CN104250535A - Solvent type ABS glue for transfer printing, and preparation method thereof - Google Patents
Solvent type ABS glue for transfer printing, and preparation method thereof Download PDFInfo
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- CN104250535A CN104250535A CN201310267732.2A CN201310267732A CN104250535A CN 104250535 A CN104250535 A CN 104250535A CN 201310267732 A CN201310267732 A CN 201310267732A CN 104250535 A CN104250535 A CN 104250535A
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- transfer printing
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Abstract
The present invention relates to a solvent type ABS glue for transfer printing, and a preparation method thereof. The raw materials comprise, by weight, 10-50 parts of an acrylic acid resin or a methacrylic acid resin, 0-20 parts of nitrocellulose, 0.1-5 parts of an anti-sticking additive, and 50-90 parts of an organic solvent. The preparation method comprises: sequentially adding the acrylic acid resin or the methacrylic acid resin, the nitrocellulose, the anti-sticking additive and the solvent to a reaction kettle according to the formula, and stirring at a normal temperature under normal pressure under controlling to make the raw materials uniformly mix so as to prepare the solvent type ABS glue for transfer printing. Compared with the solvent type ABS glue for transfer printing in the prior art, the solvent type ABS glue for transfer printing in the present invention has advantages of simple production process, good adhesion to a variety of ABS-type substrates, low production cost and the like.
Description
Technical field
The present invention relates to a kind of preparation method of ABS glue, especially relate to a kind of transfer printing solvent-borne type ABS glue and preparation method thereof.
Background technology
Hot transfer printing is a newer typography, it is made up of carrier of undertaking the printing of (being generally PET biaxially oriented polyester film), release layer, ink layer, gum layer, then through certain pressure, temperature, ink layer is stripped down from carrier of undertaking the printing of by thermoprinting machine, by the bonding effect of glue pattern is attached to securely and is transferred on base material.This technology is widely used in the industry such as packaging, decoration of daily necessities, building materials, engine oil drum etc.And according to being transferred the difference of base material material, need different glue.And ABS class material (comprising ABS, AS, PMMA, PC, PS etc.) is a kind of plastic material be widely used in stationery, cosmetic industry, as the penholder, lead box, correction tape, ruler, writing case etc. of stationery industry, the powder box, Mascara pipe etc. of cosmetic industry are all make with ABS class material.And the ABS glue of domestic thermal-transfer line industry relies on import mostly, price is higher; And because domestic transfer printing industry is because its material used is comparatively assorted, processing feed back is more, the ABS glue adaptability of a lot of import is narrower, the base material of many clients all can not normally transfer printing or sticking power inadequate.
The present invention screens one or more have better adhesiveproperties resin to the ABS substrate that makes preparations for sowing, adds one or more auxiliary agents, makees thinner with organic solvent, produce the ABS glue being applicable to hot transfer printing.
Summary of the invention
Object of the present invention is exactly provide a kind of production process simple to overcome defect that above-mentioned prior art exists, good to multiple ABS class base material sticking power, and low transfer printing solvent-borne type ABS glue of cost of manufacture and preparation method thereof.
Object of the present invention can be achieved through the following technical solutions:
A kind of transfer printing solvent-borne type ABS glue, is made up of following component and weight part content:
Described acrylic resin or methacrylic resin are for have good adhesion thermoplastic acrylic resin or thermoplastic methacrylic resin to ABS, PC, PVC or PS plastics.
Described acrylic resin or methacrylic resin are the Emulsion acrylic resin of 40-60wt%.
Described acrylic resin or methacrylic resin are commercially available ALMATEX L1093, Inalic T8238 type resin, SN-9700 or PU-10 (B) resin.
Described nitro-cotton is nitrogen content is that 11-13wt% biological nitration is cotton, and range of viscosities is 1/8 second-60 seconds, and because nitro-cotton burning-point is lower, the butanone solution being preferably made into 10-40% in order to safety is deposited.
Described antiseized auxiliary agent is the antiseized auxiliary agent of the antiseized auxiliary agent of silicon system or organic wax system, increases the smoothness of adhesive layer, prevents the sticky back of the body of printed matter in storage process.
Described organic solvent is toluene, methyl ethyl ketone or vinyl acetic monomer.
The method adds acrylic resin or methacrylic resin, nitro-cotton, antiseized auxiliary agent and solvent successively by formula in reactor, and then at normal temperatures and pressures, control stirring makes above-mentioned raw materials mix and namely prepares transfer printing solvent-borne type ABS glue.
Mixing speed is 2000-5000 rev/min; Churning time is 10-50 minute.
Compared with prior art, the present invention has the following advantages:
1) the present invention prepares simply, operational safety, only needs simple container, without the need to heating, through mechanical stirring;
2) the present invention selects acrylic resin and nitro-cotton, and this resinoid does not have active group, stable chemical nature, and the glue of preparation is placed for a long time also can not sex change;
3) the acrylic resin bonding force selected of the present invention is strong, and the nitro-cotton selected has the effect promoting sticking power to ABS substrate, and the glue sticking power of preparation is excellent, has excellent sticking power to multiple ABS class material and ink layer, coating;
4) the antiseized auxiliary agent of silicon-type that the present invention selects can well improve the easy adhesive of glue, the organic wax system auxiliary agent selected can strengthen the slipping of glue, therefore the anti-stick back of the body of the glue prepared is good, and the transfer film produced is deposited can not instead glue in summer.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail.
Embodiment 1
In batching kettle, add 20 parts of acrylic resin liquid successively, ALMATEX L1093 can be selected; Add 10 parts of NC solution again, viscosity can be selected to be the NC of 1/8 second; 1 part of antiseized auxiliary agent, can select W ' Add1500; 69 parts of toluene; Then start stirrer, rotating speed is 5000 revs/min, and stir 30 minutes, this glue in use suitably can rush rare according to viscosity requirement toluene.
Embodiment 2
In batching kettle, add 25 parts of acrylic resin liquid successively, Inalic T8238 type can be selected; Adding 5.5 parts of NC solution again, can viscosity be the NC of 1/2 second; Add 0.5 part of antiseized auxiliary agent again, 818S solvent-borne type wax can be selected to starch; 40 parts of toluene, 29 parts of methyl ethyl ketones; Then start stirrer, rotating speed is 6000 revs/min, and stir 20 minutes, this glue in use suitably can rush rare according to viscosity requirement toluene.
Embodiment 3
In batching kettle, add 28.5 parts of acrylic resin liquid successively, can SN-9700 be selected; 1.5 parts of antiseized auxiliary agents, can select the sliding flow agent of A-960 organic silicon rigidity-increasing; Then 35 parts of toluene, 35 parts of vinyl acetic monomers start stirrer, and rotating speed is 4000 revs/min, and stir 40 minutes, this glue in use suitably can rush rare according to viscosity requirement toluene.
The ABS glue standby in order to top legal system carries out intaglio plate coating, roller netting twine is 175 lines, glue viscosity is 20 seconds, coating machine speed 60m/min, the transfer film after coating scalds ABS material, PC material, PMMA material workpiece, thermoprinting machine temperature 230 degree, rubber tire moderate pressure, rubber tire linear velocity is 80cm/min, and the 3M of the workpiece after transfer printing detects adhesive tape test glue sticking power, comes off without ink layer.
Embodiment 4
A kind of transfer printing solvent-borne type ABS glue, is made up of following component and weight part content:
Acrylic resin 10, antiseized auxiliary agent 0.1, organic solvent 50, wherein, the acrylic resin of use is for have good adhesion thermoplastic acrylic resin to ABS, PC, PVC or PS plastics, and the present embodiment adopts the Emulsion acrylic resin of 40wt%.Antiseized auxiliary agent is the antiseized auxiliary agent of the antiseized auxiliary agent of silicon system or organic wax system, increases the smoothness of adhesive layer, prevents the sticky back of the body of printed matter in storage process.Organic solvent adopts vinyl acetic monomer.
The method adds acrylic resin or methacrylic resin, antiseized auxiliary agent and solvent successively by formula in reactor, then at normal temperatures and pressures, controlling mixing speed is 2000 revs/min, stirs 50 minutes, above-mentioned raw materials is mixed and namely prepares transfer printing solvent-borne type ABS glue.
Embodiment 5
A kind of transfer printing solvent-borne type ABS glue, is made up of following component and weight part content: methacrylic resin 50; Nitro-cotton 20; Antiseized auxiliary agent 5; Organic solvent 90, wherein, the methacrylic resin of use is thermoplastic methacrylic resin ABS, PC, PVC or PS plastics being had to good adhesion, can be commercially available ALMATEX L1093 resin.Nitro-cotton is nitrogen content is that 13wt% biological nitration is cotton, and range of viscosities is 60 seconds, and because nitro-cotton burning-point is lower, the butanone solution being preferably made into 10% in order to safety is deposited.Antiseized auxiliary agent is the antiseized auxiliary agent of the antiseized auxiliary agent of silicon system or organic wax system, increases the smoothness of adhesive layer, prevents the sticky back of the body of printed matter in storage process.Organic solvent adopts toluene.
The method adds acrylic resin or methacrylic resin, antiseized auxiliary agent and solvent successively by formula in reactor, then at normal temperatures and pressures, controlling mixing speed is 5000 revs/min, stirs 10 minutes, above-mentioned raw materials is mixed and namely prepares transfer printing solvent-borne type ABS glue.
Claims (9)
1. a transfer printing solvent-borne type ABS glue, is characterized in that, is made up of following component and weight part content:
2. a kind of transfer printing solvent-borne type ABS glue according to claim 1, it is characterized in that, described acrylic resin or methacrylic resin are for have good adhesion thermoplastic acrylic resin or thermoplastic methacrylic resin to ABS, PC, PVC or PS plastics.
3. a kind of transfer printing solvent-borne type ABS glue according to claim 1 and 2, it is characterized in that, described acrylic resin or methacrylic resin are the Emulsion acrylic resin of 40-60wt%.
4. a kind of transfer printing solvent-borne type ABS glue according to claim 1 and 2, it is characterized in that, described acrylic resin or methacrylic resin are commercially available ALMATEX L1093, Inalic T8238 type resin, SN-9700 or PU-10 (B) resin.
5. a kind of transfer printing solvent-borne type ABS glue according to claim 1, is characterized in that, described nitro-cotton is nitrogen content is that 11-13wt% biological nitration is cotton, and range of viscosities is 1/8 second-60 seconds.
6. a kind of transfer printing solvent-borne type ABS glue according to claim 1, is characterized in that, described antiseized auxiliary agent is the antiseized auxiliary agent of the antiseized auxiliary agent of silicon system or organic wax system, increases the smoothness of adhesive layer, prevents the sticky back of the body of printed matter in storage process.
7. a kind of transfer printing solvent-borne type ABS glue according to claim 1, it is characterized in that, described organic solvent is toluene, methyl ethyl ketone or vinyl acetic monomer.
8. the preparation method of solvent-borne type ABS glue of the transfer printing according to any one of claim 1-7, it is characterized in that, in reactor, acrylic resin or methacrylic resin, nitro-cotton, antiseized auxiliary agent and solvent is added successively by filling a prescription, then at normal temperatures and pressures, control stirring makes above-mentioned raw materials mix and namely prepares transfer printing solvent-borne type ABS glue.
9. the preparation method of a kind of transfer printing solvent-borne type ABS glue according to claim 8, it is characterized in that, mixing speed is 2000-5000 rev/min; Churning time is 10-50 minute.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201310267732.2A CN104250535B (en) | 2013-06-28 | 2013-06-28 | A kind of transfer solvent-borne type ABS glue and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310267732.2A CN104250535B (en) | 2013-06-28 | 2013-06-28 | A kind of transfer solvent-borne type ABS glue and preparation method thereof |
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| CN104250535A true CN104250535A (en) | 2014-12-31 |
| CN104250535B CN104250535B (en) | 2016-12-28 |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107245316A (en) * | 2017-05-17 | 2017-10-13 | 湖北三江航天江河橡塑有限公司 | It is a kind of for adhesive of ABS plastic part and preparation method thereof |
| CN109517542A (en) * | 2018-11-13 | 2019-03-26 | 香洋新材料（江苏）有限公司 | A kind of transfer film high grade of transparency ABS glue and preparation method thereof |
| CN112630990A (en) * | 2020-12-21 | 2021-04-09 | 浙江清华柔性电子技术研究院 | Intelligent contact lens and preparation method thereof |
| CN112874067A (en) * | 2021-01-11 | 2021-06-01 | 安徽和美瑞医用包装材料有限公司 | Medical blister film suitable for bubble cap of packing |
| CN114854341A (en) * | 2022-05-27 | 2022-08-05 | 朱宏达 | ABS glue for thermal transfer printing and manufacturing method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006272841A (en) * | 2005-03-30 | 2006-10-12 | Dainippon Printing Co Ltd | Antistatic decorative sheet restrained from being whitened when bent |
| CN101280165A (en) * | 2008-05-21 | 2008-10-08 | 山东福源聚氨酯工业有限公司 | Hot-transfer thermoprinting adhesive for electrical aluminum |
| CN102702865A (en) * | 2012-06-14 | 2012-10-03 | 上海古信机电设备有限公司 | Single transfer coating |
-
2013
- 2013-06-28 CN CN201310267732.2A patent/CN104250535B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006272841A (en) * | 2005-03-30 | 2006-10-12 | Dainippon Printing Co Ltd | Antistatic decorative sheet restrained from being whitened when bent |
| CN101280165A (en) * | 2008-05-21 | 2008-10-08 | 山东福源聚氨酯工业有限公司 | Hot-transfer thermoprinting adhesive for electrical aluminum |
| CN102702865A (en) * | 2012-06-14 | 2012-10-03 | 上海古信机电设备有限公司 | Single transfer coating |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107245316A (en) * | 2017-05-17 | 2017-10-13 | 湖北三江航天江河橡塑有限公司 | It is a kind of for adhesive of ABS plastic part and preparation method thereof |
| CN109517542A (en) * | 2018-11-13 | 2019-03-26 | 香洋新材料（江苏）有限公司 | A kind of transfer film high grade of transparency ABS glue and preparation method thereof |
| CN112630990A (en) * | 2020-12-21 | 2021-04-09 | 浙江清华柔性电子技术研究院 | Intelligent contact lens and preparation method thereof |
| CN112874067A (en) * | 2021-01-11 | 2021-06-01 | 安徽和美瑞医用包装材料有限公司 | Medical blister film suitable for bubble cap of packing |
| CN114854341A (en) * | 2022-05-27 | 2022-08-05 | 朱宏达 | ABS glue for thermal transfer printing and manufacturing method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104250535B (en) | 2016-12-28 |
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Address after: Jiading Industrial Zone, 201807 North Shanghai City Xingxian Road No. 599 Applicant after: RESPLENDENT (SHANGHAI) SPECIAL DECAL CO.,LTD. Address before: Jiading Industrial Zone, 201807 North Shanghai City Xingxian Road No. 599 Applicant before: RESPLENDENT(SHANGHAI)SPECIALDECAL Co.,Ltd. Address after: Jiading Industrial Zone, 201807 North Shanghai City Xingxian Road No. 599 Applicant after: RESPLENDENT(SHANGHAI)SPECIALDECAL Co.,Ltd. Address before: 201807 Shanghai city Jiading District Xingxian Road No. 599 Applicant before: RESPIENDENT (SHANGHAI) SPECIAL DECAL Co.,Ltd. |
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Effective date of registration: 20211213 Address after: 201807 zone B, floor 1, building 3, No. 599, Xingxian Road, Jiading Industrial Zone, Jiading District, Shanghai Patentee after: Shanghai Huagong Aimar New Material Co.,Ltd. Address before: 201807 No. 599, Xingxian Road, North District, Jiading Industrial Zone, Shanghai Patentee before: RESPLENDENT (SHANGHAI) SPECIAL DECAL CO.,LTD. |