CN107698162A - A kind of yellow bottom white point-like line high temperature crystallization glaze and preparation method thereof - Google Patents
A kind of yellow bottom white point-like line high temperature crystallization glaze and preparation method thereof Download PDFInfo
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- CN107698162A CN107698162A CN201710953067.0A CN201710953067A CN107698162A CN 107698162 A CN107698162 A CN 107698162A CN 201710953067 A CN201710953067 A CN 201710953067A CN 107698162 A CN107698162 A CN 107698162A
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- high temperature
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- temperature crystallization
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- 238000002425 crystallisation Methods 0.000 title claims abstract description 115
- 230000008025 crystallization Effects 0.000 title claims abstract description 115
- 238000002360 preparation method Methods 0.000 title claims abstract description 44
- 239000002994 raw material Substances 0.000 claims abstract description 81
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 72
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 57
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 40
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 36
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 28
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 27
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 27
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000000440 bentonite Substances 0.000 claims abstract description 26
- 229910000278 bentonite Inorganic materials 0.000 claims abstract description 26
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 26
- 238000001354 calcination Methods 0.000 claims abstract description 21
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910001887 tin oxide Inorganic materials 0.000 claims abstract description 21
- 239000011787 zinc oxide Substances 0.000 claims abstract description 20
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims abstract description 18
- 238000005245 sintering Methods 0.000 claims abstract description 13
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000292 calcium oxide Substances 0.000 claims abstract description 9
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 9
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910001950 potassium oxide Inorganic materials 0.000 claims abstract description 9
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910001948 sodium oxide Inorganic materials 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- 229910001868 water Inorganic materials 0.000 claims description 27
- 238000000498 ball milling Methods 0.000 claims description 26
- 239000000463 material Substances 0.000 claims description 18
- 229920000609 methyl cellulose Polymers 0.000 claims description 14
- 239000001923 methylcellulose Substances 0.000 claims description 14
- 238000001816 cooling Methods 0.000 claims description 9
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims description 8
- -1 By frit Substances 0.000 claims description 7
- 238000001914 filtration Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 239000002689 soil Substances 0.000 claims description 4
- 241000790917 Dioxys <bee> Species 0.000 claims description 2
- 229910003978 SiClx Inorganic materials 0.000 claims description 2
- 238000000227 grinding Methods 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 238000003756 stirring Methods 0.000 claims 1
- 230000008961 swelling Effects 0.000 claims 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims 1
- 239000000919 ceramic Substances 0.000 abstract description 24
- 230000000694 effects Effects 0.000 abstract description 16
- 238000000034 method Methods 0.000 abstract description 7
- 239000003086 colorant Substances 0.000 abstract description 5
- NOTVAPJNGZMVSD-UHFFFAOYSA-N potassium oxide Chemical compound [K]O[K] NOTVAPJNGZMVSD-UHFFFAOYSA-N 0.000 abstract 1
- 238000010304 firing Methods 0.000 description 8
- 210000003298 dental enamel Anatomy 0.000 description 4
- 239000003973 paint Substances 0.000 description 4
- 230000008859 change Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 229910010293 ceramic material Inorganic materials 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 229910052573 porcelain Inorganic materials 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 210000003462 vein Anatomy 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000001458 anti-acid effect Effects 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000002241 glass-ceramic Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/04—Opacifiers, e.g. fluorides or phosphates; Pigments
- C03C1/06—Opacifiers, e.g. fluorides or phosphates; Pigments to produce non-uniformly pigmented, e.g. speckled, marbled, or veined products
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Ceramic Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Inorganic Chemistry (AREA)
- Structural Engineering (AREA)
- Vascular Medicine (AREA)
- Health & Medical Sciences (AREA)
- Glass Compositions (AREA)
Abstract
A kind of yellow bottom white point-like line high temperature crystallization glaze and preparation method thereof, belongs to ceramic field.The yellow bottom white point-like line high temperature crystallization glaze, it is first to prepare yellow bottom white point-like line high temperature crystallization glaze, again by yellow bottom white point-like line high temperature crystallization glaze made from glazing, high temperature sintering, wherein, the raw material and the mass percent of each raw material that yellow bottom white point-like line high temperature crystallization glaze includes are：Frit 33%~43%, calcining zinc oxide 23%~33%, silica 1 3%~23%, kaolin 1%~5%, titanium dioxide 2%~8%, bentonite 1%~4% and tin oxide 4%~8%；Described frit, comprising raw material and its mass percent of each raw material be：Potassium oxide 1%~3%, sodium oxide molybdena 10%~20%, calcium oxide 4%~10%, diboron trioxide 1%~5% and silica 65~75%.This method causes occur white point-like crystallization on yellow ceramics glaze colours, and crystallization is evenly distributed, and has special artistic effect.
Description
Technical field
The present invention relates to ceramic technology field, and in particular to a kind of yellow bottom white point-like line high temperature crystallization glaze and its preparation side
Method.
Background technology
Ceramic glaze is a kind of important source material that must be used during ceramic making production, has very strong protection to the base substrate of ceramics
Effect, while the physical characteristic of silicate allows the corrosion of the effective antiacid alkali of the glass enamel of ceramic surface, has very well
Antibiotic property.Common ceramic colour glaze is by adding metallochrome in glass enamel, reaching and reach during firing
The effect of color development, often color is single for such glaze colours, it is impossible to the aesthetic and high-temperature firing mistake of prominent ceramic colour glaze itself
Caused special artistic effect in journey.Yellow bottom white point-like line high temperature crystallization glaze effectively overcomes ceramic glaze in color quality list
The deficiency of one side, mineral raw material is produced into special crystallization mechanism effect through high-temperature firing and combined with ceramic material, is reached
Very natural art veins effect, there is high aesthetic to be worth.The formula causes occur on yellow ceramics glaze colours
White point-like crystallization, crystallization are evenly distributed, and have special artistic effect.The glaze formula, pass through multiple prolonged reality
Test, overcome many technical difficulties, make yellow bottom white point-like line high temperature crystallization ceramic glaze crystallization effect obvious, ceramic glaze
Can be stable, wall brick, ceramics furnishing fields of the glaze outside architecture indoor have high actual application value.
The content of the invention
It is an object of the invention to provide a kind of yellow bottom white point-like line high temperature crystallization glaze and preparation method thereof, effectively overcome
Deficiency of the ceramic glaze at the single aspect of color quality, mineral raw material is produced into special crystallization mechanism effect through high-temperature firing
Combined with ceramic material, reached very natural art veins effect, there is high aesthetic to be worth.The formula causes
Occurs white point-like crystallization on yellow ceramics glaze colours, crystallization is evenly distributed, and has special artistic effect.The glaze formula have passed through
Prolonged adjustment and multiple experiment, Ceramic glaze surface produces smooth effect, while reaches physics and the change of ceramic glaze
Learn the stabilization of performance.
Present invention employs following technical scheme：
A kind of yellow bottom white point-like line high temperature crystallization glaze of the present invention, is first to prepare yellow bottom white point-like line high temperature crystallization glaze
Material, then by yellow bottom white point-like line high temperature crystallization glaze made from glazing, high temperature sintering, wherein, yellow bottom white point-like line high temperature
The raw material and the mass percent of each raw material that crystalline glaze material includes be：
Frit 33%~43%, calcining zinc oxide 23%~33%, silica 1 3%~23%, kaolin 1%~
5%th, titanium dioxide 2%~8%, bentonite 1%~4% and tin oxide 4%~8%；
Described frit, comprising raw material and its mass percent of each raw material be：
Potassium oxide 1%~3%, sodium oxide molybdena 10%~20%, calcium oxide 4%~10%, the and of diboron trioxide 1%~5%
Silica 65~75%.
Described yellow bottom white point-like line high temperature crystallization glaze, can also include methylcellulose, the matter of methylcellulose
Amount accounts for the quality percentage of (frit+calcining zinc oxide+silica+kaolin+titanium dioxide+bentonite+tin oxide) gross mass
Than≤3%.Preferably 1%~3%.
The purpose that methylcellulose is added in the yellow bottom white point-like line high temperature crystallization glaze is, improves raw material in glaze
Suspension degree, can effectively increase the viscosity of glaze, make glaze firmly, uniformly, be stably adhered to billet surface, improve pottery
The brightness of enamel and the uniformity.
Preferably, the matter of described yellow bottom white point-like line high temperature crystallization glaze, its raw material included and each raw material
Measuring percentage is：
Frit 38.7%, calcining zinc oxide 29.3%, silica 1 8.5%, kaolin 3.5%, titanium dioxide 4.7%,
Bentonite 1% and tin oxide 4.3%.
Preferably, described frit, comprising raw material and its mass percent of each raw material be：
Potassium oxide 1.8%, sodium oxide molybdena 15.9%, calcium oxide 7%, diboron trioxide 2% and silica 73.3%.
A kind of preparation method of yellow bottom white point-like line high temperature crystallization glaze of the present invention, comprises the following steps：First prepare Huang
Bottom white point-like line high temperature crystallization glaze, yellow bottom white point-like line high temperature crystallization glaze is made by glazing, sintering；Wherein, yellow bottom
The preparation method of white point-like line high temperature crystallization glaze is as follows：
Step 1, the preparation of frit
Dispensing is carried out according to the raw material of frit and the mass percent of each raw material, raw material is well mixed, is heated to 760
~800 DEG C, 20~40min is fired, glassy mass is melt into, water cooling, obtains frit；
Step 2, the preparation of yellow bottom white point-like line high temperature crystallization glaze
(1) matched somebody with somebody according to the raw material of yellow bottom white point-like line high temperature crystallization glaze and its mass percent of each raw material
Material, by frit, silica, kaolin, titanium dioxide, bentonite, water is added, after mixing, is added in ball mill, ball mill
Rotating speed is 450~550rpm, 4~4.5h of Ball-milling Time, filtering, removes the debris not refined；Wherein, in mass ratio, water：It is (molten
Block+silica+kaolin+titanium dioxide+bentonite)=(1~1.2):1；
(2) into ball mill, remaining raw material is added, continues ball milling, 450~550rpm of rotating speed, Ball-milling Time 0.5
~1h, yellow bottom white point-like line high temperature crystallization glaze is made.
In described step 1, the raw material of described frit is put into crucible, and heating firing is carried out with naked light.
In described step 1, frit is made on a small scale, using crucible water cooling；It is extensive to make frit, using kiln water
It is cold.Volatile matter in raw material and effective decomposition gas can effectively be excluded using the method for making frit and burn till glaze paint so as to reduce and rise
Bubble.
In described step 2, described water is pure water；Described ball mill is Quick ball grinder.
In described step 2 (1), described filtering is filtered using 400 mesh sieve, and after filtering, the particle diameter of raw material is
400~450 mesh.
In described step 2 (2), described remaining raw material is tin oxide and calcining zinc oxide.
Preferably, the ball milling parameter of described ball mill is：By frit, silica, kaolin, titanium dioxide, swollen
Profit soil, adds water for ball milling, rotating speed is preferably 450rpm, and the time is preferably 4~4.5h；After adding remaining raw material, rotating speed is preferred
For 450rpm, the time is preferably 1h.
The preparation method of described yellow bottom white point-like line high temperature crystallization glaze, by the preparation of frit in step 1, step
In 2 after the preparation of yellow bottom white point-like line high temperature crystallization glaze, by obtained yellow bottom white point-like line high temperature crystallization glaze
Methylcellulose is added in material, is stirred, the yellow bottom white point-like line high temperature crystallization glaze containing methylcellulose is made.
A kind of yellow bottom white point-like line high temperature crystallization glaze of the present invention and preparation method thereof, compared with prior art, has
Following beneficial effect：Yellow bottom white point-like line high temperature crystallization glaze, the ceramic glaze colours have distinctive ceramic glaze artistic effect,
The Ceramic glaze of yellow, which floats, reveals white point-like texture.The yellow bottom white point-like line high temperature crystallization glaze has good physical,
The long period of experiments under -30 DEG C of temperature conditionss, do not occur glaze paint crackle or obscission.The yellow bottom white point-like line high temperature knot
Brilliant glaze stable chemical performance, can be resistant to common acid and alkali corrosion, and except hydrofluoric acid, widely used, the heavy metal such as not leaded, arsenic is green
Colour circle is protected.
It is more complicated in the technique of glaze due to having used the making of frit, but be the reduction of due to the gas in raw material
Caused by glaze paint burn till after there is pin hole and phenomenon that low temperature glaze emaciated face falls.Calcining zinc oxide and metal tin oxide are in saturation state
Metal excess crystalline polamer can occur in lower fired by oxidizing flame so that ceramic surface shows the special of white round point shape
Effect.Kaolin and silica so that glass-ceramic glaze phase surface physics and chemical property are stable, fire success rate height, both
It is adapted to the art pottery to prepare a small amount of glaze, is adapted to a large amount of process scale productions of large size ceramic manufacturing enterprise again.
The yellow bottom white point-like line high temperature crystallization glaze enamel of the present invention, dioxide-containing silica is big in the glaze, so firing and
Into frit glass glossiness it is high, permeability is good.
The preparation method of the yellow bottom white point-like line high temperature crystallization glaze of the present invention, has advantages below：
It is to have made the frit with formula first, the proportioning of the frit effectively arranges the gas in oxidation and impurity
Going out, there is the phenomenon generation of pin hole and peeling in glaze paint after preventing ceramic firing, while to preventing bubble occurs in the surface of glaze from playing
Crucial effect.The making of the frit, zinc oxide has been effectively promoted it and has been crystallized during high-temperature firing process and insulation, produced
Round point shape crystallization artistic effect has been given birth to, there is very high aesthetic to be worth.
Secondly, in preparation method, it have adjusted the Ball-milling Time order of raw material；First ball milling frit, silica, kaolin,
Metal oxide, this method such as titanium dioxide, bentonite, rear ball milling calcining zinc oxide and tin oxide are effectively guaranteed the formula
Color development stability, be the program of whole preparation technology key.
Finally, the time length of ball milling, it ensure that glaze can be fine to 400~450 mesh, after being mixed with water, Ke Yigen
According to needs, selection sprays to porcelain billet surface or glazing operator is stained with glaze to porcelain billet surface.
Embodiment
With reference to embodiment, the present invention is described in further detail.
Embodiment 1
A kind of yellow bottom white point-like line high temperature crystallization glaze, it is first to prepare yellow bottom white point-like line high temperature crystallization glaze, then passes through
Cross glazing, yellow bottom white point-like line high temperature crystallization glaze made from high temperature sintering, wherein, yellow bottom white point-like line high temperature crystallization glaze
Comprising raw material and the mass percent of each raw material be：
Frit 38.7%, calcining zinc oxide 29.3%, silica 1 8.5%, kaolin 3.5%, titanium dioxide 4.7%,
Bentonite 1% and tin oxide 4.3%.
Described frit, comprising raw material and its mass percent of each raw material be：
Potassium oxide 1.8%, sodium oxide molybdena 15.9%, calcium oxide 7%, diboron trioxide 2% and silica 73.3%.
A kind of preparation method of yellow bottom white point-like line high temperature crystallization glaze, comprises the following steps：First prepare yellow bottom white point
Shape line high temperature crystallization glaze, yellow bottom white point-like line high temperature crystallization glaze is made by glazing, sintering；Wherein, yellow bottom white point-like
The preparation method of line high temperature crystallization glaze is as follows：
Step 1, the preparation of frit
Dispensing is carried out according to the raw material of frit and the mass percent of each raw material, raw material is well mixed, is heated to 760
DEG C, 30min is fired, glassy mass is melt into, water cooling, obtains frit；
Step 2, the preparation of yellow bottom white point-like line high temperature crystallization glaze
(1) matched somebody with somebody according to the raw material of yellow bottom white point-like line high temperature crystallization glaze and its mass percent of each raw material
Material, by frit, silica, kaolin, titanium dioxide, bentonite, water is added, after mixing, is added in Quick ball grinder, ball
Mill speed is 450rpm, Ball-milling Time 4.5h, is filtered with 400 mesh sieve, removes the debris not refined, obtains particle diameter as 400
The leftover materials of~450 mesh, leftover materials are continued to be put into Quick ball grinder；Wherein, in mass ratio, water：(frit+dioxy
SiClx+kaolin+titanium dioxide+bentonite)=1:1；
(2) remaining tin oxide and calcining zinc oxide are added into Quick ball grinder, continues ball milling, rotating speed 450rpm,
Ball-milling Time is 1h, and yellow bottom white point-like line high temperature crystallization glaze is made.
Embodiment 2
A kind of yellow bottom white point-like line high temperature crystallization glaze, it is first to prepare yellow bottom white point-like line high temperature crystallization glaze, then passes through
Cross glazing, yellow bottom white point-like line high temperature crystallization glaze made from high temperature sintering, wherein, yellow bottom white point-like line high temperature crystallization glaze
Comprising raw material and the mass percent of each raw material be：
Frit 33%, calcining zinc oxide 29%, silica 1 3%, kaolin 5%, titanium dioxide 8%, bentonite 4%
With tin oxide 8%；
Described frit, comprising raw material and its mass percent of each raw material be：
Potassium oxide 1%, sodium oxide molybdena 19%, calcium oxide 4%, diboron trioxide 1% and silica 75%.
A kind of preparation method of yellow bottom white point-like line high temperature crystallization glaze, comprises the following steps：First prepare yellow bottom white point
Shape line high temperature crystallization glaze, yellow bottom white point-like line high temperature crystallization glaze is made by glazing, sintering；Wherein, yellow bottom white point-like
The preparation method of line high temperature crystallization glaze is as follows：
Step 1, the preparation of frit
Dispensing is carried out according to the raw material of frit and the mass percent of each raw material, raw material is well mixed, is heated to 800
DEG C, 20min is fired, glassy mass is melt into, water cooling, obtains frit；
Step 2, the preparation of yellow bottom white point-like line high temperature crystallization glaze
(1) matched somebody with somebody according to the raw material of yellow bottom white point-like line high temperature crystallization glaze and its mass percent of each raw material
Material, by frit, silica, kaolin, titanium dioxide, bentonite, water is added, after mixing, is added in Quick ball grinder, ball
Mill speed is 550rpm, Ball-milling Time 4h, is filtered with 400 mesh sieve, removes the debris not refined, obtain particle diameter for 400~
The leftover materials of 450 mesh, leftover materials are continued to be put into Quick ball grinder；Wherein, in mass ratio, water：(frit+titanium dioxide
Silicon+kaolin+titanium dioxide+bentonite)=1.2:1；
(2) remaining tin oxide and calcining zinc oxide are added into Quick ball grinder, continues ball milling, rotating speed 550rpm,
Ball-milling Time is 0.5h, and yellow bottom white point-like line high temperature crystallization glaze is made.
(3) methylcellulose is added in obtained yellow bottom white point-like line high temperature crystallization glaze, stirred, be made and contain
The yellow bottom white point-like line high temperature crystallization glaze of methylcellulose.Wherein, in mass ratio, methylcellulose：(frit+calcining oxygen
Change zinc+silica+kaolin+titanium dioxide+bentonite+tin oxide)=2:100.
Embodiment 3
A kind of yellow bottom white point-like line high temperature crystallization glaze, it is first to prepare yellow bottom white point-like line high temperature crystallization glaze, then passes through
Cross glazing, yellow bottom white point-like line high temperature crystallization glaze made from high temperature sintering, wherein, yellow bottom white point-like line high temperature crystallization glaze
Comprising raw material and the mass percent of each raw material be：
Frit 43%, calcining zinc oxide 23%, silica 23%, kaolin 4%, titanium dioxide 2%, bentonite 1%
With tin oxide 4%；
Described frit, comprising raw material and its mass percent of each raw material be：
Potassium oxide 3%, sodium oxide molybdena 10%, calcium oxide 10%, diboron trioxide 5% and silica 72%.
A kind of preparation method of yellow bottom white point-like line high temperature crystallization glaze, comprises the following steps：First prepare yellow bottom white point
Shape line high temperature crystallization glaze, yellow bottom white point-like line high temperature crystallization glaze is made by glazing, sintering；Wherein, yellow bottom white point-like
The preparation method of line high temperature crystallization glaze is as follows：
Step 1, the preparation of frit
Dispensing is carried out according to the raw material of frit and the mass percent of each raw material, raw material is well mixed, is heated to 780
DEG C, 30min is fired, glassy mass is melt into, water cooling, obtains frit；
Step 2, the preparation of yellow bottom white point-like line high temperature crystallization glaze
(1) matched somebody with somebody according to the raw material of yellow bottom white point-like line high temperature crystallization glaze and its mass percent of each raw material
Material, by frit, silica, kaolin, titanium dioxide, bentonite, water is added, after mixing, is added in ball mill, ball mill
Rotating speed is 450rpm, Ball-milling Time 4h, is filtered with 400 mesh sieve, removes the debris not refined, it is 400~450 mesh to obtain particle diameter
Leftover materials, leftover materials are continued to be put into ball mill；Wherein, in mass ratio, water：(frit+silica+kaolin+
Titanium dioxide+bentonite)=1:1；
(2) into ball mill, remaining tin oxide and calcining zinc oxide are added, continues ball milling, rotating speed 450rpm, ball milling
Time is 1h, and yellow bottom white point-like line high temperature crystallization glaze is made.
(3) methylcellulose is added in obtained yellow bottom white point-like line high temperature crystallization glaze, stirred, be made and contain
The yellow bottom white point-like line high temperature crystallization glaze of methylcellulose.Wherein, in mass ratio, methylcellulose：(frit+calcining oxygen
Change zinc+silica+kaolin+titanium dioxide+bentonite+tin oxide)=3:100.
Embodiment 4
A kind of yellow bottom white point-like line high temperature crystallization glaze, it is first to prepare yellow bottom white point-like line high temperature crystallization glaze, then passes through
Cross glazing, yellow bottom white point-like line high temperature crystallization glaze made from high temperature sintering, wherein, yellow bottom white point-like line high temperature crystallization glaze
Comprising raw material and the mass percent of each raw material be：
Frit 32%, calcining zinc oxide 33%, silica 23%, kaolin 1%, titanium dioxide 5%, bentonite 2%
With tin oxide 4%；
Described frit, comprising raw material and its mass percent of each raw material be：
Potassium oxide 2%, sodium oxide molybdena 20%, calcium oxide 10%, diboron trioxide 3% and silica 65%.
A kind of preparation method of yellow bottom white point-like line high temperature crystallization glaze, comprises the following steps：First prepare yellow bottom white point
Shape line high temperature crystallization glaze, yellow bottom white point-like line high temperature crystallization glaze is made by glazing, sintering；Wherein, yellow bottom white point-like
The preparation method of line high temperature crystallization glaze is as follows：
Step 1, the preparation of frit
Dispensing is carried out according to the raw material of frit and the mass percent of each raw material, raw material is well mixed, is heated to 760
DEG C, 30min is fired, glassy mass is melt into, water cooling, obtains frit；
Step 2, the preparation of yellow bottom white point-like line high temperature crystallization glaze
(1) matched somebody with somebody according to the raw material of yellow bottom white point-like line high temperature crystallization glaze and its mass percent of each raw material
Material, by frit, silica, kaolin, titanium dioxide, bentonite, water is added, after mixing, is added in ball mill, ball mill
Rotating speed is 450rpm, Ball-milling Time 4h, is filtered with 400 mesh sieve, removes the debris not refined, it is 400~450 mesh to obtain particle diameter
Leftover materials, leftover materials are continued to be put into Quick ball grinder；Wherein, in mass ratio, water：(frit+silica+height
Ridge soil+titanium dioxide+bentonite)=1.1:1；
(2) into ball mill, remaining tin oxide and calcining zinc oxide are added, continues ball milling, rotating speed 450rpm, ball milling
Time is 0.5h, and yellow bottom white point-like line high temperature crystallization glaze is made.
Claims (10)
1. a kind of yellow bottom white point-like line high temperature crystallization glaze, being first to prepare yellow bottom white point-like line high temperature crystallization glaze, then pass through
Yellow bottom white point-like line high temperature crystallization glaze made from glazing, high temperature sintering, it is characterised in that described yellow bottom white point-like line is high
The raw material and the mass percent of each raw material that warm crystalline glaze material includes be：
Frit 33%~43%, calcining zinc oxide 23%~33%, silica 1 3%~23%, kaolin 1%~5%, two
Titanium oxide 2%~8%, bentonite 1%~4% and tin oxide 4%~8%；
Described frit, comprising raw material and its mass percent of each raw material be：
Potassium oxide 1%~3%, sodium oxide molybdena 10%~20%, calcium oxide 4%~10%, diboron trioxide 1%~5% and dioxy
SiClx 65~75%.
2. yellow bottom white point-like line high temperature crystallization glaze as claimed in claim 1, it is characterised in that described yellow bottom white point-like
Line high temperature crystallization glaze, comprising methylcellulose, the quality of methylcellulose accounts for (frit+calcining zinc oxide+silica+height
Ridge soil+titanium dioxide+bentonite+tin oxide) gross mass mass percent≤3%.
3. yellow bottom white point-like line high temperature crystallization glaze as claimed in claim 1, it is characterised in that described yellow bottom white point-like
The mass percent of line high temperature crystallization glaze, its raw material included and each raw material is：
Frit 38.7%, calcining zinc oxide 29.3%, silica 1 8.5%, kaolin 3.5%, titanium dioxide 4.7%, swelling
Soil 1% and tin oxide 4.3%.
4. yellow bottom white point-like line high temperature crystallization glaze as claimed in claim 1, it is characterised in that described frit, comprising
The mass percent of raw material and its each raw material is：
Potassium oxide 1.8%, sodium oxide molybdena 15.9%, calcium oxide 7%, diboron trioxide 2% and silica 73.3%.
5. the preparation method of the yellow bottom white point-like line high temperature crystallization glaze in claim 1 or 3 described in any one, including it is following
Step：Yellow bottom white point-like line high temperature crystallization glaze is first prepared, yellow bottom white point-like line high temperature crystallization is made by glazing, sintering
Glaze；Characterized in that, the preparation method of described yellow bottom white point-like line high temperature crystallization glaze is as follows：
Step 1, the preparation of frit
Dispensing is carried out according to the raw material of frit and the mass percent of each raw material, raw material is well mixed, it is heated to 760~
800 DEG C, 20~40min is fired, glassy mass is melt into, water cooling, obtains frit；
Step 2, the preparation of yellow bottom white point-like line high temperature crystallization glaze
(1) dispensing is carried out according to the raw material of yellow bottom white point-like line high temperature crystallization glaze and its mass percent of each raw material,
By frit, silica, kaolin, titanium dioxide, bentonite, water is added, after mixing, is added in ball mill, ball mill turns
Speed is 450~550rpm, 4~4.5h of Ball-milling Time, filtering, removes the debris not refined；Wherein, in mass ratio, water：(frit+
Silica+kaolin+titanium dioxide+bentonite)=(1~1.2):1；
(2) into ball mill, adding remaining raw material, continue ball milling, 450~550rpm of rotating speed, Ball-milling Time is 0.5~
1h, yellow bottom white point-like line high temperature crystallization glaze is made.
6. the preparation method of yellow bottom white point-like line high temperature crystallization glaze as claimed in claim 5, it is characterised in that described step
In rapid 1, frit is made on a small scale, using crucible water cooling；It is extensive to make frit, using kiln water cooling.
7. the preparation method of yellow bottom white point-like line high temperature crystallization glaze as claimed in claim 5, it is characterised in that described step
In rapid 2 (1), described filtering is filtered using 400 mesh sieve, and after filtering, the particle diameter of raw material is 400~450 mesh.
8. the preparation method of yellow bottom white point-like line high temperature crystallization glaze as claimed in claim 5, it is characterised in that described step
In rapid 2 (2), described remaining raw material is tin oxide and calcining zinc oxide.
9. the preparation method of yellow bottom white point-like line high temperature crystallization glaze as claimed in claim 5, it is characterised in that described ball
The ball milling parameter of grinding machine is：By frit, silica, kaolin, titanium dioxide, bentonite, water for ball milling is added, rotating speed is
450rpm, time are 4~4.5h；After adding remaining raw material, rotating speed 450rpm, time 1h.
10. the preparation method of yellow bottom white point-like line high temperature crystallization glaze as claimed in claim 5, it is characterised in that described
The preparation method of yellow bottom white point-like line high temperature crystallization glaze, by the preparation of frit in step 1, yellow bottom white point in step 2
After the preparation of shape line high temperature crystallization glaze, fine by adding methyl in obtained yellow bottom white point-like line high temperature crystallization glaze
Dimension element, stirs, and the yellow bottom white point-like line high temperature crystallization glaze containing methylcellulose is made.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110818265A (en) * | 2019-11-26 | 2020-02-21 | 曹云 | Ultra-low temperature polycrystal inorganic crystallization glaze and preparation process and application thereof |
| CN114403564A (en) * | 2022-01-14 | 2022-04-29 | 广东顺德周大福珠宝制造有限公司 | Jewelry and surface treatment method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101209930A (en) * | 2006-12-30 | 2008-07-02 | 陈东明 | Luminous ceramic and preparing process thereof |
| WO2011057730A1 (en) * | 2009-11-13 | 2011-05-19 | Vidres S.A. | Composition and process for obtaining materials for coating ceramic bodies and the articles thus obtained |
| CN104355680A (en) * | 2014-11-25 | 2015-02-18 | 福建省佳美集团公司 | Surface glaze of lead-free tableware ceramic and preparation method of glaze |
-
2017
- 2017-10-13 CN CN201710953067.0A patent/CN107698162B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101209930A (en) * | 2006-12-30 | 2008-07-02 | 陈东明 | Luminous ceramic and preparing process thereof |
| WO2011057730A1 (en) * | 2009-11-13 | 2011-05-19 | Vidres S.A. | Composition and process for obtaining materials for coating ceramic bodies and the articles thus obtained |
| CN104355680A (en) * | 2014-11-25 | 2015-02-18 | 福建省佳美集团公司 | Surface glaze of lead-free tableware ceramic and preparation method of glaze |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110818265A (en) * | 2019-11-26 | 2020-02-21 | 曹云 | Ultra-low temperature polycrystal inorganic crystallization glaze and preparation process and application thereof |
| CN110818265B (en) * | 2019-11-26 | 2022-02-15 | 曹云 | Ultra-low temperature polycrystal inorganic crystallization glaze and preparation process and application thereof |
| CN114403564A (en) * | 2022-01-14 | 2022-04-29 | 广东顺德周大福珠宝制造有限公司 | Jewelry and surface treatment method thereof |
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