CN1041895C - 吸收氧化硫并同时生产硫酸铵的方法 - Google Patents

吸收氧化硫并同时生产硫酸铵的方法 Download PDF

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Publication number
CN1041895C
CN1041895C CN94102903A CN94102903A CN1041895C CN 1041895 C CN1041895 C CN 1041895C CN 94102903 A CN94102903 A CN 94102903A CN 94102903 A CN94102903 A CN 94102903A CN 1041895 C CN1041895 C CN 1041895C
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China
Prior art keywords
ammonium sulfate
absorber
gas
prepurifier
storage tank
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Expired - Lifetime
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CN94102903A
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Chinese (zh)
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CN1093015A (zh
Inventor
A·沙林姆
E·加尔
G·N·布朗
M·L·曼格尔
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Marsulex Environmental Technologies LLC
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General Electric Environmental Services Inc
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
    • C01C1/00—Ammonia; Compounds thereof
    • C01C1/24—Sulfates of ammonium
    • C01C1/245—Preparation from compounds containing nitrogen and sulfur
    • C01C1/246—Preparation from compounds containing nitrogen and sulfur from sulfur-containing ammonium compounds
    • C01C1/247—Preparation from compounds containing nitrogen and sulfur from sulfur-containing ammonium compounds by oxidation with free oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/50—Sulfur oxides
    • B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treating Waste Gases (AREA)
  • Gas Separation By Absorption (AREA)
CN94102903A 1993-03-22 1994-03-19 吸收氧化硫并同时生产硫酸铵的方法 Expired - Lifetime CN1041895C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US035,284 1993-03-22
US08/035,284 US5362458A (en) 1993-03-22 1993-03-22 Process for the simultaneous absorption of sulfur oxides and production of ammonium sulfate

Publications (2)

Publication Number Publication Date
CN1093015A CN1093015A (zh) 1994-10-05
CN1041895C true CN1041895C (zh) 1999-02-03

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Family Applications (1)

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CN94102903A Expired - Lifetime CN1041895C (zh) 1993-03-22 1994-03-19 吸收氧化硫并同时生产硫酸铵的方法

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Country Link
US (1) US5362458A (enExample)
EP (1) EP0620187B1 (enExample)
JP (1) JP3507545B2 (enExample)
CN (1) CN1041895C (enExample)
CA (1) CA2116949C (enExample)
DE (1) DE69406704T2 (enExample)
ES (1) ES2108937T3 (enExample)
GR (1) GR3025613T3 (enExample)
TW (1) TW295573B (enExample)

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US6187278B1 (en) * 1998-09-08 2001-02-13 Marsulex Environmental Technologies, Llc Process for controlling ammonia slip in the reduction of sulfur dioxide emission
US6221325B1 (en) 1998-09-08 2001-04-24 Marsulex Environmental Technologies, Llc Process for controlling ammonia slip in the reduction of sulfur dioxide emission
US6468490B1 (en) * 2000-06-29 2002-10-22 Applied Materials, Inc. Abatement of fluorine gas from effluent
BR0013318A (pt) * 1999-08-12 2002-07-16 Ebara Corp Método e aparelho para tratamento de gás efluente
US6531104B1 (en) 2000-11-21 2003-03-11 Alstom (Schweiz) Ag Process for the absorption of sulfur oxides and the production of ammonium sulfate
US20030059352A1 (en) * 2001-08-07 2003-03-27 Maurice Karras Process and apparatus for scrubbing sulfur dioxide from flue gas and conversion to fertilizer
US6638342B2 (en) * 2001-11-28 2003-10-28 Marsulex Environmental Technologies Process and facility for removing metal contaminants from fertilizer streams
US6936231B2 (en) 2001-12-06 2005-08-30 Powerspan Corp. NOx, Hg, and SO2 removal using ammonia
CN100364647C (zh) * 2004-09-22 2008-01-30 上海弗卡斯环保工程有限公司 氨法烟气脱硫装置及其工艺
US7682574B2 (en) * 2004-11-18 2010-03-23 Applied Materials, Inc. Safety, monitoring and control features for thermal abatement reactor
US8095240B2 (en) * 2004-11-18 2012-01-10 Applied Materials, Inc. Methods for starting and operating a thermal abatement system
EP1819421A1 (de) * 2004-11-26 2007-08-22 Ashland Licensing and Intellectual Property LLC Verfahren zur feststoffabtrennung aus gasw[schern
US20080289951A1 (en) * 2005-06-27 2008-11-27 Cunping Huang Thermochemical Cycle for Production of Hydrogen and/or Oxygen Via Water Splitting Processes
US20070154374A1 (en) * 2006-01-05 2007-07-05 Envirosolv Energy Llc Method for removing sulfur dioxide and other acid gases, mercury, and nitrogen oxides from a gas stream with the optional production of ammonia based fertilizers
CN101678407A (zh) * 2007-05-25 2010-03-24 应用材料股份有限公司 用于减量系统的有效操作的方法与装置
JP2011501102A (ja) * 2007-10-26 2011-01-06 アプライド マテリアルズ インコーポレイテッド 改良された燃料回路を使用した高性能な除害の方法及び装置
US7947168B2 (en) * 2008-03-05 2011-05-24 Syncrude Canada Ltd. Segregation of streams for the production of ammonia
CN102177107A (zh) * 2008-07-31 2011-09-07 帝斯曼知识产权资产管理有限公司 经粒化的硫酸铵颗粒
CN101422688B (zh) * 2008-11-07 2011-06-29 浙江大学 氨-硫铵湿法烟气脱硫并诱导结晶回收硫酸铵的工艺
US8353980B2 (en) * 2008-12-05 2013-01-15 Marsulex Environmental Technologies Corporation Flue gas scrubbing apparatus and process
US8795416B2 (en) * 2009-10-12 2014-08-05 Babcock & Wilcox Power Generation Group, Inc. Segregated in-situ forced oxidation wet flue gas desulfurization for oxygen-fired fossil fuel combustion
CN102976357B (zh) * 2012-12-28 2014-08-13 安徽工业大学 一种氧化法从氨法脱硫废液中提取硫酸铵的方法
CN103011201B (zh) * 2012-12-28 2014-06-18 安徽工业大学 一种氧化法从氨法脱硫废液中提取硫氰酸铵的方法
CN103588340B (zh) * 2013-11-27 2014-12-24 安徽工业大学 用苛化—酸化法处理钠碱法脱硫废液的方法
CN103657367B (zh) * 2013-12-13 2016-04-27 何金整 一种单塔式钙法脱硫转双塔式氨法脱硫的装置与工艺
CN105032158A (zh) * 2015-09-09 2015-11-11 北京京城环保股份有限公司 一种污泥焚烧烟气的处理装置及方法
US10046272B2 (en) 2015-10-27 2018-08-14 Marsulex Environmental Technologies, Corp. Process and system for removing sulfur dioxide from flue gas
CN108144428A (zh) 2017-03-15 2018-06-12 江苏新世纪江南环保股份有限公司 一种氨法高效脱除气体中硫氧化物和尘的方法及装置
CN107213785B (zh) 2017-05-25 2020-08-07 江苏新世纪江南环保股份有限公司 一种fcc尾气氨法脱硝脱硫除尘的方法及装置
CN107213769B (zh) 2017-05-25 2019-09-20 江苏新世纪江南环保股份有限公司 一种分室加氨的氨法脱硫方法及装置
EP3842125B1 (en) 2017-06-14 2025-12-10 Jiangnan Environmental Protection Group Inc. Automatic ammonia-adding system and method for ammonia-based desulfurization device
US10603624B2 (en) 2017-07-03 2020-03-31 Marsulex Environmental Technologies Corporation Wet flue gas desulfurization process and apparatus
CN108722163B (zh) 2017-09-07 2019-06-07 江苏新世纪江南环保股份有限公司 一种氨法脱硫控制吸收过程气溶胶产生的方法
CN107670486A (zh) * 2017-11-29 2018-02-09 洛阳市天誉环保工程有限公司 烧结机烟气的除砷装置及除砷工艺
CN110368816A (zh) 2018-04-13 2019-10-25 江苏新世纪江南环保股份有限公司 一种氨法脱硫溶液的氧化方法及装置
CN110732227B (zh) 2018-07-20 2023-02-21 江南环保集团股份有限公司 一种酸性气处理的方法和装置
CN114870579A (zh) 2022-05-16 2022-08-09 江苏新世纪江南环保股份有限公司 一种氨法脱硫脱碳系统余热回收的方法及装置
CN110975546B (zh) 2019-12-26 2021-08-17 江苏新世纪江南环保股份有限公司 一种改进的氨法脱硫控制吸收过程气溶胶产生的方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4649033A (en) * 1982-08-26 1987-03-10 K,L+M Industria E Comercio S/P Process to eliminate air pollutants which result from the combustion of fuels containing sulphur
US4690807A (en) * 1985-08-15 1987-09-01 General Electric Environmental Services, Inc. Process for the simultaneous absorption of sulfur oxides and production of ammonium sulfate

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US3186802A (en) * 1961-03-02 1965-06-01 Carves Simon Ltd Apparatus for the production of ammonium sulphate
US3676059A (en) * 1970-06-01 1972-07-11 Albert B Welty Jr Sulfate control in ammonia flue gas desulfurization
UST909017I4 (en) * 1972-04-13 1973-04-17 Sulfur dioxide removal prom stack gases
US3843789A (en) * 1973-02-26 1974-10-22 Air Prod & Chem Removal of sulfur oxides from stack gas
JPS5513770B2 (enExample) * 1973-09-26 1980-04-11
DE2431130C3 (de) * 1974-06-28 1979-07-26 Maschinenfabrik Burkau R. Wolf Kg, 4048 Grevenbroich Verfahren zur Entfernung von sauren Komponenten aus Abgasen
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JPS5857213B2 (ja) * 1975-07-10 1983-12-19 イシカワジマハリマジユウコウギヨウ カブシキガイシヤ 排煙脱硫方法
DE2708919C2 (de) * 1977-03-02 1982-05-27 Dr. C. Otto & Comp. Gmbh, 4630 Bochum Verfahren zur Reinigung von SO↓2↓-haltigen Industrieabgasen
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DE2741116C2 (de) * 1977-09-13 1984-11-22 Dr. C. Otto & Co Gmbh, 4630 Bochum Verfahren zur Entfernung von Schwefeldioxid aus Gasen, insbesondere Industrieabgasen
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Patent Citations (2)

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US4649033A (en) * 1982-08-26 1987-03-10 K,L+M Industria E Comercio S/P Process to eliminate air pollutants which result from the combustion of fuels containing sulphur
US4690807A (en) * 1985-08-15 1987-09-01 General Electric Environmental Services, Inc. Process for the simultaneous absorption of sulfur oxides and production of ammonium sulfate

Also Published As

Publication number Publication date
JPH06271303A (ja) 1994-09-27
GR3025613T3 (en) 1998-03-31
EP0620187B1 (en) 1997-11-12
TW295573B (enExample) 1997-01-11
CA2116949A1 (en) 1994-09-23
JP3507545B2 (ja) 2004-03-15
DE69406704T2 (de) 1998-06-04
ES2108937T3 (es) 1998-01-01
EP0620187A1 (en) 1994-10-19
CN1093015A (zh) 1994-10-05
CA2116949C (en) 2004-12-28
US5362458A (en) 1994-11-08
DE69406704D1 (de) 1997-12-18

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Free format text: CORRECT: PATENTEE; FROM: GENERAL ELECTRIC ENVIRONMENTAL SERVICES, INC. TO: MASUKU HENDRIX ENVIRONMENTAL TECHNOLOGY CO., LTD.

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