CN100393651C - Preparation method of flow liner crystallite glass - Google Patents
Preparation method of flow liner crystallite glass Download PDFInfo
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- CN100393651C CN100393651C CNB2006100183135A CN200610018313A CN100393651C CN 100393651 C CN100393651 C CN 100393651C CN B2006100183135 A CNB2006100183135 A CN B2006100183135A CN 200610018313 A CN200610018313 A CN 200610018313A CN 100393651 C CN100393651 C CN 100393651C
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Abstract
The present invention relates to a preparation method of nucleated glass for architectural decoration, which comprises the steps that firstly, glass metal with different colors is smelted; one kind or many kinds of glass metal with different colors are lead in the glass metal with the other color; under a state that the nonuniform mixing of the glass metal with the different colors is kept, nonuniform mixed glass liquor is shaped into a flow liner mother glass plate by a rolling process, or a casting process or a pressing process; then, the mother glass plate is crystallized and heated so as to be converted into nucleated glass with flow liner textures combined naturally by two colors or many colors. The present invention can generate the flow liner textures with the different colors on the surfaces of nucleated glass products, and natural and active decorative effects similar to running cloud and flowing water are formed so as to enrich the kinds of the textures and the patterns of the nucleated glass.
Description
Technical field
The present invention relates to a kind of preparation method of architectural decoration devitrified glass, particularly relate to a kind of preparation method with architectural decoration devitrified glass of flow liner texture.
Background technology
Devitrified glass has compact structure, physical strength height, wear-resisting, corrosion-resistant, advantageous property such as the weathering resistance ability is strong, can be used as high-grade construction decoration material.
Although devitrified glass can satisfy the requirement of building and ornament materials from the physicochemical property fully, its texture pattern and mixing color are huge to the decorative effect influence of product.In two kinds of traditional main devitrified glass production technique, sintering process can make product form the particulate state texture, also can be by the intermingling between female glass particle of different colours, or between female glass particle admixture colorant or mill base, the pattern that generation is combined by different colours, but pattern is comparatively fuzzy and stiff; And the calendering rule is difficult to generate tangible texture and pattern.Recently, some process quilts that can obtain novel texture, pattern propose, and it is creature dross grain emulated as crackle glass crystallization method (number of patent application is 200410012997.9) product to be generated; As number of patent application 200410077319.0 a kind of method that generates colour painting at product surface has been proposed; As number of patent application 200410077319.0 a kind of generation color three dimension method of patterning has been proposed.
Summary of the invention
The object of the present invention is to provide a kind of preparation method with architectural decoration devitrified glass of flow liner texture.
Flow liner of the present invention means the pattern pattern that can show similar ryolite texture behind the devitrified glass surface economy-combat grinding and polishing light; The architectural decoration devitrified glass that the present invention will have the flow liner texture is called flow liner crystallite glass.
To achieve these goals, technical scheme of the present invention is: the preparation method of flow liner crystallite glass is characterized in that comprising the steps:
1) founding of the glass metal of multiple color: according to the glass formula of 2-9 kind different colours, the admixtion of weighing preparation 2-9 kind color drops into respectively in the glass melter more respectively, is fused into the glass metal of 2-9 kind different colours;
2) the non-homogeneous mixing of glass metal: the glass metal of 1-8 kind different colours is imported in the glass metal of another kind of color, the glass metal of different colours is carried out non-homogeneous married operation, non-homogeneous admixture between the glass metal of formation different colours makes non-homogeneous glass mixed solution;
3) moulding: rolling process or casting or the pressing of non-homogeneous glass mixed solution by routine is shaped to the female sheet glass of flow liner;
4) thermal treatment: female sheet glass is transferred to roller kiln or tunnel furnace or shuttle kiln or drawer kiln or car type furnace, after nucleation, crystallization and thermal treatment, makes the devitrified glass raw sheet;
5) precision work: the devitrified glass raw sheet is cut, polishes, polishes, make flow liner crystallite glass.
Step 2) the non-homogeneous glass mixed solution described in is meant that the glass metal with different colours merges together by any usage ratio, but be not mixed into homogeneous phase fully, its blended non-uniform degree should need to decide on texture, promptly, if will prepare fine and smooth flow liner crystallite glass, then should make between the glass metal of different colours to mix as far as possible; If will prepare rough or streamlined flow liner crystallite glass, then should make between the glass metal of different colours and only converge mutually, and inhomogeneous as far as possible mixing.Non-homogeneous blended theoretical foundation between the glass metal of realization different colours is, glass metal is a kind of full-bodied liquid, after the glass metal of different colours converges mutually, be difficult to realize uniform mixing by the Liquid Phase Diffusion process, therefore, when the glass that stirs different colours converges liquid, the mixing on the glass metal of each color will acquire a certain degree; Or when the glass that does not stir different colours converges liquid, each coloured glass liquid will keep gathering phase separately, and degree of mixing is very low; Or when the glass metal of one or more colors being imported above the glass metal curtain of another kind of color, generating does not have the non-homogeneous glass mixed solution of blended substantially.
Key problem in technology of the present invention is a step 2) and step 3), the glass metal of different colours is carried out non-homogeneous married operation, form non-homogeneous glass mixed solution, in time be shaped to the female sheet glass of flow liner again.The concrete operations mode is, 1. the glass metal of 1-8 kind different colours imported the supply channel of the melting furnaces of the glass metal of founding another kind of color, wherein, and can be in the supply channel if do not establish whipping device; To be shaped to the female sheet glass of flow liner by rolling process or casting or pressing from the effusive non-homogeneous glass mixed solution of supply channel again; Or the glass metal that 2. glass metal of 1-8 kind different colours is imported another kind of color above the formed glass metal curtain, is shaped to the female sheet glass of flow liner by rolling process or pressing again behind the melting furnaces discharge port.
Described step 2) in, by the degree that mixes between the glass metal of control different colours, can prepare the flow liner crystallite glass of different-style, promptly, 1. the glass metal of 1-8 kind different colours is imported close melting furnaces cooling end one end of supply channel of the melting furnaces of the glass metal of founding another kind of color, in the melting furnaces supply channel, whipping device is set, with the speed that is no faster than 20r/min glass being converged liquid stirs, make the mixing on acquiring a certain degree of the glass metal of different colours, just can make fine and smooth disorderly type flow liner crystallite glass; Or the supply channel of melting furnaces that 2. glass metal of 1-8 kind different colours is imported the glass metal of founding another kind of color is near melting furnaces cooling end one end, in the melting furnaces supply channel, whipping device is not set, only by the VISCOUS FLOW process of glass metal in supply channel, can realize partially mixed between the glass metal of different colours just making rough disorderly type flow liner crystallite glass; Or the supply channel of melting furnaces that 3. glass metal of 1-8 kind different colours is imported the glass metal of founding another kind of color is near discharge port one end, or the glass metal that directly glass metal of 1-8 kind different colours is imported another kind of color is behind the melting furnaces discharge port above the formed glass metal curtain time, basic not mixing just can generate streamlined flow liner crystallite glass between the glass metal of different colours.
Characteristics of the present invention: (1) the present invention converges by any usage ratio between the glass metal of different colours, can generate the flow liner texture of different colours at the devitrified glass product surface, form unique decorative effect, enrich the texture pattern kind of architectural decoration devitrified glass, improved the handiness of devitrified glass product colour allotment; (2) the flow liner texture of product surface can make product form the decorative effect of similar natural ryolite, so flow liner crystallite glass can be used as the substitute products of relevant lithotome, help reducing the exploitation of rock material resource, suppress the environmental destruction that China's stone mining industry is brought; (3) formation of flow liner is generation naturally under controlled condition, and the flow liner texture of each monolithic devitrified glass product does not duplicate, so the decorative effect of product nature, active is rich in innervation as natural and smooth, the decoration grade is high; (4) although flow liner metamorphosis multiterminal of Sheng Chenging naturally, but, after processing parameter is determined, the flow liner style of each monolithic microcrystal glass plate is close, the color assembly is close to consistent, so for the big area paving, the excellent decoration associative perception can be obtained, the deficiency that natural ryolite big area is decorated back associative perception difference can be overcome thus.
Description of drawings
To be the present invention by the glass metal of 2-9 kind different colours generate non-equal hybrid glass liquid and then prepare the process flow sheet of flow liner crystallite glass Fig. 1 (a) in the melting furnaces supply channel (* annotates: can be if do not establish whipping device in the supply channel; Dotted line is inessential flow process)
To be the present invention imported above the glass metal curtain face of another kind of color and then prepared the process flow sheet (annotate: dotted line is inessential flow process) of flow liner crystallite glass by the glass metal of 1-8 kind different colours Fig. 1 (b)
Fig. 2 is the photo in kind of the typical sample of the embodiment of the invention 1 preparation
Embodiment
In order to understand the present invention better, further illustrate content of the present invention below in conjunction with Fig. 1 (a), Fig. 1 (b) and embodiment, but content of the present invention not only is confined to the following examples.
Embodiment 1:
Shown in Fig. 1 (a), the preparation method of flow liner crystallite glass is to comprise the steps:
Founding of the glass metal of (1) two kind of color (A look and B look): the admixtion of green and yellow glass is prepared in weighing respectively, and wherein the mass percent of the main chemical compositions of green glass admixtion is: 56.0%SiO
2, 9.0%Al
2O
3, 21.0%CaO, 2.0%MgO, 2.0%K
2O, 4.5%Na
2O, 0.5%Sb
2O
3, 0.3%TFe
2O
3, 0.7%Cr
2O
3, 4.0%ZrO
2, the mass percent of the main chemical compositions of yellow glass admixtion is: 56.0%SiO
2, 8.0%Al
2O
3, 21.0%CaO, 2.0%MgO, 2.0%K
2O, 4.5%Na
2O, 0.5%Sb
2O
3, 0.8%TFe
2O
3, 4.0%ZrO
2, 1.2%MnO
2Glass batch with two kinds of colors drops into respectively in the two table glass melting furnaces again, in 1500 ℃ of insulation 2h, is fused into the glass metal of two kinds of different colours;
(2) the non-homogeneous mixing of glass metal: the supply channel that green glass liquid is imported the melting furnaces of founding yellow glass is near melting furnaces cooling end one end (usage ratio between green glass liquid and yellow glass liquid is 1: 2), do not establish whipping device in the supply channel, only converge the VISCOUS FLOW process of liquid in supply channel by glass, make the glass metal of two kinds of different colours partially mixed, generate the lower non-homogeneous glass mixed solution of degree of mixing;
(3) moulding: adopt normal pouring method technology, non-homogeneous glass mixed solution is poured in the fireproof die,, make the female sheet glass of flow liner at 650 ℃ of following insulation annealing 60min;
(4) thermal treatment: female sheet glass is placed on the backing plate, be transferred to car type furnace, insulation coring 1h under 700 ℃ (hour), be incubated crystallization 1.5h down at 1050 ℃ again, make the devitrified glass raw sheet;
(5) precision work: the devitrified glass raw sheet is cut, polishes, polishes, make rough disorderly type flow liner crystallite glass green and yellow combination.The photo in kind of typical sample as shown in Figure 2.
Embodiment 2:
Shown in Fig. 1 (a), the preparation method of flow liner crystallite glass is to comprise the steps:
Founding of the glass metal of (1) two kind of color (A look and B look): with embodiment 1;
(2) the non-homogeneous mixing of glass metal: the supply channel that green glass liquid is imported the melting furnaces of founding yellow glass is near melting furnaces cooling end one end (usage ratio between green glass liquid and yellow glass liquid is 1: 2), whipping device is set in the supply channel, with the speed of 8r/min glass being converged liquid stirs, make the mixing on acquiring a certain degree of the glass metal of two kinds of different colours, generate the higher non-homogeneous glass mixed solution of degree of mixing;
(3) moulding: with embodiment 1;
(4) thermal treatment: with embodiment 1;
(5) precision work: the devitrified glass raw sheet is cut, polishes, polishes, make disorderly type flow liner crystallite glass green and the yellow exquisiteness that makes up.
Embodiment 3:
Shown in Fig. 1 (a), the preparation method of flow liner crystallite glass is to comprise the steps:
Founding of the glass metal of (1) two kind of color (A look and B look): with embodiment 1;
(2) the non-homogeneous mixing of glass metal: the supply channel that yellow glass liquid is imported the melting furnaces of founding green glass is near melting furnaces discharge port one end (usage ratio between yellow glass liquid and green glass liquid is 1: 2), yellow, green two kinds of glass metals are converging mutually when discharge port flows out, and generate the extremely low non-homogeneous glass mixed solution of degree of mixing;
(3) moulding: with embodiment 1;
(4) thermal treatment: with embodiment 1;
(5) precision work: the devitrified glass raw sheet is cut, polishes, polishes, make streamlined flow liner crystallite glass yellow and green combination.
Embodiment 4:
Shown in Fig. 1 (b), the preparation method of flow liner crystallite glass is to comprise the steps:
Founding of the glass metal of (1) two kind of color (A look and B look): with embodiment 1;
(2) the non-homogeneous mixing of glass metal: yellow glass liquid is imported green glass liquid behind the melting furnaces discharge port above the formed glass metal curtain (usage ratio between yellow glass liquid and green glass liquid is 1: 4), Huang, green two kinds of glass metals are converged mutually, and generating does not have the non-homogeneous glass mixed solution of blended substantially;
(3) moulding: adopt conventional rolling process technology,,, make the female sheet glass of flow liner again at 650 ℃ of following insulation annealing 60min with non-homogeneous glass mixed solution calendering moulding;
(4) thermal treatment: with embodiment 1;
(5) precision work: the devitrified glass raw sheet is cut, polishes, polishes, make streamlined flow liner crystallite glass yellow and green combination.
Embodiment 5:
Shown in Fig. 1 (a), the preparation method of flow liner crystallite glass is to comprise the steps:
Founding of the glass metal of (1) three kind of color (A look, B look and C look): the admixtion of redness, green and yellow glass is prepared in weighing respectively, and wherein the mass percent of the main chemical compositions of red glass admixtion is: 55.0%SiO
2, 7.0%Al
2O
3, 21.0%CaO, 2.0%MgO, 2.0%K
2O, 4.5%Na
2O, 0.5%Sb
2O
3, 0.4%TFe
2O
3, 4.0%ZrO
2, 1.2%MnO
2, 1.6%CdS, 0.8%Se, the mass percent of the main chemical compositions of green glass admixtion is: 56.0%SiO
2, 9.0%Al
2O
3, 21.0%CaO, 2.0%MgO, 2.0%K
2O, 4.5%Na
2O, 0.5%Sb
2O
3, 0.3%TFe
2O
3, 0.7%Cr
2O
3, 4.0%ZrO
2, the mass percent of the main chemical compositions of yellow glass admixtion is: 56.0%SiO
2, 8.0%Al
2O
3, 21.0%CaO, 2.0%MgO, 2.0%K
2O, 4.5%Na
2O, 0.5%Sb
2O
3, 0.8%TFe
2O
3, 4.0%ZrO
2, 1.2%MnO
2Glass batch with three kinds of colors drops into respectively in the three table glass melting furnaces again, in 1500 ℃ of insulation 2h, is fused into the glass metal of three kinds of different colours;
(2) the non-homogeneous mixing of glass metal: green and red glass liquid are imported the supply channel of the melting furnaces of founding yellow glass near melting furnaces cooling end one end (usage ratio between green glass liquid, red glass liquid and yellow glass liquid is 1: 1: 2), whipping device is set in the supply channel, with the speed of 8r/min glass being converged liquid stirs, make the mixing on acquiring a certain degree of the glass metal of three kinds of different colours, generate the higher non-homogeneous glass mixed solution of degree of mixing;
(3) moulding: adopt conventional rolling process technology,,, make the female sheet glass of flow liner again at 660 ℃ of following insulation annealing 60min with non-homogeneous glass mixed solution calendering moulding;
(4) thermal treatment: female sheet glass is placed on the backing plate, be transferred to roller kiln, be incubated coring 1h down, be incubated crystallization 1.5h down at 1050 ℃ again, make the devitrified glass raw sheet at 720 ℃;
(5) precision work: the devitrified glass raw sheet is cut, polishes, polishes, make the disorderly type flow liner crystallite glass of the exquisiteness of green and red and yellow combination.
Embodiment 6:
Shown in Fig. 1 (a), the preparation method of flow liner crystallite glass is to comprise the steps:
Founding of the glass metal of (1) three kind of color (A look, B look and C look): with embodiment 5;
(2) the non-homogeneous mixing of glass metal: green and red glass liquid are imported the supply channel of the melting furnaces of founding yellow glass near melting furnaces cooling end one end (usage ratio between green glass liquid, red glass liquid and yellow glass liquid is 1: 1: 1), do not establish whipping device in the supply channel, only converge the VISCOUS FLOW process of liquid in supply channel by glass, make the glass metal of three kinds of different colours partially mixed, generate the lower non-homogeneous glass mixed solution of degree of mixing;
(3) moulding: with embodiment 5;
(4) thermal treatment: with embodiment 5;
(5) precision work: the devitrified glass raw sheet is cut, polishes, polishes, make rough disorderly type flow liner crystallite glass green and red and yellow combination.
Embodiment 7:
Shown in Fig. 1 (a), the preparation method of flow liner crystallite glass is to comprise the steps:
Founding of the glass metal of (1) three kind of color (A look, B look and C look): with embodiment 5;
(2) the non-homogeneous mixing of glass metal: yellow and red glass liquid are imported the supply channel of the melting furnaces of founding green glass near melting furnaces discharge port one end (usage ratio between yellow glass liquid, red glass liquid and green glass liquid is 1: 1: 2), three kinds of glass metals are converging mutually when discharge port flows out, and generate the extremely low non-homogeneous glass mixed solution of degree of mixing;
(3) moulding: with embodiment 5;
(4) thermal treatment: with embodiment 5;
(5) precision work: the devitrified glass raw sheet is cut, polishes, polishes, make streamlined flow liner crystallite glass yellow and red and green combination.
Claims (4)
1. the preparation method of flow liner crystallite glass is characterized in that comprising the steps:
1) founding of the glass metal of multiple color: according to the glass formula of 2-9 kind different colours, the admixtion of weighing preparation 2-9 kind color drops into respectively in the glass melter more respectively, is fused into the glass metal of 2-9 kind different colours;
2) the non-homogeneous mixing of glass metal: the glass metal of 1-8 kind different colours is imported in the glass metal of another kind of color, the glass metal of different colours is carried out non-homogeneous married operation, non-homogeneous admixture between the glass metal of formation different colours makes non-homogeneous glass mixed solution;
3) moulding: rolling process or casting or the pressing of non-homogeneous glass mixed solution by routine is shaped to the female sheet glass of flow liner;
4) thermal treatment: female sheet glass is transferred to roller kiln or tunnel furnace or shuttle kiln or drawer kiln or car type furnace, after nucleation, crystallization and thermal treatment, makes the devitrified glass raw sheet;
5) precision work: the devitrified glass raw sheet is cut, polishes, polishes, make flow liner crystallite glass.
2. the preparation method of flow liner crystallite glass according to claim 1, it is characterized in that: described step 2) glass metal of different colours being carried out non-homogeneous married operation is: the supply channel of melting furnaces that the glass metal of 1-8 kind different colours is imported the glass metal of founding another kind of color is near melting furnaces cooling end one end, in the melting furnaces supply channel, whipping device is set, with the speed that is no faster than 20r/min glass is converged liquid and stir, be created on the non-homogeneous glass mixed solution of blended to a certain extent.
3. the preparation method of flow liner crystallite glass according to claim 1, it is characterized in that: described step 2) glass metal of different colours being carried out non-homogeneous married operation is: the supply channel of melting furnaces that the glass metal of 1-8 kind different colours is imported the glass metal of founding another kind of color is near melting furnaces cooling end one end, by the VISCOUS FLOW process of glass metal in supply channel, the non-homogeneous glass mixed solution of generating portion blended.
4. the preparation method of flow liner crystallite glass according to claim 1, it is characterized in that: described step 2) glass metal of different colours being carried out non-homogeneous married operation is: the supply channel of melting furnaces that the glass metal of 1-8 kind different colours is imported the glass metal of founding another kind of color is near discharge port one end, the glass metal of different colours is converging mutually when discharge port flows out, and generates the extremely low non-homogeneous glass mixed solution of degree of mixing.
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| CN101555092A (en) * | 2008-04-08 | 2009-10-14 | 杨德宁 | Device and process for fabricating float wear-resisting high-vitrification porcelain plate and glass-ceramics |
| CN101565265B (en) * | 2008-04-23 | 2013-06-26 | 贺奇玻璃制造(大连)有限公司 | Process method device for producing stained glass by continuous casting |
| CN103588418B (en) * | 2012-08-15 | 2017-03-15 | 张桂兰 | Twist tire microlite and its production method and special equipment |
| CN104176937A (en) * | 2013-05-27 | 2014-12-03 | 朱晓明 | Manufacturing method for colored microcrystalline glass |
| CN104445867B (en) * | 2014-12-24 | 2018-08-24 | 河北省沙河玻璃技术研究院 | A kind of manufacture craft and making apparatus of color microcrystalline glass |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002226224A (en) * | 2001-01-31 | 2002-08-14 | Central Glass Co Ltd | Decorative glass and its manufacturing method |
| CN1562830A (en) * | 2004-04-09 | 2005-01-12 | 中国地质大学（武汉） | Manufacturing technique for preparing microcrystalline glass of imitating biologic clast through crystallization method of crack glass |
| CN1647949A (en) * | 2004-12-15 | 2005-08-03 | 黎志煊 | Micro crystal glass color picture and making method |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002226224A (en) * | 2001-01-31 | 2002-08-14 | Central Glass Co Ltd | Decorative glass and its manufacturing method |
| CN1562830A (en) * | 2004-04-09 | 2005-01-12 | 中国地质大学（武汉） | Manufacturing technique for preparing microcrystalline glass of imitating biologic clast through crystallization method of crack glass |
| CN1647949A (en) * | 2004-12-15 | 2005-08-03 | 黎志煊 | Micro crystal glass color picture and making method |
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