CN104262860A - Conductive PVC (polyvinyl chloride) shoe material and manufacturing method thereof - Google Patents
Conductive PVC (polyvinyl chloride) shoe material and manufacturing method thereof Download PDFInfo
- Publication number
- CN104262860A CN104262860A CN201410566377.3A CN201410566377A CN104262860A CN 104262860 A CN104262860 A CN 104262860A CN 201410566377 A CN201410566377 A CN 201410566377A CN 104262860 A CN104262860 A CN 104262860A
- Authority
- CN
- China
- Prior art keywords
- footwear material
- pvc
- conduction
- conduction pvc
- obtains
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B1/00—Footwear characterised by the material
- A43B1/14—Footwear characterised by the material made of plastics
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
- C08J9/102—Azo-compounds
- C08J9/103—Azodicarbonamide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
- C08J9/107—Nitroso compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/04—N2 releasing, ex azodicarbonamide or nitroso compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/001—Conductive additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The invention provides a conductive PVC (polyvinyl chloride) shoe material. The conductive PVC shoe material comprises the following components in parts by weight: 40-50 parts of PVC, 10-20 parts of conductive metal coating fibers, 2-10 parts of coupling agent, 2-5 parts of reinforcing agent, 15-30 parts of plasticizer, 1-4 parts of foaming agent, 1-10 parts of compatilizer and 2-10 parts of filler. The invention further discloses a manufacturing method of the conductive PVC shoe material. The conductive PVC shoe material provided by the invention is better in conductivity.
Description
Technical field:
The present invention relates to a kind of footwear material, particularly relate to a kind of conduction PVC footwear material and manufacture method thereof.
Background technology:
PVC and polyvinyl chloride, have stronger reactive force between molecule, be a kind of hard and crisp material; Resistance to impact shock is lower.After adding impact modifying agent, the elastomer particle of impact modifying agent can reduce total initiation stress, and utilizes distortion and the shear zone of particle self, sponges the striking energy in material, thus reaches shock proof object.The footwear material that PVC makes has good physicals and chemical property, and feature is light, and glossiness is strong, makes the three-dimensional sense organ of shoes strong.But, PVC footwear material does not possess conducting function, the electrostatic of human body can not be eliminated, and in electron production workshop, the electrostatic that human body gathers can damage electronic devices and components, the electrostatic gathered at petrochemical industry workshop human body can discharge and produce electrical spark and cause blasting, and therefore existing PVC footwear material can not be applicable to these occasions.
Summary of the invention:
The technical problem to be solved in the present invention is to provide a kind of conduction PVC footwear material, and conductivity is better.
For solving the problems of the technologies described above, technical scheme of the present invention is:
A kind of conduction PVC footwear material, its weight part consists of:
Preferably, plating conductive metallic fiber of the present invention is one or more in silvered glass fiber, silver-plated polyimide fiber, silver-plated trevira or nickel-coated carbon fibers.
Preferably, coupling agent of the present invention is silane coupling agent.
Preferably, strengthening agent of the present invention is white carbon black.
Preferably, softening agent of the present invention to be softening agent be in dioctyl phthalate (DOP), dibutyl phthalate, dioctyl sebacate, tritolyl phosphate, triphenylphosphate one or both.
Preferably, whipping agent of the present invention is one or both in azo foaming agent, nitroso group foaming agent.
Preferably, compatilizer of the present invention is chlorinatedpolyethylene.
Preferably, filler of the present invention is hard calcium carbonate or nano-calcium carbonate.
Another technical problem that the present invention will solve is to provide the manufacture method of above-mentioned conduction PVC footwear material.
For solving the problems of the technologies described above, technical scheme is:
Conduct electricity the manufacture method of PVC footwear material, comprise the following steps:
(1) pre-treatment: dry after plating conductive metallic fiber, coupling agent being stirred by formula;
(2) mixing: by formula by mixing to PVC, softening agent, temperature is 55 ~ 150 DEG C, then other component added in formula is mixing, obtains the material mixed;
(3) extrude: the material that step (2) obtains is added forcing machine, extrude and obtain conduction PVC pellet;
(4) injection moulding: the conduction PVC pellet that step (3) obtains is added injection moulding machine, injection moulding obtains conduction PVC footwear material.
Therefore compared with prior art, the present invention has following beneficial effect:
Under the effect of coupling agent, plating conductive metallic fiber can be scattered in colloid well, improves consistency between the two, defines effective conductive network, make footwear material be provided with good conductivity; Strengthening agent effectively can improve tensile strength, wear resistance, fold resistance, the ageing resistance of footwear material; Softening agent effectively can soften plating conductive metallic fiber, provides plasticity-and mobility.
Embodiment
Describe the present invention in detail below in conjunction with specific embodiment, be used for explaining the present invention in this illustrative examples of the present invention and explanation, but not as a limitation of the invention.
Embodiment 1
A kind of conduction PVC footwear material, its weight part consists of:
Its manufacture method comprises the following steps:
(1) pre-treatment: dry after plating conductive metallic fiber, coupling agent being stirred by formula;
(2) mixing: by formula by mixing to PVC, softening agent, temperature is 150 DEG C, then other component added in formula is mixing, obtains the material mixed;
(3) extrude: the material that step (2) obtains is added forcing machine, extrude and obtain conduction PVC pellet;
(4) injection moulding: the conduction PVC pellet that step (3) obtains is added injection moulding machine, injection moulding obtains conduction PVC footwear material.
Embodiment 2
A kind of conduction PVC footwear material, its weight part consists of:
Its manufacture method comprises the following steps:
(1) pre-treatment: dry after plating conductive metallic fiber, coupling agent being stirred by formula;
(2) mixing: by formula by mixing to PVC, softening agent, temperature is 55 DEG C, then other component added in formula is mixing, obtains the material mixed;
(3) extrude: the material that step (2) obtains is added forcing machine, extrude and obtain conduction PVC pellet;
(4) injection moulding: the conduction PVC pellet that step (3) obtains is added injection moulding machine, injection moulding obtains conduction PVC footwear material.
Embodiment 3
A kind of conduction PVC footwear material, its weight part consists of:
Its manufacture method comprises the following steps:
(1) pre-treatment: dry after plating conductive metallic fiber, coupling agent being stirred by formula;
(2) mixing: by formula by mixing to PVC, softening agent, temperature is 100 DEG C, then other component added in formula is mixing, obtains the material mixed;
(3) extrude: the material that step (2) obtains is added forcing machine, extrude and obtain conduction PVC pellet;
(4) injection moulding: the conduction PVC pellet that step (3) obtains is added injection moulding machine, injection moulding obtains conduction PVC footwear material.
Embodiment 4
A kind of conduction PVC footwear material, its weight part consists of:
Its manufacture method comprises the following steps:
(1) pre-treatment: dry after plating conductive metallic fiber, coupling agent being stirred by formula;
(2) mixing: by formula by mixing to PVC, softening agent, temperature is 80 DEG C, then other component added in formula is mixing, obtains the material mixed;
(3) extrude: the material that step (2) obtains is added forcing machine, extrude and obtain conduction PVC pellet;
(4) injection moulding: the conduction PVC pellet that step (3) obtains is added injection moulding machine, injection moulding obtains conduction PVC footwear material.
Embodiment 5
A kind of conduction PVC footwear material, its weight part consists of:
Its manufacture method comprises the following steps:
(1) pre-treatment: dry after plating conductive metallic fiber, coupling agent being stirred by formula;
(2) mixing: by formula by mixing to PVC, softening agent, temperature is 120 DEG C, then other component added in formula is mixing, obtains the material mixed;
(3) extrude: the material that step (2) obtains is added forcing machine, extrude and obtain conduction PVC pellet;
(4) injection moulding: the conduction PVC pellet that step (3) obtains is added injection moulding machine, injection moulding obtains conduction PVC footwear material.
Embodiment 6
A kind of conduction PVC footwear material, its weight part consists of:
Its manufacture method comprises the following steps:
(1) pre-treatment: dry after plating conductive metallic fiber, coupling agent being stirred by formula;
(2) mixing: by formula by mixing to PVC, softening agent, temperature is 75 DEG C, then other component added in formula is mixing, obtains the material mixed;
(3) extrude: the material that step (2) obtains is added forcing machine, extrude and obtain conduction PVC pellet;
(4) injection moulding: the conduction PVC grain that step (3) obtains is added injection moulding machine, injection moulding obtains conduction PVC sole material.
By the examination criteria of conduction PVC footwear material obtained for embodiment 1 to 6 according to GB GB21148-2007, test its volume resistance respectively, result is respectively 7.3 × 10
5Ω cm, 3.6 × 10
5Ω cm, 2.2 × 10
6Ω cm, 4.9 × 10
5Ω cm, 5.4 × 10
5Ω cm, 8.1 × 10
5Ω cm, conductivity is all better.
Above-described embodiment is illustrative principle of the present invention and effect thereof only, but not for limiting the present invention.Any person skilled in the art scholar all without prejudice under spirit of the present invention and category, can modify above-described embodiment or changes.Therefore, such as have in art usually know the knowledgeable do not depart from complete under disclosed spirit and technological thought all equivalence modify or change, must be contained by claim of the present invention.
Claims (9)
1. a conduction PVC footwear material, is characterized in that: its weight part consists of:
2. one conduction PVC footwear material according to claim 1, is characterized in that: described plating conductive metallic fiber is one or more in silvered glass fiber, silver-plated polyimide fiber, silver-plated trevira or nickel-coated carbon fibers.
3. one conduction PVC footwear material according to claim 1, is characterized in that: described coupling agent is silane coupling agent.
4. one conduction PVC footwear material according to claim 1, is characterized in that: described strengthening agent is white carbon black.
5. one conduction PVC footwear material according to claim 1, is characterized in that: described softening agent is one or both in dioctyl phthalate (DOP), dibutyl phthalate, dioctyl sebacate, tritolyl phosphate, triphenylphosphate.
6. one conduction PVC footwear material according to claim 1, is characterized in that: described whipping agent is one or both in azo foaming agent, nitroso group foaming agent.
7. one conduction PVC footwear material according to claim 1, is characterized in that: described compatilizer is chlorinatedpolyethylene.
8. one conduction PVC footwear material according to claim 1, is characterized in that: described filler is hard calcium carbonate or nano-calcium carbonate.
9. a kind of according to claim 1 ~ 8 any one conducts electricity the manufacture method of PVC footwear material, it is characterized in that: comprise the following steps:
(1) pre-treatment: dry after plating conductive metallic fiber, coupling agent being stirred by formula;
(2) mixing: by formula by mixing to PVC, softening agent, temperature is 55 ~ 150 DEG C, then other component added in formula is mixing, obtains the material mixed;
(3) extrude: the material that step (2) obtains is added forcing machine, extrude and obtain conduction PVC pellet;
(4) injection moulding: the conduction PVC pellet that step (3) obtains is added injection moulding machine, injection moulding obtains conduction PVC footwear material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410566377.3A CN104262860B (en) | 2014-10-22 | A kind of conduction PVC footwear material and manufacture method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410566377.3A CN104262860B (en) | 2014-10-22 | A kind of conduction PVC footwear material and manufacture method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104262860A true CN104262860A (en) | 2015-01-07 |
| CN104262860B CN104262860B (en) | 2017-01-04 |
Family
ID=
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102504440A (en) * | 2011-10-31 | 2012-06-20 | 深圳市新纶科技股份有限公司 | Conducting shoe material and manufacturing method thereof |
| US20130029183A1 (en) * | 2011-07-29 | 2013-01-31 | Fujifilm Corporation | Carbon black composition and usage thereof |
| CN102993603A (en) * | 2012-11-29 | 2013-03-27 | 宁波先锋新材料股份有限公司 | Polyvinyl chloride composite material with microwave absorption property and preparation method thereof |
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20130029183A1 (en) * | 2011-07-29 | 2013-01-31 | Fujifilm Corporation | Carbon black composition and usage thereof |
| CN102504440A (en) * | 2011-10-31 | 2012-06-20 | 深圳市新纶科技股份有限公司 | Conducting shoe material and manufacturing method thereof |
| CN102993603A (en) * | 2012-11-29 | 2013-03-27 | 宁波先锋新材料股份有限公司 | Polyvinyl chloride composite material with microwave absorption property and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104356441B (en) | A kind of wear-resisting antistatic rubber sole and preparation method thereof | |
| CN106010126B (en) | A kind of graphene-based anti-static and abrasion-resistant bicomponent epoxy resin coating | |
| CN103265781B (en) | Acrylic elastomer cable jacket material of a kind of modified hydrotalcite powder and preparation method thereof | |
| CN102863703B (en) | Low-temperature-resistant high-elasticity chlorinated polyethylene blend and preparation method thereof | |
| CN103985453B (en) | There is the cable of strong crushing resistance | |
| CN104231492A (en) | Anti-static PVC sole material and manufacturing method thereof | |
| CN103214774A (en) | Polyvinylchloride insulating electric power cable material and preparation method thereof | |
| CN102816435A (en) | Flame retardation-type rubber insulating flexible cable material and preparation method thereof | |
| CN104262860A (en) | Conductive PVC (polyvinyl chloride) shoe material and manufacturing method thereof | |
| CN104479277A (en) | ABS composite material for plastic toys and preparation method thereof | |
| CN104277356A (en) | Antistatic PVC foamed sole material and manufacturing method thereof | |
| CN105037845A (en) | High-oil-resistance conducting sealant | |
| CN104262857A (en) | Highly wear-resistant PVC (Polyvinyl Chloride) sole material and manufacturing method thereof | |
| CN104262860B (en) | A kind of conduction PVC footwear material and manufacture method thereof | |
| CN102161804A (en) | -R type polrvinyl chloride wire and cable insulation material | |
| CN106589949A (en) | Conductive rubber and preparation method thereof | |
| CN106543487B (en) | A kind of rubber using slag micro powder as rubber filler | |
| CN106346671A (en) | Manufacturing method of polyurethane conductive conveying belt | |
| CN107778560A (en) | A kind of high-strength conductive rubber and preparation method thereof | |
| TW201834835A (en) | Composites reinforced for elastic substance and the manufacturing method for the same | |
| CN106496715B (en) | A kind of microballoon pole plate high-performance rubber material | |
| CN110713642A (en) | Chloroprene rubber sole | |
| CN103881261A (en) | PVC (Polyvinyl Chloride) thermoplastic elastomer cable material and preparation method thereof | |
| CN109385013A (en) | The production method of conductive elastomer, pressure-sensitive circuit board and pressure-sensitive circuit board | |
| CN103539992B (en) | A kind of neoprene cable sheath material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |