CN1042692C - 口香糖胶基及含有该胶基的口香糖的制备方法 - Google Patents
口香糖胶基及含有该胶基的口香糖的制备方法 Download PDFInfo
- Publication number
- CN1042692C CN1042692C CN92110639.4A CN92110639A CN1042692C CN 1042692 C CN1042692 C CN 1042692C CN 92110639 A CN92110639 A CN 92110639A CN 1042692 C CN1042692 C CN 1042692C
- Authority
- CN
- China
- Prior art keywords
- weight
- tocopherol
- composition
- chewing gum
- employed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 title claims abstract description 73
- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 title claims abstract description 61
- 229930003799 tocopherol Natural products 0.000 title claims abstract description 57
- 239000011732 tocopherol Substances 0.000 title claims abstract description 57
- 235000010384 tocopherol Nutrition 0.000 title claims abstract description 57
- 229960001295 tocopherol Drugs 0.000 title claims abstract description 57
- 229940112822 chewing gum Drugs 0.000 claims abstract description 75
- 235000015218 chewing gum Nutrition 0.000 claims abstract description 75
- 239000000203 mixture Substances 0.000 claims abstract description 60
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 claims abstract description 16
- GZIFEOYASATJEH-VHFRWLAGSA-N δ-tocopherol Chemical compound OC1=CC(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1 GZIFEOYASATJEH-VHFRWLAGSA-N 0.000 claims abstract description 14
- 235000010382 gamma-tocopherol Nutrition 0.000 claims abstract description 8
- 235000004835 α-tocopherol Nutrition 0.000 claims abstract description 8
- 239000002076 α-tocopherol Substances 0.000 claims abstract description 8
- 239000002478 γ-tocopherol Substances 0.000 claims abstract description 8
- QUEDXNHFTDJVIY-DQCZWYHMSA-N γ-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-DQCZWYHMSA-N 0.000 claims abstract description 8
- GZIFEOYASATJEH-UHFFFAOYSA-N D-delta tocopherol Natural products OC1=CC(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 GZIFEOYASATJEH-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229940087168 alpha tocopherol Drugs 0.000 claims abstract description 7
- 235000010389 delta-tocopherol Nutrition 0.000 claims abstract description 7
- 229960000984 tocofersolan Drugs 0.000 claims abstract description 7
- 239000002446 δ-tocopherol Substances 0.000 claims abstract description 7
- 238000000034 method Methods 0.000 claims description 33
- 239000003795 chemical substances by application Substances 0.000 claims description 14
- 229920001971 elastomer Polymers 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 14
- 239000000806 elastomer Substances 0.000 claims description 13
- 235000003599 food sweetener Nutrition 0.000 claims description 12
- 239000003765 sweetening agent Substances 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 11
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 9
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 9
- 150000002148 esters Chemical class 0.000 claims description 9
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 9
- 239000011159 matrix material Substances 0.000 claims description 8
- 239000001993 wax Substances 0.000 claims description 8
- 229920002367 Polyisobutene Polymers 0.000 claims description 7
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 7
- 229920003052 natural elastomer Polymers 0.000 claims description 6
- 229920001194 natural rubber Polymers 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 6
- 235000019198 oils Nutrition 0.000 claims description 6
- 239000011118 polyvinyl acetate Substances 0.000 claims description 6
- WGVKWNUPNGFDFJ-DQCZWYHMSA-N β-tocopherol Chemical compound OC1=CC(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C WGVKWNUPNGFDFJ-DQCZWYHMSA-N 0.000 claims description 6
- 244000043261 Hevea brasiliensis Species 0.000 claims description 5
- 238000005984 hydrogenation reaction Methods 0.000 claims description 5
- 229920001206 natural gum Polymers 0.000 claims description 5
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 4
- VHOQXEIFYTTXJU-UHFFFAOYSA-N Isobutylene-isoprene copolymer Chemical compound CC(C)=C.CC(=C)C=C VHOQXEIFYTTXJU-UHFFFAOYSA-N 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000001506 calcium phosphate Substances 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- 239000011347 resin Substances 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 4
- 239000003760 tallow Substances 0.000 claims description 4
- LOVYCUYJRWLTSU-UHFFFAOYSA-N 2-(3,4-dichlorophenoxy)-n,n-diethylethanamine Chemical compound CCN(CC)CCOC1=CC=C(Cl)C(Cl)=C1 LOVYCUYJRWLTSU-UHFFFAOYSA-N 0.000 claims description 3
- BFISPZRRDMGRPB-UHFFFAOYSA-N C=C.C(CCCCCCCCCCC)(=O)O.C(C)(=O)OC=C Chemical compound C=C.C(CCCCCCCCCCC)(=O)O.C(C)(=O)OC=C BFISPZRRDMGRPB-UHFFFAOYSA-N 0.000 claims description 3
- 108010010803 Gelatin Proteins 0.000 claims description 3
- 241001495453 Parthenium argentatum Species 0.000 claims description 3
- 229920000159 gelatin Polymers 0.000 claims description 3
- 239000008273 gelatin Substances 0.000 claims description 3
- 235000019322 gelatine Nutrition 0.000 claims description 3
- 235000011852 gelatine desserts Nutrition 0.000 claims description 3
- 229920000126 latex Polymers 0.000 claims description 3
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- 240000002636 Manilkara bidentata Species 0.000 claims description 2
- 240000006474 Theobroma bicolor Species 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- PZZYQPZGQPZBDN-UHFFFAOYSA-N aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 claims description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 2
- 235000016302 balata Nutrition 0.000 claims description 2
- 235000015278 beef Nutrition 0.000 claims description 2
- YYRMJZQKEFZXMX-UHFFFAOYSA-L calcium bis(dihydrogenphosphate) Chemical compound [Ca+2].OP(O)([O-])=O.OP(O)([O-])=O YYRMJZQKEFZXMX-UHFFFAOYSA-L 0.000 claims description 2
- 239000001913 cellulose Substances 0.000 claims description 2
- 229920002678 cellulose Polymers 0.000 claims description 2
- 235000019219 chocolate Nutrition 0.000 claims description 2
- 239000004927 clay Substances 0.000 claims description 2
- 229910052570 clay Inorganic materials 0.000 claims description 2
- 229940075507 glyceryl monostearate Drugs 0.000 claims description 2
- 239000008172 hydrogenated vegetable oil Substances 0.000 claims description 2
- 235000012204 lemonade/lime carbonate Nutrition 0.000 claims description 2
- 150000002632 lipids Chemical class 0.000 claims description 2
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 claims description 2
- 239000000391 magnesium silicate Substances 0.000 claims description 2
- 229910052919 magnesium silicate Inorganic materials 0.000 claims description 2
- 235000019792 magnesium silicate Nutrition 0.000 claims description 2
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 claims description 2
- 229910000150 monocalcium phosphate Inorganic materials 0.000 claims description 2
- 235000019691 monocalcium phosphate Nutrition 0.000 claims description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- 239000000454 talc Substances 0.000 claims description 2
- 229910052623 talc Inorganic materials 0.000 claims description 2
- 235000012222 talc Nutrition 0.000 claims description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 2
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 claims description 2
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims description 2
- 229910000391 tricalcium phosphate Inorganic materials 0.000 claims description 2
- 229940078499 tricalcium phosphate Drugs 0.000 claims description 2
- 235000019731 tricalcium phosphate Nutrition 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims 2
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 claims 2
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 claims 1
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Natural products CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims 1
- AUZONCFQVSMFAP-UHFFFAOYSA-N disulfiram Chemical compound CCN(CC)C(=S)SSC(=S)N(CC)CC AUZONCFQVSMFAP-UHFFFAOYSA-N 0.000 claims 1
- 239000001095 magnesium carbonate Substances 0.000 claims 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims 1
- 229960001708 magnesium carbonate Drugs 0.000 claims 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims 1
- 235000014380 magnesium carbonate Nutrition 0.000 claims 1
- 239000012169 petroleum derived wax Substances 0.000 claims 1
- 235000019381 petroleum wax Nutrition 0.000 claims 1
- 239000003963 antioxidant agent Substances 0.000 abstract description 6
- 235000006708 antioxidants Nutrition 0.000 abstract description 6
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 24
- SEQDDYPDSLOBDC-UHFFFAOYSA-N Temazepam Chemical compound N=1C(O)C(=O)N(C)C2=CC=C(Cl)C=C2C=1C1=CC=CC=C1 SEQDDYPDSLOBDC-UHFFFAOYSA-N 0.000 description 16
- 230000003647 oxidation Effects 0.000 description 15
- 238000007254 oxidation reaction Methods 0.000 description 15
- 239000003112 inhibitor Substances 0.000 description 10
- BGNXCDMCOKJUMV-UHFFFAOYSA-N Tert-Butylhydroquinone Chemical compound CC(C)(C)C1=CC(O)=CC=C1O BGNXCDMCOKJUMV-UHFFFAOYSA-N 0.000 description 8
- 230000003078 antioxidant effect Effects 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 150000002978 peroxides Chemical class 0.000 description 7
- 239000003292 glue Substances 0.000 description 6
- -1 tenderizer Substances 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 235000013399 edible fruits Nutrition 0.000 description 5
- 239000003995 emulsifying agent Substances 0.000 description 5
- 230000001590 oxidative effect Effects 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 230000003026 anti-oxygenic effect Effects 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 239000003925 fat Substances 0.000 description 4
- 239000000796 flavoring agent Substances 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000004250 tert-Butylhydroquinone Substances 0.000 description 4
- 235000019281 tert-butylhydroquinone Nutrition 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 235000019197 fats Nutrition 0.000 description 3
- 235000013355 food flavoring agent Nutrition 0.000 description 3
- 125000005908 glyceryl ester group Chemical group 0.000 description 3
- 239000004519 grease Substances 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 235000012424 soybean oil Nutrition 0.000 description 3
- 239000003549 soybean oil Substances 0.000 description 3
- 235000019871 vegetable fat Nutrition 0.000 description 3
- 235000013311 vegetables Nutrition 0.000 description 3
- XMGQYMWWDOXHJM-JTQLQIEISA-N (+)-α-limonene Chemical compound CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 description 2
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 2
- 108010011485 Aspartame Proteins 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- 229920001908 Hydrogenated starch hydrolysate Polymers 0.000 description 2
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 2
- 108010009736 Protein Hydrolysates Proteins 0.000 description 2
- 239000004902 Softening Agent Substances 0.000 description 2
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 2
- 229930003427 Vitamin E Natural products 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- 239000008122 artificial sweetener Substances 0.000 description 2
- 235000021311 artificial sweeteners Nutrition 0.000 description 2
- 239000000605 aspartame Substances 0.000 description 2
- 235000010357 aspartame Nutrition 0.000 description 2
- IAOZJIPTCAWIRG-QWRGUYRKSA-N aspartame Chemical compound OC(=O)C[C@H](N)C(=O)N[C@H](C(=O)OC)CC1=CC=CC=C1 IAOZJIPTCAWIRG-QWRGUYRKSA-N 0.000 description 2
- 229960003438 aspartame Drugs 0.000 description 2
- 150000001720 carbohydrates Chemical class 0.000 description 2
- 235000014633 carbohydrates Nutrition 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000001683 mentha spicata herb oil Substances 0.000 description 2
- 150000004702 methyl esters Chemical class 0.000 description 2
- 235000013336 milk Nutrition 0.000 description 2
- 239000008267 milk Substances 0.000 description 2
- 210000004080 milk Anatomy 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 229920002689 polyvinyl acetate Polymers 0.000 description 2
- 230000003449 preventive effect Effects 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 235000019605 sweet taste sensations Nutrition 0.000 description 2
- 229920003051 synthetic elastomer Polymers 0.000 description 2
- 239000006188 syrup Substances 0.000 description 2
- 235000020357 syrup Nutrition 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- 235000019165 vitamin E Nutrition 0.000 description 2
- 239000011709 vitamin E Substances 0.000 description 2
- 229940046009 vitamin E Drugs 0.000 description 2
- WTARULDDTDQWMU-RKDXNWHRSA-N (+)-β-pinene Chemical compound C1[C@H]2C(C)(C)[C@@H]1CCC2=C WTARULDDTDQWMU-RKDXNWHRSA-N 0.000 description 1
- WTARULDDTDQWMU-IUCAKERBSA-N (-)-Nopinene Natural products C1[C@@H]2C(C)(C)[C@H]1CCC2=C WTARULDDTDQWMU-IUCAKERBSA-N 0.000 description 1
- AOFUBOWZWQFQJU-SNOJBQEQSA-N (2r,3s,4s,5r)-2,5-bis(hydroxymethyl)oxolane-2,3,4-triol;(2s,3r,4s,5s,6r)-6-(hydroxymethyl)oxane-2,3,4,5-tetrol Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O.OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@@H]1O AOFUBOWZWQFQJU-SNOJBQEQSA-N 0.000 description 1
- NUFKRGBSZPCGQB-FLBSXDLDSA-N (3s)-3-amino-4-oxo-4-[[(2r)-1-oxo-1-[(2,2,4,4-tetramethylthietan-3-yl)amino]propan-2-yl]amino]butanoic acid;pentahydrate Chemical compound O.O.O.O.O.OC(=O)C[C@H](N)C(=O)N[C@H](C)C(=O)NC1C(C)(C)SC1(C)C.OC(=O)C[C@H](N)C(=O)N[C@H](C)C(=O)NC1C(C)(C)SC1(C)C NUFKRGBSZPCGQB-FLBSXDLDSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- KMZHZAAOEWVPSE-UHFFFAOYSA-N 2,3-dihydroxypropyl acetate Chemical compound CC(=O)OCC(O)CO KMZHZAAOEWVPSE-UHFFFAOYSA-N 0.000 description 1
- UHOPWFKONJYLCF-UHFFFAOYSA-N 2-(2-sulfanylethyl)isoindole-1,3-dione Chemical compound C1=CC=C2C(=O)N(CCS)C(=O)C2=C1 UHOPWFKONJYLCF-UHFFFAOYSA-N 0.000 description 1
- XRCRJFOGPCJKPF-UHFFFAOYSA-N 2-butylbenzene-1,4-diol Chemical compound CCCCC1=CC(O)=CC=C1O XRCRJFOGPCJKPF-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- WRFYIYOXJWKONR-UHFFFAOYSA-N 4-bromo-2-methoxyaniline Chemical compound COC1=CC(Br)=CC=C1N WRFYIYOXJWKONR-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 239000004377 Alitame Substances 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 235000019499 Citrus oil Nutrition 0.000 description 1
- 244000180278 Copernicia prunifera Species 0.000 description 1
- 235000010919 Copernicia prunifera Nutrition 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 description 1
- 241001553290 Euphorbia antisyphilitica Species 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 240000007232 Illicium verum Species 0.000 description 1
- 235000008227 Illicium verum Nutrition 0.000 description 1
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229930195725 Mannitol Natural products 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 108050004114 Monellin Proteins 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- WTARULDDTDQWMU-UHFFFAOYSA-N Pseudopinene Natural products C1C2C(C)(C)C1CCC2=C WTARULDDTDQWMU-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- 239000004376 Sucralose Substances 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 244000223014 Syzygium aromaticum Species 0.000 description 1
- 235000016639 Syzygium aromaticum Nutrition 0.000 description 1
- 241000534944 Thia Species 0.000 description 1
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 1
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 description 1
- YGCFIWIQZPHFLU-UHFFFAOYSA-N acesulfame Chemical compound CC1=CC(=O)NS(=O)(=O)O1 YGCFIWIQZPHFLU-UHFFFAOYSA-N 0.000 description 1
- 229960005164 acesulfame Drugs 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 235000019409 alitame Nutrition 0.000 description 1
- 108010009985 alitame Proteins 0.000 description 1
- XCPQUQHBVVXMRQ-UHFFFAOYSA-N alpha-Fenchene Natural products C1CC2C(=C)CC1C2(C)C XCPQUQHBVVXMRQ-UHFFFAOYSA-N 0.000 description 1
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 1
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 1
- 230000003064 anti-oxidating effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 1
- 229930006722 beta-pinene Natural products 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000001055 chewing effect Effects 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 239000010500 citrus oil Substances 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 239000008121 dextrose Substances 0.000 description 1
- QGGZBXOADPVUPN-UHFFFAOYSA-N dihydrochalcone Chemical compound C=1C=CC=CC=1C(=O)CCC1=CC=CC=C1 QGGZBXOADPVUPN-UHFFFAOYSA-N 0.000 description 1
- PXLWOFBAEVGBOA-UHFFFAOYSA-N dihydrochalcone Natural products OC1C(O)C(O)C(CO)OC1C1=C(O)C=CC(C(=O)CC(O)C=2C=CC(O)=CC=2)=C1O PXLWOFBAEVGBOA-UHFFFAOYSA-N 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000006471 dimerization reaction Methods 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- LCWMKIHBLJLORW-UHFFFAOYSA-N gamma-carene Natural products C1CC(=C)CC2C(C)(C)C21 LCWMKIHBLJLORW-UHFFFAOYSA-N 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 235000010985 glycerol esters of wood rosin Nutrition 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229960004232 linoleic acid Drugs 0.000 description 1
- 229960004488 linolenic acid Drugs 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 230000005389 magnetism Effects 0.000 description 1
- 235000009973 maize Nutrition 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000001525 mentha piperita l. herb oil Substances 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- OSWPMRLSEDHDFF-UHFFFAOYSA-N methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 description 1
- 239000013081 microcrystal Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 235000021096 natural sweeteners Nutrition 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 229960002969 oleic acid Drugs 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 235000019477 peppermint oil Nutrition 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000019721 spearmint oil Nutrition 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 235000019408 sucralose Nutrition 0.000 description 1
- BAQAVOSOZGMPRM-QBMZZYIRSA-N sucralose Chemical compound O[C@@H]1[C@@H](O)[C@@H](Cl)[C@@H](CO)O[C@@H]1O[C@@]1(CCl)[C@@H](O)[C@H](O)[C@@H](CCl)O1 BAQAVOSOZGMPRM-QBMZZYIRSA-N 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000005846 sugar alcohols Chemical class 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 235000020238 sunflower seed Nutrition 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000000892 thaumatin Substances 0.000 description 1
- 235000010436 thaumatin Nutrition 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 239000009637 wintergreen oil Substances 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G4/00—Chewing gum
- A23G4/06—Chewing gum characterised by the composition containing organic or inorganic compounds
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G4/00—Chewing gum
- A23G4/06—Chewing gum characterised by the composition containing organic or inorganic compounds
- A23G4/08—Chewing gum characterised by the composition containing organic or inorganic compounds of the chewing gum base
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G4/00—Chewing gum
- A23G4/06—Chewing gum characterised by the composition containing organic or inorganic compounds
- A23G4/12—Chewing gum characterised by the composition containing organic or inorganic compounds containing microorganisms or enzymes; containing paramedical or dietetical agents, e.g. vitamins
- A23G4/126—Chewing gum characterised by the composition containing organic or inorganic compounds containing microorganisms or enzymes; containing paramedical or dietetical agents, e.g. vitamins containing vitamins, antibiotics
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Microbiology (AREA)
- Nutrition Science (AREA)
- Confectionery (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Coloring Foods And Improving Nutritive Qualities (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
口香糖胶基的制法，包括将5-95%重量的选自聚异丁烯-异戊二烯共聚物、苯乙烯-丁二烯共聚物、聚醋酸乙烯酯、醋酸乙烯-乙烯月桂酸酯共聚物、天然橡胶、天然树胶及其混合物组成的组中的弹性体、0-75%重量的选自天然松香酯和合成萜烯树脂组成的组中的弹性体增塑剂、1-65%重量的填充料和0.01-1.00%重量的由7-20%重量的α-生育酚，45-75%重量的γ-生育酚，18-32%重量的δ-生育酚和0-3%重量的-β-生育酚构成的生育酚混合物混合在一起。
Description
本发明涉及一种口香糖胶基材料，其中含有生育酚同系物特殊配料，从而改进了抗氧化效果。
从现有技术中知，口香糖的典型组合物包括水溶性的填充部分、水不溶性的口香糖胶基部分和典型的水不溶增香剂。在咀嚼过程中，溶于水的成分和一部分增香剂被消耗掉了，而胶基部分则一直留在嘴里。
口香糖胶基包括许多成分，其中一些在储藏过程中会氧化变质。这种水不溶性胶基通常包括弹性体、弹性体增塑剂、蜡、脂肪、油脂、软化剂、乳化剂、填充料、增稠剂及诸如抗氧化剂、防腐剂、着色剂、漂白剂等多种成分。碳原子间含有双键的成分，包括脂肪、油脂、一些弹性体及弹性体增塑剂，容易受到氧化作用。口香糖胶基构成口香糖组合物重量的5-95％，更典型的是10-50％(重量)，最通常的为15-25％(重量)。
通常使用的天然或人造抗氧化剂/防腐剂包括β-胡萝卜素、酸化剂(例如：维生素C)、酸丙酯、丁基对羟基苯甲醚(BHA)、2,6-二叔丁基对甲酚(BHT)、和叔丁基对苯二酚(TBHQ)。其中最著名、最通用的是合成抗氧剂BHA、BHT和TBHQ。
生育酚是已知具有抗氧特性的、天然存在的化合物。最普通的生育酚，α-生育酚，也被称作维生素E。其他的普通同系物是β、γ和δ生育酚。所有这些生育酚同系物均是FDA允许的、动物试验安全的食品添加剂。天然生育酚通常从植物油酯、特别是大豆油中得到，也可以从许多香料水果、坚果、种子和其他植物来源中得到。
不幸地，在阻止口香糖胶基成分的氧化反应方而，生育酚同系物通常比BHA和BHT效果要差。而且生育酚还具有使用上限，高于该上限，口香糖胶基成分的氧化作用又开始加剧。与一些合成稳定剂共用时，生育酚可有效地用作某些口香糖胶基成分，如：苯乙稀丁二烯橡胶的稳定剂。U.S.4489099(Shaheen等人)中就公开了将维生素E生育酚与二月桂基二硫代丙酸酯(DLTDP)共同使用的方法。但是，迄今以前，在口香糖胶基成分中单独使用生育酚的效果是不理想的。
我们发现，将某种生育酚同系物的混和物以一定的比例，用于口香糖胶基，其抗氧性能呈现出重大的改进。本发明所用的该种同系物混和物在阻止口香糖胶基成分氧化反应方面，比任何单独使用的同系物组分都更有效，并且与BHT效果相当，有时还更好。
我们还发现，当生育酚被用在典型的，80℃-150℃温度下生产的口香糖胶基中时，它不象BHT挥发的那么多。这使得在口香糖胶基中其抗氧化剂水平能在最初加入量的基础上保持相对恒定。而且，生育酚加入量可大于0.1％(重量)，方便易行而且抗氧效果更佳。美国食品和药物管理局规则规定，BHT浓度为0.1％(重量)，而典型使用的BHT浓度为0.02-0.09％(重量)。
本发明使用的生育酚混合物含有至少3种生育酚同系物：α、γ和δ-生育酚，以特殊的比例配制。β-生育酚及其他可能的同系物也可以小量存在。
用百分数表示活性成分的含量为(即：占生育酚总量的重量百分数)，7-20％α-生育酚，45-75％γ-生育酚和18-32％δ-生育酚。β-生育酚可选择性存在，含量上限至3％。
本发明使用的生育酚混和物可以是天然存在的物质、天然物质的混和物、天然物质的改性物、生育酚组分的混和物或加入了生育酚组分的天然物质的混和物。常规中，生育酚混和物存在于稀释液中，最普通是植物油中。从抗氧剂观点上说，稀释剂的量并不重要，但从粘度和操作的角度看，优选的活性水平为约70％(指生育酚占重量的约70％，稀释剂占约30％)。
由上述考虑，本发明的一个特征和优点是为口香糖胶基提供一种稳定剂，从而使口香糖胶基成分的氧化反应减至最小而不必使用合成抗氧剂，如BHA和BHT。
本发明的又一特征和优点是为口香糖提供一种胶基成分、其货架期稳定且不含合成抗氧化剂。
本发明的又一特征和优点是提供了一种口香糖组合物，它性质稳定而又避免了使用合成BHA和BHT抗氧剂。
由阅读下文的描述及公开了本发明优选方案的实施例，可以使本发明的上述及其他特征和优点更为明显。可以理解的是，由所附权利要求及其等同物所定义的本发明的范围可由下文的叙述进一步说明而不是被其限定。
口香糖胶基成分的氧化会导致口香糖的颜色、风味、组织和味道发生不理想的变化，而口香糖制造者总想达到保证质量和延长口香糖货架期的重要目标，因此，他们面临的一个主要问题就是口香糖成分，包括胶基成分的氧化问题。
以前，主要用合成抗氧剂BHA、BHT和TBHQ来稳定口香糖胶基。这些化合物都可以有效地抗氧化是因为它们共同的特征是具有酚基结构，如下所示：
生育酚是从蔬菜和其他植物种子如大豆、葵花籽及各种水果和坚果中得到的天然物质。因其取自天然，使他们比合成抗氧化剂对口香糖制造者和消费者具有更大的吸引力。从抗氧化剂的观点看，生育酚令人感兴趣是因为它含有类似BHA、BHT、TBHQ中的酚基基团：β-生育酚
γ-生育酚
δ-生膏酚
单独使用时，不同的生育酚同系物呈现出不同的化学活性，包括不同的抗氧活性水平。由于这个原因，人们改进了从混和物中分离单一同系物的方法及将一种生育酚同系物变成另一种的方法。这些方法在U.S.4977282(Baldwin等人)中有所公开。
本发明以前，还不知道经特殊混合的生育酚同系物在口香糖胶基中所能呈现的、比任何一个单独使用的同系物所呈现的活性更高的抗氧化活性，该活性可与BHT的活性相比。如前所述，本发明涉及在口香糖胶基中使用生育酚混和物，有效地提高抗氧活性，该抗氧活性与使用典型BHT用量的抗氧活性类似或者更高。
生育酚混和物的优选量依具体的口香糖胶基组合物而不同，也可以依使用胶基的口香糖的具体组合物而不同，因为部分抗氧剂会转移到口香糖的其他成分中去。下文表1列出本发明所用生育酚混和物的优选组合物和加入到口香糖胶基组合物中的优选量。表1 生育酚组合物的用量
| 生育酚组合物(％)(占生育酚总量的重量百分数(A) | β-生育酚(％)(C) | 使用量(％)(加入到口香糖中的重量百分数(B) | |
| 范围 | 7-20％α-生育酚45-75％γ-生育酚18-32％δ-生育酚 | 0-3％ | 0.01-1.00％ |
应当注意到，许多胶基成分包括脂肪、氢化植物油脂和卵磷脂，含有少量天然存在的生育酚，含量范围占胶基成分重量的约0.01％-0.15％之间，表1中B栏列出的百分数，是指加入到口香糖胶基的生育酚量，它比任何天然存在的生育酚量要大。向口香糖胶基中加入生育酚混和物可在制造口香糖胶基时直接加入；或者，将生育酚混和物溶于溶剂，制成乳状液，悬浮液或溶液，然后与口香糖胶基混和，食用脂肪或油脂是优选的溶剂；或者，将生育酚(或乳状液、溶液、干粉或其悬浮液)与一种或几种口香糖胶基成分预混和。
水不溶性的口香糖胶基一般构成口香糖重量的约5至约95％。较优选的范围在10-50％之间，最优选的范围在约20至约35％之间。本发明可使用任何商业上可接受的口香糖胶基。
弹性体构成胶基重量的约5至约95％，优选范围在10-70％，最优选的范围在15-45％之间。弹性体包括聚异丁烯、异丁烯-异戊二烯共聚物、苯乙烯-丁二烯共聚物、聚醋酸乙烯酯、醋酸乙烯-乙烯月桂酸酯共聚物及其混合物。天然的弹性体包括烟状或液状的胶乳和银菊胶等天然橡胶以及天然的树胶如明胶、lechicaspi、perillo、massaranduba balata、massaranduba chocolate、nispero、rosindinha，糖胶树胶(chile)、gutta hang kang或它们的混和物。
弹性体增塑剂构成口香糖胶基重量的约0至约75％，优选的范围是5至45％，最优选的范围是10-30％。弹性体增塑剂包括天然的松香酯如部分加氢松香的甘油酯、聚合松香的甘油酯、部分二聚松香的甘油酯、松香甘油酯、部分加氢松香的季戊四酯、松香甲酯和部分氢化松香甲酯、松香季戊四酯或混和物。弹性体增塑剂还包括由α-蒎烯、β-蒎烯和/或d-柠檬烯中提取的萜烯树脂合成物。
蜡，包括合成的(如聚乙烯和Fischer-Tropsch waxes)和天然的(小烛树蜡(candelilla)巴西棕榈蜡(carnauba)；蜂蜡、米糠或其混合物)及石油的(如：微晶体和石蜡)。使用蜡质一般至多占口香糖胶基重量的30％。
软化剂/乳化剂包括动物脂、氢化动物脂氢化和部分氢化植物油、可可脂、硬脂酸单甘油酯、三乙酸甘油酯、卵磷脂、单一、双一、三一甘油酯、乙酰甘油酯及脂肪酸(如：硬脂酸、棕榈酸、油酸、亚油酸、亚麻酸)或它们的混和物。软化剂/乳化剂通常占口香糖胶基重量的0.5-40％。
填充料和增稠剂包括镁和钙的碳酸盐、细石灰，硅酸盐如硅酸镁、硅酸铝、粘土、氧化铝、滑石，还有氧化钛、磷酸一钙、磷酸二钙、磷酸三钙，纤维素聚合物如乙基、甲基的聚合物和木质或它们的混和物。优选的填充料占口香糖胶基重量约1至约65％。
着色剂和漂白剂包括FD&C-型染料和色淀，水果、蔬菜提取液、二氧化钛或其混和物。
制造口香糖胶基，一般方法是向加热的曲拐式搅拌机(Sigma blade mixer)中加入一定量的弹性体、弹性体增塑剂和填充料，其中前后桨速比为2∶1。胶基原料最初加入量由混和槽的工作能力决定，从而得到合适的稠度。最初加入的原料混匀后，以连续的方式将平衡量的弹性体增塑剂、填充料、软化剂等加入，至得到完全均匀熔融的料团。这项操作通常需要1-4小时，视口香糖配方而定。最终料温可在60-150℃之间，优选范围在80-120℃之间。操作完毕后，将熔融料团从混和槽中倒空，移至夹层锅或带衬里的锅中，压成或铸成所需形状，而后冷却、成型。
口香糖中的水溶性部分包括软化剂、甜味剂、增香剂及其混和物。加入软化剂可使口香糖的咀嚼性和口感达到最佳。软化剂，工艺中也已知其为增塑剂，通常占口香糖重量的约0.5-15.0％之间。本发明使用的软化剂包括甘油、卵磷脂及其混和物。此外，甜味剂水溶液，如山梨糖醇、氢化淀粉水解物、玉米糖浆及其混和物，可在口香糖中用作软化剂和粘合剂。
大量的甜味剂占口香糖重量的20-80％，包括糖类和非糖类甜味剂。糖类甜味剂包括多糖，包括但不限于蔗糖、右旋糖、麦芽糖、糊精、干制转化糖、果糖、左旋糖、半乳糖、玉米糖浆固形物等，可单独使用或联合使用。非糖类甜味剂指具有甜味特性但组成中没有通常所知的糖类的成分。非糖类甜味剂包括但不限于糖醇，如山梨糖醇、甘露糖醇、木糖醇、氢化淀粉水解物、麦芽糖醇等，可单独或联合使用。
也可使用高强度甜味剂，包括但不限于sucralose，阿斯巴特糖精(aspartame)、氧硫杂连氮酯盐(acesulfame)、alitame、糖精及其盐、环己烷氨基磺酸及其盐、二氢查尔酮、thaumatin、monellin等，单独或联合使用。
口香糖中还可使用糖/或非糖甜味剂的混和物。甜味剂能够全部或部分地作为水溶性的填充剂在口香糖中发生作用。此外，软化剂与糖液或醛醇液一起又可以提供附加的甜味。
口香糖中可有一种或几种增香剂，含量占口香糖重量的约0.1至约10.0％以内，优选的范围是从约0.5至约5.0％。增香剂包括精油、天然或合成香味剂或其混和物，包括但不限于从植物和水果中提取的油，如：柑桔油、水果香精、胡椒薄荷油、绿薄荷油、其他薄荷油、丁香油、冬青油、大茴香油等。人造增香剂也可使用。本领域的技术人员知道天然和人造增香剂可以以任何感觉能接受的方式联合使用。所有这些香味剂和香味剂混和物均可用于本发明。
供选择的成分，如着色剂、乳化剂、药物成分可加入口香糖中。
通常，现有技术中制造口香糖是向商购混和槽中连续地加入各种口香糖原料。原料充分混和后，口香糖团从混和槽中排出，制成需要的形状，如：滚成薄片、切成条、挤压成块、制模成粒等。
一般，原料混和要先将口香糖胶基软化(如加热)，加入到启动了的混和槽中，也可以在混和槽中软化胶基。着色剂和乳化剂在此时加入。软化剂，例如甘油，与糖浆和部分填充剂一起也可此时加入，其后加入另一部分填充剂，景后一部分填充剂随同增香剂一起加入混和槽。
全部混和过程一般需要5到15分钟，有时需要稍长时间。本领域技术人员知道，上述操作的变动或不同的操作是可以允许的。
对本领域技术人员来说，很明显上述的发明实施方案可以进行很大的变化和改进。下文的实施例不能被解释为对发明的限制，而仅仅是用以举例说明优选的方案。
实施例1
Tenox GT-2生育酚混和物(可由Eastman Kodak购得)，含有12.5％α-生育酚，63.9％γ-生育酚和23.6％δ-生育酚(占生育酚总重的百分数)，用大豆油稀释(70％生育酚，30％大豆油)。将其加入到口香糖胶基中，胶基成分如下：成分 百分重量合成弹性体：异戊二烯-异丁烯 9.38聚异丁烯 6.31聚醋酸乙烯酯 24.84苯乙烯-丁二烯橡胶 1.54天然弹性体 21.59松香酯 8.13微晶蜡 8.55碳酸钙 8.91-9.41氢化植物油脂 7.38软化剂 2.87
准备5种不同的试样，前4个试样中分别含0％、0.05％、0.10和0.50％(重量)的Tenox GT-2，第5个试样含0.04％(重量)BHT，作为标准。抗氧剂直接加入到混和槽中的口香糖胶基料团中，经过约30分钟，将胶基移出混和槽。
5个试样放在100°F氧气分压100psi的反应器中存放100天。经0、7、1 4、21、28、35、42、49、56、63、70、77、83、91和98后测定试样的“过氧化物值”。用过氧化物值即过氧化物毫克当量(meg)/kg试样来表示氧化反应的情况。该值测定是用A、O、C、S法定方法Cd8-53，1986修订版。
下文表2给出了这个试验的结果。从全部时间和各种抗氧剂含量看，含有生育酚的试样的过氧化物值几乎与含BHT的试样的一样低。存放时间大于70天，含0.10％生育酚的试样的过氧化物和含0.50％生育酚的试样的过氧化物值比含BHT试样的要低。存放21天或更长，含生育酚的试样的过氧化物值比未加稳定剂的试样的要低得多。这说明，含生育酚混和物的Tenox GT-2显示出有效的抗氧化性质，与BHT等效或更好。
表2口香糖胶基中的生育酚混和物的特性
| 抗氧剂类型和含量(占口香糖胶基重量的％) | 过氧化物值(meg/kg)100°F100Psi氧 | |||||||
| 0天 | 7天 | 14天 | 21天 | 28天 | 35天 | 42天 | 49天 | |
| 0 | 7.9 | 2.0 | 2.0 | 95.4 | 113 | 141 | 131 | 136 |
| .05％ Tenox GT-2 | 2.0 | 2.0 | 4.0 | 5.8 | 6.0 | 5.9 | 6.0 | 5.9 |
| .10％ Tenox GT-2 | 7.9 | 8.0 | 4.0 | 5.9 | 6.0 | 5.9 | 6.0 | 5.9 |
| .50％ Tenox GT-2 | 4.0 | 6.0 | 4.0 | 6.0 | 5.9 | 5.9 | 6.0 | 6.0 |
| .04％ BHT | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | 4.0 | 3.9 |
| 56天 | 63天 | 70天 | 77天 | 83天 | 91天 | 98天 | ||
| 0 | 108 | 103 | 86 | 90 | 79 | 65 | 62 | |
| .05％ Tenox GT-2 | 10 | 12 | 22 | 93 | 125 | 75 | 86 | |
| .10％ Tenox GT-2 | 6.0 | 6.0 | 8.0 | 8.0 | 9.0 | 10 | 12 | |
| .50％ Tenox GT-2 | 6.0 | 6.0 | 6.0 | 6.0 | 6.0 | 6.0 | 6.0 | |
| .04％ BHT | 4.0 | 4.0 | 6.0 | 23 | 156 | 123 | 101 | |
实施例2：
实验和评估步骤同实施例1，只是口香糖胶基不同，该胶基成分如下所示：成分 重量百分数合成弹性体异戊二烯-异丁烯 12.12聚异丁烯 9.96聚醋酸乙烯脂 14.83碳酸钙 28.64-29.14氢化植物油脂 28.62软化剂 5.33
下文表3给出这个实验的结果。Tenox GT-2是一个与BHT同样有效的抗氧剂。存放91天和98天，含0.10％和0.50％生育酚的试样确实比含BHT的试样的氧化反应要少。表3口香糖胶基中生育酚混和物的特性：
| 抗氧剂类型和含量(占口香糖胶基重量的％) | 过氧化物值(meo/kg)100°F100Psi氧 | |||||||
| 0天 | 7天 | 14天 | 21天 | 28天 | 35天 | 42天 | 49天 | |
| 0 | 0 | 2.0 | 4.0 | 10.0 | 36.6 | 94.0 | 105 | 111 |
| .05％ Tenox GT-2 | 0 | 2.0 | 2.0 | 6.0 | 7.9 | 9.9 | 11.8 | 13.9 |
| .10％ Tenox GT-2 | 6.0 | 4.0 | 6.0 | 8.0 | 9.9 | 10.9 | 11.9 | 13.9 |
| .50％ Tenox GT-2 | 2.0 | 4.0 | 8.0 | 10.0 | 11.8 | 12.9 | 15.7 | 17.7 |
| .04％ BHT | 0 | 0 | 0 | 0 | 0 | 2.0 | 2.0 | 4.0 |
| 56天 | 63天 | 70天 | 77天 | 84天 | 91天 | 98天 | ||
| 0 | 109 | 94 | 78 | 60 | 47 | 35 | 28 | |
| .05％ Tenox GT-2 | 18 | 18 | 22 | 25 | 56 | 117 | 126 | |
| .10％ Tenox GT-2 | 18 | 18 | 19 | 21 | 20 | 22 | 34 | |
| .50％ Tenox GT-2 | 18 | 18 | 20 | 20 | 21 | 21 | 22 | |
| .04％ BHT | 4.0 | 6.0 | 10 | 10 | 15 | 61 | 89 | |
在此公开的本发明的实施方案目前被认为是优选的。在不背离本发明精神和范围的情况下，各种变动和改进可由此实现。本发明的范围由所附权利要求说明，在权利要求等同物的含义和范围之内的所有变动都囊括其中。
Claims (27)
1、一种口香糖胶基的制备方法，包括将下述组分混合在一起：
5-95％重量的弹性体，选自聚异丁烯一异戊二烯共聚物、苯乙烯-丁二烯共聚物、聚醋酸乙烯酯、醋酸乙烯-乙烯月桂酸酯共聚物、天然橡胶、天然树胶及其混合物组成的组；
0-75％重量的弹性体增塑剂，选自天然松香酯和合成萜烯树脂组成的组；
1-65％重量的填充料；和
0.01-1.00％重量的生育酚混合物，其中含有7-20％重量的α-生育酚，45-75％重量的γ-生育酚，18-32％重量的δ-生育酚和-3％重量的β-生育酚。
2、如权利要求1所述的方法，其特征在于所述的生育酚混合物的用量为0.05-0.50％重量。
3、如权利要求1所述的方法，其特征在于所述的生育酚混合物用量为0.08-0.20％重量。
4、如权利要求1所述的方法，其特征在于所述的弹性体的用量为10-70％重量。
5、如权利要求4所述的方法，其特征在于所述的弹性体的用量为15-45％重量。
6、如权利要求1所述的方法，其特征在于所使用的弹性体包括苯乙烯-丁二烯共聚物。
7、如权利要求1所述的方法，其特征在于所使用的弹性体包括聚异丁烯。
8、如权利要求1所述的方法，其特征在于所使用的弹性体包括异丁烯-异戊二烯共聚物。
9、如权利要求1所述的方法，其特征在于所使用的弹性体包括聚醋酸乙烯酯。
10、如权利要求1所述的方法，其特征在所使用的弹性体包括天然橡胶，其选自胶乳橡胶，银菊胶及其混合物组成的组。
11、如权利要求1所述的方法，其特征在于所使用的弹性体包括天然树胶，其选自明胶、Lechi caspi,perillo,massaranduba balatamassar and ubachocolate,nispero,rosindinha，糖胶树胶，guttahang kang及其混合物组成的组。
12、如权利要求1所述的方法，其特征在于所述的弹性体增塑剂的用量为5-45％重量。
13、如权利要求12所述的方法，其特征在于所述的弹性体增塑剂的用量为10-30％重量。
14、如权利要求12所述的方法，其特征在于所使用的弹性体增塑剂包括天然的松香酯。
15、如权利要求12所述的方法，其特征在于所使用的弹性体增塑剂包括合成萜烯树脂。
16、如权利要求1所述的方法，其特征在于其中还使用多至30％重量的蜡，选自天然蜡、合成蜡、石油蜡及其混合物组成的组。
17、如权利要求1所述的方法，其特征在于其中还使用0.5-40％重量的软化剂，选自动物脂、氢化动物脂、氢化和部分氢化植物油脂、可可脂、硬脂酸单甘油酯、三乙酸甘油酯、卵磷脂、甘油单酯、甘油二酯、甘油三酯、脂肪酸及其混合物组成的组。
18、如权利要求1所述的方法，其特征在于所使用的填充料包括下列物质组成的组中的一种或多种：碳酸镁、碳酸钙、细石灰，硅酸镁、硅酸铝、粘土、氧化铝、滑石、氧化钛、磷酸一钙、磷酸二钙、磷酸三钙、纤维素聚合物、木质及其混合物。
19、如权利要求1所述的方法，其特征在于其中的生育酚混合物与弹性要进行预混合。
20、如权利要求1所述的方法，其特征在于所制备的胶基用于口香糖中。
21、一种口香糖组合物的制备方法，包括将下述组分混合在一起：含有20-80％重量的填充用甜味剂，0.1-10％重量的增香剂，0.5-15％重量的软化剂，10-50％重量的口香糖胶基，该口香糖胶基包括：
5-95％重量的弹性体，选自聚异丁烯、异丁烯-异戊二烯共聚物、苯乙烯-丁二烯共聚物，聚醋酸乙烯酯，醋酸乙烯-乙烯月桂酸酯共聚物、天然橡胶、天然树胶及其混合物组成的组；
0-75％重量的弹性体增塑剂，选自天然松香酯和合成萜烯树脂组成的组；
1-65％重量的填充料；和
0.01-1.00％重量的生育酚混合物，其中含有7-20％重量的α-生育酚，45-75％重量的γ-生育酚，18-32％重量的δ-生育酚和O-3％重量的β-生育酚。
22、如权利要求21所述的方法，其特征在于所使用的弹性体包括苯乙烯-丁二烯共聚物。
23、如权利要求2 1所述的方法，其特征在于所使用的弹性体包括聚异丁烯。
24、如权利要求21所述的方法，其特征在于所使用的弹性体包括异丁烯-异戊二烯共聚合物。
25、如权利要求21所述的方法，其特征在于所使用的弹性体包括聚醋酸乙烯酯。
26、如权利要求21所述的方法，其特征在于所使用的弹性体包括天然橡胶，选自胶乳橡胶、银菊胶及其混合物组成的组。
27、如权利要求21所述的方法，其特征在于所使用的弹性体包括天然树胶，选自明胶、Lechi caspi,perillo,massaranduba balata,massar and ubachocolate,nispero,rosindinha，糖胶树胶，guttahang kang及其混合物组成的组。
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/743,824 US5132121A (en) | 1991-08-12 | 1991-08-12 | Gum base containing tocopherol |
| US743,824 | 1991-08-12 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1071811A CN1071811A (zh) | 1993-05-12 |
| CN1042692C true CN1042692C (zh) | 1999-03-31 |
Family
ID=24990342
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN92110639.4A Expired - Lifetime CN1042692C (zh) | 1991-08-12 | 1992-08-12 | 口香糖胶基及含有该胶基的口香糖的制备方法 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US5132121A (zh) |
| EP (1) | EP0529855B1 (zh) |
| JP (1) | JPH05276871A (zh) |
| CN (1) | CN1042692C (zh) |
| AU (1) | AU645919B2 (zh) |
| CA (1) | CA2075667C (zh) |
| DE (1) | DE69203412T2 (zh) |
| DK (1) | DK0529855T3 (zh) |
| ES (1) | ES2074827T3 (zh) |
| FI (1) | FI923584A (zh) |
| MX (1) | MX9204653A (zh) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2514692A (en) * | 1992-08-14 | 1993-10-21 | Wm. Wrigley Jr. Company | Use of antioxidants from natural sources in chewing gum |
| EP0732060A1 (en) * | 1995-03-13 | 1996-09-18 | Wm. Wrigley Jr. Company | Gum base made with reduced antioxidant and method of preparation |
| TW497956B (en) * | 1996-05-31 | 2002-08-11 | Rengo Co Ltd | Controlled release composition containing volatile compound |
| US5792494A (en) * | 1996-08-01 | 1998-08-11 | L. A. Dreyfus Co. | Gum base manufacturing method using elastomer emulsions |
| US6235319B1 (en) * | 1999-12-22 | 2001-05-22 | The Goodyear Tire & Rubber Company | Chewing gum SBR |
| US6180144B1 (en) * | 2000-01-27 | 2001-01-30 | The Goodyear Tire & Rubber Co | Chewing gum base stabilized with carnosic acid |
| US6818236B2 (en) * | 2001-06-16 | 2004-11-16 | The Goodyear Tire & Rubber Company | Chewing gum SBR |
| KR100992521B1 (ko) * | 2002-07-02 | 2010-11-05 | 굼링크 에이/에스 | 츄잉 검 압축 정제 ｉｉ |
| US7175866B2 (en) * | 2003-09-12 | 2007-02-13 | Tropicana Products, Inc. | Tocopherols as flavor antioxidant in citrus juice |
| EP1702516B1 (de) | 2005-02-17 | 2007-04-11 | Wacker Polymer Systems GmbH & Co. KG | Abbaubare Kaugummimassen |
| CN101394750B (zh) * | 2005-12-29 | 2012-02-22 | Wm.雷格利Jr.公司 | 包含苯乙烯-二烯烃嵌段共聚物的口香糖 |
| WO2008119674A1 (de) * | 2007-04-02 | 2008-10-09 | Wacker Chemie Ag | Zusammensetzungen (compounds) aus polyvinylacetat und vinylacetat-vinyllaurat-copolymerisat |
| EP2566344B1 (en) * | 2010-05-03 | 2016-03-23 | Intercontinental Great Brands LLC | Natural chewing gum including cellulose materials |
| CN103689205A (zh) * | 2013-12-20 | 2014-04-02 | 江苏银洋胶基材料有限公司 | 一种胶姆糖果基础剂 |
| CN104543306A (zh) * | 2014-12-31 | 2015-04-29 | 南通双和食品有限公司 | 一种食品用胶姆糖基础剂及其制备方法 |
| EP3518683B1 (en) | 2016-09-30 | 2023-06-07 | WM. Wrigley Jr. Company | Gum bases incorporating polymers derived from russian dandelion |
| CN107712681A (zh) * | 2017-09-27 | 2018-02-23 | 浙江海洋大学 | 一种可食用的大型水母的加工工艺 |
| CN109315568B (zh) * | 2017-12-26 | 2022-10-04 | 丰益(上海)生物技术研发中心有限公司 | 油脂组合物、其用途以及含有油脂组合物的食品 |
| WO2023110570A1 (en) * | 2021-12-14 | 2023-06-22 | Basf Se | Stabilisation of polyisobutene |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4001438A (en) * | 1974-10-15 | 1977-01-04 | International Flavors & Fragrances Inc | Flavor composition for use in orally utilizable compositions |
| JPS5179746A (zh) * | 1975-01-07 | 1976-07-12 | Yokohama Yushi Kogyo Kk | |
| US4025640A (en) * | 1975-08-26 | 1977-05-24 | American Hoechst Corporation | Oxothienobenzoxepin-acetic acids, precursors and derivatives thereof |
| US4489099A (en) * | 1983-02-28 | 1984-12-18 | The Goodyear Tire & Rubber Company | Vitamin E/DLTDP stabilizer system for chewing gum SBR |
| US4504499A (en) * | 1983-04-25 | 1985-03-12 | Basf Wyandotte Corporation | Heat-stabilized, carotenoid-colored edible oils |
| US4480108A (en) * | 1983-08-01 | 1984-10-30 | Eastman Kodak Company | Process for separation of tocopherol homologues |
| US4977282A (en) * | 1984-04-17 | 1990-12-11 | Henkel Corporation | Production of d-alpha-tocopherol from natural plant sources |
| JPS6112629A (ja) * | 1984-06-28 | 1986-01-21 | Lion Corp | 口腔内組成物 |
| JPS6239684A (ja) * | 1985-08-12 | 1987-02-20 | House Food Ind Co Ltd | 酸化防止用組成物 |
| JPS6379834A (ja) * | 1986-09-25 | 1988-04-09 | Kozo Niwa | 活性酸素抑制組成物 |
| US4948595A (en) * | 1989-06-30 | 1990-08-14 | Wm. Wrigley Jr. Company | Spearmint enhanced peppermint flavored chewing gum with improved stability |
| MX9100585A (es) * | 1990-08-21 | 1992-04-01 | Warner Lambert Co | Agentes edulcorantes de clorodeoxiazucar,estabilizados,en forma solida y metodos para preparar los mismos |
-
1991
- 1991-08-12 US US07/743,824 patent/US5132121A/en not_active Expired - Lifetime
-
1992
- 1992-08-07 DE DE69203412T patent/DE69203412T2/de not_active Expired - Lifetime
- 1992-08-07 DK DK92307267.2T patent/DK0529855T3/da active
- 1992-08-07 EP EP92307267A patent/EP0529855B1/en not_active Expired - Lifetime
- 1992-08-07 ES ES92307267T patent/ES2074827T3/es not_active Expired - Lifetime
- 1992-08-07 AU AU20900/92A patent/AU645919B2/en not_active Expired
- 1992-08-10 CA CA002075667A patent/CA2075667C/en not_active Expired - Lifetime
- 1992-08-11 FI FI923584A patent/FI923584A/fi not_active Application Discontinuation
- 1992-08-11 MX MX9204653A patent/MX9204653A/es unknown
- 1992-08-11 JP JP4214113A patent/JPH05276871A/ja active Pending
- 1992-08-12 CN CN92110639.4A patent/CN1042692C/zh not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0529855B1 (en) | 1995-07-12 |
| CA2075667C (en) | 1996-08-06 |
| DE69203412D1 (de) | 1995-08-17 |
| DK0529855T3 (da) | 1995-11-27 |
| DE69203412T2 (de) | 1996-03-07 |
| US5132121A (en) | 1992-07-21 |
| AU645919B2 (en) | 1994-01-27 |
| JPH05276871A (ja) | 1993-10-26 |
| FI923584A0 (fi) | 1992-08-11 |
| ES2074827T3 (es) | 1995-09-16 |
| FI923584A (fi) | 1993-02-13 |
| CA2075667A1 (en) | 1993-02-13 |
| MX9204653A (es) | 1993-03-01 |
| AU2090092A (en) | 1993-02-18 |
| EP0529855A1 (en) | 1993-03-03 |
| CN1071811A (zh) | 1993-05-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1042692C (zh) | 口香糖胶基及含有该胶基的口香糖的制备方法 | |
| US5800848A (en) | Chewing gum containing sucrose polyesters | |
| EP0540190B1 (en) | Gum compositions containing vinyl laurate/vinyl acetate copolymer | |
| US5474787A (en) | Chewing gum containing a lecithin/glycerol triacetate blend | |
| CN1047920C (zh) | 稳定的薄荷油组合物及含有该组合物的口香糖的制备方法 | |
| US6852345B2 (en) | Stabilized chewing gum base | |
| US6231896B1 (en) | Chewing gum base stabilized with carnosic acid | |
| EP0627885A4 (en) | WAX-FREE CHEWING-GUM WITH BETTER TREATMENT FITNESS. | |
| US5200213A (en) | Gum base containing tocopherol | |
| CA2207713C (en) | Improved chewing gum containing salatrim | |
| US6077547A (en) | Chewing gum containing cuphea oil | |
| US6180144B1 (en) | Chewing gum base stabilized with carnosic acid | |
| US6670437B2 (en) | Rubber composition stabilized with carnosic acid | |
| CA2190095C (en) | Chewing gum having improved texture and containing medium chain triglycerides | |
| US5330772A (en) | Use of gum guaiac as an antioxidant in chewing gum | |
| JPH04228034A (ja) | キシリトールとスクロースを含有するチューインガム組成物およびその製造方法 | |
| US6007849A (en) | Chewing gum containing meadowfoam oil | |
| WO1997000619A1 (en) | Improved chewing gum containing sucrose fatty acid esters | |
| WO1995032634A1 (en) | Improved chewing gum containing medium chain triglycerides | |
| AU2905295A (en) | Improved chewing gum containing sucrose polyesters | |
| WO1997048286A1 (en) | Improved chewing gum containing cuphea oil | |
| WO1998052427A1 (en) | Improved lecithin form and methods for using same | |
| AU3114800A (en) | Chewing gum having extended flavor duration and methods for making same | |
| WO1993017572A1 (en) | Improved wax-free chewing gum base and chewing gums prepared therefrom | |
| WO1997048285A1 (en) | Improved chewing gum containing meadowfoam oil |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C15 | Extension of patent right duration from 15 to 20 years for appl. with date before 31.12.1992 and still valid on 11.12.2001 (patent law change 1993) | ||
| OR01 | Other related matters | ||
| C17 | Cessation of patent right | ||
| CX01 | Expiry of patent term |
Expiration termination date: 20120812 Granted publication date: 19990331 |