CN109517542A - A kind of transfer film high grade of transparency ABS glue and preparation method thereof - Google Patents
A kind of transfer film high grade of transparency ABS glue and preparation method thereof Download PDFInfo
- Publication number
- CN109517542A CN109517542A CN201811347610.3A CN201811347610A CN109517542A CN 109517542 A CN109517542 A CN 109517542A CN 201811347610 A CN201811347610 A CN 201811347610A CN 109517542 A CN109517542 A CN 109517542A
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- resin
- transparency
- transfer film
- parts
- abs glue
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
The present invention discloses a kind of transfer film high grade of transparency ABS glue, including following ingredient according to the mass fraction: 15-40 parts of thermoplastic acrylic resin；0-5 parts of vinyl chloride-vinyl acetate resin；0-5 parts of coumarone indene resin；50-85 parts of organic solvent.The ABS glue transparency is splendid, applied widely, can be widely used for penholder and daily necessities industry, especially high-end daily necessities industry；The resin softening point of use is moderate, there is outstanding anti-reflective viscosity energy in the case where guaranteeing transparency；Replace toluene, the butanone solvent of easily making malicious class using esters solvent, safety and the relatively existing ABS glue of the feature of environmental protection are all with being obviously improved；Using low-molecular-weight resin system, can guarantee has excellent transfer performance and trimming performance in ABS substrate.
Description
Technical field
The present invention relates to the technical fields of adhesive, and in particular to a kind of transfer film high grade of transparency ABS glue and its preparation
Method.
Background technique
Heat transfer film is a kind of dielectric material of caloric transfer printing technology.Thermal transfer decoration technology is disposable by heat transfer film
Decorative pattern in thermal transfer, is needed on the process on decorative building material surface, being formed high-quality facing film by heating.In thermal transfer
In the process, separate protective layer and pattern layer from polyester substrate using the collective effect of heat and pressure, hot melt adhesive makes entirely to fill
It adorns layer and substrate is permanently glued.ABS (acrylonitrile-butadiene-styrene (ABS)) resin is due to good mechanical property and processability
Can, therefore ABS plastic is widely used in packaging industry, especially in stationery, building materials and daily necessities industry.At present in transfer film industry
There is anti-viscous phenomenon in winding in order to prevent in the ABS glue of use, and it is anti-to improve often to add the auxiliary agent of the wax powder class of opaque class
Viscous phenomenon, basic ABS glue is all opaque muddy shape, and the main solvent for the ABS glue that transfer film industry uses at present is with toluene
Based on butanone.
Summary of the invention
The object of the present invention is to provide a kind of transfer film high grade of transparency ABS glue and preparation method thereof, solve above-mentioned existing
One or more in technical problem.
The present invention provides a kind of transfer film high grade of transparency ABS glue, including following ingredient according to the mass fraction:
15-40 parts of thermoplastic acrylic resin；
0-5 parts of vinyl chloride-vinyl acetate resin；
0-5 parts of coumarone indene resin；
50-85 parts of organic solvent.
In some embodiments, it is 40-90 DEG C that thermoplastic acrylic resin, which is glass temperature range, the thermoplasticity
The molecular weight ranges of acrylic resin are 2w-7w.
In some embodiments, vinyl chloride-vinyl acetate resin is carboxyl acid modified ternary chlorine vinegar resin, content of vinylchloride 84%, vinegar
Sour ethylene contents are 15%, maleic content 1%.
In some embodiments, the softening point of coumarone indene resin be 100-140 DEG C, the coumarone indene resin be it is colourless or
It is faint yellow.
In some embodiments, organic solvent be ethyl acetate, n-propyl acetate, it is a kind of or several in n-butyl acetate
Kind.
A kind of preparation method of transfer film high grade of transparency ABS glue, comprising the following steps:
S1, organic solvent is put into reaction kettle, blender revolving speed is at 800-1500 revs/min；
S2, it is kept stirring and thermoplastic acrylic resin, vinyl chloride-vinyl acetate resin and coumarone indene resin is successively put into reaction kettle
In, it stirs 0.5-2.5 hours；
S3, it is to be mixed completely, after solution clear, using 220 mesh filter screens, filtering obtains the transfer film and uses
High grade of transparency ABS glue.
The utility model has the advantages that
The transfer film of the exploitation of the embodiment of the present invention with high grade of transparency ABS glue compared with prior art:
1, the ABS glue transparency of the embodiment of the present invention is splendid, applied widely, can be widely used for penholder and daily conduct
Industry, especially high-end daily necessities industry；
2, the resin softening point that the ABS glue of the embodiment of the present invention uses is moderate, has in the case where guaranteeing transparency outstanding
Anti-reflective viscosity energy；
3, the ABS glue of the embodiment of the present invention replaces toluene, the butanone solvent of easily making malicious class using esters solvent, safety and
The relatively existing ABS glue of the feature of environmental protection is all with being obviously improved；
4, the ABS glue of the embodiment of the present invention uses low-molecular-weight resin system, and can guarantee has excellent turn in ABS substrate
Print performance and trimming performance.
Specific embodiment
The present invention is described in more detail below by embodiment.
Embodiment 1
A1,50 parts of organic solvent is put into reaction kettle, blender revolving speed is at 800-1500 revs/min, wherein organic
Solvent is ethyl acetate；
A2, it is kept stirring and puts into 15 parts of thermoplastic acrylic resin in reaction kettle, stir 0.5-2.5 hours；Its
In, thermoplastic acrylic resin is that glass temperature range is 40 DEG C, and the molecular weight ranges of the thermoplastic acrylic resin are
2w；
A3, it is to be mixed completely, after solution clear, using 220 mesh filter screens, filtering obtains the transfer film and uses
High grade of transparency ABS glue.
Embodiment 2
B1,85 parts of organic solvent is put into reaction kettle, blender revolving speed is at 800-1500 revs/min, wherein organic
Solvent is 50 parts of ethyl acetate and 35 parts of n-propyl acetate；
B 2, it is kept stirring and by 40 parts of thermoplastic acrylic resin, 5 parts of vinyl chloride-vinyl acetate resin and 5 parts of coumarone tree
Rouge is successively put into reaction kettle, is stirred 0.5-2.5 hours；Wherein, it is 90 that thermoplastic acrylic resin, which is glass temperature range,
DEG C, the molecular weight ranges of the thermoplastic acrylic resin are 7w；Vinyl chloride-vinyl acetate resin is carboxyl acid modified ternary chlorine vinegar resin；Ancient horse
The softening point of grand resin is 140 DEG C, and the coumarone indene resin is faint yellow；
B3, it is to be mixed completely, after solution clear, using 220 mesh filter screens, filtering obtains the transfer film and uses
High grade of transparency ABS glue.
Embodiment 3
C1,80 parts of organic solvent is put into reaction kettle, blender revolving speed is at 800-1500 revs/min, wherein organic
Solvent is n-butyl acetate；
C2, it is kept stirring and by 30 parts of thermoplastic acrylic resin, 2 parts of vinyl chloride-vinyl acetate resin and 2 parts of coumarone tree
Rouge is successively put into reaction kettle, is stirred 0.5-2.5 hours；Wherein, it is 60 that thermoplastic acrylic resin, which is glass temperature range,
DEG C, the molecular weight ranges of the thermoplastic acrylic resin are 5w；Vinyl chloride-vinyl acetate resin is carboxyl acid modified ternary chlorine vinegar resin；Ancient horse
The softening point of grand resin is 120 DEG C, and the coumarone indene resin is colourless；
C3, it is to be mixed completely, after solution clear, using 220 mesh filter screens, filtering obtains the transfer film and uses
High grade of transparency ABS glue.
The ABS glue that embodiment 1 produces is coated on heat transfer film by following technique and is tested for the property: wherein heat turns
Die technique: PET- mould release-ink.ABS glue knitting technology: ABS glue is diluted by 40%, 150- using esters solvent
The coating of 175 mesh anilox rolls, machine speed 100m/min, drying temperature is at 100 DEG C or so.The transfer film of coated ABS glue is transferred
Onto ABS substrate, it is tested for the property.
The minimum transfer temperature of the transfer film of the exploitation of the embodiment of the present invention 1 high grade of transparency ABS glue, resists transfer fastness
After-tack energy, transparency and cutting property meet test request.
The ABS glue of the embodiment of the present invention is compared with prior art:
1, the ABS glue transparency of the embodiment of the present invention is splendid, applied widely, can be widely used for penholder and daily conduct
Industry, especially high-end daily necessities industry；
2, the resin softening point that the ABS glue of the embodiment of the present invention uses is moderate, has in the case where guaranteeing transparency outstanding
Anti-reflective viscosity energy；
3, the ABS glue of the embodiment of the present invention replaces toluene, the butanone solvent of easily making malicious class using esters solvent, safety and
The relatively existing ABS glue of the feature of environmental protection is all with being obviously improved；
4, the ABS glue of the embodiment of the present invention uses low-molecular-weight resin system, and can guarantee has excellent turn in ABS substrate
Print performance and trimming performance.
What has been described above is only a preferred embodiment of the present invention, it is noted that for those skilled in the art,
Without depart from that overall concept of the invention, several changes and improvements can also be made, these also should be considered as of the invention
Protection scope.
Claims (6)
1. a kind of transfer film high grade of transparency ABS glue, which is characterized in that including following ingredient according to the mass fraction:
15-40 parts of thermoplastic acrylic resin；
0-5 parts of vinyl chloride-vinyl acetate resin；
0-5 parts of coumarone indene resin；
50-85 parts of organic solvent.
2. a kind of transfer film according to claim 1 high grade of transparency ABS glue, which is characterized in that the thermoplastic propene
Acid resin is that glass temperature range is 40-90 DEG C, and the molecular weight ranges of the thermoplastic acrylic resin are 2w-7w.
3. a kind of transfer film according to claim 1 high grade of transparency ABS glue, which is characterized in that the vinyl chloride-vinyl acetate resin is
Carboxyl acid modified ternary chlorine vinegar resin.
4. a kind of transfer film according to claim 1 high grade of transparency ABS glue, which is characterized in that the coumarone indene resin
Softening point be 100-140 DEG C, the coumarone indene resin be it is colourless or faint yellow.
5. a kind of transfer film according to claim 1 high grade of transparency ABS glue, which is characterized in that the organic solvent is
It is ethyl acetate, n-propyl acetate, one or more of in n-butyl acetate.
6. a kind of preparation method of transfer film high grade of transparency ABS glue described in any claim in claim 1 to 5,
It is characterized in that, comprising the following steps:
S1, organic solvent is put into reaction kettle, blender revolving speed is at 800-1500 revs/min；
S2, it is kept stirring and successively puts into thermoplastic acrylic resin, vinyl chloride-vinyl acetate resin and coumarone indene resin in reaction kettle, stir
It mixes 0.5-2.5 hours；
S3, it is to be mixed completely, after solution clear, using 220 mesh filter screens, filtering, obtain the transfer film with it is high thoroughly
Lightness ABS glue.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811347610.3A CN109517542A (en) | 2018-11-13 | 2018-11-13 | A kind of transfer film high grade of transparency ABS glue and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811347610.3A CN109517542A (en) | 2018-11-13 | 2018-11-13 | A kind of transfer film high grade of transparency ABS glue and preparation method thereof |
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| CN109517542A true CN109517542A (en) | 2019-03-26 |
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| CN201811347610.3A Pending CN109517542A (en) | 2018-11-13 | 2018-11-13 | A kind of transfer film high grade of transparency ABS glue and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112831296A (en) * | 2021-01-11 | 2021-05-25 | 东莞市迪奥顺水性涂料有限公司 | Glue for bonding glass and metal and preparation method thereof |
| CN114854341A (en) * | 2022-05-27 | 2022-08-05 | 朱宏达 | ABS glue for thermal transfer printing and manufacturing method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102673287A (en) * | 2012-05-14 | 2012-09-19 | 保定乐凯新材料股份有限公司 | Non-halogen transfer type decoration film used for plastic surface decoration |
| CN103045130A (en) * | 2012-12-10 | 2013-04-17 | 江苏中金玛泰医药包装有限公司 | Heat-sealing adhesive for polystyrene and preparation method of heat-sealing adhesive |
| CN104250535A (en) * | 2013-06-28 | 2014-12-31 | 禹辉(上海)转印材料有限公司 | Solvent type ABS glue for transfer printing, and preparation method thereof |
| CN105647435A (en) * | 2016-01-13 | 2016-06-08 | 广州慧谷工程材料有限公司 | Adhesive agent for IML and preparation method and application thereof |
| CN105969259A (en) * | 2016-05-17 | 2016-09-28 | 佛山市加恩新材料有限公司 | Hot-melt adhesive for parchment paper heat-transfer hot stamping and preparation method thereof |
| JP2018058968A (en) * | 2016-10-04 | 2018-04-12 | Ｄｉｃグラフィックス株式会社 | Adhesive composition for sealing, and press-through pack package |
-
2018
- 2018-11-13 CN CN201811347610.3A patent/CN109517542A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102673287A (en) * | 2012-05-14 | 2012-09-19 | 保定乐凯新材料股份有限公司 | Non-halogen transfer type decoration film used for plastic surface decoration |
| CN103045130A (en) * | 2012-12-10 | 2013-04-17 | 江苏中金玛泰医药包装有限公司 | Heat-sealing adhesive for polystyrene and preparation method of heat-sealing adhesive |
| CN104250535A (en) * | 2013-06-28 | 2014-12-31 | 禹辉(上海)转印材料有限公司 | Solvent type ABS glue for transfer printing, and preparation method thereof |
| CN105647435A (en) * | 2016-01-13 | 2016-06-08 | 广州慧谷工程材料有限公司 | Adhesive agent for IML and preparation method and application thereof |
| CN105969259A (en) * | 2016-05-17 | 2016-09-28 | 佛山市加恩新材料有限公司 | Hot-melt adhesive for parchment paper heat-transfer hot stamping and preparation method thereof |
| JP2018058968A (en) * | 2016-10-04 | 2018-04-12 | Ｄｉｃグラフィックス株式会社 | Adhesive composition for sealing, and press-through pack package |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112831296A (en) * | 2021-01-11 | 2021-05-25 | 东莞市迪奥顺水性涂料有限公司 | Glue for bonding glass and metal and preparation method thereof |
| CN112831296B (en) * | 2021-01-11 | 2023-02-03 | 东莞市迪奥顺水性涂料有限公司 | Glue for bonding glass and metal and preparation method thereof |
| CN114854341A (en) * | 2022-05-27 | 2022-08-05 | 朱宏达 | ABS glue for thermal transfer printing and manufacturing method thereof |
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Application publication date: 20190326 |