CN104262860B - A kind of conduction PVC footwear material and manufacture method thereof - Google Patents
A kind of conduction PVC footwear material and manufacture method thereof Download PDFInfo
- Publication number
- CN104262860B CN104262860B CN201410566377.3A CN201410566377A CN104262860B CN 104262860 B CN104262860 B CN 104262860B CN 201410566377 A CN201410566377 A CN 201410566377A CN 104262860 B CN104262860 B CN 104262860B
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- Prior art keywords
- footwear material
- pvc
- conduction
- conduction pvc
- mixing
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- 229920000915 polyvinyl chloride Polymers 0.000 title claims abstract description 61
- 239000000463 material Substances 0.000 title claims abstract description 56
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 12
- 229920000914 Metallic fiber Polymers 0.000 claims abstract description 13
- 238000007747 plating Methods 0.000 claims abstract description 13
- 239000007822 coupling agent Substances 0.000 claims abstract description 12
- 239000004014 plasticizer Substances 0.000 claims abstract description 12
- 239000004088 foaming agent Substances 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 6
- 230000003014 reinforcing Effects 0.000 claims abstract description 4
- 239000000945 filler Substances 0.000 claims abstract description 3
- 238000001125 extrusion Methods 0.000 claims description 16
- 238000002347 injection Methods 0.000 claims description 16
- 239000007924 injection Substances 0.000 claims description 16
- 239000008188 pellet Substances 0.000 claims description 15
- 230000005611 electricity Effects 0.000 claims description 10
- 238000001746 injection moulding Methods 0.000 claims description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 4
- 239000000835 fiber Substances 0.000 claims description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- 229960003563 Calcium Carbonate Drugs 0.000 claims description 2
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 2
- 239000004709 Chlorinated polyethylene Substances 0.000 claims description 2
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims description 2
- XZZNDPSIHUTMOC-UHFFFAOYSA-N Triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 claims description 2
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 claims description 2
- 239000004917 carbon fiber Substances 0.000 claims description 2
- 239000003365 glass fiber Substances 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 125000000018 nitroso group Chemical group N(=O)* 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N silane Chemical group [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 2
- 229910000077 silane Inorganic materials 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- 229920001721 Polyimide Polymers 0.000 claims 1
- 239000004642 Polyimide Substances 0.000 claims 1
- 238000009825 accumulation Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000002742 anti-folding Effects 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000010892 electric spark Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002466 imines Chemical class 0.000 description 1
- 230000000977 initiatory Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 210000000697 sensory organs Anatomy 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Abstract
The present invention provides a kind of conduction PVC footwear material, and its weight portion consists of: PVC 40～50 parts, plating conductive metallic fiber 10～20 parts, coupling agent 2～10 parts, reinforcing agent 2～5 parts, plasticizer 15～30 parts, foaming agent 1～4 parts, compatilizer 1～10 parts, filler 2～10 parts.The invention also discloses the manufacture method of this conduction PVC footwear material.The electric conductivity of the conduction PVC footwear material that the present invention provides is preferable.
Description
Technical field:
The present invention relates to a kind of footwear material, particularly relate to a kind of conduction PVC footwear material and manufacturer thereof
Method.
Background technology:
PVC i.e. polrvinyl chloride, has stronger active force between molecule, be a kind of hard and crisp
Material；Impact strength is relatively low.After adding impact modifying agent, the elastomer grain of impact modifying agent
Son can reduce total initiation stress, and utilizes deformation and the shear band of particle self, sponges
Impact energy in material, thus reach shock proof purpose.The footwear material that PVC makes has well
Physical property and chemical property, feature is light, and glossiness is strong, makes shoes solid sense organ strong.
But, PVC footwear material does not possess conducting function, it is impossible to eliminate the electrostatic of human body, and raw at electronics
Producing workshop, the electrostatic of human body accumulation can damage electronic devices and components, in the accumulation of petrochemical industry workshop human body
Electrostatic can discharge generation electric spark cause exploding, the most existing PVC footwear material can not be suitable for
In these occasions.
Summary of the invention:
The technical problem to be solved in the present invention is to provide a kind of conduction PVC footwear material, and electric conductivity is relatively
Good.
For solving above-mentioned technical problem, the technical scheme is that
A kind of conduction PVC footwear material, its weight portion consists of:
Described reinforcing agent is white carbon,
Described plasticizer is one or both in tricresyl phosphate, triphenyl phosphate.
Preferably, plating conductive metallic fiber of the present invention is silvered glass fiber, silver-plated polyamides
One or more in imine fiber, silver-plated polyester fiber or nickel-coated carbon fibers.
Preferably, coupling agent of the present invention is silane coupler.
Preferably, during foaming agent of the present invention is azo foaming agent, nitroso group foaming agent
One or both.
Preferably, compatilizer of the present invention is chlorinated polyethylene.
Preferably, filler of the present invention is hard calcium carbonate or nano-calcium carbonate.
Another technical problem that the invention solves the problems that is to provide the manufacture of above-mentioned conduction PVC footwear material
Method.
For solving above-mentioned technical problem, technical scheme is:
A kind of manufacture method conducting electricity PVC footwear material, comprises the following steps:
(1) pretreatment: dry after plating conductive metallic fiber, coupling agent being stirred by formula
Dry；
(2) mixing: by formula by mixing to PVC, plasticizer, temperature is 55～150 DEG C, then
Add other component in formula mixing, the material being uniformly mixed；
(3) extrusion: material step (2) obtained adds extruder, extrusion is conducted electricity
PVC pellet；
(4) injection: conduction PVC pellet step (3) obtained adds injection machine, injection
Molding obtains conduction PVC footwear material.
Therefore, compared with prior art, the method have the advantages that
Under the effect of coupling agent, plating conductive metallic fiber can be well dispersed in colloid,
Improve the compatibility between the two, define effective conductive network so that footwear material is provided with
Preferably electric conductivity；Reinforcing agent can be effectively improved the tensile strength of footwear material, wearability, anti-folding
Property, ageing resistace；Plasticizer can effectively soften plating conductive metallic fiber, it is provided that plasticity and
Mobility.
Detailed description of the invention
The present invention is described in detail, schematic in this present invention below in conjunction with specific embodiment
Embodiment and explanation are used for explaining the present invention, but not as a limitation of the invention.
Embodiment 1
A kind of conduction PVC footwear material, its weight portion consists of:
Its manufacture method comprises the following steps:
(1) pretreatment: dry after plating conductive metallic fiber, coupling agent being stirred by formula
Dry；
(2) mixing: by formula by mixing to PVC, plasticizer, temperature is 150 DEG C, adds
Other component in formula is mixing, the material being uniformly mixed；
(3) extrusion: material step (2) obtained adds extruder, extrusion is conducted electricity
PVC pellet；
(4) injection: conduction PVC pellet step (3) obtained adds injection machine, injection
Molding obtains conduction PVC footwear material.
Embodiment 2
A kind of conduction PVC footwear material, its weight portion consists of:
Its manufacture method comprises the following steps:
(1) pretreatment: dry after plating conductive metallic fiber, coupling agent being stirred by formula
Dry；
(2) mixing: by formula by mixing to PVC, plasticizer, temperature is 55 DEG C, adds
Other component in formula is mixing, the material being uniformly mixed；
(3) extrusion: material step (2) obtained adds extruder, extrusion is conducted electricity
PVC pellet；
(4) injection: conduction PVC pellet step (3) obtained adds injection machine, injection
Molding obtains conduction PVC footwear material.
Embodiment 3
A kind of conduction PVC footwear material, its weight portion consists of:
Its manufacture method comprises the following steps:
(1) pretreatment: dry after plating conductive metallic fiber, coupling agent being stirred by formula
Dry；
(2) mixing: by formula by mixing to PVC, plasticizer, temperature is 100 DEG C, adds
Other component in formula is mixing, the material being uniformly mixed；
(3) extrusion: material step (2) obtained adds extruder, extrusion is conducted electricity
PVC pellet；
(4) injection: conduction PVC pellet step (3) obtained adds injection machine, injection
Molding obtains conduction PVC footwear material.
Embodiment 4
A kind of conduction PVC footwear material, its weight portion consists of:
Its manufacture method comprises the following steps:
(1) pretreatment: dry after plating conductive metallic fiber, coupling agent being stirred by formula
Dry；
(2) mixing: by formula by mixing to PVC, plasticizer, temperature is 80 DEG C, adds
Other component in formula is mixing, the material being uniformly mixed；
(3) extrusion: material step (2) obtained adds extruder, extrusion is conducted electricity
PVC pellet；
(4) injection: conduction PVC pellet step (3) obtained adds injection machine, injection
Molding obtains conduction PVC footwear material.
Embodiment 5
A kind of conduction PVC footwear material, its weight portion consists of:
Its manufacture method comprises the following steps:
(1) pretreatment: dry after plating conductive metallic fiber, coupling agent being stirred by formula
Dry；
(2) mixing: by formula by mixing to PVC, plasticizer, temperature is 120 DEG C, adds
Other component in formula is mixing, the material being uniformly mixed；
(3) extrusion: material step (2) obtained adds extruder, extrusion is conducted electricity
PVC pellet；
(4) injection: conduction PVC pellet step (3) obtained adds injection machine, injection
Molding obtains conduction PVC footwear material.
Embodiment 6
A kind of conduction PVC footwear material, its weight portion consists of:
Its manufacture method comprises the following steps:
(1) pretreatment: dry after plating conductive metallic fiber, coupling agent being stirred by formula
Dry；
(2) mixing: by formula by mixing to PVC, plasticizer, temperature is 75 DEG C, adds
Other component in formula is mixing, the material being uniformly mixed；
(3) extrusion: material step (2) obtained adds extruder, extrusion is conducted electricity
PVC pellet；
(4) injection: conduction PVC grain step (3) obtained adds injection machine, is molded into
Type obtains conduction PVC sole material.
Conduction PVC footwear material embodiment 1 to 6 prepared is according to GB GB21148-2007
Examination criteria, tests its volume resistance respectively, and result is respectively 7.3 × 105Ω·cm、3.6×105
Ω·cm、2.2×106Ω·cm、4.9×105Ω·cm、5.4×105Ω·cm、8.1×105
Ω cm, electric conductivity is preferable.
The principle of above-described embodiment only illustrative present invention and effect thereof, not for restriction
The present invention.Any person skilled in the art all can be in the spirit and the scope without prejudice to the present invention
Under, above-described embodiment is modified or changes.Therefore, such as art has
Generally skill completed under without departing from disclosed spirit and technological thought one
Cut equivalence modify or change, must be contained by the claim of the present invention.
Claims (7)
1. a conduction PVC footwear material, it is characterised in that: its weight portion consists of:
Described reinforcing agent is white carbon,
Described plasticizer is one or both in tricresyl phosphate, triphenyl phosphate.
A kind of conduction PVC footwear material the most according to claim 1, it is characterised in that: institute
Stating plating conductive metallic fiber is silvered glass fiber, silver-plated polyimide fiber, silver-plated polyester fibre
One or more in dimension or nickel-coated carbon fibers.
A kind of conduction PVC footwear material the most according to claim 1, it is characterised in that: institute
Stating coupling agent is silane coupler.
A kind of conduction PVC footwear material the most according to claim 1, it is characterised in that: institute
Stating foaming agent is one or both in azo foaming agent, nitroso group foaming agent.
A kind of conduction PVC footwear material the most according to claim 1, it is characterised in that: institute
Stating compatilizer is chlorinated polyethylene.
A kind of conduction PVC footwear material the most according to claim 1, it is characterised in that: institute
Stating filler is hard calcium carbonate or nano-calcium carbonate.
7. the manufacture of PVC footwear material is conducted electricity according to a kind of described in claim 1～6 any one
Method, it is characterised in that: comprise the following steps:
(1) pretreatment: dry after plating conductive metallic fiber, coupling agent being stirred by formula
Dry；
(2) mixing: by formula by mixing to PVC, plasticizer, temperature is 55～150 DEG C, then
Add other component in formula mixing, the material being uniformly mixed；
(3) extrusion: material step (2) obtained adds extruder, extrusion is conducted electricity
PVC pellet；
(4) injection: conduction PVC pellet step (3) obtained adds injection machine, injection
Molding obtains conduction PVC footwear material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410566377.3A CN104262860B (en) | 2014-10-22 | A kind of conduction PVC footwear material and manufacture method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410566377.3A CN104262860B (en) | 2014-10-22 | A kind of conduction PVC footwear material and manufacture method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104262860A CN104262860A (en) | 2015-01-07 |
| CN104262860B true CN104262860B (en) | 2017-01-04 |
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