CN104250433A - 一种pbt用阻燃增韧剂及由其制备的高强度阻燃pbt材料 - Google Patents
一种pbt用阻燃增韧剂及由其制备的高强度阻燃pbt材料 Download PDFInfo
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- CN104250433A CN104250433A CN201410304439.3A CN201410304439A CN104250433A CN 104250433 A CN104250433 A CN 104250433A CN 201410304439 A CN201410304439 A CN 201410304439A CN 104250433 A CN104250433 A CN 104250433A
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 80
- 239000000463 material Substances 0.000 title claims abstract description 50
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract description 28
- 239000012745 toughening agent Substances 0.000 title abstract 4
- 239000012757 flame retardant agent Substances 0.000 title abstract 3
- 239000003822 epoxy resin Substances 0.000 claims abstract description 29
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 29
- 239000002994 raw material Substances 0.000 claims abstract description 20
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 44
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 40
- 239000002131 composite material Substances 0.000 claims description 36
- 239000000843 powder Substances 0.000 claims description 36
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 26
- 229910052799 carbon Inorganic materials 0.000 claims description 26
- 229910052802 copper Inorganic materials 0.000 claims description 26
- 239000010949 copper Substances 0.000 claims description 26
- 235000019353 potassium silicate Nutrition 0.000 claims description 22
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 22
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 20
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 20
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 20
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- 239000003963 antioxidant agent Substances 0.000 claims description 15
- 230000003078 antioxidant effect Effects 0.000 claims description 15
- 239000002245 particle Substances 0.000 claims description 15
- HCWYXKWQOMTBKY-UHFFFAOYSA-N calcium;dodecyl benzenesulfonate Chemical compound [Ca].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 HCWYXKWQOMTBKY-UHFFFAOYSA-N 0.000 claims description 13
- 238000001035 drying Methods 0.000 claims description 11
- VUTSITSGGYCKFP-UHFFFAOYSA-J [C+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O Chemical compound [C+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O VUTSITSGGYCKFP-UHFFFAOYSA-J 0.000 claims description 10
- 239000002041 carbon nanotube Substances 0.000 claims description 10
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 10
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 10
- 239000006185 dispersion Substances 0.000 claims description 10
- 239000002048 multi walled nanotube Substances 0.000 claims description 10
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 claims description 9
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 9
- 239000003112 inhibitor Substances 0.000 claims description 9
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical group OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 claims description 9
- 230000003647 oxidation Effects 0.000 claims description 9
- 238000007254 oxidation reaction Methods 0.000 claims description 9
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 229920001897 terpolymer Polymers 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
- 239000013078 crystal Substances 0.000 claims description 5
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- 229960004756 ethanol Drugs 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims 1
- 230000007613 environmental effect Effects 0.000 abstract description 4
- 230000002195 synergetic effect Effects 0.000 abstract description 3
- 231100000053 low toxicity Toxicity 0.000 abstract 2
- BZQKBFHEWDPQHD-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-[2-(2,3,4,5,6-pentabromophenyl)ethyl]benzene Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1CCC1=C(Br)C(Br)=C(Br)C(Br)=C1Br BZQKBFHEWDPQHD-UHFFFAOYSA-N 0.000 abstract 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 65
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 19
- 230000000052 comparative effect Effects 0.000 description 16
- 230000000694 effects Effects 0.000 description 15
- 238000011056 performance test Methods 0.000 description 12
- 238000000034 method Methods 0.000 description 10
- 238000002485 combustion reaction Methods 0.000 description 9
- 239000000377 silicon dioxide Substances 0.000 description 9
- 235000012239 silicon dioxide Nutrition 0.000 description 9
- 229960001866 silicon dioxide Drugs 0.000 description 9
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 7
- 239000007789 gas Substances 0.000 description 7
- 238000005452 bending Methods 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 4
- 231100000419 toxicity Toxicity 0.000 description 4
- 230000001988 toxicity Effects 0.000 description 4
- 239000001569 carbon dioxide Substances 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000001354 calcination Methods 0.000 description 2
- 229920006351 engineering plastic Polymers 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 231100000518 lethal Toxicity 0.000 description 2
- 230000001665 lethal effect Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- KVGZZAHHUNAVKZ-UHFFFAOYSA-N 1,4-Dioxin Chemical compound O1C=COC=C1 KVGZZAHHUNAVKZ-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical group C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000012433 hydrogen halide Substances 0.000 description 1
- 229910000039 hydrogen halide Inorganic materials 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- -1 polybutylene terephthalate Polymers 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
性质 | 方法 | 单位 | 数据 |
比重 | ASTMD792 | — | 1.51 |
模收缩 | ASTMD955 | % | 0.35-0.9 |
延伸率 | ASTMD638 | % | 10 |
拉伸强度 | ASTMD638 | Mpa | 56 |
弯曲强度 | ASTMD790 | Mpa | 90 |
弯曲模数 | ASTMD790 | Mpa | 2500 |
缺口冲击强度(1/8") | ASTMD256 | KJ/M2 | 15 |
热变形温度(1.8Mpa) | ASTMD648 | ℃ | 55 |
热变形温度(0.45Mpa) | ASTMD648 | ℃ | 70 |
耐燃性 | UL94 | (1/16") | V0 |
干燥时间 | — | HR | 4 |
熔融温度 | — | ℃ | 230-270 |
建议模温 | — | ℃ | 50 |
性质 | 方法 | 单位 | 数据 |
比重 | ASTMD792 | — | 1.51 |
模收缩 | ASTMD955 | % | 0.35-0.9 |
延伸率 | ASTMD638 | % | 19 |
拉伸强度 | ASTMD638 | Mpa | 60 |
弯曲强度 | ASTMD790 | Mpa | 89 |
弯曲模数 | ASTMD790 | Mpa | 2400 |
缺口冲击强度(1/8") | ASTMD256 | KJ/M2 | 13 |
热变形温度(1.8Mpa) | ASTMD648 | ℃ | 55 |
热变形温度(0.45Mpa) | ASTMD648 | ℃ | 70 |
耐燃性 | UL94 | (1/16") | V0 |
干燥时间 | — | HR | 4 |
熔融温度 | — | ℃ | 230-270 |
建议模温 | — | ℃ | 50 |
性质 | 方法 | 单位 | 数据 |
比重 | ASTMD792 | — | 1.51 |
模收缩 | ASTMD955 | % | 0.35-0.9 |
延伸率 | ASTMD638 | % | 11 |
拉伸强度 | ASTMD638 | Mpa | 63 |
弯曲强度 | ASTMD790 | Mpa | 85 |
弯曲模数 | ASTMD790 | Mpa | 2350 |
缺口冲击强度(1/8") | ASTMD256 | KJ/M2 | 10 |
热变形温度(1.8Mpa) | ASTMD648 | ℃ | 55 |
热变形温度(0.45Mpa) | ASTMD648 | ℃ | 70 |
耐燃性 | UL94 | (1/16") | V0 |
干燥时间 | — | HR | 4 |
熔融温度 | — | ℃ | 230-270 |
建议模温 | — | ℃ | 50 |
性质 | 方法 | 单位 | 数据 |
比重 | ASTMD792 | — | 1.51 |
模收缩 | ASTMD955 | % | 0.35-0.9 |
延伸率 | ASTMD638 | % | 10 |
拉伸强度 | ASTMD638 | Mpa | 53 |
弯曲强度 | ASTMD790 | Mpa | 85 |
弯曲模数 | ASTMD790 | Mpa | 2208 |
缺口冲击强度(1/8") | ASTMD256 | KJ/M2 | 5 |
热变形温度(1.8Mpa) | ASTMD648 | ℃ | 55 |
热变形温度(0.45Mpa) | ASTMD648 | ℃ | 70 |
耐燃性 | UL94 | (1/16") | V0 |
干燥时间 | — | HR | 4 |
熔融温度 | — | ℃ | 230-270 |
建议模温 | — | ℃ | 50 |
性质 | 方法 | 单位 | 数据 |
比重 | ASTMD792 | — | 1.51 |
模收缩 | ASTMD955 | % | 0.35-0.9 |
延伸率 | ASTMD638 | % | 5 |
拉伸强度 | ASTMD638 | Mpa | 41 |
弯曲强度 | ASTMD790 | Mpa | 70 |
弯曲模数 | ASTMD790 | Mpa | 1900 |
缺口冲击强度(1/8") | ASTMD256 | KJ/M2 | 4 |
热变形温度(1.8Mpa) | ASTMD648 | ℃ | 55 |
热变形温度(0.45Mpa) | ASTMD648 | ℃ | 70 |
耐燃性 | UL94 | (1/16") | V0 |
干燥时间 | — | HR | 4 |
熔融温度 | — | ℃ | 230-270 |
建议模温 | — | ℃ | 50 |
性质 | 方法 | 单位 | 数据 |
比重 | ASTMD792 | — | 1.51 |
模收缩 | ASTMD955 | % | 0.35-0.9 |
延伸率 | ASTMD638 | % | 6 |
拉伸强度 | ASTMD638 | Mpa | 42 |
弯曲强度 | ASTMD790 | Mpa | 70 |
弯曲模数 | ASTMD790 | Mpa | 1950 |
缺口冲击强度(1/8") | ASTMD256 | KJ/M2 | 4 |
热变形温度(1.8Mpa) | ASTMD648 | ℃ | 55 |
热变形温度(0.45Mpa) | ASTMD648 | ℃ | 70 |
耐燃性 | UL94 | (1/16") | HB |
干燥时间 | — | HR | 4 |
熔融温度 | — | ℃ | 230-270 |
建议模温 | — | ℃ | 50 |
测试组 | 测试结果 |
实施例5 | 加热到100摄氏度后,表面湿润且由气体逸出;继续加热,表面的水膜消失;加热到300摄氏度后,PBT材料开始燃烧,随即燃烧部位出现二氧化硅覆盖,燃烧停止。燃烧过程无异味产生,不发生滴落。 |
实施例6 | 加热到100摄氏度后,表面湿润且由气体逸出;继续加热,表面的水膜消失;加热到300摄氏度后,PBT材料开始燃烧,随即燃烧部位出现二氧化硅覆盖,燃烧停止。燃烧过程无异味产生,不发生滴落。 |
实施例7 | 加热到100摄氏度后,表面湿润且由气体逸出;继续加热,表面的水膜消失;加热到300摄氏度后,PBT材料开始燃烧,随即燃烧部位出现二氧化硅覆盖,燃烧停止。燃烧过程无异味产生,不发生滴落。 |
实施例8 | 加热到100摄氏度后,表面湿润且由气体逸出;继续加热,表面的水膜消失;加热到300摄氏度后,PBT材料开始燃烧,燃烧持续1—2min后,燃烧部位出现二氧化硅覆盖,燃烧停止。燃烧过程无异味产生,不发生滴落。 |
对比例3 | 加热到100摄氏度后,表面湿润且由气体逸出;继续加热,表面的水膜消失;加热到300摄氏度后,PBT材料开始燃烧,燃烧持续1—2min后,燃烧部位出现二氧化硅覆盖,燃烧停止。 |
对比例4 | 被火焰灼烧一段时间后开始燃烧,燃烧时伴随着火焰滴落。 |
Claims (5)
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107286597A (zh) * | 2017-06-22 | 2017-10-24 | 江苏亨通光电股份有限公司 | 一种防鼠防猴可导雷电的基站用射频拉远光缆及制备方法 |
CN109401174A (zh) * | 2018-10-08 | 2019-03-01 | 东莞市创之源新材料科技有限公司 | 一种pbt增韧剂及其制备方法 |
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JP2005336472A (ja) * | 2004-04-28 | 2005-12-08 | Konoshima Chemical Co Ltd | 水酸化マグネシウム系難燃剤とその製造方法、及び難燃性樹脂組成物 |
CN102558868A (zh) * | 2011-12-21 | 2012-07-11 | 天津金发新材料有限公司 | 一种阻燃协效剂及其制备的阻燃abs |
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Non-Patent Citations (1)
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CN107286597A (zh) * | 2017-06-22 | 2017-10-24 | 江苏亨通光电股份有限公司 | 一种防鼠防猴可导雷电的基站用射频拉远光缆及制备方法 |
CN109401174A (zh) * | 2018-10-08 | 2019-03-01 | 东莞市创之源新材料科技有限公司 | 一种pbt增韧剂及其制备方法 |
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