CN104220159B - 用于从合成气合成二甲基醚的催化活性体 - Google Patents

用于从合成气合成二甲基醚的催化活性体 Download PDF

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CN104220159B
CN104220159B CN201380019884.9A CN201380019884A CN104220159B CN 104220159 B CN104220159 B CN 104220159B CN 201380019884 A CN201380019884 A CN 201380019884A CN 104220159 B CN104220159 B CN 104220159B
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weight
value
catalytically active
active body
component
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CN104220159A (zh
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A·舍费尔
费伦 T·冯
R·马东
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BASF SE
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BASF SE
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C07C43/04—Saturated ethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C07C43/04—Saturated ethers
    • C07C43/043—Dimethyl ether

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201380019884.9A 2012-02-15 2013-02-14 用于从合成气合成二甲基醚的催化活性体 Active CN104220159B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261598931P 2012-02-15 2012-02-15
US61/598,931 2012-02-15
PCT/EP2013/052959 WO2013120945A1 (en) 2012-02-15 2013-02-14 Catalytically active body for the synthesis of dimethyl ether from synthesis gas

Publications (2)

Publication Number Publication Date
CN104220159A CN104220159A (zh) 2014-12-17
CN104220159B true CN104220159B (zh) 2016-12-28

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Country Status (9)

Country Link
US (1) US9393555B2 (https=)
EP (1) EP2814600B1 (https=)
JP (1) JP6426004B2 (https=)
KR (1) KR20140126375A (https=)
CN (1) CN104220159B (https=)
CA (1) CA2864582A1 (https=)
RU (1) RU2624015C2 (https=)
WO (1) WO2013120945A1 (https=)
ZA (1) ZA201406697B (https=)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102017201691A1 (de) 2016-02-05 2017-08-10 Basf Se Verfahren zur Herstellung von Polyoxymethylen-Ethern aus Hüttengasen
US10189763B2 (en) 2016-07-01 2019-01-29 Res Usa, Llc Reduction of greenhouse gas emission
US9981896B2 (en) 2016-07-01 2018-05-29 Res Usa, Llc Conversion of methane to dimethyl ether
US9938217B2 (en) 2016-07-01 2018-04-10 Res Usa, Llc Fluidized bed membrane reactor
CA3086707A1 (en) 2017-12-20 2019-06-27 Basf Se Catalyst system and process for preparing dimethyl ether
CN111556785B (zh) 2017-12-20 2023-11-03 巴斯夫欧洲公司 用于制备二甲醚的催化剂和方法
US11045793B1 (en) * 2020-07-24 2021-06-29 Qatar University Controlled on-pot design of mixed copper/zinc oxides supported aluminum oxide as an efficient catalyst for conversion of syngas to heavy liquid hydrocarbons and alcohols under ambient conditions feasible for the Fischer-Tropsch synthesis

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4423155A (en) * 1981-02-20 1983-12-27 Mobil Oil Corporation Dimethyl ether synthesis catalyst
CN101190415A (zh) * 2006-11-28 2008-06-04 韩国燃气公社 制备用于从含二氧化碳的合成气合成二甲醚的催化剂的方法
US20110105306A1 (en) * 2009-10-30 2011-05-05 Atomic Energy Council-Institute Of Nuclear Energy Research Method of Fabricating Cu-Zn-Al Catalyst for Producing Methanol and Dimethyl Ether

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GB1405012A (en) * 1972-01-21 1975-09-03 Ici Ltd Method of making composition convertible to a catalyst precursor and catalyst and methanol synthesis using the catalyst
AU5902490A (en) * 1989-07-18 1991-08-01 Air Products And Chemicals Inc. One-step liquid phase process for dimethyl ether synthesis
DK173614B1 (da) 1999-02-02 2001-04-30 Topsoe Haldor As Fremgangsmåde til fremstilling af methanol/dimethyletherblanding fra syntesegas
US6608114B1 (en) 2002-03-13 2003-08-19 Air Products And Chemicals, Inc. Process to produce DME
JP2003047861A (ja) * 2002-06-03 2003-02-18 Nkk Corp ジメチルエーテル製造用触媒の製造方法およびジメチルエーテルの製造方法
JP4283709B2 (ja) * 2003-03-06 2009-06-24 ジェイエフイーホールディングス株式会社 スラリー床反応方式用媒体油及びジメチルエーテルの製造方法
US7241713B2 (en) * 2003-10-02 2007-07-10 Exxonmobil Chemical Patents Inc. Molecular sieve catalyst composition, its making and use in conversion processes
JP5145213B2 (ja) * 2005-04-15 2013-02-13 ユニヴァーシティー オブ サザン カリフォルニア 二酸化炭素のメタノール、ジメチルエーテルおよび派生生成物への効率的且つ選択的変換法
US7485767B2 (en) 2005-06-29 2009-02-03 Exxonmobil Chemical Patents Inc. Production of synthesis gas blends for conversion to methanol or Fischer-Tropsch liquids
DE102006020158B4 (de) * 2006-05-02 2009-04-09 Argillon Gmbh Extrudierter Vollkatalysator sowie Verfahren zu seiner Herstellung
US7906559B2 (en) 2007-06-21 2011-03-15 University Of Southern California Conversion of carbon dioxide to methanol and/or dimethyl ether using bi-reforming of methane or natural gas
US20100216897A1 (en) 2007-07-12 2010-08-26 Thomas Rostrup-Nielsen Process for the preparation of dimethyl ether
EP2072491A1 (en) * 2007-12-17 2009-06-24 BP p.l.c. Process for the conversion of alcohol(s) into alcohol(s) with increased carbon-chain
US8378150B2 (en) * 2009-08-12 2013-02-19 Catalytic Distillation Technologies Process for the production of dimethyl ether
US20130197288A1 (en) * 2012-01-31 2013-08-01 Linde Ag Process for the conversion of synthesis gas to olefins
US9295978B2 (en) * 2012-02-15 2016-03-29 Basf Corporation Catalyst and method for the direct synthesis of dimethyl ether from synthesis gas

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4423155A (en) * 1981-02-20 1983-12-27 Mobil Oil Corporation Dimethyl ether synthesis catalyst
CN101190415A (zh) * 2006-11-28 2008-06-04 韩国燃气公社 制备用于从含二氧化碳的合成气合成二甲醚的催化剂的方法
US20110105306A1 (en) * 2009-10-30 2011-05-05 Atomic Energy Council-Institute Of Nuclear Energy Research Method of Fabricating Cu-Zn-Al Catalyst for Producing Methanol and Dimethyl Ether

Also Published As

Publication number Publication date
EP2814600A1 (en) 2014-12-24
EP2814600B1 (en) 2016-07-06
RU2014137014A (ru) 2016-04-10
JP6426004B2 (ja) 2018-11-21
KR20140126375A (ko) 2014-10-30
CN104220159A (zh) 2014-12-17
US9393555B2 (en) 2016-07-19
RU2624015C2 (ru) 2017-06-30
WO2013120945A1 (en) 2013-08-22
ZA201406697B (en) 2016-07-27
JP2015511881A (ja) 2015-04-23
US20130210612A1 (en) 2013-08-15
CA2864582A1 (en) 2013-08-22

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