CN107032612A - A kind of ceramic ink jet of mine tailing containing lepidolite oozes colored cover-coat enamel - Google Patents
A kind of ceramic ink jet of mine tailing containing lepidolite oozes colored cover-coat enamel Download PDFInfo
- Publication number
- CN107032612A CN107032612A CN201611070132.7A CN201611070132A CN107032612A CN 107032612 A CN107032612 A CN 107032612A CN 201611070132 A CN201611070132 A CN 201611070132A CN 107032612 A CN107032612 A CN 107032612A
- Authority
- CN
- China
- Prior art keywords
- coat enamel
- parts
- colored cover
- glaze
- ink jet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/002—Use of waste materials, e.g. slags
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
Abstract
Colored cover-coat enamel is oozed the invention discloses a kind of ceramic ink jet of mine tailing containing lepidolite, is made up of potassium feldspar, albite, quartz, kaolin, burning talcum and lepidolite mine tailing.The ceramics of the present invention ooze colored cover-coat enamel and had the following advantages that：（1）Each mineral composition ratio of glaze slip of this technique productions is reasonable, be conducive to molten matter and the mixing of glaze of base substrate, the chemical composition and property in intermediate layer is set gradually to be transitioned into constituting for glaze by constituting for base substrate, so as to reduce the defect for reducing ceramic tile product because of the harmful stress that nature difference occurs；（2）The glaze viscosity is appropriate, and suspension is good, thus meets Production of Ceramics manufacturing process, is readily available the glaze of smooth defect free；（3）The glaze abrasive lapping of the technique productions obtains very thin, below the mesh of fineness 325, and each mineral are well mixed, and promotes transformation of the quartz in high temperature, and melting is tended to be complete, can reduce ink-jet and ooze the tendency that flower prod glaze splits.
Description
Technical field
Colored cover-coat enamel is oozed the present invention relates to a kind of ceramic ink jet, the ceramic ink jet of more particularly to a kind of mine tailing containing lepidolite oozes flower
Cover-coat enamel.
Background technology
It is reforming again for ceramic decoration technology that ceramics, which ooze colored ink, in the production applied to ink-jet polished bricks, not only
The color, level and texture of polished bricks are improved, and improves the decorative effect of Ceramic Tiles, is brought entirely to whole ceramic industry
New opportunity to develop.Why ink-jet pattern permeating tile product can emerge and promptly by market acceptance, be because its decorative pattern energy
Matched in excellence or beauty with the full decorative pattern for throwing glaze, and case hardness and polished bricks is consistent, close to 4.5-5.5 grades.Ink-jet pattern permeating tile maximum
Advantage is that texture svelteness exquisiteness, third dimension are strong, compensate for throwing the ink-jet printed stereoeffect not reached of glaze entirely, reaches again
Abrasion resistant effect, so as to add selectivity of the consumer to tile product.
Currently with the main using two kinds of techniques of the ink-jet pattern permeating tile for oozing colored ink production：One kind is pouring sizing process：Cloth
Material → press → drying → pouring glaze+nanometer assistant toner → drying → glaze line ink-jet+penetration-assisting agent → kiln, will by the way of glaze is drenched
Glaze slip containing nanometer assistant toner is layered in adobe as inkjet printing patterned layer；Another is secondary material distributing technique：Secondary cloth
The thin material of cloth+nanometer assistant toner → press → drying → glaze line ink-jet+penetration-assisting agent → kiln in material → adobe, using secondary material distributing,
Cloth last layer contains the thin layer of nanometer assistant toner as inkjet printing patterned layer in adobe, and different-effect oozes Hua Mo respectively
Water brick product.But, it is shallower due to oozing colored ink color development at present, it is necessary to the expensive assistant toner of addition, even secondary material distributing,
Impossible cloth is very thin, so cost is too high, only the strong producer of only a few just can so produce.So, most pottery
Porcelain factory can select to drench sizing process production ink-jet pattern permeating tile.
Lepidolite tailings is to exploit the mine tailing that rare metal niobium tantalum is produced（Tailings）, because one of its main mineral constituent is lithium
Mica, therefore frequently referred to lepidolite tailings.Such as Yichuan Nb-Ta mineral, exploit over more than 40 years, accumulation lepidolite tailings reaches number
Ten million ton, these so-called lepidolite tailings block river, pollution environment, the destruction ecological balance, and certain funds need to be expended every year
Tailings is handled, the development to enterprise brings huge pressure.In recent years, governments at all levels and enterprise are to various industry, mining industry solid
Waste is increased input the carry out comprehensive regulation, therefore, and comprehensive utilization industry, Resourcization of Mining Solid Waste turn into one that current environment is protected
Key subjects.Lepidolite tailings is a kind of ceramic raw material of high-quality, and the comprehensive utilization for carrying out lepidolite tailings is not only good
Environment protection significance, and have preferable social effect and economic value.The ceramic glaze of various performances is prepared using mine tailing, can not only
The problems such as enough realizing the abundant and effective utilization of resource, and environment and financial cost that tailings impoundment is brought can be solved, it is real
Existing economy, environment and the multiple-effect of society.
Architectural pottery glaze is produced using formula based on lepidolite ore tailings again additional other appropriate raw mineral materials
Material products are feasible, then the ceramic glaze that above-mentioned composition is produced is made after ceramic tile, can make building decoration surface lining.
In addition, there is abundant lepidolite ore tailings resource in China, make raw material production architectural pottery glaze with lepidolite ore tailings, in China
There is vast potential for future development.Up to now, especially with lepidolite mine tailing prepared by the research that ceramics ooze colored cover-coat enamel to mine tailing
It is less.
The content of the invention
A kind of cost-effective it is an object of the invention to be prepared using lepidolite mine tailing, hardness is high, and wearability is good, and performance is steady
Fixed, the ceramics for contributing to ceramics to ooze colored ink color development ooze colored cover-coat enamel.
The technical solution used in the present invention is：
A kind of ceramic ink jet of mine tailing containing lepidolite oozes colored cover-coat enamel, by potassium feldspar, albite, quartz, kaolin, burning talcum and lithium
Mica mine tailing is constituted.It is preferred that, its quality group turns into：30~45 parts of potassium feldspar, 5~20 parts of albite, quartz 15~33 parts,
3~8 parts of kaolin, 1~5 part of talcum of burning, 3~46 parts of lepidolite mine tailing；Further, its quality group turns into：Potassium feldspar 30~
40 parts, 5~15 parts of albite, quartz 15~30 parts, 3~8 parts of kaolin, burn 1~5 part of talcum, 3~40 parts of lepidolite mine tailing；
More preferably, its quality group turns into：30~37 parts of potassium feldspar, 5~13 parts of albite, quartz 15~25 parts, 3~6 parts of kaolin,
Burn 1~3 part of talcum, 8~25 parts of lepidolite mine tailing..
A kind of ceramic tile, with glaze layer, the ceramic ink jet of glaze layer from the above mentioned oozes colored cover-coat enamel and formed.
A kind of ceramic ink jet oozes the preparation method of colored cover-coat enamel, comprises the following steps：
1) proportioning of colored cover-coat enamel is oozed by above-mentioned ceramic ink jet, raw material is weighed, mixed；
2) appropriate thickener, degumming agent and water, wet ball grinding are added, obtains oozing colored cover-coat enamel glaze slip；
3) crossing screens out old after iron, obtains ceramic ink jet and oozes colored cover-coat enamel.
As the further improvement of above-mentioned preparation method, cross to screen out and add proper amount of nano in colored cover-coat enamel glaze slip is oozed after iron and help
Toner, is carried out old after being thoroughly mixed.
As the further improvement of above-mentioned preparation method, the fineness for oozing colored cover-coat enamel glaze slip is 325 mesh screen residues 0.2~0.8%.
As the further improvement of above-mentioned preparation method, the Auto-regulating System of Density of Heavy Medium that ceramic ink jet oozes colored cover-coat enamel is 1.70~1.78g/
ml。
As above-mentioned preparation method further improvement nanometer assistant toner be ooze colored cover-coat enamel siccative quality 3~4%.
The beneficial effects of the invention are as follows：
The present invention adjusts the composition of pattern permeating glaze by introducing lepidolite mine tailing in glaze, makes it in glaze sintering process
Easy melt crystallization, produces the wear-resisting glaze of high rigidity.The ceramics that the present invention is prepared using lepidolite mine tailing ooze colored cover-coat enamel, its glaze
Surface hardness is high, wearability is good, glaze smooth uniform, and such a mine tailing low in raw material price, and performance is stable, so as to produce one kind
Low cost, the ceramic ink jet of high-strength abrasion-proof ooze flower prod.
The ceramics of the present invention ooze colored cover-coat enamel and had the following advantages that：（1）Each mineral composition ratio of glaze slip of this technique productions is closed
Reason, is conducive to molten matter and the mixing of glaze of base substrate, the chemical composition and property in intermediate layer is gradually constituted transition by base substrate
To the composition of glaze, so as to reduce the defect that ceramic tile product is reduced because of the harmful stress that nature difference occurs；（2）The glaze
Expect that viscosity is appropriate, suspension is good, thus meets Production of Ceramics manufacturing process, is readily available the glaze of smooth defect free；（3）The work
The glaze abrasive lapping of skill production obtains very thin, below the mesh of fineness 325, and each mineral are well mixed, and promotes transformation of the quartz in high temperature, and
Melting is tended to be complete, ink-jet can be reduced and ooze the tendency that flower prod glaze splits.
The present invention can reasonable development lepidolite resource of tailings, reduction pollution, while products obtained therefrom is generalized into ceramic row again
Industry, reduces Production of Ceramics entreprise cost.The present invention has low cost, performance stable, and hardness is high, and abrasion resistance is good, is conducive to ink-jet
Colored ink color development is oozed, high-quality glaze is easily obtained.
Brief description of the drawings
Fig. 1 is the photo that ceramic ink jet prepared by the embodiment of the present invention 1 oozes colored ceramic tile；
Fig. 2 is the photo that ceramic ink jet prepared by the embodiment of the present invention 4 oozes colored ceramic tile；
Fig. 3 is the SEM figures for the product section that ceramic ink jet prepared by embodiment 1 oozes colored ceramic tile.
Embodiment
A kind of ceramic ink jet of mine tailing containing lepidolite oozes colored cover-coat enamel, by potassium feldspar, albite, quartz, kaolin, burning talcum
With lepidolite mine tailing composition.It is preferred that, its quality group turns into：30~45 parts of potassium feldspar, 5~20 parts of albite, quartz 15~33
Part, 3~8 parts of kaolin, 1~5 part of talcum of burning, 3~46 parts of lepidolite mine tailing；Further, its quality group turns into：Potassium feldspar 30
~40 parts, 5~15 parts of albite, quartz 15~30 parts, 3~8 parts of kaolin, burn 1~5 part of talcum, lepidolite mine tailing 3~40
Part；More preferably, its quality group turns into：30~37 parts of potassium feldspar, 5~13 parts of albite, quartzy 15~25 parts, kaolin 3~6
Part, 1~3 part of talcum of burning, 8~25 parts of lepidolite mine tailing..
A kind of ceramic tile, with glaze layer, the ceramic ink jet of glaze layer from the above mentioned oozes colored cover-coat enamel and formed.
A kind of ceramic ink jet oozes the preparation method of colored cover-coat enamel, comprises the following steps：
1) proportioning of colored cover-coat enamel is oozed by above-mentioned ceramic ink jet, raw material is weighed, mixed；
2) appropriate thickener, degumming agent and water, wet ball grinding are added, obtains oozing colored cover-coat enamel glaze slip；
3) crossing screens out old after iron, obtains ceramic ink jet and oozes colored cover-coat enamel.
As the further improvement of above-mentioned preparation method, cross to screen out and add proper amount of nano in colored cover-coat enamel glaze slip is oozed after iron and help
Toner, is carried out old after being thoroughly mixed.
As the further improvement of above-mentioned preparation method, the fineness for oozing colored cover-coat enamel glaze slip is 325 mesh screen residues 0.2~0.8%.
As the further improvement of above-mentioned preparation method, the Auto-regulating System of Density of Heavy Medium that ceramic ink jet oozes colored cover-coat enamel is 1.70~1.78g/
ml。
As above-mentioned preparation method further improvement nanometer assistant toner be ooze colored cover-coat enamel siccative quality 3~4%.
Thickener and degumming agent are the thickener and degumming agent that those skilled in the art commonly use, and thickener can be CMC,
Degumming agent can be sodium tripolyphosphate.Its consumption can be adjusted correspondingly according to actual needs.
The effect of nanometer assistant toner is the chromophoric characteristic for improving ink, allows its stable color development in glaze layer.It is conventional
Nanometer assistant toner can be porous nano silica material.Its consumption can be adjusted correspondingly as needed.
With reference to embodiment, technical scheme is further illustrated.
For the sake of conveniently comparing, the lepidolite mine tailing used in following examples is the lepidolite tail of Yichuan Nb-Ta mineral
Ore deposit.Certainly, other lepidolite mine tailings are also to use.
Embodiment 1
A kind of ceramic ink jet of mine tailing containing lepidolite oozes colored cover-coat enamel, is made up of the raw material of following mass parts：30 parts of potassium feldspar, sodium are long
8 parts of stone, 33 parts of quartz, 3 parts of kaolin, 2 parts of talcum of burning, 24 parts of lepidolite mine tailing.
Its method of preparation and use comprises the following steps：
1）Wet ball grinding：Mixture is well mixed to obtain after all raw materials for oozing colored cover-coat enamel are weighed according to mass percent respectively,
Then mixture is put into ball mill, then appropriate methyl, trimerization and water is separately added into ball mill, carry out wet method ball
Mill, controls glaze slip fineness：0.2%（325 mesh sieves）, colored cover-coat enamel glaze slip must be oozed；
2）Screen out iron to oozing colored cover-coat enamel glaze slip, and added and account for the nanometer for oozing colored cover-coat enamel siccative mass percent 3.7% and help color
Agent, be thoroughly mixed it is uniform, it is old after, colored cover-coat enamel must be oozed；
3）Glazing：By step 2）It is obtained to ooze colored cover-coat enamel glaze slip proportion and be adjusted to 1.70g/ml, pottery is imposed on using secondary glaze pouring
The surface of porcelain pattern permeating tile base, secondary glazing total amount：165g/330*330 (mm) disk；
4）Inkjet printing：By step 3）It is obtained to ooze after colored cover-coat enamel drying, penetration-assisting agent printing type is added by glaze line ink-jet, will be oozed
Flower ink jet printing is in oozing on colored cover-coat enamel；
5）Burn till：Enter in roller kilns and burn till, firing temperature is 1208 DEG C, firing period 55 minutes, the semi-finished product after cooling are through throwing
Light, obtains oozing the ink-jet pattern permeating tile of colored print pattern with ink-jet.
Embodiment 2
A kind of ceramic ink jet of mine tailing containing lepidolite oozes colored cover-coat enamel, is made up of the raw material of following mass parts：37 parts of potassium feldspar, sodium are long
10 parts of stone, 15 parts of quartz, 8 parts of kaolin, 5 parts of talcum of burning, 25 parts of lepidolite mine tailing.
Its method of preparation and use comprises the following steps：
1）Wet ball grinding：Mixture is well mixed to obtain after all raw materials for oozing colored cover-coat enamel are weighed according to mass percent respectively,
Then mixture is put into ball mill, then appropriate methyl, trimerization and water is separately added into ball mill, carry out wet method ball
Mill, controls glaze slip fineness：0. 5%（325 mesh sieves）, colored cover-coat enamel glaze slip must be oozed；
2）Screen out iron to oozing colored cover-coat enamel glaze slip, and added and account for the nanometer for oozing colored cover-coat enamel siccative mass percent 3.0% and help color
Agent, be thoroughly mixed it is uniform, it is old after, colored cover-coat enamel must be oozed；
3）Glazing：By step 2）It is obtained to ooze colored cover-coat enamel glaze slip proportion and be adjusted to 1.76g/ml, pottery is imposed on using secondary glaze pouring
The surface of porcelain pattern permeating tile base, secondary glazing total amount：170g/330*330 (mm) disk；
4）Inkjet printing：By step 3）It is obtained to ooze after colored cover-coat enamel drying, penetration-assisting agent printing type is added by glaze line ink-jet, will be oozed
Flower ink jet printing is in oozing on colored cover-coat enamel；
5）Burn till：Enter in roller kilns and burn till, firing temperature is 1210 DEG C, firing period 60 minutes, the semi-finished product after cooling are through throwing
Light, obtains oozing the ink-jet pattern permeating tile of colored print pattern with ink-jet.
Embodiment 3
A kind of ceramic ink jet of mine tailing containing lepidolite oozes colored cover-coat enamel, is made up of the raw material of following mass parts：30 parts of potassium feldspar, sodium are long
5 parts of stone, 15 parts of quartz, 3 parts of kaolin, 1 part of talcum of burning, 46 parts of lepidolite mine tailing.
Its method of preparation and use comprises the following steps：
1）Wet ball grinding：Mixture is well mixed to obtain after all raw materials for oozing colored cover-coat enamel are weighed according to mass percent respectively,
Then mixture is put into ball mill, then appropriate methyl, trimerization and water is separately added into ball mill, carry out wet method ball
Mill, controls glaze slip fineness：0.4%（325 mesh sieves）, colored cover-coat enamel glaze slip must be oozed；
2）Screen out iron to oozing colored cover-coat enamel glaze slip, and added and account for the nanometer for oozing colored cover-coat enamel siccative mass percent 3.5% and help color
Agent, be thoroughly mixed it is uniform, it is old after, colored cover-coat enamel must be oozed；
3）Glazing：By step 2）It is obtained to ooze colored cover-coat enamel glaze slip proportion and be adjusted to 1.75g/ml, pottery is imposed on using secondary glaze pouring
The surface of porcelain pattern permeating tile base, secondary glazing total amount：160g/330*330 (mm) disk；
4）Inkjet printing：By step 3）It is obtained to ooze after colored cover-coat enamel drying, penetration-assisting agent printing type is added by glaze line ink-jet, will be oozed
Flower ink jet printing is in oozing on colored cover-coat enamel；
5）Burn till：Enter in roller kilns and burn till, firing temperature is 1190 DEG C, firing period 45 minutes, the semi-finished product after cooling are through throwing
Light, obtains oozing the ink-jet pattern permeating tile of colored print pattern with ink-jet.
Embodiment 4
A kind of ceramic ink jet of mine tailing containing lepidolite oozes colored cover-coat enamel, is made up of the raw material of following mass parts：45 parts of potassium feldspar, sodium are long
20 parts of stone, 25 parts of quartz, 4 parts of kaolin, 3 parts of talcum of burning, 3 parts of lepidolite mine tailing.
Its method of preparation and use comprises the following steps：
1）Wet ball grinding：Mixture is well mixed to obtain after all raw materials for oozing colored cover-coat enamel are weighed according to mass percent respectively,
Then mixture is put into ball mill, then appropriate methyl, trimerization and water is separately added into ball mill, carry out wet method ball
Mill, controls glaze slip fineness：0.8%（325 mesh sieves）, colored cover-coat enamel glaze slip must be oozed；
2）Screen out iron to oozing colored cover-coat enamel glaze slip, and added and account for the nanometer for oozing colored cover-coat enamel siccative mass percent 4.0% and help color
Agent, be thoroughly mixed it is uniform, it is old after, colored cover-coat enamel must be oozed；
3）Glazing：By step 2）It is obtained to ooze colored cover-coat enamel glaze slip proportion and be adjusted to 1.70g/ml, pottery is imposed on using secondary glaze pouring
The surface of porcelain pattern permeating tile base, secondary glazing total amount：175g/330*330 (mm) disk；
4）Inkjet printing：By step 3）It is obtained to ooze after colored cover-coat enamel drying, penetration-assisting agent printing type is added by glaze line ink-jet, will be oozed
Flower ink jet printing is in oozing on colored cover-coat enamel；
5）Burn till：Enter in roller kilns and burn till, firing temperature is 1230 DEG C, firing period 70 minutes, the semi-finished product after cooling are through throwing
Light, obtains oozing the ink-jet pattern permeating tile of colored print pattern with ink-jet.
Embodiment 5
A kind of ceramic ink jet of mine tailing containing lepidolite oozes colored cover-coat enamel, is made up of the raw material of following mass parts：40 parts of potassium feldspar, sodium are long
13 parts of stone, 30 parts of quartz, 6 parts of kaolin, 3 parts of talcum of burning, 8 parts of lepidolite mine tailing.
Its method of preparation and use comprises the following steps：
1）Wet ball grinding：Mixture is well mixed to obtain after all raw materials for oozing colored cover-coat enamel are weighed according to mass percent respectively,
Then mixture is put into ball mill, then appropriate methyl, trimerization and water is separately added into ball mill, carry out wet method ball
Mill, controls glaze slip fineness：0.6%（325 mesh sieves）, colored cover-coat enamel glaze slip must be oozed；
2）Screen out iron to oozing colored cover-coat enamel glaze slip, and added and account for the nanometer for oozing colored cover-coat enamel siccative mass percent 3.8% and help color
Agent, be thoroughly mixed it is uniform, it is old after, colored cover-coat enamel must be oozed；
3）Glazing：By step 2）It is obtained to ooze colored cover-coat enamel glaze slip proportion and be adjusted to 1.74g/ml, pottery is imposed on using secondary glaze pouring
The surface of porcelain pattern permeating tile base, secondary glazing total amount：180g/330*330 (mm) disk；
4）Inkjet printing：By step 3）It is obtained to ooze after colored cover-coat enamel drying, penetration-assisting agent printing type is added by glaze line ink-jet, will be oozed
Flower ink jet printing is in oozing on colored cover-coat enamel；
5）Burn till：Enter in roller kilns and burn till, firing temperature is 1220 DEG C, firing period 63 minutes, the semi-finished product after cooling are through throwing
Light, obtains oozing the ink-jet pattern permeating tile of colored print pattern with ink-jet.
Embodiment 6
A kind of ceramic ink jet of mine tailing containing lepidolite oozes colored cover-coat enamel, is made up of the raw material of following mass parts：30 parts of potassium feldspar, sodium are long
20 parts of stone, 18 parts of quartz, 5 parts of kaolin, 2 parts of talcum of burning, 25 parts of lepidolite mine tailing.
Its method of preparation and use comprises the following steps：
1）Wet ball grinding：Mixture is well mixed to obtain after all raw materials for oozing colored cover-coat enamel are weighed according to mass percent respectively,
Then mixture is put into ball mill, then appropriate methyl, trimerization and water is separately added into ball mill, carry out wet method ball
Mill, controls glaze slip fineness：0.4%（325 mesh sieves）, colored cover-coat enamel glaze slip must be oozed；
2）Screen out iron to oozing colored cover-coat enamel glaze slip, and added and account for the nanometer for oozing colored cover-coat enamel siccative mass percent 3.3% and help color
Agent, be thoroughly mixed it is uniform, it is old after, colored cover-coat enamel must be oozed；
3）Glazing：By step 2）It is obtained to ooze colored cover-coat enamel glaze slip proportion and be adjusted to 1.78g/ml, pottery is imposed on using secondary glaze pouring
The surface of porcelain pattern permeating tile base, secondary glazing total amount：162g/330*330 (mm) disk；
4）Inkjet printing：By step 3）It is obtained to ooze after colored cover-coat enamel drying, penetration-assisting agent printing type is added by glaze line ink-jet, will be oozed
Flower ink jet printing is in oozing on colored cover-coat enamel；
5）Burn till：Enter in roller kilns and burn till, firing temperature is 1180 DEG C, firing period 52 minutes, the semi-finished product after cooling are through throwing
Light, obtains oozing the ink-jet pattern permeating tile of colored print pattern with ink-jet.
Performance detection：
Fig. 1 is the photo that ceramic ink jet prepared by the embodiment of the present invention 1 oozes colored ceramic tile；Fig. 2 is pottery prepared by the embodiment of the present invention 4
The photo of colored ceramic tile is oozed in porcelain ink-jet.From photo as can be seen that its glaze smooth defect free, color are naturally, transition is coordinated, decoration is imitated
It is really splendid.
Fig. 3 is the SEM figures for the product section that ceramic ink jet prepared by embodiment 1 oozes colored ceramic tile, is schemed from the SEM of product section
Piece can be seen that cover-coat enamel and is combined with billet surface, and intermediate layer development has certain thickness, and this explanation intermediate layer physically well develops,
The chemical composition and property in intermediate layer are gradually transitioned into constituting for glaze by constituting for base substrate, so as to reduce because nature difference occurs
Harmful stress, reduce the defect of ceramic tile product；Visually observed from product appearance, the overall glaze of product is relatively put down
It is whole, the defect such as pin-free, crackle, this causes product to have preferable stain resistance and surface abrasion resistance.
In summary, ceramics of the invention ooze colored cover-coat enamel and had the following advantages that：
1) each mineral composition ratio of the glaze slip of this technique productions rationally, is conducive to molten matter and the mixing of glaze of base substrate, makes centre
The chemical composition and property of layer are gradually transitioned into constituting for glaze by constituting for base substrate, so as to reduce because of having that nature difference occurs
Evil stress, reduces the defect of ceramic tile product；
2) glaze viscosity is appropriate, and suspension is good, thus meets Production of Ceramics manufacturing process, is readily available the glaze of smooth defect free
Face；
The glaze abrasive lapping of the technique productions obtains very thin, below the mesh of fineness 325, and each mineral are well mixed, and promotes quartz in high temperature
Transformation, and melting is tended to be complete, ink-jet can be reduced and ooze the tendency that flower prod glaze splits.
Claims (10)
1. a kind of ceramic ink jet of mine tailing containing lepidolite oozes colored cover-coat enamel, by potassium feldspar, albite, quartz, kaolin, burn talcum and
Lepidolite mine tailing is constituted.
2. ceramic ink jet according to claim 1 oozes colored cover-coat enamel, it is characterised in that：Its quality group turns into：Potassium feldspar 30~
45 parts, 5~20 parts of albite, quartz 15~33 parts, 3~8 parts of kaolin, burn 1~5 part of talcum, 3~46 parts of lepidolite mine tailing.
3. ceramic ink jet according to claim 1 oozes colored cover-coat enamel, it is characterised in that：Its quality group turns into：Potassium feldspar 30~
40 parts, 5~15 parts of albite, quartz 15~30 parts, 3~8 parts of kaolin, burn 1~5 part of talcum, 3~40 parts of lepidolite mine tailing.
4. ceramic ink jet according to claim 1 oozes colored cover-coat enamel, it is characterised in that：Its quality group turns into：Potassium feldspar 30~
37 parts, 5~13 parts of albite, quartz 15~25 parts, 3~6 parts of kaolin, burn 1~3 part of talcum, 8~25 parts of lepidolite mine tailing.
5. a kind of ceramic tile, with glaze layer, it is characterised in that：Glaze layer is oozed as the ceramic ink jet described in claims 1 to 3 any one
Flower cover-coat enamel is formed.
6. a kind of ceramic ink jet oozes the preparation method of colored cover-coat enamel, comprise the following steps：
1）The proportioning that the ceramic ink jet as described in claim 2~4 any one oozes colored cover-coat enamel weighs raw material, mixes；
2）Appropriate thickener, degumming agent and water are added, wet ball grinding obtains oozing colored cover-coat enamel glaze slip；
3）Cross and screen out old after iron, obtain ceramic ink jet and ooze colored cover-coat enamel.
7. preparation method according to claim 6, it is characterised in that：Cross to screen out to add in colored cover-coat enamel glaze slip is oozed after iron and fit
Nanometer assistant toner is measured, is carried out after being thoroughly mixed old.
8. the preparation method according to claim 6 or 7, it is characterised in that：The fineness for oozing colored cover-coat enamel glaze slip is 325 mesh screen residues
0.2~0.8%.
9. the preparation method according to claim 6 or 7, it is characterised in that：The Auto-regulating System of Density of Heavy Medium that ceramic ink jet oozes colored cover-coat enamel is
1.70~1.78g/ml.
10. the preparation method according to claim 6 or 7, it is characterised in that：Nanometer assistant toner is to ooze colored cover-coat enamel siccative quality
3~4%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611070132.7A CN107032612A (en) | 2016-11-28 | 2016-11-28 | A kind of ceramic ink jet of mine tailing containing lepidolite oozes colored cover-coat enamel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611070132.7A CN107032612A (en) | 2016-11-28 | 2016-11-28 | A kind of ceramic ink jet of mine tailing containing lepidolite oozes colored cover-coat enamel |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107032612A true CN107032612A (en) | 2017-08-11 |
Family
ID=59530906
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611070132.7A Pending CN107032612A (en) | 2016-11-28 | 2016-11-28 | A kind of ceramic ink jet of mine tailing containing lepidolite oozes colored cover-coat enamel |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107032612A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107777886A (en) * | 2017-11-22 | 2018-03-09 | 恩平市新锦成陶瓷有限公司 | A kind of ceramic glaze of ink-jet infiltration and preparation method thereof and application process |
| CN108218235A (en) * | 2017-12-18 | 2018-06-29 | 佛山科学技术学院 | A kind of production technology of energy-saving environment-friendly ceramic ink-jet polished bricks |
| CN108640512A (en) * | 2018-08-20 | 2018-10-12 | 合肥汉甲陶瓷科技有限公司 | A kind of antibacterial abrasion-resistant clear glaze |
| CN110803944A (en) * | 2019-10-25 | 2020-02-18 | 界首市伟盛古窑彩陶制作发展有限公司 | Glaze dipping process for ceramic glazing |
| CN111515124A (en) * | 2020-06-05 | 2020-08-11 | 江苏拜富科技股份有限公司 | Matt ceramic glaze with strong anti-pollution capability and strong color development |
| CN111559867A (en) * | 2020-06-11 | 2020-08-21 | 武汉山羽新材料科技有限公司 | Special overglaze for ceramic digital ink and preparation method thereof |
| CN112479589A (en) * | 2020-12-24 | 2021-03-12 | 湖州海程塑业有限公司 | Light pink glaze and preparation method thereof |
| CN112574596A (en) * | 2020-12-14 | 2021-03-30 | 江西陶瓷工艺美术职业技术学院 | Ceramic underglaze pigment beneficial to line expression |
| CN115893978A (en) * | 2022-12-19 | 2023-04-04 | 江西和美陶瓷有限公司 | Ceramic body, ceramic tile and preparation method thereof |
| CN116396105A (en) * | 2023-03-22 | 2023-07-07 | 广东欧文莱陶瓷有限公司 | Method for preparing ceramic tile with clear texture by adopting 3D digital glaze spraying technology |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101134853A (en) * | 2006-08-31 | 2008-03-05 | 宝山钢铁股份有限公司 | Coating material preventing carbon deposition of coke oven and method for making same |
| KR20100027471A (en) * | 2008-09-02 | 2010-03-11 | 아이에스동서 주식회사 | Ceramic lightweight tile and manufacturing method thereof |
| CN103030436A (en) * | 2012-12-31 | 2013-04-10 | 广东金意陶陶瓷有限公司 | Basic glaze for ink jet printing, preparation method of basic glaze, and ceramic tile |
| CN103497004A (en) * | 2013-09-18 | 2014-01-08 | 重庆鸽牌电瓷有限公司 | High-voltage ceramic insulated dark blue glaze |
-
2016
- 2016-11-28 CN CN201611070132.7A patent/CN107032612A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101134853A (en) * | 2006-08-31 | 2008-03-05 | 宝山钢铁股份有限公司 | Coating material preventing carbon deposition of coke oven and method for making same |
| KR20100027471A (en) * | 2008-09-02 | 2010-03-11 | 아이에스동서 주식회사 | Ceramic lightweight tile and manufacturing method thereof |
| CN103030436A (en) * | 2012-12-31 | 2013-04-10 | 广东金意陶陶瓷有限公司 | Basic glaze for ink jet printing, preparation method of basic glaze, and ceramic tile |
| CN103497004A (en) * | 2013-09-18 | 2014-01-08 | 重庆鸽牌电瓷有限公司 | High-voltage ceramic insulated dark blue glaze |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107777886A (en) * | 2017-11-22 | 2018-03-09 | 恩平市新锦成陶瓷有限公司 | A kind of ceramic glaze of ink-jet infiltration and preparation method thereof and application process |
| CN108218235A (en) * | 2017-12-18 | 2018-06-29 | 佛山科学技术学院 | A kind of production technology of energy-saving environment-friendly ceramic ink-jet polished bricks |
| CN108640512A (en) * | 2018-08-20 | 2018-10-12 | 合肥汉甲陶瓷科技有限公司 | A kind of antibacterial abrasion-resistant clear glaze |
| CN110803944A (en) * | 2019-10-25 | 2020-02-18 | 界首市伟盛古窑彩陶制作发展有限公司 | Glaze dipping process for ceramic glazing |
| CN111515124A (en) * | 2020-06-05 | 2020-08-11 | 江苏拜富科技股份有限公司 | Matt ceramic glaze with strong anti-pollution capability and strong color development |
| CN111559867A (en) * | 2020-06-11 | 2020-08-21 | 武汉山羽新材料科技有限公司 | Special overglaze for ceramic digital ink and preparation method thereof |
| CN112574596A (en) * | 2020-12-14 | 2021-03-30 | 江西陶瓷工艺美术职业技术学院 | Ceramic underglaze pigment beneficial to line expression |
| CN112479589A (en) * | 2020-12-24 | 2021-03-12 | 湖州海程塑业有限公司 | Light pink glaze and preparation method thereof |
| CN115893978A (en) * | 2022-12-19 | 2023-04-04 | 江西和美陶瓷有限公司 | Ceramic body, ceramic tile and preparation method thereof |
| CN115893978B (en) * | 2022-12-19 | 2023-12-15 | 江西和美陶瓷有限公司 | Ceramic blank, ceramic brick and preparation method thereof |
| CN116396105A (en) * | 2023-03-22 | 2023-07-07 | 广东欧文莱陶瓷有限公司 | Method for preparing ceramic tile with clear texture by adopting 3D digital glaze spraying technology |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107032612A (en) | A kind of ceramic ink jet of mine tailing containing lepidolite oozes colored cover-coat enamel | |
| CN102617123B (en) | Formula and method for manufacturing ceramic tile blank bodies and glazed tiles by utilizing polished waste residues | |
| CN104140297B (en) | The glaze of embossment phantom ornamental brick and preparation | |
| CN101386528B (en) | Method for producing ceramic tile by metallurgical steel slag | |
| CN105272375B (en) | A kind of Buddha's warrior attendant glaze of wear-resisting high rigidity, preparation method and application | |
| CN104761239B (en) | The burning process of blue and white porcelain | |
| CN105948503A (en) | Wear-resistant transparent glaze and method for preparing glazed tile by utilizing same | |
| CN107963814A (en) | Compound glaze, the wear-resisting porcelain Antique Imitation Tiles of compound glaze slip and the soft face of 4-8 degree | |
| CN105948820A (en) | Wear-resistant glaze and method for preparing glazed tile by utilizing the same | |
| CN102417343B (en) | Production method of sandstone-like porcelain exterior wall tile | |
| CN105000866A (en) | Glazed tile prepared from sludge with mirror-effect surface and preparation method thereof | |
| CN105060843B (en) | A kind of preparation method and its obtained product for strengthening beautiful matter porcelain | |
| CN103626476A (en) | Method for producing light-weight heat-insulating decorative ceramic plate by using solid waste in production and processing course of expanded pearlite | |
| CN106986540A (en) | One kind, which is sunk, peels off marble galze making formula | |
| CN106220017A (en) | A kind of inhibitor suppressing ceramic tile polishing waste residue high temperature sintering to foam and method | |
| CN105801145A (en) | Unfired, impregnation-free and environment-friendly sliding plate brick bound through organic silicone modified phenolic resin, production method and application | |
| CN103145449B (en) | Method for preparing iron tailing into ceramic frit glaze | |
| CN106630938A (en) | High-strength ceramic floor tile and preparation method thereof | |
| CN105218170B (en) | A kind of high-hardness, wearable exempts to polish iron microcrystalline glass in series ceramic clad plate and preparation method thereof | |
| CN106810297B (en) | Production process of ceramic tile with high-brightness matte surface and precious metal luster | |
| CN104355640A (en) | Castable specially used for mouths of 5000T cement kilns | |
| CN107265865B (en) | Easy clean protection glaze and preparation method thereof | |
| CN104844254A (en) | Method for producing foamed red mud decoration ceramic tile by using roller hearth kiln | |
| CN108892481B (en) | Ecological stone and preparation method thereof | |
| CN114920541B (en) | High-wear-resistance ceramic material for ceramic tiles, preparation method of high-wear-resistance ceramic material and high-wear-resistance ceramic tiles |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170811 |
|
| RJ01 | Rejection of invention patent application after publication |