CN104194588A - Ultraviolet photocuring alkene unsaturated polyester coating for ceramic - Google Patents
Ultraviolet photocuring alkene unsaturated polyester coating for ceramic Download PDFInfo
- Publication number
- CN104194588A CN104194588A CN201410430847.3A CN201410430847A CN104194588A CN 104194588 A CN104194588 A CN 104194588A CN 201410430847 A CN201410430847 A CN 201410430847A CN 104194588 A CN104194588 A CN 104194588A
- Authority
- CN
- China
- Prior art keywords
- parts
- unsaturated polyester
- coating
- alkene unsaturated
- polyester coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Paints Or Removers (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
The invention discloses an ultraviolet photocuring alkene unsaturated polyester coating for ceramic. The coating is prepared from the following raw materials: bisphenol A butyl acetate glyceryl ether, carboxymethylcellulose, methylene-succinic acid, lithopone, n-butyl acetate, calcium carbonate heavy, a photosensitizer, talcum powder, acrylic acid, ultramarine, a cross-linking agent, sodium silicate, methacryloyloxyethyl isocyanate, zinc oxide and dibulytin dilaurate. The glossiness of the product, namely the ultraviolet photocuring alkene unsaturated polyester coating is 110-130%, and the coating coated in amyl acetate in 1-3 days is free from bubbling and shedding phenomena. The coating is acetone-resistant and is free from abnormalities after being rubbed by a cotton ball soaked by 5% ammonium water for 24-48 hours. The coating is free from bubbling and wrinkling after being soaked in a 95% ethanol solution for 12-36 hours. The scrub resistance of the product reaches 600-800 times, and can be widely produced and continuously replace existing materials.
Description
Technical field
The application belongs to paint field, relates in particular to a kind of pottery ultraviolet photo-curing alkene unsaturated polyester coating.
Background technology
Ceramic industry is very fast in China's development, and selling market turns to rise gradually.China is a Production of Ceramics big country, also increasing to ceramic demand.From domestic market situation, in recent years have a gratifying situation, supply falls short of demand for new, special products of famous brands, of extra fine quality ceramic product, and high-grade ceramic and medium-to-high grade snitaryware are very in great demand, and the measured traditional product of matter continues to be in great demand, and unsalable is ropy product.Pottery is the various goods of the material that makes of, moulding mixing through pulverizing taking natural clay and various natural mineral as main raw material and calcining.People were called pottery the article of high-temperature firing in special kiln that are made into potter's clay in the past, and pottery is the general name of pottery and porcelain.The traditional concept of pottery refers to all artificial Industrial products taking inorganic non-metallic mineral such as clays as raw material.It comprises by clay or the mixture that contains clay through mixing, is shaped, and calcining and the various goods made.All belonged to its scope to the meticulousst fine pottery and porcelain by the most coarse earthenware.Be to take from natural silicate minerals (as clay, quartz etc.) for its main raw material, therefore with industry such as glass, N-BUTYL ACETATE mud, enamel, refractory materialss, belong to the category of " silicate industry ".Up to now, defining like can briefly be described as follows of pottery: pottery be with aluminium silicate mineral or some oxide compound etc. be main raw material, the technique rock with a shaping type of at high temperature making with certain temperature and atmosphere by specific physical and chemical process according to people's intention.Surface can glazing or not glazing, and some porcelains also have translucency in various degree, entire body be by one or more crystal or with amorphous cementing matter and pore or with the microstructures such as grog inclusion.
Coating (paint), our usual said paint is one wherein.Refer to coat that body surface can form film under certain conditions and play protection, decorate or a class I liquid I or the solid material of other specific functions (insulation, antirust, mildew-resistant, heat-resisting etc.).Because early stage coating is main raw material mainly with vegetables oil greatly, therefore be called again paint.Replace vegetables oil at synthetic resins, therefore be called coating.Coating is not liquid, and powder coating is the large class of coating variety one.Coating belongs to organic chemical industry's macromolecular material, and the film forming belongs to macromolecular compound type.According to the classification of current Chemicals of modern times, coating belongs to fine chemical product.Modern coating is progressively becoming the polyfunctional engineering materials of a class, is an important industry in chemical industry.Ceramic coating weathering resistance and processing characteristics excellence, bear dirty and resistance to damage.Although the resistance to damage of ceramic coating in the past, if the parts after application are carried out to bending machining, easily cracks, and fluorine resin paints and organic coating, easily by the damage such as sandstone, dust.Therefore, the appearance of ceramic coating, has been subject to the favor of ceramic industry, and the infiltration of forward other industry, promise well.
Ceramic coating is that one can make organism and inorganics react, thereby has had both the novel ceramic coating of both advantages.More than the hardness of the ceramic coating of a new generation can reach 6H.High temperature resistant 400 degree, not sticky effect, color is multiple.And can make N-BUTYL ACETATE ceramic coating.Founding of New, over 60 years, is accompanied by the development of national economy every profession and trade, progressively develops into the requisite important industry of all fields of national economy as its supporting coatings industry from an extremely unobtrusive little industry.Struggling hard, pioneering and keeping forging ahead through several generations, China has become second-biggest-in-the-world coating material production state and country of consumption, enter into the main flow of world's coating industry development. and popularizing along with humanity concept, and the formation of novel harmonious society, design a kind of resistance to amyl acetate-n, acetone, 95% ethanol and 5% ammoniacal liquor and soak cotton balls friction, and wear-resisting, heat-resisting pottery is very important with ultraviolet photo-curing alkene unsaturated polyester coating.
Summary of the invention
The technical problem solving:
The application is for above-mentioned technical problem, a kind of pottery ultraviolet photo-curing alkene unsaturated polyester coating is provided, solve existing the pottery not resistance to amyl acetate-n of ultraviolet photo-curing alkene unsaturated polyester coating, acetone, 95% ethanol and 5% ammoniacal liquor and soak cotton balls friction, and the technical problem such as wear-resisting, poor heat resistance.
Technical scheme:
A kind of pottery ultraviolet photo-curing alkene unsaturated polyester coating, described pottery is as follows by the raw materials by weight portion proportioning of ultraviolet photo-curing alkene unsaturated polyester coating: 100 parts of dihydroxyphenyl propane contracting N-BUTYL ACETATE glyceryl ethers; Carboxymethyl cellulose 10-30 part; Methylene-succinic acid 20-30 part; Zinc sulfide white 5-25 part; N-BUTYL ACETATE 40-50 part; Three fly powder 10-20 part; Photosensitizers 5-15 part; Talcum powder 15-25 part; Vinylformic acid 20-40 part; Ultramarine 1-5 part; Linking agent 1-10 part; Water glass 15-35 part; Methacrylic acid isocyanide acyl group ethyl ester 25-35 part; Zinc oxide 20-30 part; Dibutyl tin laurate 30-40 part.
As a preferred technical solution of the present invention: described pottery is as follows by the raw materials by weight portion proportioning of ultraviolet photo-curing alkene unsaturated polyester coating: 100 parts of dihydroxyphenyl propane contracting N-BUTYL ACETATE glyceryl ethers; 20 parts of carboxymethyl celluloses; 25 parts of methylene-succinic acids; 15 parts, zinc sulfide white; 45 parts of N-BUTYL ACETATEs; Three fly 15 parts, powder; 10 parts of photosensitizerss; 20 parts of talcum powder; 30 parts, vinylformic acid; 3 parts, ultramarine; 5 parts of linking agents; 25 parts of water glass; 30 parts of methacrylic acid isocyanide acyl group ethyl esters; 25 parts, zinc oxide; 35 parts of dibutyl tin laurates.
As a preferred technical solution of the present invention: described photosensitizers adopts Benzoin ethyl ether or benzophenone.
As a preferred technical solution of the present invention: described linking agent adopts hexamethoxymethyl melamine or vinylbenzene.
Beneficial effect:
A kind of pottery of the present invention adopts above technical scheme compared with prior art with ultraviolet photo-curing alkene unsaturated polyester coating, there is following technique effect: 1, product glossiness 110%-130%, soaks after 1-3d without bubbling, obscission in amyl acetate-n; 2, resistance to acetone, 5% ammoniacal liquor soak cotton balls friction 24-48h without extremely; 3, in 95% ethanolic soln, soak that 12-36h is non-foaming, elephant skin; 4, the washable wiping of product 600-800 time, can the not division of history into periods of widespread production replace current material.
Embodiment
Embodiment 1:
A kind of pottery is used ultraviolet photo-curing alkene unsaturated polyester coating, and its raw materials by weight portion proportioning is as follows: 100 parts of dihydroxyphenyl propane contracting N-BUTYL ACETATE glyceryl ethers; 10 parts of carboxymethyl celluloses; 20 parts of methylene-succinic acids; 5 parts, zinc sulfide white; 40 parts of N-BUTYL ACETATEs; Three fly 10 parts, powder; 5 parts of benzophenone; 15 parts of talcum powder; 20 parts, vinylformic acid; 1 part, ultramarine; 1 part of hexamethoxymethyl melamine; 15 parts of water glass; 25 parts of methacrylic acid isocyanide acyl group ethyl esters; 20 parts, zinc oxide; 30 parts of dibutyl tin laurates.
Above-mentioned raw materials is heated in reactor to 70 DEG C and stirs 12h, after mixing, be cooled to room temperature, drop into grinding machine for grinding 1h.
Product glossiness 110%, soaks after 1d without bubbling, obscission in amyl acetate-n; Resistance to acetone, 5% ammoniacal liquor soak cotton balls friction 24h without extremely; In 95% ethanolic soln, soak that 12h is non-foaming, elephant skin, washable wiping 600 times.
Embodiment 2:
A kind of pottery is used ultraviolet photo-curing alkene unsaturated polyester coating, and its raw materials by weight portion proportioning is as follows: 100 parts of dihydroxyphenyl propane contracting N-BUTYL ACETATE glyceryl ethers; 30 parts of carboxymethyl celluloses; 30 parts of methylene-succinic acids; 25 parts, zinc sulfide white; 50 parts of N-BUTYL ACETATEs; Three fly 20 parts, powder; 15 parts of Benzoin ethyl ethers; 25 parts of talcum powder; 40 parts, vinylformic acid; 5 parts, ultramarine; 10 parts of hexamethoxymethyl melamines; 35 parts of water glass; 35 parts of methacrylic acid isocyanide acyl group ethyl esters; 30 parts, zinc oxide; 40 parts of dibutyl tin laurates.
Above-mentioned raw materials is heated in reactor to 80 DEG C and stirs 16h, after mixing, be cooled to room temperature, drop into grinding machine for grinding 2h.
Product glossiness 120%, soaks after 2d without bubbling, obscission in amyl acetate-n; Resistance to acetone, 5% ammoniacal liquor soak cotton balls friction 36h without extremely; In 95% ethanolic soln, soak that 24h is non-foaming, elephant skin, washable wiping 700 times.
Embodiment 3:
A kind of pottery is used ultraviolet photo-curing alkene unsaturated polyester coating, and its raw materials by weight portion proportioning is as follows: 100 parts of dihydroxyphenyl propane contracting N-BUTYL ACETATE glyceryl ethers; 20 parts of carboxymethyl celluloses; 25 parts of methylene-succinic acids; 15 parts, zinc sulfide white; 45 parts of N-BUTYL ACETATEs; Three fly 15 parts, powder; 10 parts of Benzoin ethyl ethers; 20 parts of talcum powder; 30 parts, vinylformic acid; 3 parts, ultramarine; 5 parts of vinylbenzene; 25 parts of water glass; 30 parts of methacrylic acid isocyanide acyl group ethyl esters; 25 parts, zinc oxide; 35 parts of dibutyl tin laurates.
Above-mentioned raw materials is heated in reactor to 75 DEG C and stirs 14h, after mixing, be cooled to room temperature, drop into grinding machine for grinding 1h.
Product glossiness 130%, soaks after 3d without bubbling, obscission in amyl acetate-n; Resistance to acetone, 5% ammoniacal liquor soak cotton balls friction 48h without extremely; In 95% ethanolic soln, soak that 36h is non-foaming, elephant skin, washable wiping 800 times.
Composition all components in above embodiment all can business be bought.
Above-described embodiment is just for content of the present invention is set forth, instead of restriction, and therefore any change in implication and the scope suitable with claims of the present invention, all should think to be included in the scope of claims.
Claims (4)
1. pottery is used a ultraviolet photo-curing alkene unsaturated polyester coating, it is characterized in that the raw materials by weight portion proportioning of described pottery ultraviolet photo-curing alkene unsaturated polyester coating is as follows: 100 parts of dihydroxyphenyl propane contracting N-BUTYL ACETATE glyceryl ethers; Carboxymethyl cellulose 10-30 part; Methylene-succinic acid 20-30 part; Zinc sulfide white 5-25 part; N-BUTYL ACETATE 40-50 part; Three fly powder 10-20 part; Photosensitizers 5-15 part; Talcum powder 15-25 part; Vinylformic acid 20-40 part; Ultramarine 1-5 part; Linking agent 1-10 part; Water glass 15-35 part; Methacrylic acid isocyanide acyl group ethyl ester 25-35 part; Zinc oxide 20-30 part; Dibutyl tin laurate 30-40 part.
2. a kind of pottery according to claim 1 is used ultraviolet photo-curing alkene unsaturated polyester coating, it is characterized in that the raw materials by weight portion proportioning of described pottery ultraviolet photo-curing alkene unsaturated polyester coating is as follows: 100 parts of dihydroxyphenyl propane contracting N-BUTYL ACETATE glyceryl ethers; 20 parts of carboxymethyl celluloses; 25 parts of methylene-succinic acids; 15 parts, zinc sulfide white; 45 parts of N-BUTYL ACETATEs; Three fly 15 parts, powder; 10 parts of photosensitizerss; 20 parts of talcum powder; 30 parts, vinylformic acid; 3 parts, ultramarine; 5 parts of linking agents; 25 parts of water glass; 30 parts of methacrylic acid isocyanide acyl group ethyl esters; 25 parts, zinc oxide; 35 parts of dibutyl tin laurates.
3. a kind of pottery according to claim 1 is used ultraviolet photo-curing alkene unsaturated polyester coating, it is characterized in that: described photosensitizers adopts Benzoin ethyl ether or benzophenone.
4. a kind of pottery according to claim 1 is used ultraviolet photo-curing alkene unsaturated polyester coating, it is characterized in that: described linking agent adopts hexamethoxymethyl melamine or vinylbenzene.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410430847.3A CN104194588B (en) | 2014-08-28 | 2014-08-28 | Ultraviolet photo-curing alkene unsaturated polyester coating used by a kind of pottery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410430847.3A CN104194588B (en) | 2014-08-28 | 2014-08-28 | Ultraviolet photo-curing alkene unsaturated polyester coating used by a kind of pottery |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104194588A true CN104194588A (en) | 2014-12-10 |
| CN104194588B CN104194588B (en) | 2016-06-29 |
Family
ID=52079966
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410430847.3A Active CN104194588B (en) | 2014-08-28 | 2014-08-28 | Ultraviolet photo-curing alkene unsaturated polyester coating used by a kind of pottery |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104194588B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4075261A (en) * | 1972-06-28 | 1978-02-21 | Toyo Boseki Kabushiki Kaisha | Powder coating composition |
| CN101760118A (en) * | 2008-11-24 | 2010-06-30 | 王虹 | Ultraviolet curing alkene unsaturated polyester coating and preparation method thereof |
| CN103013305A (en) * | 2012-12-24 | 2013-04-03 | 辽宁圣铎涂料科技有限公司 | Cold-coating bi-component unsaturated polyester resin highway marking paint |
-
2014
- 2014-08-28 CN CN201410430847.3A patent/CN104194588B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4075261A (en) * | 1972-06-28 | 1978-02-21 | Toyo Boseki Kabushiki Kaisha | Powder coating composition |
| CN101760118A (en) * | 2008-11-24 | 2010-06-30 | 王虹 | Ultraviolet curing alkene unsaturated polyester coating and preparation method thereof |
| CN103013305A (en) * | 2012-12-24 | 2013-04-03 | 辽宁圣铎涂料科技有限公司 | Cold-coating bi-component unsaturated polyester resin highway marking paint |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104194588B (en) | 2016-06-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101067062B (en) | High performance outer wall paint preparation method | |
| CN106590252A (en) | Graphene-modified building exterior wall heat-insulation coating and preparation method thereof | |
| CN104194441A (en) | Acrylate coating for ceramics | |
| CN104292903A (en) | Acrylic epoxy resin powder paint for ceramics | |
| CN104371396A (en) | Scrubbing-resistant interior-wall coating for building | |
| CN104312235B (en) | A kind of ceramic with corrosion-resistant acrylic acid epoxy resin powdery paints | |
| CN104151896B (en) | Radiation curing epoxy coating used by a kind of pottery | |
| CN102173874A (en) | Ceramic glaze for generating natural weathering and erosion on surface of ceramic product | |
| CN104152014A (en) | Carboxyl-type polyester powder paint used for ceramic | |
| CN104327631A (en) | Improved-hardness heat-radiation aqueous coating for glass doors, and its preparation method | |
| CN104312417A (en) | Acrylic carboxyl polyurethane powder coating for ceramic | |
| CN104194588A (en) | Ultraviolet photocuring alkene unsaturated polyester coating for ceramic | |
| CN104292902A (en) | Thermosetting acrylic powder paint for ceramics | |
| CN104031538B (en) | A kind of epoxy resin ground thick coating | |
| CN104178019A (en) | Photocuring coating for ceramic | |
| CN104031448B (en) | A kind of zero diopter exterior coating | |
| CN104177992B (en) | A kind of pottery radiation curing acrylate resin coating | |
| CN104312236A (en) | Acrylic resin polyurethane powder coating for ceramics | |
| CN104152003B (en) | A kind of pottery epoxy powder coating | |
| CN104151894A (en) | Ultraviolet curing polyacrylic ester paint used for ceramic | |
| CN104293063A (en) | Thermosetting acrylic resin powder coating for ceramic | |
| CN104151895B (en) | A kind of pottery polyacrylate coating | |
| CN104312237B (en) | A kind of pottery is with containing carboxy acrylic ester toner coating | |
| CN104312418A (en) | Crylic acid polyurethane powder coating for ceramic | |
| CN104673084A (en) | Novel ultraviolet cured acrylic coating for ceramics |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20201225 Address after: 224006 room 109, no.1572, Luming Road, Yanlong street, Yandu District, Yancheng City, Jiangsu Province Patentee after: Yancheng Yanlong water Co., Ltd Address before: Room 4722, Tianlong building, no.378, Zhujiang South Road, Mudu Town, Wuzhong District, Suzhou City, Jiangsu Province Patentee before: SUZHOU LUOTELAN NEW MATERIAL TECHNOLOGY Co.,Ltd. |
|
| TR01 | Transfer of patent right |