CN104193176A - Method and device for producing pattern and texture microcrystal glass plate of fluorosilicone calcium sodium stone crystal phase - Google Patents

Method and device for producing pattern and texture microcrystal glass plate of fluorosilicone calcium sodium stone crystal phase Download PDF

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CN104193176A
CN104193176A CN201410471374.1A CN201410471374A CN104193176A CN 104193176 A CN104193176 A CN 104193176A CN 201410471374 A CN201410471374 A CN 201410471374A CN 104193176 A CN104193176 A CN 104193176A
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glass plate
calcium sodium
work pool
crystalline phase
sodium stone
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CN104193176B (en
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朱新明
戴长禄
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Jiangxi Kangjia New Material Technology Co., Ltd.
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JINFENGHUANG DECORATIVE MATERIALS CO Ltd JIUJIANG
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Abstract

The invention relates to the field of microcrystal glass plates, and in particular relates to a method and a device for producing pattern and texture microcrystal glass plate of fluorosilicone calcium sodium stone crystal phase. The method comprises the following steps: respectively putting a main material and an auxiliary material of different colors into different melting furnaces for smelting; firstly, directly feeding the molten main material into a working tank, secondly, feeding molten auxiliary material solutions of different colors into the working tank through a plurality of channels which are arranged in parallel above the working tank at intervals, spreading the auxiliary material solutions above the main material solution to form strips which are arranged in parallel and which are of different colors, stirring in a fixed direction, and controlling the temperature of the working tank to be within 1100-1350 DEG C; calendaring a mixed material which is uniformly stirred and cooled, coring, crystallizing, annealing, performing rough polishing and performing fine polishing, thereby obtaining the pattern and texture microcrystal glass plate of fluorosilicone calcium sodium stone crystal phase. By adopting the method and the device, the current situation that a product of a microcrystal glass plate is single in color and has no decorative art texture is changed.

Description

Production method and the device of the pattern texture microcrystal glass plate of fluorine silico-calcium sodium stone crystalline phase
Technical field
The present invention relates to microcrystal glass plate production field, relate in particular to a kind of production method and device of pattern texture microcrystal glass plate of fluorine silico-calcium sodium stone crystalline phase.
Background technology
The type material that devitrified glass is comprised of glassy phase and crystallization phases.Its physicochemical property are by the relative content of these two kinds of phases and performance is common determines.The Application Areas of devitrified glass is extensive.As building and ornament materials, many-sided performances such as its mechanical property, chemical stability, the feature of environmental protection, aberration consistence are all better than stone material, thereby are described as " finishing material of 21 century ".The production method of devitrified glass mainly comprises two kinds of sintering process and rolling processes.No matter be that principal crystalline phase is fluorine silico-calcium alkali stone (Na 4k 2ca 5< Si 12o 30> F 4) tradition calendering microcrystal glass plate, or principal crystalline phase is fluorine silico-calcium sodium stone (NaCa 2< Si 2o 5> 2f) novel calendering microcrystal glass plate, the color of product is very single, an adularescent, let alone have the imitative stone striped of decoration.In order to improve the decorative art level of calendering devitrified glass, strengthen the competitive power in market, expand market sale field and scale, must change color single, without the low grade products present situation of any decorative art striped.
Be subject to the inspiration of the genesis mechanism of ryolite in geology, applicant has sprouted the thinking of the decorative patterns production method of the mutual mixed flow generation of the glass melt flow liner that adopts different colours.And different colours, can separate out that to take devitrified glass that fluorine silico-calcium sodium stone is principal crystalline phase be to realize according to ion coloring, colloid is painted, semiconductor microcrystallite is painted three large modern theories.For realizing the mixing of different colours glass melt, need to change the process layout of traditional melting furnaces to a crystallization kiln, set up new a plurality of melting furnaces to a crystallization kiln or a plurality of melting furnaces the process layout to many crystallization kilns.
Summary of the invention
For above-mentioned technical problem, the present invention has designed and developed a kind of production method and device of pattern texture microcrystal glass plate of fluorine silico-calcium sodium stone crystalline phase, object is to provide a kind of method that can produce the microcrystal glass plate of different colours texture, change microcrystal glass plate color single, without the present situation on product of any decorative art texture.
Another object of the present invention is to by designing a plurality of melting furnaces and a plurality of material road, the glass melt of different colours is mixed at work pool, and control the temperature of work pool and the mixing direction of directed agitator, improve stability and artistic effect that microcrystal glass plate different colours texture forms.
Technical scheme provided by the invention is:
A devitrified glass plate producing process for the pattern texture of fluorine silico-calcium sodium stone crystalline phase, comprises the following steps:
Step 1, by the auxiliary material of major ingredient and different colours, be placed in respectively different melting furnaces and found, auxiliary material is different colours take the devitrified glass liquation that fluorine silico-calcium sodium stone is principal crystalline phase;
Step 2, first fusing after major ingredient liquation directly enter the bottom that forms microcrystal glass plate in work pool, the auxiliary material liquation of the different colours after fusing enters in described work pool through a plurality of material road that is arranged on work pool top spaced in parallel to each other respectively afterwards, and the top that is laid on described major ingredient liquation forms the texture of the different colours of parallel arrangement, pattern texture as microcrystal glass plate, hybrid glass liquation is carried out to orientation and stir, control the temperature of work pool between 1100~1350 ℃;
Step 3, the hybrid glass liquation after stirring, through rolling equipment calendering formation, coring, crystallization, annealing, rough polishing, essence are thrown, and obtain the microcrystal glass plate that fluorine silico-calcium sodium stone is principal crystalline phase of take of different colours texture;
Wherein, the operative orientation of the directed raker stirrer stirring be flow direction along described hybrid glass liquation to work pool Way out horizontal reciprocating movement, the liquation of the fluorine silico-calcium sodium stone crystalline phase of different colours is mixed to form take the pattern texture microcrystal glass plate that fluorine silico-calcium sodium stone is principal crystalline phase.
Preferably, in the devitrified glass plate producing process of the pattern texture of described fluorine silico-calcium sodium stone crystalline phase, described work pool comprises glass melt mixing zone and glass melt stirring area, and described glass melt mixing zone and glass melt stirring area connect and arrange.
Preferably, in the devitrified glass plate producing process of the pattern texture of described fluorine silico-calcium sodium stone crystalline phase, the raker stirrer that the described directed direction stirring is directed stirrer stirs along described glass melt mixing zone Way out to described glass melt stirring area Way out horizontal reciprocating.
A microcrystal glass plate production equipment for the pattern texture of fluorine silico-calcium sodium stone crystalline phase, comprising:
A plurality of melting furnaces, are placed with respectively the auxiliary material to be founded of major ingredient to be founded and different colours in it, a plurality of melting furnaces are corresponding to a crystallization kiln or many crystallization kilns;
Work pool, the melting furnaces of major ingredient to be founded described in its sidepiece is connected with, the outlet of the melting furnaces of major ingredient described to be founded is directly communicated in described work pool, described work pool upper parallel is arranged at intervals with the melting furnaces of a plurality of auxiliary materials to be founded, the melting furnaces of each auxiliary material to be founded are communicated to described work pool by least one material road, the outlet of described work pool is communicated to rolling equipment, and the working temperature of described work pool is between 1100~1350 ℃;
Directed agitator, its raker stirrer is arranged in described work pool, and the operative orientation of the raker stirrer of described directed agitator is that flow direction along hybrid glass liquation is to work pool Way out horizontal reciprocating movement.
Preferably, in the microcrystal glass plate production equipment of the pattern texture of described fluorine silico-calcium sodium stone crystalline phase, described work pool comprises glass melt mixing zone and glass melt stirring area, described glass melt mixing zone and glass melt stirring area connect and arrange, the raker stirrer of described directed agitator is arranged in described glass melt stirring area, and the mixing direction of described directed agitator is that raker stirrer stirs along described glass melt mixing zone Way out to described glass melt stirring area Way out horizontal reciprocating.
Preferably, in the microcrystal glass plate production equipment of the pattern texture of described fluorine silico-calcium sodium stone crystalline phase, the raker stirrer of described directed agitator is arranged on a transmission component, described transmission component comprises a lifting transmission component and a horizontal transmission component, and described lifting transmission component is connected with a motor respectively with horizontal transmission component.
Preferably, in the microcrystal glass plate production equipment of the pattern texture of described fluorine silico-calcium sodium stone crystalline phase, described raker stirrer comprises a body of rod and is arranged on a plurality of stirrer gears on the described body of rod, the described body of rod comprises a water inlet pipe and a rising pipe, described water inlet pipe is set in described rising pipe, a plurality of stirrer gears are all set to tubulose, and one end of each stirrer gear is communicated with described water inlet pipe, and the other end is communicated with described rising pipe.
Preferably, in the microcrystal glass plate production equipment of the pattern texture of described fluorine silico-calcium sodium stone crystalline phase, on described directed agitator, be also provided with a revolving member, described revolving member is fixed on described transmission component top, described revolving member comprises at least one turning axle and a pair of deflecting roller, described a pair of deflecting roller is intermeshing, and arrange in the orthogonal mode of turning direction, a rotor wheel and described turning axle pivot joint, another rotor wheel is set on the body of rod of described raker stirrer and fixes with the described body of rod, and under the effect of described turning axle, drive the described body of rod to rotate.
Preferably, in the microcrystal glass plate production equipment of the pattern texture of described fluorine silico-calcium sodium stone crystalline phase, between described revolving member and described stirrer gear, be also provided with a baffle plate, the body of rod of described raker stirrer passes the through hole of described baffle plate and extends in described work pool and arranges.
In the pattern texture microcrystal glass plate of fluorine silico-calcium sodium stone crystalline phase of the present invention and production method and device, the auxiliary material of major ingredient and different colours is placed in respectively different melting furnaces and founds, first major ingredient liquation after fusing enters the bottom that forms microcrystal glass plate in described work pool, the auxiliary material liquation of the different colours after fusing enters in work pool through the difference material road being arranged on work pool spaced in parallel to each other respectively afterwards, and the top that is laid on described major ingredient liquation forms the texture of the different colours of parallel arrangement, as the pattern texture of microcrystal glass plate.The strict temperature of controlling in work pool, unlikely because excess Temperature makes different colours glass melt phase cross equalization, also the unlikely too high and mobility variation of glass melt viscosity that makes because temperature is too low, affect the artistic decorative effect of the mixing of different glass liquation or the striped that flows, improved stability and artistic effect that the imitative stone striped of microcrystal glass plate different colours forms.Described raker stirrer is uniformly mixed material along described glass melt mixing zone Way out to described glass melt stirring area Way out horizontal reciprocating under the effect of described lifting transmission component and horizontal transmission component in described work pool, not only can effectively get rid of the bubble in compound, and guarantee that pattern grain effect is better simultaneously.
Accompanying drawing explanation
Fig. 1 is the pattern texture microcrystal glass plate production equipment schematic diagram of fluorine silico-calcium sodium stone crystalline phase of the present invention;
Fig. 2 is the structural representation of directed agitator of the present invention.
Embodiment
Below in conjunction with accompanying drawing, the present invention is described in further detail, to make those skilled in the art can implement according to this with reference to specification sheets word.
The pattern texture devitrified glass plate producing process that the invention provides a kind of fluorine silico-calcium sodium stone crystalline phase, comprises the following steps:
Step 1, by the auxiliary material of major ingredient and different colours, be placed in respectively different melting furnaces and found, major ingredient and auxiliary material can be not containing any painted metal ion, any metallic colloid, any micritization compound that can be painted that can be painted; Also can be containing any painted metal ion, as mn ion, nickel ion, titanium ion, cerium ion, cobalt ion etc., numerous; Also can be containing copper colloid that can be painted, silver colloid, gold colloid etc.; Also can be containing micritization compounds such as Cadmium Sulfide that can be painted, cadmium selenides.Melting furnaces can arrange a plurality of, are two in the present embodiment, i.e. melting pool 1 and electric smelter 2, and the more major ingredient of consumption is placed in bulky melting pool, and the less auxiliary material of consumption is placed in electric smelter;
Step 2, first the major ingredient liquation after fusing directly enters the bottom that forms microcrystal glass plate in work pool, the auxiliary material liquation of the different colours after fusing enters in described work pool 4 through a plurality of material road 3 that is arranged on work pool top spaced in parallel to each other respectively afterwards, and the top that is laid on described major ingredient liquation forms the texture of the different colours of parallel arrangement, pattern texture as microcrystal glass plate, each top, material road is provided with a plurality of tear drops hole 5, can in work pool, add auxiliary material by tear drop hole, to control the shade of compound in work pool, compound is carried out to orientation to be stirred, Stirring with respect to existing installation, directed stirring is more stable to the control of compound texture, control the temperature of work pool between 1100~1350 ℃, unlikely because excess Temperature makes different colours glass melt phase cross equalization, also the unlikely too high and mobility variation of glass melt viscosity that makes because temperature is too low, affect the artistic decorative effect of the mixing of different glass liquation or the texture that flows, and glass melting temperature in melting furnaces is 1400~1500 ℃, if the raw material of different colours will permeate by phase cross equalization mix fusing in melting furnaces after, can not form the pattern texture of many colors, do not reach expected effect,
Hybrid glass liquation after step 3, stirring, through rolling equipment calendering formation, coring, crystallization, annealing, rough polishing, essence are thrown, and obtain the microcrystal glass plate that different colours texture bultfonteinite is principal crystalline phase;
Wherein, the operative orientation of the directed raker stirrer stirring be flow direction along described hybrid glass liquation to work pool Way out horizontal reciprocating movement, the liquation of the fluorine silico-calcium sodium stone crystalline phase of different colours is mixed to form take the pattern texture microcrystal glass plate that fluorine silico-calcium sodium stone is principal crystalline phase.
In the pattern texture devitrified glass plate producing process of described fluorine silico-calcium sodium stone crystalline phase, described work pool comprises glass melt mixing zone 6 and glass melt stirring area 7, and described glass melt mixing zone and glass melt stirring area connect and arrange.
In the pattern texture devitrified glass plate producing process of described fluorine silico-calcium sodium stone crystalline phase, the raker stirrer that the described directed direction stirring is directed stirrer stirs along described glass melt mixing zone Way out to described glass melt stirring area Way out horizontal reciprocating, rather than the Stirring in existing installation, by controlling the depth of the movement velocity adjusting compound striped color of raker stirrer.
Embodiment 1
A pattern texture devitrified glass plate producing process for fluorine silico-calcium sodium stone crystalline phase, comprises the following steps:
Step 1, by the auxiliary material of major ingredient and different colours, being placed in respectively different melting furnaces founds, melting furnaces can arrange two, be a melting pool and an electric smelter, the major ingredient that consumption is more, is placed in bulky melting pool, and the less auxiliary material of consumption is placed in electric smelter, in the present embodiment, major ingredient is metal ion not take the devitrified glass liquation that fluorine silico-calcium sodium stone is principal crystalline phase, and auxiliary material is the devitrified glass liquation that fluorine silico-calcium sodium stone is principal crystalline phase of take containing cerium ion and titanium ion;
Step 2, first fusing after major ingredient liquation directly enter the bottom that forms microcrystal glass plate in work pool, the auxiliary material liquation containing cerium ion and titanium ion after fusing enters in described work pool through the Liang Geliao road, work pool top that is arranged on spaced in parallel to each other respectively afterwards, and the top that is laid on described major ingredient liquation forms the yellow texture of parallel arrangement, yellow texture as microcrystal glass plate, compound is carried out to orientation and stir, the temperature of controlling work pool is 1100 ℃;
Hybrid glass liquation after step 3, stirring, through rolling equipment calendering formation, coring, crystallization, annealing, rough polishing, essence are thrown, the microcrystal glass plate that the bultfonteinite that obtains white substrate, yellow cord is principal crystalline phase;
Wherein, the operative orientation of the directed raker stirrer stirring be flow direction along described hybrid glass liquation to work pool Way out horizontal reciprocating movement, the liquation of the fluorine silico-calcium sodium stone crystalline phase of different colours is mixed to form take the pattern texture microcrystal glass plate that fluorine silico-calcium sodium stone is principal crystalline phase.
Embodiment 2
A pattern texture devitrified glass plate producing process for fluorine silico-calcium sodium stone crystalline phase, comprises the following steps:
Step 1, by the auxiliary material of major ingredient and different colours, being placed in respectively different melting furnaces founds, melting furnaces can arrange two, be a melting pool and an electric smelter, the major ingredient that consumption is more, is placed in bulky melting pool, and the less auxiliary material of consumption is placed in electric smelter, in the present embodiment, major ingredient is the painted semiconductor microcrystallite compound that contains Cadmium Sulfide, cadmium selenide, and auxiliary material is the devitrified glass liquation that fluorine silico-calcium sodium stone is principal crystalline phase of take containing nickel ion and cobalt ion;
Step 2, first fusing after major ingredient liquation directly enter the bottom that forms microcrystal glass plate in work pool, the auxiliary material liquation containing nickel ion and cobalt ion after fusing enters in described work pool through the Liang Geliao road, work pool top that is arranged on spaced in parallel to each other respectively afterwards, and the top that is laid on described major ingredient liquation forms the black texture of parallel arrangement, black texture as microcrystal glass plate, compound is carried out to orientation and stir, the temperature of controlling work pool is 1350 ℃;
Hybrid glass liquation after step 3, stirring, through rolling equipment calendering formation, coring, crystallization, annealing, rough polishing, essence are thrown, the microcrystal glass plate that the bultfonteinite that obtains red substrate, blackstreak is principal crystalline phase;
Wherein, the operative orientation of the directed raker stirrer stirring be flow direction along described hybrid glass liquation to work pool Way out horizontal reciprocating movement, the liquation of the fluorine silico-calcium sodium stone crystalline phase of different colours is mixed to form take the pattern texture microcrystal glass plate that fluorine silico-calcium sodium stone is principal crystalline phase.
Fracture toughness property of take the microcrystal glass plate that fluorine silico-calcium sodium stone is main crystalline phase of the present invention is 2.1Mpa.m 1/2, belonging to higher toughness material, this both can keep certain opposing mechanical external force performance, can be beneficial to the mechanical workouts such as cutting again.And the fracture toughness property of the original product that principal crystalline phase is fluorcanasite is at 4Mpa.m 1/2although its opposing mechanical external force is strong, it is difficult to very much cutting, is unfavorable for deep processing.
And of the present inventionly take fluorine silico-calcium and receive the microcrystal glass plate surface porosity that stone is main crystalline phase and reduce, acid resistance is good, and life-time service does not ftracture.And the surface porosity of original product is on the high side, acid resistance does not reach Expectation of Glass-Ceramics Used as Decorated Materials building material industry standard (JC/T 872-2000) sometimes.According to this standard, product soaks 650 hours at 1% sulphuric acid soln, mass loss rate≤0.2%, and also outward appearance is unchanged.For excellent product, not only acid resistance is qualified, and the pore of > 1mm is unallowed.The pore of 0.5mm-1mm does not allow to surpass 2/m 2, the pore of < 0.5mm is not subject to quantity limitation, only needs not intensive.
Tracking by nearly 1 year detects, and product acid resistance of the present invention all reaches building material industry standard, and gas hole defect rate is no more than 4%.And original product usually can't pass acid resistance standard detection the whole year, and gas hole defect rate generally all surpasses 4%, and maximum reaches 20% sometimes.
As shown in Figure 1, a kind of pattern texture microcrystal glass plate production equipment of fluorine silico-calcium sodium stone crystalline phase, comprising:
A plurality of melting furnaces, are placed with respectively the auxiliary material to be founded of major ingredient to be founded and different colours in it, a plurality of melting furnaces are corresponding to a crystallization kiln or many crystallization kilns;
Work pool, the melting furnaces of major ingredient to be founded described in its sidepiece is connected with, the outlet of the melting furnaces of major ingredient described to be founded is directly communicated in described work pool, described work pool upper parallel is arranged at intervals with the melting furnaces of a plurality of auxiliary materials to be founded, the melting furnaces of each auxiliary material to be founded are communicated to described work pool by least one material road, the outlet of described work pool is communicated to rolling equipment, the working temperature of described work pool is between 1100~1350 ℃, work pool surrounding offers a plurality of bottoming holes 8 and vision slit 9, with control the temperature of work pool inside and observe internal mix material number, to adjust at any time temperature, increase in time liquation,
Directed agitator 10, its raker stirrer is arranged in described work pool, and the operative orientation of the raker stirrer 11 of described directed agitator is that flow direction along hybrid glass liquation is to work pool Way out horizontal reciprocating movement.
In the pattern texture microcrystal glass plate production equipment of described fluorine silico-calcium sodium stone crystalline phase, described work pool comprises glass melt mixing zone and glass melt stirring area, described glass melt mixing zone and glass melt stirring area connect and arrange, the glass melt of different colours is after the preliminary mixing in mixing zone, flowing into stirring area further mixes, the raker stirrer of described directed agitator is arranged in described glass melt stirring area, the mixing direction of described directed agitator is that raker stirrer stirs along described glass melt mixing zone Way out to described glass melt stirring area Way out horizontal reciprocating.
In the pattern texture microcrystal glass plate production equipment of described fluorine silico-calcium sodium stone crystalline phase, as shown in Figure 2, the raker stirrer of described directed agitator is arranged on a transmission component, transmission component is placed in a box body 12, box body bottom is provided with mounting block 13, to facilitate the directed agitator that secured adjusted is good, described transmission component comprises a lifting transmission component 14 and a horizontal transmission component 15, described lifting transmission component is connected with a motor respectively with horizontal transmission component, two motors are fixed on respectively one end of raker stirrer by lifting transmission component and horizontal transmission component, thereby regulate vertical height and the tangential movement of raker stirrer.
In the pattern texture microcrystal glass plate production equipment of described fluorine silico-calcium sodium stone crystalline phase, as shown in Figure 2, described raker stirrer comprises a body of rod 16 and is arranged on a plurality of stirrer gears 17 on the described body of rod, the described body of rod comprises a water inlet pipe 18 and a rising pipe 19, described water inlet pipe is set in described rising pipe, water-in and water outlet are arranged on the one end away from stirrer gear, a plurality of stirrer gears are all set to U-shaped tubulose, be arranged in parallel within body of rod below, glass melt to different colours stirs simultaneously, one end of each stirrer gear is communicated with described water inlet pipe, the other end is communicated with described rising pipe, by flowing of water in water inlet pipe and rising pipe, the compound in work pool is lowered the temperature, raker stirrer is protected simultaneously.
In the pattern texture microcrystal glass plate production equipment of described fluorine silico-calcium sodium stone crystalline phase, as shown in Figure 2, on described directed agitator, be also provided with a revolving member, described revolving member is fixed on described transmission component top, described revolving member comprises at least one turning axle 20 and a pair of deflecting roller, turning axle is fixed on the top of box body, described a pair of deflecting roller is intermeshing, and arrange in the orthogonal mode of turning direction, a rotor wheel 21 and described turning axle pivot joint, another rotor wheel 22 is set on the body of rod of described raker stirrer and fixes with the described body of rod, the rotation of turning axle drives a rotor wheel of pivot joint with it to rotate, another rotor wheel is because engagement is rotated and drives the body of rod of raker stirrer to rotate thereupon, thereby stirrer gear can freely be rotated at vertical direction and horizontal direction.
In the pattern texture microcrystal glass plate production equipment of described fluorine silico-calcium sodium stone crystalline phase, as shown in Figure 2, between described revolving member and described stirrer gear, be also provided with a baffle plate 23, the body of rod of described raker stirrer passes the through hole 24 of described baffle plate and extends in described work pool and arranges, because the through hole on baffle plate is that level is offered, stirrer gear can not pass through smoothly, therefore revolving member is arranged so that when directed agitator is installed, the direction of stirrer gear is consistent with the direction of baffle plate through hole, when stirrer gear is through after through hole, Stirring tooth to vertical direction carries out stirring work again.
Although embodiment of the present invention are open as above, but it is not restricted to listed utilization in specification sheets and embodiment, it can be applied to various applicable the field of the invention completely, for those skilled in the art, can easily realize other modification, therefore do not deviating under the universal that claim and equivalency range limit, the present invention is not limited to specific details and illustrates here and the legend of describing.

Claims (9)

1. a production method for the microcrystal glass plate of the pattern texture of fluorine silico-calcium sodium stone crystalline phase, is characterized in that, comprises the following steps:
Step 1, by the auxiliary material of major ingredient and different colours, be placed in respectively different melting furnaces and found, auxiliary material is different colours take the devitrified glass liquation that fluorine silico-calcium sodium stone is principal crystalline phase;
Step 2, first fusing after major ingredient liquation directly enter the bottom that forms microcrystal glass plate in work pool, the auxiliary material liquation of the different colours after fusing enters in described work pool through a plurality of material road that is arranged on work pool top spaced in parallel to each other respectively afterwards, and the top that is laid on described major ingredient liquation forms the texture of the different colours of parallel arrangement, pattern texture as microcrystal glass plate, hybrid glass liquation is carried out to orientation and stir, control the temperature of work pool between 1100~1350 ℃;
Step 3, the hybrid glass liquation after stirring, through rolling equipment calendering formation, coring, crystallization, annealing, rough polishing, essence are thrown, and obtain the microcrystal glass plate that fluorine silico-calcium sodium stone is principal crystalline phase of take of different colours texture;
Wherein, the operative orientation of the directed raker stirrer stirring be flow direction along described hybrid glass liquation to work pool Way out horizontal reciprocating movement, the liquation of the fluorine silico-calcium sodium stone crystalline phase of different colours is mixed to form take the pattern texture microcrystal glass plate that fluorine silico-calcium sodium stone is principal crystalline phase.
2. the production method of the microcrystal glass plate of the pattern texture of fluorine silico-calcium sodium stone crystalline phase as claimed in claim 1, it is characterized in that, described work pool comprises glass melt mixing zone and glass melt stirring area, and described glass melt mixing zone and glass melt stirring area connect and arrange.
3. the production method of the microcrystal glass plate of the pattern texture of fluorine silico-calcium sodium stone crystalline phase as claimed in claim 2, the raker stirrer that the described directed direction stirring is directed stirrer stirs along described glass melt mixing zone Way out to described glass melt stirring area Way out horizontal reciprocating.
4. a production equipment for the microcrystal glass plate of the pattern texture of fluorine silico-calcium sodium stone crystalline phase, is characterized in that, comprising:
A plurality of melting furnaces, are placed with respectively the auxiliary material to be founded of major ingredient to be founded and different colours in it, a plurality of melting furnaces are corresponding to a crystallization kiln or many crystallization kilns;
Work pool, the melting furnaces of major ingredient to be founded described in its sidepiece is connected with, the outlet of the melting furnaces of major ingredient described to be founded is directly communicated in described work pool, described work pool upper parallel is arranged at intervals with the melting furnaces of a plurality of auxiliary materials to be founded, the melting furnaces of each auxiliary material to be founded are communicated to described work pool by least one material road, the outlet of described work pool is communicated to rolling equipment, and the working temperature of described work pool is between 1100~1350 ℃;
Directed agitator, its raker stirrer is arranged in described work pool, and the operative orientation of the raker stirrer of described directed agitator is that flow direction along hybrid glass liquation is to work pool Way out horizontal reciprocating movement.
5. the production equipment of the microcrystal glass plate of the pattern texture of fluorine silico-calcium sodium stone crystalline phase as claimed in claim 4, it is characterized in that, described work pool comprises glass melt mixing zone and glass melt stirring area, described glass melt mixing zone and glass melt stirring area connect and arrange, the raker stirrer of described directed agitator is arranged in described glass melt stirring area, and the mixing direction of described directed agitator is that raker stirrer stirs along described glass melt mixing zone Way out to described glass melt stirring area Way out horizontal reciprocating.
6. the production equipment of the microcrystal glass plate of the pattern texture of fluorine silico-calcium sodium stone crystalline phase as claimed in claim 4, it is characterized in that, the raker stirrer of described directed agitator is arranged on a transmission component, described transmission component comprises a lifting transmission component and a horizontal transmission component, and described lifting transmission component is connected with a motor respectively with horizontal transmission component.
7. the production equipment of the microcrystal glass plate of the pattern texture of fluorine silico-calcium sodium stone crystalline phase as claimed in claim 6, it is characterized in that, described raker stirrer comprises a body of rod and is arranged on a plurality of stirrer gears on the described body of rod, the described body of rod comprises a water inlet pipe and a rising pipe, described water inlet pipe is set in described rising pipe, a plurality of stirrer gears are all set to tubulose, and one end of each stirrer gear is communicated with described water inlet pipe, and the other end is communicated with described rising pipe.
8. the production equipment of the microcrystal glass plate of the pattern texture of fluorine silico-calcium sodium stone crystalline phase as claimed in claim 7, it is characterized in that, on described directed agitator, be also provided with a revolving member, described revolving member is fixed on described transmission component top, described revolving member comprises at least one turning axle and a pair of deflecting roller, described a pair of deflecting roller is intermeshing, and arrange in the orthogonal mode of turning direction, a rotor wheel and described turning axle pivot joint, another rotor wheel is set on the body of rod of described raker stirrer and fixes with the described body of rod, and under the effect of described turning axle, drive the described body of rod to rotate.
9. the production equipment of the microcrystal glass plate of the pattern texture of fluorine silico-calcium sodium stone crystalline phase as claimed in claim 8, it is characterized in that, between described revolving member and described stirrer gear, be also provided with a baffle plate, the body of rod of described raker stirrer passes the through hole of described baffle plate and extends in described work pool and arranges.
CN201410471374.1A 2014-09-01 2014-09-16 Method and device for producing pattern and texture microcrystal glass plate of fluorosilicone calcium sodium stone crystal phase Active CN104193176B (en)

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CN2014104413569 2014-09-01
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Publication number Priority date Publication date Assignee Title
CN107867791A (en) * 2017-12-21 2018-04-03 九江金凤凰装饰材料有限公司 A kind of kiln and melting method of the production of nano microcrystalline sheet material

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US5275978A (en) * 1987-12-11 1994-01-04 Nippon Electric Glass Company, Limited Colored crystallized glass article and method for producing the same
JPH08225343A (en) * 1995-02-23 1996-09-03 Nippon Electric Glass Co Ltd Crystallized glass article for construction material and production of the article
CN1647949A (en) * 2004-12-15 2005-08-03 黎志煊 Micro crystal glass color picture and making method
CN1847175A (en) * 2005-04-17 2006-10-18 谢骏峰 Painted glass tile producing process and apparatus
CN202170292U (en) * 2011-07-22 2012-03-21 中航三鑫太阳能光电玻璃有限公司 Novel horizontal mixer for glass liquid

Patent Citations (5)

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Publication number Priority date Publication date Assignee Title
US5275978A (en) * 1987-12-11 1994-01-04 Nippon Electric Glass Company, Limited Colored crystallized glass article and method for producing the same
JPH08225343A (en) * 1995-02-23 1996-09-03 Nippon Electric Glass Co Ltd Crystallized glass article for construction material and production of the article
CN1647949A (en) * 2004-12-15 2005-08-03 黎志煊 Micro crystal glass color picture and making method
CN1847175A (en) * 2005-04-17 2006-10-18 谢骏峰 Painted glass tile producing process and apparatus
CN202170292U (en) * 2011-07-22 2012-03-21 中航三鑫太阳能光电玻璃有限公司 Novel horizontal mixer for glass liquid

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107867791A (en) * 2017-12-21 2018-04-03 九江金凤凰装饰材料有限公司 A kind of kiln and melting method of the production of nano microcrystalline sheet material

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