various aphid, leafhopper, plant hopper, aleyrodid, grub, colorado potato beetle, nematode, ground beetle, leaf miner.Both can be used for cauline leaf process, seed treatment, also can be used for soil treatment.
Diazinon belongs to organophosphorus insecticides, and its mechanism of action is acetylcholine esterase inhibition, has good preventive effect to the various pests such as Lepidoptera, Homoptera, also can dress seed simultaneously and prevent and treat the soil insect of various crop.It has tag, stomach toxicity, fumigation, the effect such as interior suction, can be used for the insects such as control striped rice borer, paddy stem borer, leaf-roller, rice water weevil, rice fulgorid, cotton bollworm, two spotted spider mite, cabbage caterpillar, grub.But this kind is due to long-term use, some insect has created different pesticide resistance.
The resistance problems of pest is global problems, is the emphasis problem that agricultural science and technology worker pays close attention to always.Along with the continuity year in year out of Chemical Control of Harmful Insects, the increase of Pesticide use amount and the not factor such as scientifical use agricultural chemicals, cause pest resistance day by day serious, the pest species producing resistance is on the increase.Meanwhile, the use agricultural chemicals of high strength, result in that Practice for Pesticide Residue in Agricultural Products exceeds standard, the series of problems such as contaminated environment and the increase of peasant's drug cost, is unfavorable for the sustainable development of agricultural.
Therefore, development is efficient, low toxicity, low-residual, the different mechanism of action, have again the complex preparation of synergistic function simultaneously, not only contribute to the generation delaying pest resistance to insecticide, but also the service life of pesticide species can be extended, reduce using dosage, cost-saving, reduce the pollution to environment.
The compounded formula screening of the present inventor to Diacloden and diazinon conducts in-depth research, find that Diacloden and diazinon carry out composite, within the scope of certain compound proportion, there is obvious synergistic function, in actual use, to the homoptera pest on crops, lepidoptera pest and soil insect as aphid, leafhopper, rice fulgorid, striped rice borer, paddy stem borer, mole cricket, grub etc. all have good control efficiency, after further study, the present invention is completed.
Summary of the invention
The object of the present invention is to provide a kind of Pesticidal combination containing Diacloden and diazinon, this complex composition has obvious synergistic function, expand insecticidal spectrum, be mainly used in homoptera pest on crops, lepidoptera pest and soil insect, as the control of aphid, leafhopper, rice fulgorid, striped rice borer, paddy stem borer, mole cricket, grub etc.
Another object of the present invention is to the Pesticidal combination containing Diacloden and diazinon, the generation that in use can reduce dosage, reduce the residual quantity of agricultural chemicals on crops, delay pest resistance to insecticide, it can also be made to be used alone to compare than single dose to the control efficiency of various insect and to significantly improve, laborsaving, economical, reduce farmer's burdens.
Technical solution of the present invention: a kind of Pesticidal combination containing Diacloden and diazinon, with Diacloden and diazinon for active ingredient, the weight ratio of Diacloden and diazinon is 40:1 ~ 1:40, preferred weight ratio is 10:1 ~ 1:20, Diacloden and diazinon weight summation percentage by weight are in the composition 0.1% ~ 85%, and all the other are allow in agricultural chemicals to use and acceptable auxiliary element.
Described auxiliary element is one or more the combination in solvent, emulsifier, wetting agent, dispersant, stabilizing agent, antifreezing agent, thickener, binding agent, disintegrant, defoamer, bleeding agent, synergist, film forming agent, preservative, warning colouration and filler, above material is known substance conventional in pesticidal preparations, change to some extent according to being prepared into the different formulations of pesticide, but be not particularly limited.
Pesticidal combination of the present invention can be prepared into any one formulation that applicable agricultural production uses by known method, reasonable formulation has suspension seed-coating agent, suspending agent, aqueous emulsion, microemulsion, water dispersible granules, wetting powder and granule.
The frequency of administration of Pesticidal combination of the present invention and amount of application change with crops, insect, weather condition and have small variations, can by the object using suitable dosage reach effectively control.
Compared with prior art, the invention has the advantages that:
1, Diacloden and diazinon is composite has synergistic function, is used alone the control efficiency significantly improved insect, expands insecticidal spectrum simultaneously, solve the defect to some insect weak effect when single dose is used alone than single dose.
2, Diacloden and diazinon two kinds of active ingredients composite, decrease Pesticide use amount, reduce use cost, alleviate pollution to environment, delayed the generation of pest resistance to insecticide, add the service life of agricultural chemicals.
Embodiment
In order to understand essence of the present invention better, below in conjunction with embodiment, content of the present invention is described further, but can not limitation of the present invention be considered as.
(1) Formulation Example.
In following each embodiment, active ingredient adopts the former medicine of 98% Diacloden and the former medicine of 95% diazinon, and each component percentages is weight percentage.
Embodiment 1:22% Diacloden diazinon suspending agent.
Diacloden 2%, diazinon 20%, alkylphenol-formaldehyde resin polyvinyl sulfonate 5%, dodecyl sodium sulfate 5%, polyethylene glycol 3%, carboxymethyl cellulose 1%, silicone oil 0.1%, deionized water supplies 100%.By above-mentioned active ingredient, dispersant, wetting agent, antifreezing agent, thickener and defoamer sand milling in high speed shear dispersion, sand mill, the high dispersive formed in water-medium, stable suspension system, can obtain 22% Diacloden diazinon suspending agent.
Embodiment 2:35% Diacloden diazinon aqueous emulsion.
Diacloden 5%, diazinon 30%, dimethylbenzene 10%, cyclohexanone 5%, castor oil polyoxyethylene ether 10%, sodium lignin sulfonate 2%, xylitol 1%, glycerine 1%, deionized water supplies 100%.Above-mentioned active ingredient, solvent, emulsifier, dispersant and stabilizing agent are mixed to form oil phase, antifreezing agent dissolves and forms aqueous phase in water, slowly oil phase is added in aqueous phase under clipper effect, and continue to shear about 30 minutes, the Diacloden diazinon aqueous emulsion of obtained 35%.
Embodiment 3:40% Diacloden diazinon microemulsion.
Diacloden 10%, diazinon 30%, cyclohexanone 20%, castor oil polyoxyethylene ether 10%, sodium citrate 2%, organosilicon 1%, double to kill 2%, deionized water supplies 100%.Active ingredient solvent is dissolved completely, and then add emulsifier, stabilizing agent, bleeding agent, synergist mix, finally add deionized water, after fully stirring, the Diacloden diazinon microemulsion of 40% can be obtained.
Embodiment 4:50% Diacloden diazinon wetting powder.
Diacloden 10%, diazinon 40%, alkylphenol polyoxyethylene 10%, lauryl sodium sulfate 10%, kaolin supplies 100%.By above-mentioned, active ingredient, dispersant, wetting agent and filler are mixed, again through air-flow crushing after mechanical crushing, mix, 50% Diacloden diazinon wetting powder can be obtained.
Embodiment 5:70% Diacloden diazinon water dispersible granules.
Diacloden 10%, diazinon 60%, polycarboxylate 5%, calcium dodecyl benzene sulfonate 5%, ammonium sulfate 2%, diatomite supplies 100%.Above-mentioned active ingredient, dispersant, wetting agent, disintegrant and filler are mixed, pulverize with micro jet, through mediating, then adding in fluidized-bed granulation dryer and carrying out granulation, drying, screening, 70% Diacloden diazinon water dispersible granules can be obtained.Embodiment 6:10% Diacloden diazinon suspension seed-coating agent.
Diacloden 1%, diazinon 9%, lauryl sodium sulfate 2%, polyoxyethylene poly-oxygen propylene aether block copolymer 3%, glycerine 5%, dimethyl silicone polymer 0.1%, Sodium Benzoate 0.5%, sodium carboxymethylcellulose 2%, xanthans 1%, basic rhodamine 1%, deionized water supplies 100%.Above-mentioned active ingredient, wetting agent, dispersant, antifreezing agent, defoamer, preservative, film forming agent, thickener and warning colouration are mixed, grind 3 ~ 4 hours in sand mill, make particle diameter all below 5 μm, filtration can obtained 10% Diacloden diazinon suspension seed-coating agent.
Embodiment 7:1.5% Diacloden diazinon granule.
Diacloden 0.1%, diazinon 1.4%, sodium butylnaphthalenesulfonate 10%, alkylphenol polyoxyethylene 10%, carboxymethyl cellulose 15%, clay complements to 100%.Above-mentioned active ingredient and auxiliary agent are mediated through mixing and water adding, uses pinch-out granulator pinch out and be shaped, afterwards by particle fluid-bed drying, screening, 1.5% Diacloden diazinon granule can be obtained.
(2) the indoor biological determination of activity of the present composition and field control effectiveness test.
Embodiment 8: Diacloden and diazinon are to the indoor joint toxicity measuring of rice hoppers.
For examination worm: indoor rice fulgorid 3 nymph in age for many generations raising health.
Reagent agent: the former medicine of 98% Diacloden and the former medicine of 95% diazinon.
Test method: adopt rice-stem dipping method to measure, specific as follows.
First choose 2 leaf 1 heart rice seedling 15 strains, within 30 seconds, take out nature afterwards supplying dipping in reagent liquid and dry, encase root moisturizing with wet absorbent cotton, outsourcing preservative film, be placed in teat glass (200 × 30mm), every concentration repeats for 4 times.Then with rice fulgorid 3 nymph in age of writing brush access ether light anesthesia, often pipe 20, the white gauze of the mouth of pipe is tightened, and is placed in indoor observation.After process, 72h investigation examination worm death condition (gently stinging examination worm without autonomic response for judging the standard of examination worm death with pin), records dead borer population and total borer population.
Carry out statistical analysis with DPS statistical analysis software, calculate the LC of each medicament
50, and the co-toxicity coefficient (CTC value) of mixture is calculated according to the abundant method of Sun Yun.
Actual measurement toxicity index (ATI)=(standard agent LC
50/ reagent agent LC
50) × 100.
In theoretical toxicity index (TTI)=A medicament toxicity index × mixture A percentage composition+B medicament toxicity index × mixture in the percentage composition of B.
Co-toxicity coefficient (CTC)=[the theoretical toxicity index (TTI) of mixture actual measurement toxicity index (ATI)/mixture] × 100.
According to the NY/T11547.7-2006 insecticide combination effect criteria for classifying: co-toxicity coefficient (CTC) >=120 shows as synergistic effect; Co-toxicity coefficient (CTC)≤80 shows as antagonism; 80 < co-toxicity coefficient (CTC) < 120 show as summation action.
As can be seen from Table 1, when Diacloden and diazinon are composite in the scope of 40:1 ~ 1:40 (by weight), co-toxicity coefficient (CTC) is all greater than 120, synergistic function is shown to rice hoppers, especially time composite in the scope of 10:1 ~ 1:20 (by weight), synergistic function is more obvious, and co-toxicity coefficient (CTC) is all greater than 170, visible Diacloden and diazinon is composite has reasonability and feasibility.
Table 1, Diacloden and diazinon are to the indoor joint toxicity measuring result of rice hoppers.
| Medicament title and proportioning (weight ratio) | LC 50(mg/L) | ATI | TTI | CTC |
| Diacloden | 1.78 | 100.00 | - | - |
| Diazinon | 18.24 | 9.76 | - | - |
| Diacloden: diazinon (40:1) | 1.43 | 124.48 | 97.80 | 127.28 |
| Diacloden: diazinon (30:1) | 1.31 | 135.88 | 97.09 | 139.95 |
| Diacloden: diazinon (20:1) | 1.19 | 149.58 | 95.70 | 156.30 |
| Diacloden: diazinon (10:1) | 1.08 | 164.81 | 91.80 | 179.53 |
| Diacloden: diazinon (1:1) | 1.78 | 100.00 | 54.88 | 182.22 |
| Diacloden: diazinon (1:10) | 4.53 | 39.29 | 17.96 | 218.76 |
| Diacloden: diazinon (1:20) | 7.04 | 25.28 | 14.06 | 179.80 |
| Diacloden: diazinon (1:30) | 9.58 | 18.58 | 12.67 | 146.65 |
| Diacloden: diazinon (1:40) | 12.25 | 14.53 | 11.96 | 121.49 |
Embodiment 9: Diacloden and diazinon are to the indoor joint toxicity measuring test of soil insect grub.
For examination worm: field gathers and raises the grub of breeding in indoor.
Reagent agent: the former medicine of 98% Diacloden and the former medicine of 95% diazinon.
Test method: adopt soil to mix medicine method and measure, specific as follows.
Be the mother liquor that solvent is mixed with certain mass concentration with acetone by each reagent agent, and with the aqueous solution containing 0.1% POLYSORBATE 80, above each mother liquor be diluted to certain mass concentration respectively for examination.Sandy loam crosses 850 μm of sieves, disinfects 4h at one hundred and twenty degrees centigrade with far infrared flash dryer.Take as above dry soil samples 1.0Kg/ part, get a certain amount of liquid and add in dry ground, then after adding suitable quantity of water, make its soil moisture content about 18%.Being stirred in " V " type mixer by this pesticide-clay mixture makes it mix in 2 minutes, load the glass having accessed 1 grub and support scolite (diameter 1.8cm, high 8cm) in, put into a small amount of just germinated wheat seed as food, plug is escaped to prevent and treat examination worm beyond the Great Wall.Using the distilled water containing 0.1% POLYSORBATE 80 and 0.1% acetone as blank.Often process examination worm is no less than 60, repeats 3 times.By process after examination worm be placed in temperature be about 24 degrees Celsius, humidity be about 60% greenhouse raise.Within 5 days, check examination worm death condition (death standard: polypide obviously shrinks or tactile can not normally creeping) afterwards, and calculate lethality.
Carry out statistical analysis with DPS statistical analysis software, calculate the LC of each medicament
50, and the co-toxicity coefficient (CTC value) of mixture is calculated according to the abundant method of Sun Yun.
Actual measurement toxicity index (ATI)=(standard agent LC
50/ reagent agent LC
50) × 100.
In theoretical toxicity index (TTI)=A medicament toxicity index × mixture A percentage composition+B medicament toxicity index × mixture in the percentage composition of B.
Co-toxicity coefficient (CTC)=[the theoretical toxicity index (TTI) of mixture actual measurement toxicity index (ATI)/mixture] × 100.
According to the NY/T11547.7-2006 insecticide combination effect criteria for classifying: co-toxicity coefficient (CTC) >=120 shows as synergistic effect; Co-toxicity coefficient (CTC)≤80 shows as antagonism; 80 < co-toxicity coefficient (CTC) < 120 show as summation action.
As can be seen from Table 2, when Diacloden and diazinon are composite in the scope of 40:1 ~ 1:40 (by weight), co-toxicity coefficient (CTC) is all greater than 120, synergistic function is shown to soil insect grub, especially time composite in the scope of 10:1 ~ 1:20 (by weight), synergistic function is more obvious, and co-toxicity coefficient (CTC) is all greater than 190, visible Diacloden and diazinon is composite has reasonability and feasibility.
Table 2, Diacloden and diazinon are to the indoor joint toxicity measuring of soil insect grub.
| Medicament title and proportioning (weight ratio) | LC 50(mg/L) | ATI | TTI | CTC |
| Diacloden | 4.39 | 100.00 | - | - |
| Diazinon | 27.58 | 15.92 | - | - |
| Diacloden: diazinon (40:1) | 3.35 | 131.04 | 97.95 | 133.78 |
| Diacloden: diazinon (30:1) | 3.04 | 144.41 | 97.29 | 148.43 |
| Diacloden: diazinon (20:1) | 2.81 | 156.23 | 96.00 | 162.74 |
| Diacloden: diazinon (10:1) | 2.49 | 176.31 | 92.36 | 190.89 |
| Diacloden: diazinon (1:1) | 3.76 | 116.76 | 57.96 | 201.45 |
| Diacloden: diazinon (1:10) | 7.18 | 61.14 | 23.56 | 259.51 |
| Diacloden: diazinon (1:20) | 10.34 | 42.46 | 19.92 | 213.15 |
| Diacloden: diazinon (1:30) | 14.01 | 31.33 | 18.63 | 168.17 |
| Diacloden: diazinon (1:40) | 17.64 | 24.89 | 17.97 | 138.51 |
Embodiment 10: to the field control effectiveness test of rice hoppers.
Adopt embodiment 2 (35% Diacloden diazinon aqueous emulsion) for preventing and treating rice hoppers, investigation insect population radix before dispenser, after medicine, 3d, 7d, 10d investigate residual borer population of living respectively, investigation Shi Mei community is undertaken by parallel jump method, investigate 20 points, 2 clumps often, shake or beating rice clump, between statistics rice clump, the plant hopper quantity of floating on water, calculates control efficiency.Control efficiency computational methods are as follows:
Preventive effect (%)=(1-CK
1× Pt
1/ CK
2× Pt
2) × 100.
Wherein: CK
1represent insect population number before the medicine of check plot; Pt
1represent insect population number after treatment region medicine;
CK
2represent insect population number after the medicine of check plot; Pt
2represent insect population number before treatment region medicine;
As can be seen from Table 3, when 35% Diacloden diazinon aqueous emulsion consumption is 50-60g.a.i./ha, after medicine, 3d, 7d, 14d are all better than each single dose to the preventive effect of rice hoppers and are used alone, and after medicine, 14d preventive effect all still reaches more than 85% simultaneously, illustrates that this compound drug has good lasting effect.In pilot survey process, do not find that this compound drug produces poisoning to paddy rice.
The result of the test of table 3, each process chemical control rice hoppers.
Embodiment 11: to the field control effectiveness test of wheat grub.
Adopting embodiment 7 (1.5% Diacloden diazinon granule) for preventing and treating wheat grub, adopting randomized arrangement method in setting community, field, each community 40m
2, adopt clear water contrast, each process repeats for 3 times.Medicament is imposed near wheat seedling base portion according to the effective ingredient consumption ditch of test setting, covers thin soil.Within after dispenser 7 days, observe the withered calculation of wheat seedling, calculate withered heart rate, with reference to the withered heart rate of contrast, calculate preventive effect.Control efficiency computational methods are as follows:
Control efficiency (%)=(the withered heart rate of the withered heart rate-treatment region in check plot) × 100/ withered heart rate in check plot.
The result of the test of table 4, each process chemical control wheat grub.
As can be seen from Table 4, when 1.5% Diacloden diazinon granule consumption is 500-600g.a.i./ha, after medicine, 7d is all better than each single dose to the preventive effect of wheat grub and is used alone, and after medicine, 7d preventive effect all still reaches more than 85% simultaneously, illustrates that this compound drug has good lasting effect.In pilot survey process, do not find that this compound drug produces poisoning to wheat.
In sum, the present invention adopts two kinds of active components to be the complex composition of Diacloden and diazinon, has synergistic function, compared with existing unitary agent, insecticidal effect significantly improves, and the lasting period is long, to crop safety, be worth applying in agricultural production.
Claims (4)
1. one kind contains the Pesticidal combination of Diacloden and diazinon, it is characterized in that: active ingredient is Diacloden and diazinon, the weight ratio of Diacloden and diazinon is 40:1 ~ 1:40, and Diacloden and diazinon total weight percent is in the composition 0.1 ~ 85%.
2. a kind of Pesticidal combination containing Diacloden and diazinon according to claim 1, is characterized in that: the weight ratio of Diacloden and diazinon is 10:1 ~ 1:20.
3. a kind of Pesticidal combination containing Diacloden and diazinon according to claim 1, is characterized in that: the formulation of said composition is the one in suspension seed-coating agent, suspending agent, aqueous emulsion, microemulsion, water dispersible granules, wetting powder and granule.
4. a kind of Pesticidal combination containing Diacloden and diazinon according to claim 1 is applicable to homoptera pest, lepidoptera pest and soil insect on control crops.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104472531A (en) * | 2014-12-03 | 2015-04-01 | 联保作物科技有限公司 | Insecticide composition as well as application and preparation of insecticide composition |
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| CN102273444A (en) * | 2011-09-13 | 2011-12-14 | 广西田园生化股份有限公司 | Ultralow volume liquid containing thiamethoxam |
| CN102379297A (en) * | 2011-09-13 | 2012-03-21 | 广西田园生化股份有限公司 | Macrolide compound ultralow volume formulation |
| CN103875704A (en) * | 2014-03-19 | 2014-06-25 | 黄业新 | Pesticide granules containing clothianidin and diazinon |
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2014
- 2014-09-10 CN CN201410458106.6A patent/CN104286015A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101999399A (en) * | 2010-10-21 | 2011-04-06 | 广州甘蔗糖业研究所 | Sugarcane insecticide containing neonicotinoid insecticide |
| CN102273444A (en) * | 2011-09-13 | 2011-12-14 | 广西田园生化股份有限公司 | Ultralow volume liquid containing thiamethoxam |
| CN102379297A (en) * | 2011-09-13 | 2012-03-21 | 广西田园生化股份有限公司 | Macrolide compound ultralow volume formulation |
| CN103875704A (en) * | 2014-03-19 | 2014-06-25 | 黄业新 | Pesticide granules containing clothianidin and diazinon |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104472531A (en) * | 2014-12-03 | 2015-04-01 | 联保作物科技有限公司 | Insecticide composition as well as application and preparation of insecticide composition |
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Application publication date: 20150121 |