CN104230392A - Microcrystal mirror polishing wall tile and manufacturing method thereof - Google Patents
Microcrystal mirror polishing wall tile and manufacturing method thereof Download PDFInfo
- Publication number
- CN104230392A CN104230392A CN201410470564.1A CN201410470564A CN104230392A CN 104230392 A CN104230392 A CN 104230392A CN 201410470564 A CN201410470564 A CN 201410470564A CN 104230392 A CN104230392 A CN 104230392A
- Authority
- CN
- China
- Prior art keywords
- parts
- glaze
- brick
- coat enamel
- ground
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Finishing Walls (AREA)
Abstract
The invention relates to a microcrystal mirror polishing wall tile and a manufacturing method thereof and belongs to the technical field of ceramic glazing tiles. The microcrystal mirror polishing wall tile is characterized in that a greenware bottom tile (1) is provided with a glaze surface layer which is formed by applying a ground glaze layer (2), a surface glaze layer (3), an enameling layer (4) and a full-polishing glaze layer (5) layer by layer from bottom to top. The manufacturing method is characterized by comprising the following steps: once firing the greenware bottom tile firstly, and sequentially applying the ground glaze, the surface glaze and the full-polishing glaze on the greenware bottom tile after water spraying; enameling on the surface glaze; and then carrying out secondary firing. According to the microcrystal mirror polishing wall tile disclosed by the invention, as the special constituted surface glaze layer is added, under glaze colors are realized on the greenware bottom tile; as the problem that expansion coefficients among glaze layers of a microcrystal glaze surface of a ceramic green body which is sintered at low temperature are not matched is solved, the glaze surface cannot crack.
Description
Technical field
A kind of crystallite mirror polish wall tile and making method, belong to ceramic glazing brick technical field.
Background technology
Ceramic tile can be divided into porcelain brick and pottery brick two class from the materials of end base.The density of porcelain brick is large, unit weight is greatly generally suitable for as floor tile, and the density of pottery brick is relatively little, unit weight is little, Chang Zuowei wall tile.In current technology only at the bottom of porcelain base brick in the full glaze technology of throwing of application obtain crystallite brick.Porcelain brick adopts single firing process, once calcines and get final product after namely piling up various glaze and spraying decoration on unfired biscuit.Because the firing temperature of porcelain is higher, mostly more than 1200 DEG C, what even have reaches about 1400 DEG C.Gained porcelain brick at high temperature can better color development, and the full throwing glaze layer transparency on spraying decoration layer is also higher, also there will not be the phenomenon of bubbling, pore, glaze paint injustice.
But pottery brick, because end base is the reason of ceramic, need adopts double sintering technique, namely first carry out biscuit sintering, then carry out double sintering after glazing on sintering greenwave.The firing temperature of pottery is minimum reaches less than 800 DEG C, and the highest also only have about 1100 DEG C.Because the firing temperature of pottery is all lower than porcelain, the pottery brick sintered at low temperatures need adopt the mode of bedying outside glaze, the easy wear-out failure picture of pattern that this form is formed.And if apply again entirely to throw glaze after the outer spraying decoration of the ground-coat enamel of pottery brick, then can because of the unmatched reason of the ceramic brick glaze interlayer coefficient of expansion; make into that You layer easily chaps, the problem of surface finish low lightness, and spraying decoration is also because the low color development of sintering temperature is not enough, pattern is deepened and dim, spraying decoration with entirely throw glaze in conjunction with bad, easily to subside, again due to many pores on sintering greenwave, there is when double sintering a large amount of bubble to emerge, cause glaze paint porous, glaze paint uneven.
Summary of the invention
The technical problem to be solved in the present invention is: overcome the deficiencies in the prior art, provide a kind of spraying decoration firmly, the crystallite mirror polish wall tile of glaze paint flat smooth and making method.
The technical solution adopted for the present invention to solve the technical problems is: this crystallite mirror polish wall tile, comprise end brick, it is characterized in that: described end brick is brick at the bottom of greenwave, brick at the bottom of described greenwave is provided with and forms You surface layer by the ground glaze layer successively applied, cover coat, spraying decoration layer and full glaze layer of throwing from bottom to top.
The feature of crystallite mirror polish wall tile of the present invention is that brick at the bottom of greenwave achieves under glazed, namely also has transparent full throwing glaze layer on spraying decoration layer.By adding cover coat between ground glaze layer and spraying decoration layer, solve the unmatched problem of the glaze interlayer coefficient of expansion of low sintering pottery brick, glaze paint can not ftracture.Thus making the spraying decoration layer of crystallite mirror polish wall tile and full glaze layer of throwing in conjunction with solid and reliable, the glaze paint of full throwing glaze layer is smooth, transparency is high.
At the bottom of described greenwave, the bottom surface of brick is provided with anticreep projection.It is firmly bonding when crystallite mirror polish wall tile uses on wall.Difficult drop-off.
At the bottom of described greenwave, the parts by weight of raw materials of brick consists of: mussite 36 ~ 40 parts, 27 ~ 29 parts, Laiyang soil, flint clay 12 ~ 16 parts, blue clay 8 ~ 10 parts, 1.5 ~ 2.5 parts, talcum, magnetite 1.5 ~ 2.5 parts, black mud 6 ~ 8 parts.
The parts by weight of raw materials of described ground glaze layer consists of: glaze 100 parts, Mierocrystalline cellulose 0.05 ~ 0.1 part, and tripoly phosphate sodium STPP 0.3 ~ 0.5 part, surface finish brightness reaches more than 98%.
The parts by weight of raw materials of described cover coat consists of glaze 100 parts, 3 ~ 15 parts, quartz, kaolin 5 ~ 12 parts, Mierocrystalline cellulose 0.15 ~ 0.2 part.By changing the composition of cover coat in the present invention, the cover coat of this special composition being not only can regulate the volume coefficient of whole body You layer, also make the effect of the concrete color development of the cover coat of this component, make spraying decoration layer color development when low-firing complete, the color effect of wall tile is better.
Full throwing glaze uses normal full throwing glaze raw material, and volume coefficient when it is fired is generally 160 ~ 170.
The present invention is by regulating the composition of each component, and regulate the volume coefficient of brick, ground glaze layer, cover coat at the bottom of greenwave mutually to arrange in pairs or groups, the volume coefficient of cover-coat enamel is greater than throws glaze entirely.Wherein, Mierocrystalline cellulose has thickening moisturizing as tackifier, increases the effect of the suspension of ink-jet.Improve the thermostability of glaze paint by cover-coat enamel and improve the moisture retention of cover-coat enamel and extend sintering time and solve the problem that glaze surface hot gas and the full throwing glaze that causes of powder falling play glaze bubble.
A making method for above-mentioned crystallite mirror polish wall tile, it is characterized in that, preparation process is:
1) form by the weight part of potter's clay raw material: mussite 36 ~ 40 parts, 27 ~ 29 parts, Laiyang soil, flint clay 12 ~ 16 parts, blue clay 8 ~ 10 parts, 1.5 ~ 2.5 parts, talcum, magnetite 1.5 ~ 2.5 parts, black mud 6 ~ 8 parts preparation, potter's clay raw material is through ball milling, powder process, old rear compression moulding obtains biscuit, biscuit is once fired, the firing temperature controlling once to fire is at 1060 DEG C ~ 1100 DEG C, sintering time 43 min ~ 48min, at the bottom of the greenwave be fired into, the volume coefficient of brick is 200 ~ 210, to once fire brick water spray process at the bottom of obtained greenwave, every 0.18 square meter injection flow rate is 18 ~ 23 grams,
2) ground-coat enamel is applied on brick at the bottom of the greenwave after water spray, ground-coat enamel parts by weight of raw materials consists of: glaze 100 parts, Mierocrystalline cellulose 0.05 ~ 0.1 part, tripoly phosphate sodium STPP 0.3 ~ 0.5 part, the applying thickness of ground-coat enamel is 0.2 mm ~ 0.3mm, the volume coefficient forming ground glaze layer when firing is 210 ~ 220, ground-coat enamel applies cover-coat enamel again, the parts by weight of raw materials of cover-coat enamel consists of glaze 100 parts, 3 ~ 15 parts, quartz, kaolin 5 ~ 12 parts, Mierocrystalline cellulose 0.15 ~ 0.2 part, the applying thickness of cover-coat enamel is 0.15 mm ~ 0.2mm, the volume coefficient forming cover coat when firing is 180 ~ 185, cover-coat enamel carries out ink-jet system flower, and then spoon and entirely throw glaze,
3) carry out secondary to brick at the bottom of the greenwave after glazing to fire, control the firing temperature fired of secondary at 1100 DEG C ~ 1120 DEG C, sintering time is 44 min ~ 49min, secondary fired after through polishing and get final product.
The present invention continues to use the double-firing process of pottery brick, first on ground-coat enamel, applies certain thickness cover-coat enamel, in order to regulate the unmatched coefficient of expansion between ground-coat enamel, ink-jet unlike the present invention on ground-coat enamel before spraying decoration.And ensureing that ink-jet color development under the firing temperature of pottery is complete by the color development effect that cover-coat enamel is formed, final obtained brick color effect is better.Simultaneously under the moisture retention of cover-coat enamel regulates, apply entirely to throw glaze Hou ， You layer outward at spraying decoration layer and also no longer chap, do not play glaze bubble, surface finish brightness also brings up to more than 97%.The present invention regulates brick water spray treatment capacity at the bottom of greenwave, reduces glaze paint water ratio in addition, coordinates the moisture retention of cover-coat enamel, and extends sintering time, thus reduce bubble generation, control glaze paint void content.
Preferably, step 2) described in ink-jet Hua Houxian be coated with fixing glue on spraying decoration surface, then drench and entirely throw glaze.Be coated with fixing glue after spraying decoration on spraying decoration surface and increase full glaze of throwing further in conjunction with firmness.And by the full throwing glaze zone segregation of spraying decoration layer and formation, the color of spraying decoration layer can be ensured.
Preferably, the weight part composition of the raw material of potter's clay described in step 1): mussite 38 parts, 28 parts, Laiyang soil, flint clay 14 parts, blue clay 9 parts, 2 parts, talcum, magnetite 2 parts, black mud 7 parts.Preferably, the parts by weight of raw materials of ground-coat enamel described in step 2 consists of: glaze 100 parts, Mierocrystalline cellulose 0.05 part, tripoly phosphate sodium STPP 0.3 part; The parts by weight of raw materials of cover-coat enamel consists of: glaze 100 parts, 8 parts, quartz, kaolin 9 parts, Mierocrystalline cellulose 0.2 part.Under this preferred ingredient, the coefficient of expansion coupling of glaze interlayer reaches best effect, and the color development effect of cover-coat enamel reaches the strongest, and surface finish brightness can reach more than 98%.
Mirror polish wall tile of the present invention adopts double-firing process, and thermostability is better, and brightness improves, and brings up to more than 95% from traditional about 80%.Solve the glaze paint not crude problem having pin hole of plane surface.
Compared with prior art, the beneficial effect that crystallite mirror polish wall tile of the present invention and making method have is: the cover coat increasing specific composition in crystallite mirror polish wall tile of the present invention, makes crystallite mirror polish wall tile of the present invention brick at the bottom of greenwave achieves under glazed.Solve the unmatched problem of the glaze interlayer coefficient of expansion of low sintering pottery brick, glaze paint can not ftracture.Thus making the spraying decoration layer of crystallite mirror polish wall tile and full glaze layer of throwing in conjunction with solid and reliable, the glaze paint of full throwing glaze layer is smooth, transparency is high.The smooth cleaning in plate face, uniform hue is consistent, texture is elegant and tasteful, soft sparkling and crystal-clear, the hard exquisiteness of quality of gloss, do not absorb water, anti-pollution, acid and alkali-resistance weathering resistance.The present invention continues to use the double-firing process of pottery brick, and first on ground-coat enamel, applies certain thickness cover-coat enamel, in order to regulate the unmatched coefficient of expansion between ground-coat enamel, ink-jet before spraying decoration on ground-coat enamel.The color development effect formed by cover-coat enamel ensures that ink-jet color development under the firing temperature of pottery is complete, and final obtained brick color effect more.Simultaneously under the moisture retention of cover-coat enamel regulates, apply entirely to throw glaze Hou ， You layer outward at spraying decoration layer and also no longer chap, do not play glaze bubble, surface finish brightness also brings up to more than 95%.
Accompanying drawing explanation
Fig. 1 is the laminate structure schematic diagram of crystallite mirror polish wall tile of the present invention.
Wherein: 1, brick 2, ground glaze layer 3, cover coat 4, spraying decoration layer 5, full throwing glaze layer 6, anticreep projection at the bottom of greenwave.
Embodiment
Fig. 1 is the most preferred embodiment of crystallite mirror polish wall tile of the present invention, and below in conjunction with accompanying drawing 1, the present invention will be further described.
With reference to accompanying drawing 1: a kind of crystallite mirror polish wall tile of the present invention, comprise brick 1 at the bottom of greenwave, ground glaze layer 2, cover coat 3, spraying decoration layer 4, full throwing glaze layer 5, brick 1 at the bottom of greenwave is provided with and forms You surface layer by the ground glaze layer 2 successively applied, cover coat 3, spraying decoration layer 4 and full glaze layer 5 of throwing from bottom to top.At the bottom of greenwave, the bottom surface of brick 1 is provided with anticreep projection 6.
Below in conjunction with specific embodiment specific embodiment, the preparation method to crystallite mirror polish wall tile of the present invention is described further, and wherein embodiment 1 is most preferred embodiment.
Embodiment 1
1) by potter's clay raw material by weight: mussite 38 parts, 28 parts, Laiyang soil, flint clay 14 parts, blue clay 9 parts, 2 parts, talcum, magnetite 2 parts, black mud 7 parts are got the raw materials ready.Biscuit is obtained in ball milling, powder process, old rear compression moulding, the biscuit of compression moulding is once fired, the firing temperature controlling once to fire is at 1080 DEG C, sintering time 45min, being fired into brick volume coefficient at the bottom of greenwave is 205, to once fire brick water spray process at the bottom of obtained greenwave, every 0.18 square meter 20 grams of injection flow rate;
2) brick at the bottom of the greenwave after water spray first applies ground-coat enamel, and ground-coat enamel is first by weight: glaze 100 parts, Mierocrystalline cellulose 0.06 part, tripoly phosphate sodium STPP 0.4 part batching.The applying thickness of ground-coat enamel is 0.25mm, and ground-coat enamel applies cover-coat enamel again, and cover-coat enamel is made up of weight part: glaze 100 parts, 8 parts, quartz, kaolin 9 parts, Mierocrystalline cellulose 0.2 part together ball milling obtain.The applying thickness of cover-coat enamel is 0.15 mm, and cover-coat enamel carries out ink-jet system flower, and ink-jet Hua Houxian in spraying decoration surface painting fixing glue, and then spoons and entirely throws glaze;
3) carry out secondary to brick at the bottom of the greenwave after three layers of glazing to fire, the firing temperature that control secondary is fired is at 1100 DEG C, and sintering time is 45min, and volume coefficient when ground-coat enamel is fired is 215, volume coefficient when cover-coat enamel is fired is 182, and volume coefficient when full throwing glaze is fired is 165; Secondary fired after through polishing and get final product.
Gained crystallite mirror polish wall tile glaze paint detects flawless, and glaze paint is smooth without bubbling, and spraying decoration layer hair color effect is complete, and pattern is bright-coloured, and the full throwing glaze layer transparency after polishing is large, and brick surface imaging is clear, and surface finish brightness reaches more than 98%.
Embodiment 2
1) by potter's clay raw material by weight: mussite 39 parts, 27 parts, Laiyang soil, flint clay 15 parts, blue clay 8 parts, 2.2 parts, talcum, magnetite 1.8 parts, black mud 7.5 parts are got the raw materials ready.Biscuit is obtained in ball milling, powder process, old rear compression moulding, the biscuit of compression moulding is once fired, the firing temperature controlling once to fire is at 1090 DEG C, sintering time 44min, being fired into brick volume coefficient at the bottom of greenwave is 207, to once fire brick water spray process at the bottom of obtained greenwave, every 0.18 square meter 21 grams of injection flow rate;
2) brick at the bottom of the greenwave after water spray first applies ground-coat enamel, and ground-coat enamel is first by weight: glaze 100 parts, Mierocrystalline cellulose 0.05 part, tripoly phosphate sodium STPP 0.3 part batching.The applying thickness of ground-coat enamel is 0.3mm, and ground-coat enamel applies cover-coat enamel again, and cover-coat enamel is made up of weight part: glaze 100 parts, 10 parts, quartz, kaolin 11 parts, Mierocrystalline cellulose 0.15 part together ball milling obtain.The applying thickness of cover-coat enamel is 0.18mm, and cover-coat enamel carries out ink-jet system flower, and ink-jet Hua Houxian in spraying decoration surface painting fixing glue, and then spoons and entirely throws glaze;
3) carry out secondary to brick at the bottom of the greenwave after three layers of glazing to fire, the firing temperature that control secondary is fired is at 1110 DEG C, sintering time is 46min, volume coefficient when ground-coat enamel is fired is 217, volume coefficient when cover-coat enamel is fired is 182, and the full volume coefficient thrown when glaze is fired obtains through polishing after having fired at 162 2 times.
Gained crystallite mirror polish wall tile glaze paint detects flawless, and glaze paint is smooth without bubbling, and spraying decoration layer hair color effect is complete, and pattern is bright-coloured, and the full throwing glaze layer transparency after polishing is large, and brick surface imaging is clear, and surface finish brightness reaches 96%.
Embodiment 3
1) by potter's clay raw material by weight: mussite 37 parts, 29 parts, Laiyang soil, flint clay 13 parts, blue clay 10 parts, 2.2 parts, talcum, magnetite 1.6 parts, black mud 6.5 parts are got the raw materials ready.Biscuit is obtained in ball milling, powder process, old rear compression moulding, the biscuit of compression moulding is once fired, the firing temperature controlling once to fire is at 1070 DEG C, sintering time 46min, being fired into brick volume coefficient at the bottom of greenwave is 208, to once fire brick water spray process at the bottom of obtained greenwave, every 0.18 square meter 22 grams of injection flow rate;
2) brick at the bottom of the greenwave after water spray first applies ground-coat enamel, and ground-coat enamel is first by weight: glaze 100 parts, Mierocrystalline cellulose 0.07 part, tripoly phosphate sodium STPP 0.4 part batching.The applying thickness of ground-coat enamel is 0.3mm, and ground-coat enamel applies cover-coat enamel again, and cover-coat enamel is made up of weight part: glaze 100 parts, 5 parts, quartz, kaolin 6 parts, Mierocrystalline cellulose 0.16 part together ball milling obtain.The applying thickness of cover-coat enamel is 0.15 mm, and cover-coat enamel carries out ink-jet system flower, and ink-jet Hua Houxian in spraying decoration surface painting fixing glue, and then spoons and entirely throws glaze;
3) carry out secondary to brick at the bottom of the greenwave after three layers of glazing to fire, the firing temperature that control secondary is fired is at 1100 DEG C, sintering time is 48min, volume coefficient when ground-coat enamel is fired is 218, volume coefficient when cover-coat enamel is fired is 183, and the full volume coefficient thrown when glaze is fired obtains through polishing after having fired at 167 2 times.
Gained crystallite mirror polish wall tile glaze paint detects flawless, and glaze paint is smooth without bubbling, and spraying decoration layer hair color effect is complete, and pattern is bright-coloured, and the full throwing glaze layer transparency after polishing is large, and brick surface imaging is clear, and surface finish brightness reaches 96%.
Embodiment 4
1) by potter's clay raw material by weight: mussite 36 parts, 29 parts, Laiyang soil, flint clay 12 parts, blue clay 10 parts, 1.5 parts, talcum, magnetite 2.5 parts, black mud 6 parts are got the raw materials ready.Biscuit is obtained in ball milling, powder process, old rear compression moulding, the biscuit of compression moulding is once fired, the firing temperature controlling once to fire is at 1060 DEG C, sintering time 48min, being fired into brick volume coefficient at the bottom of greenwave is 200, to once fire brick water spray process at the bottom of obtained greenwave, every 0.18 square meter 18 grams of injection flow rate;
2) brick at the bottom of the greenwave after water spray first applies ground-coat enamel, and ground-coat enamel is first by weight: glaze 100 parts, Mierocrystalline cellulose 0.03 part, tripoly phosphate sodium STPP 0.5 part batching.The applying thickness of ground-coat enamel is 0.3mm, and ground-coat enamel applies cover-coat enamel again, and cover-coat enamel is made up of weight part: glaze 100 parts, 15 parts, quartz, kaolin 5 parts, Mierocrystalline cellulose 0.2 part together ball milling obtain.The applying thickness of cover-coat enamel is 0.2 mm, and cover-coat enamel carries out ink-jet system flower, and ink-jet Hua Houxian in spraying decoration surface painting fixing glue, and then spoons and entirely throws glaze;
3) carry out secondary to brick at the bottom of the greenwave after three layers of glazing to fire, the firing temperature that control secondary is fired is at 1080 DEG C, sintering time is 49min, volume coefficient when ground-coat enamel is fired is 210, volume coefficient when cover-coat enamel is fired is 180, and the full volume coefficient thrown when glaze is fired obtains through polishing after having fired at 160 2 times.
Gained crystallite mirror polish wall tile glaze paint detects flawless, and glaze paint is smooth without bubbling, and spraying decoration layer hair color effect is complete, and pattern is bright-coloured, and the full throwing glaze layer transparency after polishing is large, and brick surface imaging is clear, and surface finish brightness reaches 95%.
Embodiment 5
1) by potter's clay raw material by weight: mussite 40 parts, 27 parts, Laiyang soil, flint clay 16 parts, blue clay 8 parts, 2.5 parts, talcum, magnetite 1.5 parts, black mud 8 parts are got the raw materials ready.Biscuit is obtained in ball milling, powder process, old rear compression moulding, the biscuit of compression moulding is once fired, the firing temperature controlling once to fire is at 1100 DEG C, sintering time 43min, being fired into brick volume coefficient at the bottom of greenwave is 210, to once fire brick water spray process at the bottom of obtained greenwave, every 0.18 square meter 23 grams of injection flow rate;
2) brick at the bottom of the greenwave after water spray first applies ground-coat enamel, and ground-coat enamel is first by weight: glaze 100 parts, Mierocrystalline cellulose 0.08 part, tripoly phosphate sodium STPP 0.3 part batching.The applying thickness of ground-coat enamel is 0.2mm, and ground-coat enamel applies cover-coat enamel again, and cover-coat enamel is made up of weight part: glaze 100 parts, 3 parts, quartz, kaolin 12 parts, Mierocrystalline cellulose 0.15 part together ball milling obtain.The applying thickness of cover-coat enamel is 0.15mm, and cover-coat enamel carries out ink-jet system flower, and ink-jet Hua Houxian in spraying decoration surface painting fixing glue, and then spoons and entirely throws glaze;
3) carry out secondary to brick at the bottom of the greenwave after three layers of glazing to fire, the firing temperature that control secondary is fired is at 1120 DEG C, sintering time is 44min, volume coefficient when ground-coat enamel is fired is 220, volume coefficient when cover-coat enamel is fired is 185, and the full volume coefficient thrown when glaze is fired obtains through polishing after having fired at 170 2 times.
Gained crystallite mirror polish wall tile glaze paint detects flawless, and glaze paint is smooth without bubbling, and spraying decoration layer hair color effect is complete, and pattern is bright-coloured, and the full throwing glaze layer transparency after polishing is large, and brick surface imaging is clear, and surface finish brightness reaches 95%.
Comparative example 1
1) by potter's clay raw material by weight: mussite 38 parts, 28 parts, Laiyang soil, flint clay 14 parts, blue clay 9 parts, 2 parts, talcum, magnetite 2 parts, black mud 7 parts are got the raw materials ready.Biscuit is obtained in ball milling, powder process, old rear compression moulding.
2) on biscuit, first apply ground-coat enamel, ground-coat enamel is first by weight: glaze 100 parts, Mierocrystalline cellulose 0.06 part, tripoly phosphate sodium STPP 0.4 part batching.The applying thickness of ground-coat enamel is 0.25mm, and ground-coat enamel applies cover-coat enamel again, and cover-coat enamel is made up of weight part: glaze 100 parts, 8 parts, quartz, kaolin 9 parts, Mierocrystalline cellulose 0.2 part together ball milling obtain.The applying thickness of cover-coat enamel is 0.15 mm, and cover-coat enamel carries out ink-jet system flower, and ink-jet Hua Houxian in spraying decoration surface painting fixing glue, and then spoons and entirely throws glaze;
3) fire the biscuit after three layers of glazing, control firing temperature at 1100 DEG C, sintering time is 45min, secondary fired after through polishing and get final product.
Gained polishing wall tile thermostability is too poor, bulk deformation, and two dimensional structure is destroyed, and intensive bubbling appears in glaze paint, cannot apply.
Comparative example 2
1) by potter's clay raw material by weight: mussite 38 parts, 28 parts, Laiyang soil, flint clay 14 parts, blue clay 9 parts, 2 parts, talcum, magnetite 2 parts, black mud 7 parts are got the raw materials ready.Biscuit is obtained in ball milling, powder process, old rear compression moulding, the biscuit of compression moulding is once fired, the firing temperature controlling once to fire is at 1080 DEG C, sintering time 45min, being fired into brick volume coefficient at the bottom of greenwave is 205, to once fire brick water spray process at the bottom of obtained greenwave, every 0.18 square meter 20 grams of injection flow rate;
2) brick at the bottom of the greenwave after water spray first applies ground-coat enamel, and ground-coat enamel is first by weight: glaze 100 parts, Mierocrystalline cellulose 0.06 part, tripoly phosphate sodium STPP 0.4 part batching.The applying thickness of ground-coat enamel is 0.25mm, and ground-coat enamel carries out ink-jet system flower, and ink-jet Hua Houxian in spraying decoration surface painting fixing glue, and then spoons and entirely throws glaze;
3) carry out secondary to brick at the bottom of the greenwave after three layers of glazing to fire, control the firing temperature fired of secondary at 1100 DEG C, sintering time is 45min, secondary fired after through polishing and get final product.
Gained polishing wall tile glaze paint glaze paint has intensive crackle, and spraying decoration layer color development is bad, and pattern is dim.
Comparative example 3
1) by potter's clay raw material by weight: mussite 38 parts, 28 parts, Laiyang soil, flint clay 14 parts, blue clay 9 parts, 2 parts, talcum, magnetite 2 parts, black mud 7 parts are got the raw materials ready.Biscuit is obtained in ball milling, powder process, old rear compression moulding, the biscuit of compression moulding is once fired, the firing temperature controlling once to fire is at 1080 DEG C, sintering time 30min, being fired into brick volume coefficient at the bottom of greenwave is 205, to once fire brick water spray process at the bottom of obtained greenwave, every 0.18 square meter 20 grams of injection flow rate;
2) brick at the bottom of the greenwave after water spray first applies ground-coat enamel, and ground-coat enamel is first by weight: glaze 100 parts, Mierocrystalline cellulose 0.06 part, tripoly phosphate sodium STPP 0.4 part batching.The applying thickness of ground-coat enamel is 0.25mm, and ground-coat enamel applies cover-coat enamel again, and cover-coat enamel is made up of weight part: glaze 100 parts, 8 parts, quartz, kaolin 9 parts, Mierocrystalline cellulose 0.2 part together ball milling obtain.The applying thickness of cover-coat enamel is 0.15 mm, and cover-coat enamel carries out ink-jet system flower, and ink-jet Hua Houxian in spraying decoration surface painting fixing glue, and then spoons and entirely throws glaze;
3) carry out secondary to brick at the bottom of the greenwave after three layers of glazing to fire, control the firing temperature fired of secondary at 1100 DEG C, sintering time is 30min, secondary fired after through polishing and get final product.
Gained polishing wall tile due to sintering time not enough, glaze paint unfairness because there is residual bubbling.
Comparative example 4
1) by potter's clay raw material by weight: mussite 38 parts, 28 parts, Laiyang soil, flint clay 14 parts, blue clay 9 parts, 2 parts, talcum, magnetite 2 parts, black mud 7 parts are got the raw materials ready.Biscuit is obtained in ball milling, powder process, old rear compression moulding, the biscuit of compression moulding is once fired, the firing temperature controlling once to fire is at 1080 DEG C, sintering time 45min, being fired into brick volume coefficient at the bottom of greenwave is 205, to once fire brick water spray process at the bottom of obtained greenwave, every 0.18 square meter 30 grams of injection flow rate;
2) brick at the bottom of the greenwave after water spray first applies ground-coat enamel, and ground-coat enamel is first by weight: glaze 100 parts, Mierocrystalline cellulose 0.06 part, tripoly phosphate sodium STPP 0.4 part batching.The applying thickness of ground-coat enamel is 0.25mm, and ground-coat enamel applies cover-coat enamel again, and cover-coat enamel is made up of weight part: glaze 100 parts, 8 parts, quartz, kaolin 9 parts, Mierocrystalline cellulose 0.2 part together ball milling obtain.The applying thickness of cover-coat enamel is 0.15 mm, and cover-coat enamel carries out ink-jet system flower, and ink-jet Hua Houxian in spraying decoration surface painting fixing glue, and then spoons and entirely throws glaze;
3) carry out secondary to brick at the bottom of the greenwave after three layers of glazing to fire, control the firing temperature fired of secondary at 1100 DEG C, sintering time is 45min, secondary fired after through polishing and get final product.
Gained polishing wall tile due to brick water content at the bottom of greenwave excessive, there is pore in glaze paint, surface finish brightness only has 85%.
Comparative example 5
1) by potter's clay raw material by weight: mussite 38 parts, 28 parts, Laiyang soil, flint clay 14 parts, blue clay 9 parts, 2 parts, talcum, magnetite 2 parts, black mud 7 parts are got the raw materials ready.Biscuit is obtained in ball milling, powder process, old rear compression moulding, the biscuit of compression moulding is once fired, the firing temperature controlling once to fire is at 1080 DEG C, sintering time 45min, being fired into brick volume coefficient at the bottom of greenwave is 205, to once fire brick water spray process at the bottom of obtained greenwave, every 0.18 square meter 20 grams of injection flow rate;
2) brick at the bottom of the greenwave after water spray first applies ground-coat enamel, and ground-coat enamel is first by weight: glaze 100 parts, Mierocrystalline cellulose 0.06 part, tripoly phosphate sodium STPP 0.4 part batching.The applying thickness of ground-coat enamel is 0.25mm, and ground-coat enamel applies cover-coat enamel again, and cover-coat enamel is made up of weight part: glaze 100 parts, 20 parts, quartz, kaolin 25 parts, Mierocrystalline cellulose 0.2 part together ball milling obtain.The applying thickness of cover-coat enamel is 0.15 mm, and cover-coat enamel carries out ink-jet system flower, and ink-jet Hua Houxian in spraying decoration surface painting fixing glue, and then spoons and entirely throws glaze;
3) carry out secondary to brick at the bottom of the greenwave after three layers of glazing to fire, the firing temperature that control secondary is fired is at 1110 DEG C, and sintering time is 45min, and volume coefficient when ground-coat enamel is fired is 215, volume coefficient when cover-coat enamel is fired is 162, and volume coefficient when full throwing glaze is fired is 165; Secondary fired after through polishing and get final product.
Apply the quartz of glaze paint cover-coat enamel in gained polishing wall tile, kaolin addition carrys out control agent coefficient of expansion size, without ground-coat enamel and the transitional function entirely thrown between glaze, cause glaze paint to occur a large amount of crazing cracks.
The above is only preferred embodiment of the present invention, and be not restriction the present invention being made to other form, any those skilled in the art may utilize the technology contents of above-mentioned announcement to be changed or be modified as the Equivalent embodiments of equivalent variations.But everyly do not depart from technical solution of the present invention content, any simple modification, equivalent variations and the remodeling done above embodiment according to technical spirit of the present invention, still belong to the protection domain of technical solution of the present invention.
Claims (7)
1. a crystallite mirror polish wall tile, comprise end brick, it is characterized in that: described end brick is brick (1) at the bottom of greenwave, brick (1) at the bottom of described greenwave is provided with and forms You surface layer by the ground glaze layer successively applied (2), cover coat (3), spraying decoration layer (4) and full glaze layer (5) of throwing from bottom to top.
2. a kind of crystallite mirror polish wall tile according to claim 1, is characterized in that: at the bottom of described greenwave, the bottom surface of brick (1) is provided with anticreep projection (6).
3. a kind of crystallite mirror polish wall tile according to claim 1, it is characterized in that: at the bottom of described greenwave, the parts by weight of raw materials of brick (1) consists of: mussite 36 ~ 40 parts, 27 ~ 29 parts, Laiyang soil, flint clay 12 ~ 16 parts, blue clay 8 ~ 10 parts, 1.5 ~ 2.5 parts, talcum, magnetite 1.5 ~ 2.5 parts, black mud 6 ~ 8 parts.
4. a kind of crystallite mirror polish wall tile according to claim 1, is characterized in that: the parts by weight of raw materials of described ground glaze layer (2) consists of: glaze 100 parts, Mierocrystalline cellulose 0.05 ~ 0.1 part, tripoly phosphate sodium STPP 0.3 ~ 0.5 part.
5. a kind of crystallite mirror polish wall tile according to claim 1, is characterized in that: the parts by weight of raw materials of described cover coat (3) consists of glaze 100 parts, 3 ~ 15 parts, quartz, kaolin 5 ~ 12 parts, Mierocrystalline cellulose 0.15 ~ 0.2 part.
6. a making method for crystallite mirror polish wall tile as claimed in claim 1, it is characterized in that, preparation process is:
1) form by the weight part of potter's clay raw material: mussite 36 ~ 40 parts, 27 ~ 29 parts, Laiyang soil, flint clay 12 ~ 16 parts, blue clay 8 ~ 10 parts, 1.5 ~ 2.5 parts, talcum, magnetite 1.5 ~ 2.5 parts, black mud 6 ~ 8 parts preparation, potter's clay raw material is through ball milling, powder process, old rear compression moulding obtains biscuit, biscuit is once fired, the firing temperature controlling once to fire is at 1060 DEG C ~ 1100 DEG C, sintering time 43 min ~ 48min, at the bottom of the greenwave be fired into, the volume coefficient of brick (1) is 200 ~ 210, to once fire brick (1) water spray process at the bottom of obtained greenwave, every 0.18 square meter injection flow rate is 18 ~ 23 grams,
2) ground-coat enamel is applied on brick at the bottom of the greenwave after water spray, ground-coat enamel parts by weight of raw materials consists of: glaze 100 parts, Mierocrystalline cellulose 0.05 ~ 0.1 part, tripoly phosphate sodium STPP 0.3 ~ 0.5 part, the applying thickness of ground-coat enamel is 0.2 mm ~ 0.3mm, the volume coefficient forming ground glaze layer (2) when firing is 210 ~ 220, ground-coat enamel applies cover-coat enamel again, the parts by weight of raw materials of cover-coat enamel consists of glaze 100 parts, 3 ~ 15 parts, quartz, kaolin 5 ~ 12 parts, Mierocrystalline cellulose 0.15 ~ 0.2 part, the applying thickness of cover-coat enamel is 0.15 mm ~ 0.2mm, the volume coefficient forming cover coat (3) when firing is 180 ~ 185, cover-coat enamel carries out ink-jet system flower, and then spoon and entirely throw glaze,
3) carry out secondary to brick (1) at the bottom of the greenwave after glazing to fire, control the firing temperature fired of secondary at 1100 DEG C ~ 1120 DEG C, sintering time is 44 min ~ 49min, secondary fired after through polishing and get final product.
7. the making method of a kind of crystallite mirror polish wall tile according to claim 6, is characterized in that: step 2) described in ink-jet Hua Houxian be coated with fixing glue on spraying decoration surface, then drench and entirely throw glaze.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410470564.1A CN104230392B (en) | 2014-09-16 | 2014-09-16 | A kind of making method of crystallite mirror polish wall tile |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410470564.1A CN104230392B (en) | 2014-09-16 | 2014-09-16 | A kind of making method of crystallite mirror polish wall tile |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104230392A true CN104230392A (en) | 2014-12-24 |
| CN104230392B CN104230392B (en) | 2016-04-20 |
Family
ID=52219409
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410470564.1A Active CN104230392B (en) | 2014-09-16 | 2014-09-16 | A kind of making method of crystallite mirror polish wall tile |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104230392B (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104761248A (en) * | 2015-03-14 | 2015-07-08 | 广东博华陶瓷有限公司 | Production method of polished tile having stone texture |
| CN104947899A (en) * | 2015-05-21 | 2015-09-30 | 杭州茂华工贸有限公司 | Three-dimensional art tile and making process and application thereof |
| CN104961502A (en) * | 2015-06-10 | 2015-10-07 | 佛山欧神诺陶瓷股份有限公司 | Raw-glaze novel microcrystalline tactile sensation-imitation thick glaze-polished brick and production method thereof |
| CN105272365A (en) * | 2015-11-24 | 2016-01-27 | 武汉广益交通科技股份有限公司 | Energy-accumulating luminous glazed tile, glazing technology and glazing equipment |
| CN105541343A (en) * | 2015-12-18 | 2016-05-04 | 蒙娜丽莎集团股份有限公司 | Method for preparing inkjet-penetrated travertine polished tiles |
| CN105906382A (en) * | 2016-04-27 | 2016-08-31 | 淄博格伦凯陶瓷有限公司 | Marble polished ceramic tile and production method thereof |
| CN108249776A (en) * | 2017-11-21 | 2018-07-06 | 佛山市龙晶装饰材料有限公司 | A kind of process for calcining of glass block |
| CN108975704A (en) * | 2018-09-29 | 2018-12-11 | 广东新润成陶瓷有限公司 | A kind of acid and alkali-resistance throws vitreous brick and preparation method thereof entirely |
| CN110256113A (en) * | 2019-07-01 | 2019-09-20 | 广东易成陶瓷实业有限公司 | A kind of ceramic large area overglaze color anticracking color technique of white clouds soil |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102557583A (en) * | 2012-03-08 | 2012-07-11 | 淄博汉索夫陶瓷科技有限公司 | Energy-saving dry powder production method for building ceramics |
| CN102731169A (en) * | 2012-07-13 | 2012-10-17 | 佛山市科捷制釉有限公司 | Fully glazed ceramic chip and preparation method thereof |
| CN203569832U (en) * | 2013-10-17 | 2014-04-30 | 惠州市惠阳皇磁陶瓷有限公司 | Novel ceramic material |
| CN204079810U (en) * | 2014-09-16 | 2015-01-07 | 淄博格伦凯陶瓷有限公司 | A kind of crystallite mirror polish wall tile |
-
2014
- 2014-09-16 CN CN201410470564.1A patent/CN104230392B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102557583A (en) * | 2012-03-08 | 2012-07-11 | 淄博汉索夫陶瓷科技有限公司 | Energy-saving dry powder production method for building ceramics |
| CN102731169A (en) * | 2012-07-13 | 2012-10-17 | 佛山市科捷制釉有限公司 | Fully glazed ceramic chip and preparation method thereof |
| CN203569832U (en) * | 2013-10-17 | 2014-04-30 | 惠州市惠阳皇磁陶瓷有限公司 | Novel ceramic material |
| CN204079810U (en) * | 2014-09-16 | 2015-01-07 | 淄博格伦凯陶瓷有限公司 | A kind of crystallite mirror polish wall tile |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104761248A (en) * | 2015-03-14 | 2015-07-08 | 广东博华陶瓷有限公司 | Production method of polished tile having stone texture |
| CN104947899A (en) * | 2015-05-21 | 2015-09-30 | 杭州茂华工贸有限公司 | Three-dimensional art tile and making process and application thereof |
| CN104961502A (en) * | 2015-06-10 | 2015-10-07 | 佛山欧神诺陶瓷股份有限公司 | Raw-glaze novel microcrystalline tactile sensation-imitation thick glaze-polished brick and production method thereof |
| CN105272365A (en) * | 2015-11-24 | 2016-01-27 | 武汉广益交通科技股份有限公司 | Energy-accumulating luminous glazed tile, glazing technology and glazing equipment |
| CN105541343A (en) * | 2015-12-18 | 2016-05-04 | 蒙娜丽莎集团股份有限公司 | Method for preparing inkjet-penetrated travertine polished tiles |
| CN105541343B (en) * | 2015-12-18 | 2018-01-26 | 蒙娜丽莎集团股份有限公司 | A kind of preparation method of ink-jet infiltration hole stone polished brick |
| CN105906382A (en) * | 2016-04-27 | 2016-08-31 | 淄博格伦凯陶瓷有限公司 | Marble polished ceramic tile and production method thereof |
| CN105906382B (en) * | 2016-04-27 | 2018-09-11 | 淄博格伦凯陶瓷有限公司 | A kind of marble polishing ceramic tile and preparation method thereof |
| CN108249776A (en) * | 2017-11-21 | 2018-07-06 | 佛山市龙晶装饰材料有限公司 | A kind of process for calcining of glass block |
| CN108975704A (en) * | 2018-09-29 | 2018-12-11 | 广东新润成陶瓷有限公司 | A kind of acid and alkali-resistance throws vitreous brick and preparation method thereof entirely |
| CN110256113A (en) * | 2019-07-01 | 2019-09-20 | 广东易成陶瓷实业有限公司 | A kind of ceramic large area overglaze color anticracking color technique of white clouds soil |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104230392B (en) | 2016-04-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104230392B (en) | A kind of making method of crystallite mirror polish wall tile | |
| CN103467103B (en) | Production method of once-fired super-spar ceramic tile and ceramic tile | |
| CN105801177B (en) | Light-weight environment-friendly imitates rock glaze ceramics and preparation process | |
| CN106116688A (en) | A kind of manufacture method of the pottery with multiple structure | |
| CN103332966B (en) | Preparation method of composite opaque glaze | |
| CN114804824A (en) | Strong-transparency ceramic rock plate with deep-engraved concave-convex textures and preparation method thereof | |
| CN102731169A (en) | Fully glazed ceramic chip and preparation method thereof | |
| CN104261897A (en) | Ceramic tile having antiskid effect and manufacturing method thereof | |
| CN106045577B (en) | Medium temperature snowflake glaze ceramic and its production method | |
| CN107857475A (en) | A kind of ceramic whiteware glaze | |
| CN106316356A (en) | Method for preparing stone jade porcelain polished tile | |
| CN111605043A (en) | Porous gradient ceramic tile and manufacturing method thereof | |
| CN111807873A (en) | High-strength ceramic glazed tile and preparation method thereof | |
| CN110078375B (en) | Crack glaze for glass mosaic and preparation process of glass mosaic | |
| CN106219976A (en) | A kind of combined decoration metallic Ceramic Tiles and manufacture method thereof | |
| CN104909545A (en) | Large-size simulated granite porcelain thin plate and preparation method therefor | |
| CN105541112A (en) | A super-flat glaze frit and a method of manufacturing super spar from the same | |
| CN106542848B (en) | Daily porous composite ceramics with thermal insulation property and preparation method thereof | |
| CN202543089U (en) | Glazed ceramic tile with stereoscopic and level impressions | |
| CN104591695A (en) | Manufacturing method of large-sized regenerated ceramic | |
| CN204079810U (en) | A kind of crystallite mirror polish wall tile | |
| CN203145400U (en) | Polished crystal tile | |
| CN110330324A (en) | Ceramic thin plate of high tenacity and preparation method thereof | |
| CN203976648U (en) | A kind of glass-ceramic clad plate | |
| CN204689902U (en) | Brilliant minute surface ceramics thrown by a kind of interior wall |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |