CN104262737B - A kind of preparation method and applications of article of everyday use additive - Google Patents
A kind of preparation method and applications of article of everyday use additive Download PDFInfo
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- CN104262737B CN104262737B CN201410331904.2A CN201410331904A CN104262737B CN 104262737 B CN104262737 B CN 104262737B CN 201410331904 A CN201410331904 A CN 201410331904A CN 104262737 B CN104262737 B CN 104262737B
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- everyday use
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- use additive
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
Abstract
The present invention provides the preparation method of a kind of article of everyday use additive, with seaweed plant as raw material, processed by soda acid extraction, enzymolysis processing, microwave treatment and interpolation corrosion-resistant agent, the extraction efficiency of Sargassum active substance can be significantly improved, and by flora fermentation, active component therein is modified making it have decomposition macromolecular mass, remove the functions such as harmful substance, process by adding corrosion-resistant agent, it can be made to be applicable to daily necessities field, be used for improving air ambient.
Description
Technical field
The present invention relates to the preparation method and applications of a kind of article of everyday use additive, particularly to seaweeds
The biological extraction process of Plant functional active substance, using seaweed plant as raw material prepare daily
Product additive application, when article of everyday use, can disperse the macromolecular mass in the material contacted with this article of everyday use,
And play sterilizing and remove the effect of harmful substance.
Background technology
Sargassum belongs to rudimentary plant, and whole frond can absorb inorganic matter from sea water and little molecule has
Machine material makees nutriment, the most also can secret out of organic or inorganic material to surrounding, is grown in sea water complicated
Sargassum in environment, its metabolic process and metabolite are extremely different compared with land plant.Greatly
Most Sargassums contain abundant carbohydrate (xylan, dry dew polysaccharide and sugar alcohol etc.), nitrogenous chemical combination
Thing (aminoacid, peptides, amine, cytochrome C, Benzazole compounds and carbohydrase class etc.), pigment (leaf
Verdazulene, class recklessly trailing plants b element and phycobniliprotein), lipoid substance (triacylglycerol, hydro carbons, wax ester, fat
Fat acid, phospholipid and glycolipid class etc.), phenolic compound, vitamin (precursor of vitamin A and D with
And the water soluble vitamins such as the fatsoluble vitamin such as vitamin E, K and vitamin B group), Sargassum medicine class
(agglutinin etc.) and inorganic constituents etc..Therefore, Sargassum has abundant nutritive value and medical value.
Sargassum extract has drawn from the large-scale economic algae in region, deep-sea, it contain abundant aminoacid,
Mineral, polysaccharide, vitamin and biological active substances, to improving crop yield, improving quality and carrying
Morning is ripe and all has obvious effect at aspects such as fruit freshness preserving and opposing pest and disease damages.Substantial amounts of research table
Extract in some marine algae bright can promote plant growth, increase yield, reduce pest and disease damage,
Increase crop cold resistance, drought-resistant ability.And the article of everyday use additive about making with Sargassum extract is used
Decomposing macromolecular mass, sterilizing, the effect of removal harmful substance have not been reported.
It practice, the character of Sargassum extract and using effect are affected the biggest by extracting mode.At present,
The preparation technology of Sargassum extract mainly has alkali extraction method, neutral water solution, acid extraction method and machinery broken
Broken extraction method.Additionally, also sonioation method, enzymatic isolation method and hot-water soak method.But, at these
In traditional extracting method, the bioactive ingredients of Sargassum is hindered by cell wall main component cellulose
Hinder, it tends to be difficult to be extracted efficiently, the present invention rightly by traditional extraction, enzymatic isolation method with
Microwave treatment combines to improve extraction efficiency, is become by activity in flora fermentation regulation extract simultaneously
The content divided and character, make each component preferably synergism in extract, thus promote macromolecular mass
Decomposition, remove the function such as harmful substance, expand it and improving healthy or air, soil, water environment
In application.
Summary of the invention
It is an object of the invention to provide the preparation method and applications of a kind of article of everyday use additive.
In a first aspect of the present invention, it is provided that a kind of article of everyday use additive dispersibling agglomerate molecule,
By weight percentage, it is mainly composed of water 91.7%, acetic acid 4.2%, carbohydrate 2.4%,
Protein 0.1%.Additionally, possibly together with the lipid of trace, ash, sodium, potassium, calcium, magnesium, phosphorus, ferrum,
Sub-lead, copper, titanium, zinc, zirconium, rhodium, palladium, Vitamin A, vitamin D, Vitamin B1, dimension
He orders B2, nicotinic acid, Vitamin B6, Vitamin B12, folic acid, pantothenic acid, vitamin C.
Another aspect of the present invention, it is provided that the preparation of the above-mentioned article of everyday use additive dispersibling agglomerate molecule
Method, it comprises the following steps:
(1) extraction processes:
Sargassum is cleaned chopping, and with the water of 10～30 times or 10～95% ethanol extraction, temperature is
50～100 DEG C, extract 3 times altogether, merge 3 extracting solution；
(2) microwave treatment:
The extracting solution of step (1) is carried out microwave treatment, radiated time 5-10min, microwave power
800-1200W；
(3) enzymolysis:
The microwave treatment extracting solution of step (2) is evaporated to the 1/3-1/4 of original volume, adds and comprise fibre
Dimension element enzyme, 1,4 beta-glucanase, the compound enzymic preparation of papain, through 30 DEG C of water-bath 8-12 of constant temperature
Take out after hour, put quick-freezing Cheng Bing at-18 DEG C, take out and put thaw at room temperature, this quick-freezing thaw cycle weight
Multiple three times；
(4) flora fermentation:
The volume ratio pressing 1-5% in the enzymolysis solution of step (3) accesses fermentative microflora, and at 25～30 DEG C
Lower sealed fermenting 3～6 days, obtain seaweed extracted liquor；Described fermentative microflora be aspergillus niger, rhizopus,
Trichoderma reesei, Bacillus licheniformis, bacillus subtilis, micrococcus roseum, lactobacillus plantarum,
The fermentative microflora that pseudomonas, Alteromonad, plant yeast, yeast rich in selenium are formed；
(5) activated carbon adsorption is discolored:
Seaweed extracted liquor in step (4) adds activated-charcoal column and carries out decolorization adsorption process, treats this
Filter removal activated-charcoal column after the color substantially transparent of seaweed extracted liquor and obtain article of everyday use additive.
Specifically, described Sargassum raw material is selected from Macrocystis pyrifera (L.) Ag., Fucus Vesiculosus, Alga Sgrgassi Enerves, sea capsule algae, bubble leaf
Algae, red algae any one, or select the mixing of two or more Sargassum thing.Preferably Alga Sgrgassi Enerves, more preferably
State, Wei Alga Sgrgassi Enerves or Sargassum henslowianum.
According to another aspect of the present invention, above-mentioned steps (1) can use mechanical shock cutting mill,
Air blast ultramicro powder comminution, ball mill, Ball-stirring mill or vibromill carry out micronizing.
According to another aspect of the present invention, the compound enzymic preparation used in above-mentioned steps (3) is by weight
Amount portion rate be 1.2～3.6:2.1～5.2:1.6～4.5 cellulase, 1,4 beta-glucanase, Fructus Chaenomelis
Protease forms.Preferably ratio of weight and number 1.2:2.1:1.6.
According to another aspect of the present invention, described in above-mentioned steps (4), fermentation condition is: temperature
28 DEG C, original ph 6.5, mixing speed 100r/min, intermittent stirring 5min/2h, fermentation period
72 hours.
According to another aspect of the invention, in above-mentioned steps (4), fermentative microflora by ratio of weight and number is
The aspergillus niger of 1.8:1.2:1.6:1.1:1.5:3.1:2.4:2.7:1.9:1.3:1, rhizopus, inner
Family name's Trichoderma spp., Bacillus licheniformis, bacillus subtilis, micrococcus roseum, lactobacillus plantarum, vacation
Zymomonas mobilis, Alteromonad, plant yeast, yeast rich in selenium form.
Described article of everyday use includes kitchenware and sanitary ware, bath accessory.
Described kitchenware and sanitary ware includes ferment bucket, lunch box, chopsticks basket, energy cup, and described bath accessory includes
Tooth glass, toothbrush.
Described article of everyday use additive is added in food-grade polyethylene plastic pellet, passes through injection mo(u)lding
Described food-grade polyethylene plastic pellet is molded into energy cup.
The article of everyday use additive that the present invention provides, metallic element therein can form gold during the fermentation
Belong to oxide or metal complex, the extract obtained after above-mentioned fermentation is made in the supercritical state
The super micro nano particle of metal-oxide, this super micro nano particle has high far infrared transmission ability,
The far infrared of its radiation contacts or non-contacting material near acting on, and such as big water clusters, makes
Hydrone produces resonance absorption, so that the hydrogen bond rupture between portion of water, makes this part water
Molecule can separate, and then make water molecule cluster diminish and activated.And this article of everyday use is by being molded into
When type or other dry means make powder body or other solids exist in article of everyday use, its super micro nano particle
Presented in can be in ultra-fine nanocrystallines, the most active, contact it is thus possible to purify with article of everyday use
Material, such as rice, water.
Detailed description of the invention
Embodiment 1: containing the preparation of the article of everyday use additive of state, Wei gulfweed extract
Take state, 100g Wei Alga Sgrgassi Enerves and clean chopping, prepare as steps described below:
(1) extraction processes:
With the water extraction of 30 times, temperature is 100 DEG C, extracts 3 times altogether, merges 3 extracting solution；
(2) microwave treatment:
The extracting solution of step (1) is carried out microwave treatment, radiated time 10min, microwave power 1200W；
(3) enzymolysis:
The microwave treatment extracting solution of step (2) is evaporated to the 1/3 of original volume, adds parts by weight
Cellulase than 1.2:2.1:1.6,1,4 beta-glucanase, the compound enzymic preparation of papain composition,
Take out after 30 DEG C of water-baths of constant temperature 8 hours, quick-freezing Cheng Bing at putting-18 DEG C, take out and put thaw at room temperature,
This quick-freezing thaw cycle is in triplicate；
(4) flora fermentation:
In the enzymolysis solution of step (3), the volume ratio by 5% accesses fermentative microflora, and close at 25 DEG C
Close fermentation 3 days, obtain extracting solution；Described fermentative microflora be aspergillus niger, rhizopus, trichoderma reesei,
Clothing bacillus cereus, bacillus subtilis, micrococcus roseum, lactobacillus plantarum, pseudomonas, friendship
The fermentative microflora formed for Zymomonas mobilis, plant yeast, yeast rich in selenium；
(5) activated carbon adsorption is discolored:
Seaweed extracted liquor in step (4) adds activated-charcoal column and carries out decolorization adsorption process, treats this
Filter removal activated-charcoal column after the color substantially transparent of seaweed extracted liquor and obtain article of everyday use additive.Pass through
Desolventing technology so that this article of everyday use additive does not has color, thus does not interferes with article of everyday use when application
Color.
Embodiment 2: go back the preparation of the article of everyday use additive of Sargassum henslowianum extracting solution
Take 100g Sargassum henslowianum and clean chopping, prepare as steps described below:
(1) extraction processes:
With 95% ethanol extraction of 10 times, temperature is 50 DEG C, extracts 3 times altogether, merges 3 extractions
Liquid；
(2) microwave treatment:
The extracting solution of step (1) is carried out microwave treatment, radiated time 5min, microwave power 800W；
(3) enzymolysis:
The microwave treatment extracting solution of step (1) is evaporated to the 1/4 of original volume, adds parts by weight
Cellulase than 3.6:5.2:4.5,1,4 beta-glucanase, the compound enzymic preparation of papain composition,
Take out after 30 DEG C of water-baths of constant temperature 8 hours, quick-freezing Cheng Bing at putting-18 DEG C, take out and put thaw at room temperature,
This quick-freezing thaw cycle is in triplicate；
(4) flora fermentation:
In the enzymolysis solution of step (3), the volume ratio by 2% accesses fermentative microflora, and close at 30 DEG C
Close fermentation 6 days, obtain extracting solution；Described fermentative microflora be aspergillus niger, rhizopus, trichoderma reesei,
Clothing bacillus cereus, bacillus subtilis, micrococcus roseum, lactobacillus plantarum, pseudomonas, friendship
The fermentative microflora formed for Zymomonas mobilis, plant yeast, yeast rich in selenium；
(5) activated carbon adsorption is discolored:
Seaweed extracted liquor in step (4) adds activated-charcoal column and carries out decolorization adsorption process, treats this
Filter removal activated-charcoal column after the color substantially transparent of seaweed extracted liquor and obtain article of everyday use additive.Pass through
Desolventing technology so that this article of everyday use additive does not has color, thus does not interferes with article of everyday use when application
Color.
Embodiment 3: the measure of merit of activated water
The article of everyday use additive that above-described embodiment 1,2 prepares is added on food-grade polyethylene respectively mould
In material particle, by injection mo(u)lding, described food-grade polyethylene plastic pellet is molded into energy cup 1 He
Energy cup 2.
A group: take in undressed common 10mL tap water, filters after 10min, centrifugation, takes
Supernatant testing moisture17O nuclear magnetic resonance, NMR halfwidth (NMRFWHM).
B group: take undressed common 10mL tap water and put in energy cup 1, static 12
Filter after hour, centrifugation, take supernatant testing moisture17O nuclear magnetic resonance, NMR halfwidth
(NMRFWHM)。
C group: take undressed common 10mL tap water and put in energy cup 2, static 12
Filter after hour, centrifugation, take supernatant testing moisture17O nuclear magnetic resonance, NMR halfwidth
(NMRFWHM)。
Test instrunment is the NMR spectrometer with superconducting magnet of BruckerAVANCE III 400MHz, foundation
JY/T007-1996 superconducting pulse fourier transform NMR spectral method is measured.
Test result: it is as shown in the table for half peak height of 3 groups of samples:
| Sample | Half peak height/Hz |
| A group: tap water | 78 |
| B group: activated water | 54 |
| C group: activated water | 52 |
Table 1
It is indicated above that energy cup 1,2 all can reduce the 17ONMR halfwidth of hydrone, i.e. carry
Having the ratio of the subset of 5～6 associated water molecules in high water, hydrone activity is carried
High.
Embodiment 4: the measure of merit of ferment
The article of everyday use additive that above-described embodiment 1,2 prepares is added on food-grade polyethylene respectively mould
In material particle, by injection mo(u)lding, described food-grade polyethylene plastic pellet is molded into ferment bucket 1 He
Ferment bucket 2.Ferment 1 and ferment 2 is prepared, according to GB respectively with ferment bucket 1 and ferment bucket 2
19297-2003, GB2760-2011 national standard, detection method is to prepared ferment 1 and ferment
2 test.(experiment condition: temperature 20 DEG C ± 2 DEG C；Relative humidity 50% ± 10%), detection knot
Fruit see table:
Sample detection account
To sum up, the article of everyday use additive that the present invention provides, metallic element therein during the fermentation may be used
Form metal-oxide or metal complex, by the extract that obtains after above-mentioned fermentation in supercriticality
Under make the super micro nano particle of metal-oxide, this super micro nano particle has high far infrared transmission
Ability, the far infrared of its radiation acts on neighbouring contact or non-contacting material, such as big hydrone
Group, makes hydrone produce resonance absorption, so that the hydrogen bond rupture between portion of water, makes this
Portion of water can separate, and then make water molecule cluster diminish and activated.And this article of everyday use passes through
When injection mo(u)lding or other dry means make powder body or other solids exist in article of everyday use, its ultra micro is received
Presented in rice corpuscles can be in ultra-fine nanocrystallines, the most active, it is thus possible to purify with daily
The material of product contact, such as rice, water.
It should be appreciated that the above-mentioned detailed description of the invention of the present invention is used only for exemplary illustration or solution
Release the principle of the present invention, and be not construed as limiting the invention.Therefore, in the essence without departing from the present invention
Any modification, equivalent substitution and improvement etc. done in the case of god and scope, should be included in this
Within bright protection domain.Want additionally, claims of the present invention are intended to fall into appended right
That asks in the equivalents on scope and border or this scope and border whole changes and modifications example.
Claims (8)
1. the preparation method of an article of everyday use additive, it is characterised in that comprise the following steps:
(1) extraction processes:
Sargassum is cleaned chopping, and with the water of 10～30 times or 10～95% ethanol extraction, temperature is
50～100 DEG C, extract 3 times altogether, merge 3 extracting solution；
(2) microwave treatment:
The extracting solution of step (1) is carried out microwave treatment, radiated time 5-10min, microwave power
800-1200W；
(3) enzymolysis:
The microwave treatment extracting solution of step (2) is evaporated to the 1/3-1/4 of original volume, adds and comprise fibre
Dimension element enzyme, 1,4 beta-glucanase, the compound enzymic preparation of papain, through 30 DEG C of water-bath 8-12 of constant temperature
Take out after hour, put quick-freezing Cheng Bing at-18 DEG C, take out and put thaw at room temperature, this quick-freezing thaw cycle weight
Multiple three times；
(4) flora fermentation:
The volume ratio pressing 1-5% in the enzymolysis solution of step (3) accesses fermentative microflora, and at 25～30 DEG C
Lower sealed fermenting 3～6 days, obtain seaweed extracted liquor；Described fermentative microflora be aspergillus niger, rhizopus,
Trichoderma reesei, Bacillus licheniformis, bacillus subtilis, micrococcus roseum, lactobacillus plantarum,
The fermentative microflora that pseudomonas, Alteromonad, plant yeast, yeast rich in selenium are formed；
(5) activated carbon adsorption is discolored:
Seaweed extracted liquor in step (4) adds activated-charcoal column and carries out decolorization adsorption process, treats this
Filter removal activated-charcoal column after the color substantially transparent of seaweed extracted liquor and obtain article of everyday use additive.
2. the preparation method of an article of everyday use additive as claimed in claim 1, it is characterised in that institute
State Sargassum be Macrocystis pyrifera (L.) Ag., Fucus Vesiculosus, Alga Sgrgassi Enerves, sea capsule algae, yellow tang, red algae any one, or choosing
Mixing with two or more Sargassum things.
3. the preparation method of an article of everyday use additive as claimed in claim 1, it is characterised in that step
Suddenly the consisting of of compound enzymic preparation described in (3): cellulase, 1,4 beta-glucanase, papain
Weight is 1.2～3.6:2.1～5.2:1.6～4.5.
4. the preparation method of an article of everyday use additive as claimed in claim 1, it is characterised in that step
Suddenly described in (4), fermentation condition is: temperature 28 DEG C, original ph 6.5, mixing speed 100r/min,
Intermittent stirring 5min/2h, fermentation period 72 hours.
5. the preparation method of an article of everyday use additive as claimed in claim 1, it is characterised in that institute
The seaweed extracted liquor stated, its extracting solution includes following main component:
And the lipid of trace, ash, sodium, potassium, calcium, magnesium, phosphorus, ferrum, sub-lead, copper, titanium,
Zinc, zirconium, rhodium, palladium, Vitamin A, vitamin D, Vitamin B1, Verdoflavin, nicotinic acid,
Vitamin B6, Vitamin B12, folic acid, pantothenic acid, vitamin C.
6. the preparation method of an article of everyday use additive as claimed in claim 1, it is characterised in that
Described article of everyday use includes kitchenware and sanitary ware, bath accessory.
7. the preparation method of an article of everyday use additive as claimed in claim 6, it is characterised in that
Described kitchenware and sanitary ware includes ferment bucket, lunch box, chopsticks basket, energy cup, and described bath accessory includes gargling
Cup, toothbrush.
8. the application of an article of everyday use additive, it is characterised in that by by the side described in claim 1
Article of everyday use additive prepared by method is added in food-grade polyethylene plastic pellet, will by injection mo(u)lding
Described food-grade polyethylene plastic pellet is molded into energy cup.
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| CN107573544A (en) * | 2017-07-31 | 2018-01-12 | 浦江县昂宝生物技术有限公司 | The preparation method of edible packing membrane based on sargassan |
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| CN101445819A (en) * | 2008-12-22 | 2009-06-03 | 重庆大学 | Method for preparing hydrolyzed oligosaccharides and short peptides from salt algae residues |
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| WO2010042842A2 (en) * | 2008-10-09 | 2010-04-15 | Eudes De Crecy | A method of producing fatty acids for biofuel, biodiesel, and other valuable chemicals |
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| CN101445819A (en) * | 2008-12-22 | 2009-06-03 | 重庆大学 | Method for preparing hydrolyzed oligosaccharides and short peptides from salt algae residues |
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