CN104194588B - Ultraviolet photo-curing alkene unsaturated polyester coating used by a kind of pottery - Google Patents
Ultraviolet photo-curing alkene unsaturated polyester coating used by a kind of pottery Download PDFInfo
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- CN104194588B CN104194588B CN201410430847.3A CN201410430847A CN104194588B CN 104194588 B CN104194588 B CN 104194588B CN 201410430847 A CN201410430847 A CN 201410430847A CN 104194588 B CN104194588 B CN 104194588B
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Abstract
The invention discloses a kind of pottery ultraviolet photo-curing alkene unsaturated polyester coating, raw material is: bisphenol-A contracting butyl acetate glycerin ether, carboxymethyl cellulose, methylene-succinic acid, lithopone, butyl acetate, three fly powder, photosensitizer, Pulvis Talci, acrylic acid, ultramarine, cross-linking agent, sodium silicate, methacrylic acid isocyanato ethyl ester, zinc oxide and dibutyl tin laurate；Product glossiness 110%-130%, without foaming, obscission after immersion 1-3d in amyl acetate；Resistant to acetone, 5% ammonia leaching cotton balls friction 24-48h are without exception；95% alcoholic solution soaks 12-36h is non-foaming, elephant skin；Product scrub resistance 600-800 time, it is possible to current material is replaced in the widespread production not division of history into periods.
Description
Technical field
The application belongs to paint field, particularly relates to a kind of pottery ultraviolet photo-curing alkene unsaturated polyester coating.
Background technology
Ceramic industry is very fast in China's development, and selling market turns to rise gradually.China is a Production of Ceramics big country, and the demand of pottery is also increasing.From domestic market situation, in recent years having a gratifying situation, supply falls short of demand for new, special products of famous brands, of extra fine quality ceramic product, and high-grade ceramic and medium-to-high grade sanitary ceramics are very in great demand, and the measured traditional product of matter continues to be in great demand, unsalable simply ropy product.Pottery is the various goods of the material prepared for primary raw material through mixing, the molding of pulverizing and calcining with natural clay and various natural minerals.People were called pottery the article of high-temperature firing in special kiln being fabricated to potter's clay in the past, and pottery is the general name of pottery and porcelain.The traditional concept of pottery refers to all artificial industrial products being raw material with Inorganic nonmetal mineral such as clays.It include by clay or containing the mixture of clay through mixing, shape, calcining and the various goods made.Broadly fall into its scope to the finest fine pottery and porcelain by the most coarse earthenware.Primary raw material for it is the silicate mineral (such as clay, quartz etc.) taking from nature, therefore with industry such as glass, butyl acetate mud, enamel, refractory materials, belongs to the category of " silicate industry ".Up to now, pottery define like can briefly be described as follows: pottery is to be primary raw material with aluminium silicate mineral or some oxide etc., according to the technique rock with a shaping type that the intention of people is at high temperature made with certain temperature and atmosphere by specific physical and chemical process.Surface can glazing or not glazing, some porcelains also have translucence in various degree, entire body by one or more crystal or with amorphous cement and pore or form with microstructures such as grog inclusion enclaves.
Coating (paint), our usually described paint is one therein.Refer to coat body surface to form thin film under certain conditions and play protection, the class I liquid I of decoration or other specific functions (insulation, antirust, mildew-resistant, heat-resisting etc.) or solid material.Because the coating of early stage is mostly with vegetable oil for primary raw material, therefore also referred to as paint.Instead of vegetable oil at synthetic resin, therefore be called coating.Coating non-liquid, powdery paints is the big class of coating variety one.Coating belongs to organic chemical industry's macromolecular material, and the film formed belongs to macromolecular compound type.According to the classification of the chemical products that the modern times pass through, coating belongs to fine chemical product.Modern coating is progressively becoming a polyfunctional engineering material of class, is an important industry in chemical industry.Ceramic coating weatherability and processing characteristics are excellent, bear dirty and resistant to damage.Although conventional ceramic coating resistant to damage, but if the parts after application are curved processing, it is easy to crack, and fluorine resin paints and organic coating, it is easy to damaged by sandstone, dust etc..Therefore, the appearance of ceramic coating, receive the favor of ceramic industry the infiltration of forward other industry, promise well.
Ceramic coating is that one can make Organic substance and inorganic matter react, thus having had both the novel ceramic coating of both advantages.The hardness of the ceramic coating of a new generation can reach more than 6H.High temperature resistant 400 degree, not viscous effect, color is multiple.And butyl acetate ceramic coating can be made.Founding of New is over 60 years, along with the development of national economy every profession and trade, progressively develops into the requisite important industry of all fields of national economy as its supporting coatings industry from an extremely unobtrusive little industry.Through the struggling hard of several generations, pioneer and keep forging ahead, China has become second-biggest-in-the-world coating material production state and country of consumption, enter into the main flow of world's coating industry development. and popularizing along with humanity concept, and the composition of novel harmonious society, design a kind of resistance to amyl acetate, acetone, 95% ethanol and the leaching cotton balls friction of 5% ammonia, and wear-resisting, heat-resisting pottery ultraviolet photo-curing alkene unsaturated polyester coating is very important.
Summary of the invention
Solve the technical problem that:
The application is for above-mentioned technical problem, a kind of pottery is provided to use ultraviolet photo-curing alkene unsaturated polyester coating, solve existing pottery ultraviolet photo-curing alkene unsaturated polyester coating and soak the technical problems such as cotton balls friction, and wear-resisting, poor heat resistance weak to amyl acetate, acetone, 95% ethanol and 5% ammonia.
Technical scheme:
Ultraviolet photo-curing alkene unsaturated polyester coating used by a kind of pottery, and the raw materials by weight portion proportioning of described pottery ultraviolet photo-curing alkene unsaturated polyester coating is as follows: bisphenol-A contracting butyl acetate glycerin ether 100 parts；Carboxymethyl cellulose 10-30 part；Methylene-succinic acid 20-30 part；Lithopone 5-25 part；Butyl acetate 40-50 part；Three fly powder 10-20 part；Photosensitizer 5-15 part；Pulvis Talci 15-25 part；Acrylic acid 20-40 part；Ultramarine 1-5 part；Cross-linking agent 1-10 part；Sodium silicate 15-35 part；Methacrylic acid isocyanato ethyl ester 25-35 part；Zinc oxide 20-30 part；Dibutyl tin laurate 30-40 part.
As a preferred technical solution of the present invention: the raw materials by weight portion proportioning of described pottery ultraviolet photo-curing alkene unsaturated polyester coating is as follows: bisphenol-A contracting butyl acetate glycerin ether 100 parts；Carboxymethyl cellulose 20 parts；Methylene-succinic acid 25 parts；15 parts of lithopone；Butyl acetate 45 parts；Three fly 15 parts of powder；Photosensitizer 10 parts；Pulvis Talci 20 parts；30 parts of acrylic acid；3 parts of ultramarine；Cross-linking agent 5 parts；Sodium silicate 25 parts；Methacrylic acid isocyanato ethyl ester 30 parts；Zinc oxide 25 parts；Dibutyl tin laurate 35 parts.
As a preferred technical solution of the present invention: described photosensitizer adopts benzoin ethyl ether or benzophenone.
As a preferred technical solution of the present invention: described cross-linking agent adopts hexamethoxymethyl melamine or styrene.
Beneficial effect:
A kind of pottery ultraviolet photo-curing alkene unsaturated polyester coating of the present invention adopts above technical scheme compared with prior art, have following technical effect that 1, product glossiness 110%-130%, after amyl acetate soaks 1-3d without bubbling, obscission；2, resistant to acetone, 5% ammonia leaching cotton balls friction 24-48h without exception；3, in 95% alcoholic solution, soak that 12-36h is non-foaming, elephant skin；4, product scrub resistance 600-800 time, it is possible to current material is replaced in the widespread production not division of history into periods.
Detailed description of the invention
Embodiment 1:
Ultraviolet photo-curing alkene unsaturated polyester coating used by a kind of pottery, and its raw materials by weight portion proportioning is as follows: bisphenol-A contracting butyl acetate glycerin ether 100 parts；Carboxymethyl cellulose 10 parts；Methylene-succinic acid 20 parts；5 parts of lithopone；Butyl acetate 40 parts；Three fly 10 parts of powder；Benzophenone 5 parts；Pulvis Talci 15 parts；20 parts of acrylic acid；1 part of ultramarine；Hexamethoxymethyl melamine 1 part；Sodium silicate 15 parts；Methacrylic acid isocyanato ethyl ester 25 parts；Zinc oxide 20 parts；Dibutyl tin laurate 30 parts.
Above-mentioned raw materials is heated in a kettle. 70 DEG C of stirring 12h, after mix homogeneously, is cooled to room temperature, puts into grinding machine for grinding 1h.
Product glossiness 110%, without foaming, obscission after immersion 1d in amyl acetate；Resistant to acetone, 5% ammonia leaching cotton balls friction 24h are without exception；95% alcoholic solution soaks 12h is non-foaming, elephant skin, scrub resistance 600 times.
Embodiment 2:
Ultraviolet photo-curing alkene unsaturated polyester coating used by a kind of pottery, and its raw materials by weight portion proportioning is as follows: bisphenol-A contracting butyl acetate glycerin ether 100 parts；Carboxymethyl cellulose 30 parts；Methylene-succinic acid 30 parts；25 parts of lithopone；Butyl acetate 50 parts；Three fly 20 parts of powder；Benzoin ethyl ether 15 parts；Pulvis Talci 25 parts；40 parts of acrylic acid；5 parts of ultramarine；Hexamethoxymethyl melamine 10 parts；Sodium silicate 35 parts；Methacrylic acid isocyanato ethyl ester 35 parts；Zinc oxide 30 parts；Dibutyl tin laurate 40 parts.
Above-mentioned raw materials is heated in a kettle. 80 DEG C of stirring 16h, after mix homogeneously, is cooled to room temperature, puts into grinding machine for grinding 2h.
Product glossiness 120%, without foaming, obscission after immersion 2d in amyl acetate；Resistant to acetone, 5% ammonia leaching cotton balls friction 36h are without exception；95% alcoholic solution soaks 24h is non-foaming, elephant skin, scrub resistance 700 times.
Embodiment 3:
Ultraviolet photo-curing alkene unsaturated polyester coating used by a kind of pottery, and its raw materials by weight portion proportioning is as follows: bisphenol-A contracting butyl acetate glycerin ether 100 parts；Carboxymethyl cellulose 20 parts；Methylene-succinic acid 25 parts；15 parts of lithopone；Butyl acetate 45 parts；Three fly 15 parts of powder；Benzoin ethyl ether 10 parts；Pulvis Talci 20 parts；30 parts of acrylic acid；3 parts of ultramarine；Styrene 5 parts；Sodium silicate 25 parts；Methacrylic acid isocyanato ethyl ester 30 parts；Zinc oxide 25 parts；Dibutyl tin laurate 35 parts.
Above-mentioned raw materials is heated in a kettle. 75 DEG C of stirring 14h, after mix homogeneously, is cooled to room temperature, puts into grinding machine for grinding 1h.
Product glossiness 130%, without foaming, obscission after immersion 3d in amyl acetate；Resistant to acetone, 5% ammonia leaching cotton balls friction 48h are without exception；95% alcoholic solution soaks 36h is non-foaming, elephant skin, scrub resistance 800 times.
Compositions all components in above example all can be commercially available.
Above-described embodiment is only intended to present disclosure is illustrated, rather than restriction, and the therefore any change in the implication suitable with claims of the present invention and scope, all it is believed that be included in the scope of claims.
Claims (1)
1. ultraviolet photo-curing alkene unsaturated polyester coating used by a pottery, it is characterised in that the raw materials by weight portion proportioning of described pottery ultraviolet photo-curing alkene unsaturated polyester coating is as follows: bisphenol-A contracting butyl acetate glycerin ether 100 parts；Carboxymethyl cellulose 20 parts；Methylene-succinic acid 25 parts；15 parts of lithopone；Butyl acetate 45 parts；Three fly 15 parts of powder；Photosensitizer 10 parts；Pulvis Talci 20 parts；30 parts of acrylic acid；3 parts of ultramarine；Cross-linking agent 5 parts；Sodium silicate 25 parts；Methacrylic acid isocyanato ethyl ester 30 parts；Zinc oxide 25 parts；Dibutyl tin laurate 35 parts；
Described photosensitizer adopts benzoin ethyl ether or benzophenone；
Described cross-linking agent adopts hexamethoxymethyl melamine or styrene.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410430847.3A CN104194588B (en) | 2014-08-28 | 2014-08-28 | Ultraviolet photo-curing alkene unsaturated polyester coating used by a kind of pottery |
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| CN201410430847.3A CN104194588B (en) | 2014-08-28 | 2014-08-28 | Ultraviolet photo-curing alkene unsaturated polyester coating used by a kind of pottery |
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| CN104194588A CN104194588A (en) | 2014-12-10 |
| CN104194588B true CN104194588B (en) | 2016-06-29 |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4075261A (en) * | 1972-06-28 | 1978-02-21 | Toyo Boseki Kabushiki Kaisha | Powder coating composition |
| CN101760118A (en) * | 2008-11-24 | 2010-06-30 | 王虹 | Ultraviolet curing alkene unsaturated polyester coating and preparation method thereof |
| CN103013305A (en) * | 2012-12-24 | 2013-04-03 | 辽宁圣铎涂料科技有限公司 | Cold-coating bi-component unsaturated polyester resin highway marking paint |
-
2014
- 2014-08-28 CN CN201410430847.3A patent/CN104194588B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4075261A (en) * | 1972-06-28 | 1978-02-21 | Toyo Boseki Kabushiki Kaisha | Powder coating composition |
| CN101760118A (en) * | 2008-11-24 | 2010-06-30 | 王虹 | Ultraviolet curing alkene unsaturated polyester coating and preparation method thereof |
| CN103013305A (en) * | 2012-12-24 | 2013-04-03 | 辽宁圣铎涂料科技有限公司 | Cold-coating bi-component unsaturated polyester resin highway marking paint |
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| CN104194588A (en) | 2014-12-10 |
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