CN107619191A - A kind of green bottom silver strip line high temperature crystallization glaze and preparation method thereof - Google Patents
A kind of green bottom silver strip line high temperature crystallization glaze and preparation method thereof Download PDFInfo
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- CN107619191A CN107619191A CN201710953055.8A CN201710953055A CN107619191A CN 107619191 A CN107619191 A CN 107619191A CN 201710953055 A CN201710953055 A CN 201710953055A CN 107619191 A CN107619191 A CN 107619191A
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- high temperature
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- line high
- silver strip
- temperature crystallization
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- BQCADISMDOOEFD-UHFFFAOYSA-N silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 title claims abstract description 110
- 229910052709 silver Inorganic materials 0.000 title claims abstract description 110
- 239000004332 silver Substances 0.000 title claims abstract description 110
- 238000002425 crystallisation Methods 0.000 title claims abstract description 106
- 230000005712 crystallization Effects 0.000 title claims abstract description 106
- 238000002360 preparation method Methods 0.000 title claims abstract description 44
- 239000002994 raw material Substances 0.000 claims abstract description 81
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 70
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 55
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 43
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 35
- PZZYQPZGQPZBDN-UHFFFAOYSA-N Aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 28
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 28
- 241000276489 Merlangius merlangus Species 0.000 claims abstract description 27
- HWKQNAWCHQMZHK-UHFFFAOYSA-N Trolnitrate Chemical compound [O-][N+](=O)OCCN(CCO[N+]([O-])=O)CCO[N+]([O-])=O HWKQNAWCHQMZHK-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000000440 bentonite Substances 0.000 claims abstract description 27
- 229910000278 bentonite Inorganic materials 0.000 claims abstract description 27
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 27
- 239000011787 zinc oxide Substances 0.000 claims abstract description 22
- 238000001354 calcination Methods 0.000 claims abstract description 21
- GEZOTWYUIKXWOA-UHFFFAOYSA-L copper;carbonate Chemical compound [Cu+2].[O-]C([O-])=O GEZOTWYUIKXWOA-UHFFFAOYSA-L 0.000 claims abstract description 21
- 229940116318 copper carbonate Drugs 0.000 claims abstract description 20
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N Boron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims abstract description 18
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium monoxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 18
- 238000005245 sintering Methods 0.000 claims abstract description 13
- NOTVAPJNGZMVSD-UHFFFAOYSA-N Potassium oxide Chemical compound [K]O[K] NOTVAPJNGZMVSD-UHFFFAOYSA-N 0.000 claims abstract description 9
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000292 calcium oxide Substances 0.000 claims abstract description 9
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910001950 potassium oxide Inorganic materials 0.000 claims abstract description 9
- 229910001948 sodium oxide Inorganic materials 0.000 claims abstract description 9
- 238000000498 ball milling Methods 0.000 claims description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- 239000000463 material Substances 0.000 claims description 19
- 238000010304 firing Methods 0.000 claims description 14
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2R,3R,4S,5R,6S)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2S,3R,4S,5R,6R)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2R,3R,4S,5R,6R)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 claims description 11
- 229920000609 methyl cellulose Polymers 0.000 claims description 11
- 239000001923 methylcellulose Substances 0.000 claims description 11
- 238000001816 cooling Methods 0.000 claims description 9
- -1 By frit Substances 0.000 claims description 8
- 238000001914 filtration Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 5
- 241000790917 Dioxys <bee> Species 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N TiO Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims 1
- VDGJOQCBCPGFFD-UHFFFAOYSA-N [Si+4].[O-2].[O-2].[Ti+4] Chemical compound [Si+4].[O-2].[O-2].[Ti+4] VDGJOQCBCPGFFD-UHFFFAOYSA-N 0.000 claims 1
- 239000000843 powder Substances 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 229910001929 titanium oxide Inorganic materials 0.000 claims 1
- 239000000919 ceramic Substances 0.000 abstract description 26
- 230000000694 effects Effects 0.000 abstract description 16
- 210000003298 Dental Enamel Anatomy 0.000 abstract description 6
- 239000003973 paint Substances 0.000 abstract description 6
- 235000021190 leftovers Nutrition 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 4
- 239000002585 base Substances 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 241000412565 Argentina sphyraena Species 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N HF Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- 235000016594 Potentilla anserina Nutrition 0.000 description 2
- 229910003978 SiClx Inorganic materials 0.000 description 2
- 210000003462 Veins Anatomy 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 229910010293 ceramic material Inorganic materials 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 229910052573 porcelain Inorganic materials 0.000 description 2
- 230000002035 prolonged Effects 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 206010011376 Crepitations Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000001458 anti-acid Effects 0.000 description 1
- 230000003115 biocidal Effects 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 239000002241 glass-ceramic Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052622 kaolinite Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N silicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Abstract
A kind of green bottom silver strip line high temperature crystallization glaze and preparation method thereof, belongs to ceramic field.The green bottom silver strip line high temperature crystallization glaze, it is first to prepare green bottom silver strip line high temperature crystallization glaze, then is made by glazing, high temperature sintering.The raw material and the mass percent of each raw material that green bottom silver strip line high temperature crystallization glaze includes be：Frit 33%~43%, calcining zinc oxide 23%~33%, silica 1 3%~23%, kaolin 1%~5%, titanium dioxide 2%~8%, bentonite 1%~4%, whiting 1%~6%, copper carbonate 1%~5%.The raw material and the mass percent of each raw material that frit includes be：Potassium oxide 1%~3%, sodium oxide molybdena 10%~20%, calcium oxide 4%~10%, diboron trioxide 1%~5%, silica 65~75%.This method allows ceramic enamel to produce silver color flaky crystal in green ceramic glaze paint is produced, and crystallization is evenly distributed, and has special artistic effect.
Description
Technical field
The present invention relates to ceramic technology field, and in particular to a kind of green bottom silver strip line high temperature crystallization glaze and preparation method thereof.
Background technology
Ceramic glaze is a kind of important source material that must be used during ceramic making production, has very strong protection to the base substrate of ceramics
Effect, while the physical characteristic of silicate allows the corrosion of the effective antiacid alkali of the glass enamel of ceramic surface, has very well
Antibiotic property.Common ceramic colour glaze is by adding metallochrome in glass enamel, reaching and reach during firing
The effect of color development, often color is single for such glaze colours, it is impossible to the aesthetic and high-temperature firing mistake of prominent ceramic colour glaze itself
Caused special artistic effect in journey.Green bottom silver strip line high temperature crystallization glaze effectively overcomes ceramic glaze in the single side of color quality
The deficiency in face, mineral raw material is produced into special crystallization mechanism effect through high-temperature firing and combined with ceramic material, has reached ten
Divide natural art veins effect, there is high aesthetic to be worth.The formula causes silver color occur on green ceramic glaze colours
Flaky crystal, crystallization are evenly distributed, and have special artistic effect.The glaze formula, by multiple prolonged experiment, gram
Many technical difficulties have been taken, have made green silver strip line high temperature crystallization ceramic glaze crystallization effect obvious, ceramic glaze stable performance should
Wall brick, ceramics furnishing fields of the glaze outside architecture indoor have high actual application value.
The content of the invention
It is an object of the invention to provide a kind of green bottom silver strip line high temperature crystallization glaze and preparation method thereof, pottery is effectively overcome
Mineral raw material is produced special crystallization mechanism effect and pottery in the deficiency of the single aspect of color quality by enamel through high-temperature firing
Ceramic material combines, and has reached very natural art veins effect, and there is high aesthetic to be worth.The technology to be solved is asked
Topic is to allow ceramic enamel to produce silver color flaky crystal in green ceramic glaze paint is produced, and crystallization is evenly distributed, and has special skill
Art effect.The glaze formula have passed through prolonged adjustment and multiple experiment, and Ceramic glaze surface produces smooth effect, simultaneously
Reach the stabilization of the physical and chemical properties of ceramic glaze.
Present invention employs following technical scheme：
A kind of green bottom silver strip line high temperature crystallization glaze, it is first to prepare green bottom silver strip line high temperature crystallization glaze, then by glazing, height
Green bottom silver strip line high temperature crystallization glaze made from temperature sintering, wherein, raw material that green bottom silver strip line high temperature crystallization glaze includes and each
The mass percent of raw material is：
Frit 33%~43%, calcining zinc oxide 23%~33%, silica 1 3%~23%, kaolin 1%~
5%th, titanium dioxide 2%~8%, bentonite 1%~4%, whiting 1%~6%, copper carbonate 1%~5%.
The mass percent of described frit, its raw material included and each raw material is：
Potassium oxide 1%~3%, sodium oxide molybdena 10%~20%, calcium oxide 4%~10%, diboron trioxide 1%~5%, two
Silica 65~75%.
Preferably, the quality hundred of described green bottom silver strip line high temperature crystallization glaze, its raw material included and each raw material
Point ratio is：
Frit 38%, calcining zinc oxide 28%, silica 1 8%, kaolin 3%, titanium dioxide 5%, bentonite 1%,
Whiting 4%, copper carbonate 3%.
Preferably, raw material and the mass percent of each raw material that described frit includes are：
Potassium oxide 1.8%, sodium oxide molybdena 15.9%, calcium oxide 7%, diboron trioxide 2%, silica 73.3%.
Described green bottom silver strip line high temperature crystallization glaze, can also include methylcellulose, and the quality of methylcellulose accounts for
The quality hundred of (frit+calcining zinc oxide+silica+kaolin+titanium dioxide+bentonite+whiting+copper carbonate) gross mass
Divide ratio≤3%.Preferably 1%~3%.
The purpose that methylcellulose is added in the green bottom silver strip line high temperature crystallization glaze is that raw material is outstanding in raising glaze
Floating degree, can effectively increase the viscosity of glaze, make glaze firmly, uniformly, be stably adhered to billet surface, improve ceramic glaze
Brightness and the uniformity.
A kind of preparation method of green bottom silver strip line high temperature crystallization glaze of the present invention, comprises the following steps：First prepare green bottom silver
Piece line high temperature crystallization glaze, green bottom silver strip line high temperature crystallization glaze is made by glazing, sintering；Wherein, green bottom silver strip line high temperature knot
The preparation method of brilliant glaze is as follows：
Step 1, the preparation of frit
Dispensing is carried out according to the raw material included of frit and the mass percent of each raw material, frit raw material is heated to
760~800 DEG C, after firing 20~40min, glassy mass is melt into, water cooling, frit is made.
Step 2, the preparation of green bottom silver strip line high temperature crystallization glaze
(1) matched somebody with somebody according to the raw material included of green bottom silver strip line high temperature crystallization glaze and the mass percent of each raw material
Material, by frit, silica, kaolin, titanium dioxide, bentonite, whiting, water is added, after mixing, is added to ball mill
Interior, drum's speed of rotation is 450~550rpm, 4~4.5h of Ball-milling Time, filtering, removes the debris not refined；Wherein, by quality
Than water：(frit+silica+kaolin+titanium dioxide+bentonite+whiting)=(1~1.2):1；
(2) into ball mill, remaining raw material is added, continues ball milling, 450~550rpm of rotating speed, Ball-milling Time 0.5
~1h, green bottom silver strip line high temperature crystallization glaze is made.
In described step 1, the raw material of described frit is put into crucible, and heating firing is carried out with naked light.
In described step 1, frit is made on a small scale, using crucible water cooling；It is extensive to make frit, using kiln water
It is cold, volatile matter in raw material and effective decomposition gas can effectively be excluded using the method for making frit and burn till glaze paint so as to reduce and rise
Bubble.
In described step 2, described water is pure water；Described ball mill is Quick ball grinder.
In described step 2 (1), described filtering is filtered using 400 mesh sieve, and after filtering, the particle diameter of raw material is
400~450 mesh.
In described step 2 (2), described remaining raw material is copper carbonate and calcining zinc oxide.
Preferably, the ball milling parameter of described ball mill is：By frit, silica, kaolin, titanium dioxide, swollen
Profit soil, whiting, add water for ball milling, rotating speed is preferably 450rpm, and the time is preferably 4~4.5h；After adding remaining raw material, turn
Speed is preferably 450rpm, and the time is preferably 1h；
The preparation method of described green bottom silver strip line high temperature crystallization glaze, by the preparation of frit in step 1, in step 2
After the preparation of green bottom silver strip line high temperature crystallization glaze, by adding methyl in obtained green bottom silver strip line high temperature crystallization glaze
Cellulose, stir, green bottom silver strip line high temperature crystallization glaze is made.
Green bottom silver strip line high temperature crystallization glaze of the present invention and preparation method thereof, compared with prior art, have following beneficial
Effect：
1st, green bottom silver strip line high temperature crystallization glaze, the ceramic glaze colours have distinctive ceramic glaze artistic effect, in green
Ceramic glaze, which floats, reveals argentine paillette shape texture.The green bottom silver strip line high temperature crystallization glaze has good physical, -30
DEG C temperature conditionss under long period of experiments, do not occur glaze paint crackle or obscission.The green bottom silver strip line high temperature crystallization glaze chemistry
Stable performance, can be resistant to common acid and alkali corrosion, and except hydrofluoric acid, widely used, the heavy metal such as not leaded, chromium is green.
2nd, it is more complicated in the technique of glaze due to having used the making of frit, but be the reduction of due to the gas in raw material
Occurs pin hole after glaze paint is burnt till caused by body and phenomenon that low temperature glaze emaciated face falls.Calcining zinc oxide and metal carbonate copper are in saturation shape
Metal excess crystalline polamer can be occurred by being fired under state by oxidizing flame so that ceramic surface shows argentine gloss
The special-effect of sheet.Kaolin and silica so that glass-ceramic glaze phase surface physics and chemical property are stable, are fired into
Power is high, is both adapted to the art pottery to prepare a small amount of glaze, is adapted to a large amount of process scale productions of large size ceramic manufacturing enterprise again.
3rd, green bottom silver strip line high temperature crystallization glaze enamel of the invention, dioxide-containing silica is big in the glaze, and so firing forms
Frit glass glossiness it is high, permeability is good.
The preparation method of the green bottom silver strip line high temperature crystallization glaze of the present invention, has advantages below：
(1) it is to have made the frit with formula first, the proportioning of the frit is effectively by the gas in oxidation and miscellaneous
Matter is discharged, and the phenomenon generation of pin hole and peeling occurs in glaze paint after preventing ceramic firing, while bubble occurs in the surface to preventing glaze
Play the effect of key.The making of the frit, zinc oxide has been effectively promoted it and has been tied during high-temperature firing process and insulation
Crystalline substance, silver-colored flaky crystal artistic effect is generated, there is very high aesthetic to be worth.
(2) secondly, in preparation method, it have adjusted the Ball-milling Time order of raw material；First ball milling frit, silica, kaolinite
Soil, titanium dioxide, bentonite, whiting, rear ball milling copper carbonate and calcining zinc oxide metal oxide, this method effectively ensure
The stability of the color development of the formula, it is the key of the program of whole preparation technology.
(3) finally, the time length of ball milling, it ensure that glaze can be fine to 400~450 mesh, can be with after being mixed with water
As needed, selection sprays to porcelain billet surface or glazing operator is stained with glaze to porcelain billet surface.
Embodiment
With reference to embodiment, the present invention is described in further detail.
Embodiment 1
A kind of green bottom silver strip line high temperature crystallization glaze, it is first to prepare green bottom silver strip line high temperature crystallization glaze, then by glazing, height
Green bottom silver strip line high temperature crystallization glaze made from temperature sintering, wherein, raw material that green bottom silver strip line high temperature crystallization glaze includes and each
The mass percent of raw material is：
Make frit 38%, calcining zinc oxide 28%, silica 1 8%, kaolin 3%, titanium dioxide 5%, bentonite by oneself
1%th, whiting 4%, copper carbonate 3%.
The raw material and the mass percent of each raw material that described frit includes be：
Potassium oxide 1.8%, sodium oxide molybdena 15.9%, calcium oxide 7%, diboron trioxide 2%, silica 73.3%.
A kind of preparation method of green bottom silver strip line high temperature crystallization glaze, comprises the following steps：First prepare green bottom silver strip line high temperature
Crystalline glaze material, green bottom silver strip line high temperature crystallization glaze is made by glazing, sintering；Wherein, green bottom silver strip line high temperature crystallization glaze
Preparation method is as follows：
Step 1, the preparation of frit
Dispensing is carried out according to the raw material included of frit and the mass percent of each raw material, frit raw material is heated to
800 DEG C, after firing 30min, glassy mass is melt into, water cooling, frit is made.
Step 2, the preparation of green bottom silver strip line high temperature crystallization glaze
(1) matched somebody with somebody according to the raw material included of green bottom silver strip line high temperature crystallization glaze and the mass percent of each raw material
Material, by frit, silica, kaolin, titanium dioxide, bentonite, whiting, water is added, after mixing, is added to quick ball milling
In machine, drum's speed of rotation 450rpm, Ball-milling Time 4.5h, filtered with 400 mesh sieve, remove the debris not refined, obtain grain
Footpath is the leftover materials of 400~450 mesh, and leftover materials are continued to be put into Quick ball grinder；Wherein, in mass ratio, water：It is (molten
Block+silica+kaolin+titanium dioxide+bentonite+whiting)=1:1；
(2) remaining copper carbonate and calcining zinc oxide are added into Quick ball grinder, continues ball milling, rotating speed 450rpm,
Ball-milling Time is 1h, and green bottom silver strip line high temperature crystallization glaze is made.
Embodiment 2
A kind of green bottom silver strip line high temperature crystallization glaze, it is first to prepare green bottom silver strip line high temperature crystallization glaze, then by glazing, height
Green bottom silver strip line high temperature crystallization glaze made from temperature sintering, wherein, raw material that green bottom silver strip line high temperature crystallization glaze includes and each
The mass percent of raw material is：
Frit 33%, calcining zinc oxide 23%, silica 23%, kaolin 4%, titanium dioxide 2%, bentonite 4%,
Whiting 6%, copper carbonate 5%.
The raw material and the mass percent of each raw material that described frit includes be：
Potassium oxide 3%, sodium oxide molybdena 10%, calcium oxide 10%, diboron trioxide 5% and silica 72%.
A kind of preparation method of green bottom silver strip line high temperature crystallization glaze, comprises the following steps：First prepare green bottom silver strip line high temperature
Crystalline glaze material, green bottom silver strip line high temperature crystallization glaze is made by glazing, sintering；Wherein, green bottom silver strip line high temperature crystallization glaze
Preparation method is as follows：
Step 1, the preparation of frit
Dispensing is carried out according to the raw material included of frit and the mass percent of each raw material, frit raw material is heated to
760 DEG C, after firing 40min, glassy mass is melt into, water cooling, frit is made.
Step 2, the preparation of green bottom silver strip line high temperature crystallization glaze
(1) matched somebody with somebody according to the raw material included of green bottom silver strip line high temperature crystallization glaze and the mass percent of each raw material
Material, by frit, silica, kaolin, titanium dioxide, bentonite, whiting, water is added, after mixing, is added to ball mill
It is interior, drum's speed of rotation 450rpm, Ball-milling Time 4.5h, filtered with 400 mesh sieve, remove the debris not refined, obtain particle diameter
For the leftover materials of 400~450 mesh, leftover materials are continued to be put into ball mill；Wherein, in mass ratio, water：(frit+dioxy
SiClx+kaolin+titanium dioxide+bentonite+whiting)=1:1；
(2) into ball mill, remaining copper carbonate and calcining zinc oxide are added, continues ball milling, rotating speed 500rpm, ball milling
Time is 1h, and green bottom silver strip line high temperature crystallization glaze is made.
(3) methylcellulose is added in obtained green bottom silver strip line high temperature crystallization glaze, stirred, be made and contain first
The green bottom silver strip line high temperature crystallization glaze of base cellulose.Wherein, in mass ratio, methylcellulose：(frit+calcining zinc oxide+two
Silica+kaolin+titanium dioxide+bentonite+whiting+copper carbonate)=2:100.
Embodiment 3
A kind of green bottom silver strip line high temperature crystallization glaze, it is first to prepare green bottom silver strip line high temperature crystallization glaze, then by glazing, height
Green bottom silver strip line high temperature crystallization glaze made from temperature sintering, wherein, raw material that green bottom silver strip line high temperature crystallization glaze includes and each
The mass percent of raw material is：
Frit 43%, calcining zinc oxide 33%, silica 1 3%, kaolin 1%, titanium dioxide 2%, bentonite 1%,
Whiting 6%, copper carbonate 1%.
The raw material and the mass percent of each raw material that described frit includes be：
Potassium oxide 2%, sodium oxide molybdena 20%, calcium oxide 10%, diboron trioxide 3% and silica 65%.
A kind of preparation method of green bottom silver strip line high temperature crystallization glaze, comprises the following steps：First prepare green bottom silver strip line high temperature
Crystalline glaze material, green bottom silver strip line high temperature crystallization glaze is made by glazing, sintering；Wherein, green bottom silver strip line high temperature crystallization glaze
Preparation method is as follows：
Step 1, the preparation of frit
Dispensing is carried out according to the raw material included of frit and the mass percent of each raw material, frit raw material is heated to
760~800 DEG C, after firing 30min, glassy mass is melt into, water cooling, frit is made.
Step 2, the preparation of green bottom silver strip line high temperature crystallization glaze
(1) matched somebody with somebody according to the raw material included of green bottom silver strip line high temperature crystallization glaze and the mass percent of each raw material
Material, by frit, silica, kaolin, titanium dioxide, bentonite, whiting, water is added, after mixing, is added to ball mill
It is interior, drum's speed of rotation 450rpm, Ball-milling Time 4.5h, filtered with 400 mesh sieve, remove the debris not refined, obtain particle diameter
For the leftover materials of 400~450 mesh, leftover materials are continued to be put into ball mill；Wherein, in mass ratio, water：(frit+dioxy
SiClx+kaolin+titanium dioxide+bentonite+whiting)=1:1；
(2) into ball mill, remaining copper carbonate and calcining zinc oxide are added, continues ball milling, rotating speed 550rpm, ball milling
Time is 1h, and green bottom silver strip line high temperature crystallization glaze is made.
(3) methylcellulose is added in obtained green bottom silver strip line high temperature crystallization glaze, stirred, be made and contain first
The green bottom silver strip line high temperature crystallization glaze of base cellulose.Wherein, in mass ratio, methylcellulose：(frit+calcining zinc oxide+two
Silica+kaolin+titanium dioxide+bentonite+whiting+copper carbonate)=3:100.
Embodiment 4
A kind of green bottom silver strip line high temperature crystallization glaze, it is first to prepare green bottom silver strip line high temperature crystallization glaze, then by glazing, height
Green bottom silver strip line high temperature crystallization glaze made from temperature sintering, wherein, raw material that green bottom silver strip line high temperature crystallization glaze includes and each
The mass percent of raw material is：
Frit 33%, calcining zinc oxide 29%, silica 20%, kaolin 5%, titanium dioxide 8%, bentonite 3%,
Whiting 1%, copper carbonate 1%.
The raw material and the mass percent of each raw material that described frit includes be：
Potassium oxide 1%, sodium oxide molybdena 19%, calcium oxide 4%, diboron trioxide 1% and silica 75%.
A kind of preparation method of green bottom silver strip line high temperature crystallization glaze, comprises the following steps：First prepare green bottom silver strip line high temperature
Crystalline glaze material, green bottom silver strip line high temperature crystallization glaze is made by glazing, sintering；Wherein, green bottom silver strip line high temperature crystallization glaze
Preparation method is as follows：
Step 1, the preparation of frit
Dispensing is carried out according to the raw material included of frit and the mass percent of each raw material, frit raw material is heated to
800 DEG C, after firing 20min, glassy mass is melt into, water cooling, frit is made.
Step 2, the preparation of green bottom silver strip line high temperature crystallization glaze
(1) matched somebody with somebody according to the raw material included of green bottom silver strip line high temperature crystallization glaze and the mass percent of each raw material
Material, by frit, silica, kaolin, titanium dioxide, bentonite, whiting, water is added, after mixing, is added to ball mill
It is interior, drum's speed of rotation 550rpm, Ball-milling Time 4h, filtered with 400 mesh sieve, remove the debris not refined, obtaining particle diameter is
The leftover materials of 400~450 mesh, leftover materials are continued to be put into ball mill；Wherein, in mass ratio, water：(frit+titanium dioxide
Silicon+kaolin+titanium dioxide+bentonite+whiting)=1.2:1；
(2) into ball mill, remaining copper carbonate and calcining zinc oxide are added, continues ball milling, rotating speed 550rpm, ball milling
Time is 0.5h, and green bottom silver strip line high temperature crystallization glaze is made.
Claims (10)
1. a kind of green bottom silver strip line high temperature crystallization glaze, it is first to prepare green bottom silver strip line high temperature crystallization glaze, then by glazing, high temperature
Green bottom silver strip line high temperature crystallization glaze made from sintering, it is characterised in that what described green bottom silver strip line high temperature crystallization glaze included
The mass percent of raw material and each raw material is：
Frit 33%~43%, calcining zinc oxide 23%~33%, silica 1 3%~23%, kaolin 1%~5%, two
Titanium oxide 2%~8%, bentonite 1%~4%, whiting 1%~6%, copper carbonate 1%~5%；
The mass percent of described frit, its raw material included and each raw material is：
Potassium oxide 1%~3%, sodium oxide molybdena 10%~20%, calcium oxide 4%~10%, diboron trioxide 1%~5%, titanium dioxide
Silicon 65~75%.
2. green bottom silver strip line high temperature crystallization glaze as claimed in claim 1, it is characterised in that described green bottom silver strip line high temperature knot
The mass percent of brilliant glaze, its raw material included and each raw material is：
Frit 38%, calcining zinc oxide 28%, silica 1 8%, kaolin 3%, titanium dioxide 5%, bentonite 1%, chalk
Powder 4%, copper carbonate 3%.
3. green bottom silver strip line high temperature crystallization glaze as claimed in claim 1, it is characterised in that raw material that described frit includes and
The mass percent of each raw material is：
Potassium oxide 1.8%, sodium oxide molybdena 15.9%, calcium oxide 7%, diboron trioxide 2%, silica 73.3%.
4. green bottom silver strip line high temperature crystallization glaze as claimed in claim 1, it is characterised in that described green bottom silver strip line high temperature knot
Brilliant glaze, comprising methylcellulose, the quality of methylcellulose accounts for (frit+calcining zinc oxide+silica+kaolin+dioxy
Change titanium+bentonite+whiting+copper carbonate) gross mass mass percent≤3%.
5. the preparation method of the green bottom silver strip line high temperature crystallization glaze in claims 1 to 3 described in any one, including following step
Suddenly：Green bottom silver strip line high temperature crystallization glaze is first prepared, green bottom silver strip line high temperature crystallization glaze is made by glazing, sintering；Its feature
It is, the preparation method of described green bottom silver strip line high temperature crystallization glaze is as follows：
Step 1, the preparation of frit
Dispensing is carried out according to the raw material included of frit and the mass percent of each raw material, frit raw material is heated to 760~
800 DEG C, after firing 20~40min, glassy mass is melt into, water cooling, frit is made；
Step 2, the preparation of green bottom silver strip line high temperature crystallization glaze
(1) dispensing is carried out according to the raw material included of green bottom silver strip line high temperature crystallization glaze and the mass percent of each raw material,
By frit, silica, kaolin, titanium dioxide, bentonite, whiting, water is added, after mixing, is added in ball mill, ball
Mill speed is 450~550rpm, 4~4.5h of Ball-milling Time, filtering, removes the debris not refined；Wherein, in mass ratio, water：
(frit+silica+kaolin+titanium dioxide+bentonite+whiting)=(1~1.2):1；
(2) into ball mill, adding remaining raw material, continue ball milling, 450~550rpm of rotating speed, Ball-milling Time is 0.5~
1h, green bottom silver strip line high temperature crystallization glaze is made.
6. the preparation method of green bottom silver strip line high temperature crystallization glaze as claimed in claim 5, it is characterised in that described step 1
In, frit is made on a small scale, using crucible water cooling；It is extensive to make frit, using kiln water cooling.
7. the preparation method of green bottom silver strip line high temperature crystallization glaze as claimed in claim 5, it is characterised in that described step 2
(1) in, described filtering is filtered using 400 mesh sieve, and after filtering, the particle diameter of raw material is 400~450 mesh.
8. the preparation method of green bottom silver strip line high temperature crystallization glaze as claimed in claim 5, it is characterised in that described step 2
(2) in, described remaining raw material is copper carbonate and calcining zinc oxide.
9. the preparation method of green bottom silver strip line high temperature crystallization glaze as claimed in claim 5, it is characterised in that described ball mill
Ball milling parameter be：By frit, silica, kaolin, titanium dioxide, bentonite, whiting, water for ball milling is added, rotating speed is
450rpm, time are 4~4.5h；After adding remaining raw material, rotating speed 450rpm, time 1h.
10. the preparation method of green bottom silver strip line high temperature crystallization glaze as claimed in claim 5, it is characterised in that described green bottom
The preparation method of silver strip line high temperature crystallization glaze passes through the preparation of frit in step 1, green bottom silver strip line high temperature crystallization glaze in step 2
After the preparation of material, by adding methylcellulose in obtained green bottom silver strip line high temperature crystallization glaze, stir, be made
Green bottom silver strip line high temperature crystallization glaze containing methylcellulose.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110818265A (en) * | 2019-11-26 | 2020-02-21 | 曹云 | Ultra-low temperature polycrystal inorganic crystallization glaze and preparation process and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0934910A2 (en) * | 1998-01-23 | 1999-08-11 | E.I. Dupont De Nemours And Company | Borate glass based ceramic tape |
| CN104355680A (en) * | 2014-11-25 | 2015-02-18 | 福建省佳美集团公司 | Surface glaze of lead-free tableware ceramic and preparation method of glaze |
-
2017
- 2017-10-13 CN CN201710953055.8A patent/CN107619191B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0934910A2 (en) * | 1998-01-23 | 1999-08-11 | E.I. Dupont De Nemours And Company | Borate glass based ceramic tape |
| CN104355680A (en) * | 2014-11-25 | 2015-02-18 | 福建省佳美集团公司 | Surface glaze of lead-free tableware ceramic and preparation method of glaze |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110818265A (en) * | 2019-11-26 | 2020-02-21 | 曹云 | Ultra-low temperature polycrystal inorganic crystallization glaze and preparation process and application thereof |
| CN110818265B (en) * | 2019-11-26 | 2022-02-15 | 曹云 | Ultra-low temperature polycrystal inorganic crystallization glaze and preparation process and application thereof |
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| CN107619191B (en) | 2020-12-08 |
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