CN104285965A - Bactericidal composition for preventing and treating pea fusarium nivale - Google Patents

Bactericidal composition for preventing and treating pea fusarium nivale Download PDF

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Publication number
CN104285965A
CN104285965A CN201410543819.2A CN201410543819A CN104285965A CN 104285965 A CN104285965 A CN 104285965A CN 201410543819 A CN201410543819 A CN 201410543819A CN 104285965 A CN104285965 A CN 104285965A
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China
Prior art keywords
bactericidal composition
preventing
fludioxonil
fluquinconazole
filler
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CN201410543819.2A
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Chinese (zh)
Inventor
迟宗磊
藏伟功
丁振洋
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Jinan Cavin Biotechnology Co Ltd
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Jinan Cavin Biotechnology Co Ltd
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Priority to CN201410543819.2A priority Critical patent/CN104285965A/en
Publication of CN104285965A publication Critical patent/CN104285965A/en
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Abstract

The invention belongs to the field of pesticides and particularly relates to a bactericidal composition for preventing and treating pea fusarium nivale The effective components of the bactericidal composition provided by the invention comprise: fludioxonil and fluquinconazole. The effective components-the fludioxonil and the fluquinconazole of the composition provided by the invention are mutually matched without conflict; the composition provided by the invention has a good synergistic effect within a certain range, the prevention effect is higher than that of a single agent, and the pesticide effect is relatively durable; the bactericidal composition reduces the drug resistance, reduces the repeated use times of pesticide, reduces the use amount of the pesticide and lowers the application cost of the pesticide; the composition provided by the invention has special effects on pea fusarium nivale and downy mildew and can also be used for preventing and treating cucumber downy mildew and grape downy mildew and downy mildew of other fruits and vegetables.

Description

The bactericidal composition of rotten Fusariumsp avenged by control pea
Technical field
The invention belongs to pesticide field, being specifically related to a kind of bactericidal composition avenging rotten Fusariumsp for preventing and treating pea.
background technology
Avenge rotten Fusariumsp aerial hyphae light fleece shape or one-tenth pionnote on PSA medium, sticky spore layer is yellowish pink to honey gold.The root of infringement seedling, causes dead seedling.The root of infringement seedling, causes dead seedling, mostly occurs in 2 ~ 4 leaf phases of seedling.The sick seedling flavescence look of their early stage or darkviolet, root browning, namely wilts withered soon, and serious causing is short of seedling disconnected ridge.
Germ survives with mycelium or spore or survives the winter in soil, is soil-borne disease.The plot susceptible disease of temperature low, rainy time in general 5, June or hypsography low-lying, impeded drainage.
(1) crop rotation in more than 3 years is carried out.
(2) the plot cultivation millet of high and dry easy draining is selected.
(3) chemical control 35% Apron (metalaxyl) seed dressing is dressed seed or the wet-mixing that adds water by grain weight 0.2% ~ 0.3%, or 50% first frost copper wetting powder dislikes white bacterium pellet (Ceftlofur) wetting powder by grain weight 0.2% ~ 0.25% seed dressing by grain weight 0.3% ~ 0.4% seed dressing, 64% Sandofan wetting powder by the grain weight seed dressing, 80% of 0.4% ~ 0.5%.After dosing is mixed thoroughly, should sow immediately.
Fludioxonil is a kind of contact bactericide, can be used for seed treatment, can prevent and treat seed-borne fungi and soilborne fungal disease.
For wheat, barley, corn, pea, rape, paddy rice, vegetables, grape, lawn, ornamental crops leaf surface treatment, control snow rotten Fusariumsp, wheat net raw meat black rot, rhizoctonia solani etc., have special efficacy to gray mold; To cereal and non-cereal seed process, control kind passes and soil-borne disease bacterium, as Alternaria, Ascochyta, aspergillus, Fusarium, Helminthosporium, Rhizoctonia and Penicillium bacterium. 
Fludioxonil is non-interior suction benzene pyroles suspension seed-coating agent, high-efficiency broad spectrum.Extraordinary preventive effect is had to the microbial kind biography of many cause of diseases such as sac fungi, basidiomycetes, imperfect fungus and soil-borne disease.It suppresses mycelial growth by suppressing the relevant transhipment of glucose phosphorylated, finally causes germ dead.The mechanism of action of its uniqueness, does not have cross resistance with the bactericide that other is known.When seed germination, fludioxonil can be absorbed on a small quantity, thus can control the germ of seed and caryopsis inside; Fludioxonil moves hardly in soil simultaneously, therefore, it is possible to be retained in the region around seed always, provides long-term protection to crop root.The formulation that fludioxonil is excellent in addition makes seed pelleting film forming fast, does not come off.Fludioxonil is to crop seed safety, and better tolerance, capsuled seed can directly be sowed, and also can put to next sowing sowing season under suitable storage requirement.Fludioxonil is one of product of whole world acquisition few in number EPA EPA " low-risk " certification.Fludioxonil is widely used in various crop, as cotton, wheat, peanut, soybean, paddy rice etc.
The Fluquinconazole mechanism of action and feature Main Function mechanism are sterol demethylation inhibitors, and the biosynthesis of the cell membrane important composition composition ergosterol of destruction and prevention germ, causes cell membrane not formed, and make germ dead.There is interior absorption, protection and therapeutic activity.
Suitable for crop wheat, barley, paddy rice, beet, rape, legume, vegetables, grape and apple etc.To under crop safety recommended dose to crop safety, without poisoning.Controlling object control by the fungus-caused multiple diseases of Basidiomycetes, Fungi Imperfecti and Ascomycetes as can Major Diseases on effectively preventing apple as apple scab and apple mildew, to following pathogen as Powdery Mildew, chain sclerotinia sclerotiorum, the mould genus of tail spore, Phoma, Septoria, bury the fungus-caused diseases such as Sclerotinia, Puccinia, hunchbacked spore Rust and nuclear disk mattress genus and all have good control efficiency.
Summary of the invention
In order to solve above-mentioned technical problem, the invention provides a kind of bactericidal composition avenging rotten Fusariumsp for preventing and treating pea.
The present invention avenges rotten Fusariumsp bactericidal composition for preventing and treating pea is realized by following technical scheme:
Avenge the bactericidal composition of rotten Fusariumsp for preventing and treating pea, the active ingredient of this bactericidal composition comprises: fludioxonil, Fluquinconazole.
Preferably, above-mentioned fludioxonil, the part by weight of Fluquinconazole are 1-5:2-5.
The part by weight of above-mentioned fludioxonil, Fluquinconazole is 2:3.
Avenge the bactericidal composition of rotten Fusariumsp for preventing and treating pea, this bactericidal composition also comprises auxiliary agent, and described active ingredient fludioxonil, Fluquinconazole account for the 30-65% of total composition.
In bactericidal composition of the present invention, auxiliary agent is at least one in dispersant, wetting agent, emulsifier, antifreezing agent, defoamer, thickener, disintegrant, stabilizing agent, filler, solvent, and described solvent is organic solvent or water.
Its formulation of above-mentioned bactericidal composition is any one in wetting powder, suspending agent, aqueous emulsion, water dispersible granules and missible oil.
The bactericidal composition avenging rotten Fusariumsp for preventing and treating pea of the present invention, when bactericidal composition is wetting powder, the parts by weight of each component are: fludioxonil 10-50, Fluquinconazole 20-50, dispersant 1 ~ 20, wetting agent 1 ~ 10, filler 1 ~ 70, by above-mentioned weight proportion by fludioxonil and Fluquinconazole and the mixing of dispersant, wetting agent and filler, uniform stirring in stirred tank, mixes again, obtains wetting powder bactericidal composition after airslide disintegrating mill is pulverized.
Above-mentioned dispersant is: at least one in polycarboxylate, lignosulfonates, alkylphenol polyoxyethylene formaldehyde condensation products sulphate, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate, fatty acid glyceride APEO;
Wetting agent is: lauryl sodium sulfate, calcium dodecyl benzene sulfonate, at least one pulled open in powder Ningnanmycin X., wetting and penetrating agent F, alkylnaphthalene sulfonate, polyoxyethylene tri-styryl phosphenylic acid salt, spaonin powder, silkworm excrement, soapberry powder;
Filler is: at least one in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate.
Preferably, above-mentioned dispersant is: naphthalene sulfonic acid-formaldehyde condensation product sodium salt;
Wetting agent is: polyoxyethylene tri-styryl phosphenylic acid salt;
Filler is: diatomite.
Beneficial effect of the present invention is,
(1) present composition effective active composition fludioxonil, the mutual mixture of both Fluquinconazoles can not produce conflict;
(2) present composition has good synergistic effect within the specific limits, and preventive effect is higher than single dose, and drug effect is more lasting;
(3) delay drug-fast generation, decreased agricultural chemicals Reusability number of times, reduced Pesticide use amount, reduce the use cost of agricultural chemicals;
(4) present composition avenges rotten Fusariumsp to pea, downy mildew has special efficacy, also can be used in the control of other fruits and vegetables such as cucumber downy mildew, downy mildew of garpe.
Embodiment
Below in conjunction with specific embodiment, the present invention is further described, so that those skilled in the art more understands the present invention, but does not therefore limit the present invention.
Embodiment 1
The bactericidal composition avenging rotten Fusariumsp for preventing and treating pea of the present invention, when bactericidal composition is wetting powder, the parts by weight of each component are: fludioxonil 70, dispersant 6, wetting agent 5, filler 40, by above-mentioned weight proportion by fludioxonil and Fluquinconazole and the mixing of dispersant, wetting agent and filler, uniform stirring in stirred tank, mixes again, obtains wetting powder bactericidal composition after airslide disintegrating mill is pulverized.
Above-mentioned dispersant is: naphthalene sulfonic acid-formaldehyde condensation product sodium salt;
Wetting agent is: polyoxyethylene tri-styryl phosphenylic acid salt;
Filler is: diatomite.
The anti-efficiency that above-mentioned medicine avenges rotten Fusariumsp for pea reaches 94.1%.
Comparative example 1
The bactericidal composition avenging rotten Fusariumsp for preventing and treating pea of the present invention, when bactericidal composition is wetting powder, the parts by weight of each component are: fludioxonil 40, Fluquinconazole 30, dispersant 6, wetting agent 5, filler 40, by above-mentioned weight proportion by fludioxonil and Fluquinconazole and the mixing of dispersant, wetting agent and filler, uniform stirring in stirred tank, mixes again, obtains wetting powder bactericidal composition after airslide disintegrating mill is pulverized.
Above-mentioned dispersant is: naphthalene sulfonic acid-formaldehyde condensation product sodium salt;
Wetting agent is: polyoxyethylene tri-styryl phosphenylic acid salt;
Filler is: diatomite.
The anti-efficiency that above-mentioned medicine avenges rotten Fusariumsp for pea reaches 80.5%.
Comparative example 2
The bactericidal composition avenging rotten Fusariumsp for preventing and treating pea of the present invention, when bactericidal composition is wetting powder, the parts by weight of each component are: Fluquinconazole 70, dispersant 6, wetting agent 5, filler 40, by above-mentioned weight proportion by fludioxonil and Fluquinconazole and the mixing of dispersant, wetting agent and filler, uniform stirring in stirred tank, mixes again, obtains wetting powder bactericidal composition after airslide disintegrating mill is pulverized.
Above-mentioned dispersant is: naphthalene sulfonic acid-formaldehyde condensation product sodium salt;
Wetting agent is: polyoxyethylene tri-styryl phosphenylic acid salt;
Filler is: diatomite.
The anti-efficiency that above-mentioned medicine avenges rotten Fusariumsp for pea reaches 79.2%.
As can be seen from above contrast, its effect composite of fludioxonil and Fluquinconazole is better than single fludioxonil or Fluquinconazole.
Embodiment 2
The bactericidal composition avenging rotten Fusariumsp for preventing and treating pea of the present invention, when bactericidal composition is wetting powder, the parts by weight of each component are: fludioxonil 40, Fluquinconazole 35, dispersant 10, wetting agent 8, filler 10, by above-mentioned weight proportion by fludioxonil and Fluquinconazole and the mixing of dispersant, wetting agent and filler, uniform stirring in stirred tank, mixes again, obtains wetting powder bactericidal composition after airslide disintegrating mill is pulverized.
Above-mentioned dispersant is: alkylphenol polyoxyethylene formaldehyde condensation products sulphate;
Wetting agent is: lauryl sodium sulfate;
Filler is: diatomite.
Embodiment 3
The bactericidal composition avenging rotten Fusariumsp for preventing and treating pea of the present invention, when bactericidal composition is wetting powder, the parts by weight of each component are: fludioxonil 45, Fluquinconazole 30, dispersant 8, wetting agent 6, filler 40, by above-mentioned weight proportion by fludioxonil and Fluquinconazole and the mixing of dispersant, wetting agent and filler, uniform stirring in stirred tank, mixes again, obtains wetting powder bactericidal composition after airslide disintegrating mill is pulverized.
Above-mentioned dispersant is: alkylphenol polyoxyethylene;
Wetting agent is: polyoxyethylene tri-styryl phosphenylic acid salt;
Filler is: bentonite.
Embodiment 4
The bactericidal composition avenging rotten Fusariumsp for preventing and treating pea of the present invention, when bactericidal composition is wetting powder, the parts by weight of each component are: fludioxonil 30, Fluquinconazole 40, dispersant 10, wetting agent 8, filler 45, by above-mentioned weight proportion by fludioxonil and Fluquinconazole and the mixing of dispersant, wetting agent and filler, uniform stirring in stirred tank, mixes again, obtains wetting powder bactericidal composition after airslide disintegrating mill is pulverized.
Above-mentioned dispersant is: aliphatic amine polyoxyethylene ether;
Wetting agent is: alkylnaphthalene sulfonate;
Filler is: starch.
Embodiment 5
The bactericidal composition avenging rotten Fusariumsp for preventing and treating pea of the present invention, when bactericidal composition is wetting powder, the parts by weight of each component are: fludioxonil 20, Fluquinconazole 40, dispersant 15, wetting agent 8, filler 45, by above-mentioned weight proportion by fludioxonil and Fluquinconazole and the mixing of dispersant, wetting agent and filler, uniform stirring in stirred tank, mixes again, obtains wetting powder bactericidal composition after airslide disintegrating mill is pulverized.
Above-mentioned dispersant is: naphthalene sulfonic acid-formaldehyde condensation product sodium salt;
Wetting agent is: calcium dodecyl benzene sulfonate;
Filler is: bentonite.

Claims (9)

1. avenging a bactericidal composition for rotten Fusariumsp for preventing and treating pea, it is characterized in that, the active ingredient of described bactericidal composition comprises: fludioxonil, Fluquinconazole.
2. a kind of bactericidal composition avenging rotten Fusariumsp for preventing and treating pea as claimed in claim 1, it is characterized in that, described fludioxonil, the part by weight of Fluquinconazole are 1-5:2-5.
3. a kind of bactericidal composition avenging rotten Fusariumsp for preventing and treating pea as claimed in claim 1, it is characterized in that, the part by weight of described fludioxonil, Fluquinconazole is 2:3.
4. a kind of bactericidal composition avenging rotten Fusariumsp for preventing and treating pea as claimed in claim 1, it is characterized in that, described bactericidal composition also comprises auxiliary agent, and described active ingredient fludioxonil, Fluquinconazole account for the 30-65% of total composition.
5. a kind of bactericidal composition avenging rotten Fusariumsp for preventing and treating pea as claimed in claim 1, it is characterized in that, in described bactericidal composition, auxiliary agent is at least one in dispersant, wetting agent, emulsifier, antifreezing agent, defoamer, thickener, disintegrant, stabilizing agent, filler, solvent, and described solvent is organic solvent or water.
6. a kind of bactericidal composition avenging rotten Fusariumsp for preventing and treating pea as claimed in claim 1, it is characterized in that, its formulation of described bactericidal composition is any one in wetting powder, suspending agent, aqueous emulsion, water dispersible granules and missible oil.
7. a kind of bactericidal composition avenging rotten Fusariumsp for preventing and treating pea as claimed in claim 1, is characterized in that:
When bactericidal composition is wetting powder, the parts by weight of each component are: fludioxonil 10-50, Fluquinconazole 20-50, dispersant 1 ~ 20, wetting agent 1 ~ 10, filler 1 ~ 70, by above-mentioned weight proportion by fludioxonil and Fluquinconazole and the mixing of dispersant, wetting agent and filler, uniform stirring in stirred tank, mix again after airslide disintegrating mill is pulverized, obtain wetting powder bactericidal composition.
8. a kind of bactericidal composition avenging rotten Fusariumsp for preventing and treating pea as claimed in claim 1, is characterized in that:
Described dispersant is: at least one in polycarboxylate, lignosulfonates, alkylphenol polyoxyethylene formaldehyde condensation products sulphate, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate, fatty acid glyceride APEO;
Described wetting agent is: at least one in lauryl sodium sulfate, calcium dodecyl benzene sulfonate, wetting and penetrating agent F, alkylnaphthalene sulfonate, polyoxyethylene tri-styryl phosphenylic acid salt, spaonin powder, silkworm excrement, soapberry powder;
Described filler is: at least one in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate.
9. a kind of bactericidal composition avenging rotten Fusariumsp for preventing and treating pea as claimed in claim 1, is characterized in that:
Described dispersant is: naphthalene sulfonic acid-formaldehyde condensation product sodium salt;
Described wetting agent is: polyoxyethylene tri-styryl phosphenylic acid salt;
Described filler is: diatomite.
CN201410543819.2A 2014-10-15 2014-10-15 Bactericidal composition for preventing and treating pea fusarium nivale Pending CN104285965A (en)

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Application Number Priority Date Filing Date Title
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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1038441A2 (en) * 1999-03-23 2000-09-27 Novartis AG Fungicidal mixtures

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1038441A2 (en) * 1999-03-23 2000-09-27 Novartis AG Fungicidal mixtures

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
无: "登记证号 PD20095400", 《中国农药信息网》 *

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