CN104177949B - Anion environment-friendly latex paint containing sweet marjoram natural extract - Google Patents

Anion environment-friendly latex paint containing sweet marjoram natural extract Download PDF

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Publication number
CN104177949B
CN104177949B CN201410411481.5A CN201410411481A CN104177949B CN 104177949 B CN104177949 B CN 104177949B CN 201410411481 A CN201410411481 A CN 201410411481A CN 104177949 B CN104177949 B CN 104177949B
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essential oil
latex paint
anion
oil
agent
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CN104177949A (en
Inventor
刘占川
刘存
梅少峰
刘艳菲
程璐
李幕英
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Hebei Chenyang water paint Co. Ltd.
Hebei Chenyang Industry and Trade Group Co Ltd
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Hebei Chenyang Water Paint Co Ltd
Hebei Chenyang Industry and Trade Group Co Ltd
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Abstract

The invention relates to an anion environment-friendly latex paint containing sweet marjoram natural extract. The latex paint has the characteristics of aging resistance, no scaling, no discoloration, high weather resistance, no toxicity, no smell, favorable leveling property, high constructability, scrub resistance, no toxicity or harm and fresh smell, has health-care effect, is beneficial to human health, can still keep the original strength and quality after adding proper amounts of other functional components, and can release air anions to purify air for a long time. The latex paint can resist and kill bacteria, has aromatic smell and mild properties, and has the effects of helping hormone secretion, relieving anxiety, improving insomnia and the like, thereby achieving the effects of relieving mental pressure and enhancing work efficiency. More importantly, the latex paint can not generate adverse effect on the human body, and is suitable for people at all ages.

Description

A kind of anion environmental protection emulsion paint containing marjoram natural extract
Technical field
The invention belongs to technical field of fine, particularly to a kind of anion containing marjoram natural extract Environment friendly emulsion paint.
Background technology
Emulsion paint has easy construction, the various feature of color, dominates in inner wall decoration at home.But pass The newborn emulsion paint of system does not have antibacterial action, and in hospital, easily because bacterial adsorption is on body of wall, people's imprudence is with wall for children room Body contact is easy for contaminated with bacteria, thus producing harm to body.Common antibiotic emulsion paint on the market is typically adopted at present With the compound of organic antibacterial agent organic bromine, or inorganic silver ion antimicrobial agent, the compound pair of organic antibacterial agent organic bromine PH is sensitive, and addition is big, and toxicity is relatively significantly, irritant to people and animals, and adds inorganic silver ion antimicrobial agent price Height, but activity is low, harsh to environmental requirement;And traditional emulsion paint single function, can not meet the requirement of people.
Content of the invention
In view of the shortcomings of the prior art, the technical problem to be solved is to provide one kind to contain marjoram The anion environmental protection emulsion paint of natural extract, has that anti-aging, non-scale, nondiscolouring, weatherability be strong, nontoxic, tasteless, stream Levelling is good, easy working feature, washability, and nontoxic, smell is pure and fresh, has health-care effect, is conducive to health, its It still is able to keep original intensity and quality after appropriate interpolation other function ingredients, negative aeroion not only can be discharged for a long time, Purify air, beneficial to health;And can restraining and sterilizing bacteria, fragrant odour simultaneously, property is gentle, pure and fresh soothe the spirit, help hormone to divide Secreting, anxiety of releiving, improve the effects such as have a sleepless night, thus reaching alleviation stress, improving the effect of operating efficiency, even more important It is that it will not produce harmful effect it is adaptable to each age groups to human body.
The purpose of the present invention is achieved by the following technical solution:
A kind of anion environmental protection emulsion paint containing marjoram natural extract it is characterised in that:By following weight portion The material composition of number:Polyvinyl acetate emulsion 15-20 part, water-base resin 7-12 part, levelling agent 3-5 part, carboxyethyl cellulose 3-6 Part, anion natural mineral powder 3-6 part, surfactant 1-2 part, sustained release agent 1-1.5 part, thickener 1-2 part, color agent 3- 6 parts, deionized water 60-80 part, marjoram essential oil 0.4-0.8 part, grapefruit essential oil 0.3-0.5 part, wheat malt essential oil 0.3- 0.5 part, propolis essential oil 0.3-0.5 part, refined jasmine oil 0.3-0.5 part, tea tree ethereal oil 0.3-0.5 part, P-Cymene 0.3-0.5 Part, Peppermint essential oil 0.3-0.5 part, described anion natural mineral powder is tourmaline, lanthanide rare composite salt and titanium oxide By weight 4:3:3 mixture, wherein tourmaline are dravite and elbaite by weight 6:4 mixture, described The color masterbatch of color agent is respectively SL-P10, SL-P12, SL-A26, SL-M04, SL-B01 and SL-B02.
Preferably, described surfactant is polyoxyethylene groups ethers nonionic fluorocarbon surfactant.
Wherein marjoram essential oil, grapefruit essential oil, wheat malt essential oil, propolis essential oil, refined jasmine oil, tea tree ethereal oil, Chinese mugwort Leaf essential oil and Peppermint essential oil must be sufficiently mixed with surfactant, sustained release agent, to reach slow release effect, the addition of each essential oil Must be appropriate, above-mentioned appropriate essential oil not only antibiotic and sterilizing moreover it is possible to stable mood, so having front to not normal psychological condition Effect, can purify, pacify soul, angry and beaten sensation can be mitigated, making one can be with even-tempered and good-humoured ground to life. Because its energy centre of equilibrium nerve, helpful to alarmed and dejected state, also there is significantly tranquil and function of releiving, Insomniac is had goodish relaxing put and console with spirit, for pacify hot-tempered enter or moody temper have goodish effect, Operating efficiency can be improved.
The present invention with reference to modern Chinese medicine pharmacological research, verifies from the drug screening of existing Chinese medicine and repeatedly, gives full play to respectively Component acts synergistically, and the effect of the essential oil employed in it is described as follows.
Marjoram essential oil can improve that mood is depressed and addictive disease, especially to liberal-mindedness and vigorous endurance stress symptom effectively, can expand blood Pipe, hypotensive, mitigate and burden, help eliminate palpitaition, have excellent nerve to pacify and calm function.
Grapefruit essential oil:Grape fruit is cool in nature, sweet acid, the effect that there is heat-clearing, quench the thirst, grapefruit essential oil is to be squeezed by pericarp Obtained by, smell is pure and fresh, fragrant and sweet, has the fruit flavor of oranges and tangerines.Grapefruit essential oil energy nurse tissue cell, increases muscle power, releives and props up Tracheitis, diuresis, improve fat, the disease of oedema and lymph glandular system, anti-infective.Grapefruit essential oil can also resist melancholy, especially Its melancholy occurring in winter or the symptom such as drowsy, can make one to refresh, be the conditioning agent of seasonal psychataxia.
Wheat malt essential oil acts on:There is overpowering odor to contain abundant high unit vitamin e, be famous natural(Anti- Rotten agent), the essential oil of each composition can be stablized, make the effect of perfume more lasting.
Propolis essential oil:Propolis is honeycomb side " wax glue ", is that honeybee deliberately leaps some woods, is stained with trees using back leg The resin of secretion, has arrived and resin has taken during honeycomb side the enzyme spuing and beeswax are mixed into propolis with oneself again, it can antibacterial Antiviral, whole honeycomb is survived under aseptic conditions after protection larva, young honeybee and honeybee etc., and recent studies proves, contained by propolis Have abundant and the bioactivator of uniqueness so as to have antibacterial, anti-inflammatory, antipruritic, anti-oxidant, strengthen multiple work(such as immunity Energy.
Tea tree ethereal oil is used for for air cleaning, elimination of off flavor, and deodorant, insect protected is dust-proof to be hidden from, permissible:Anion scent diffusion equipment: The use of wealthy perfume device is most effective and direct mode, by wealthy perfume device, tea tree ethereal oil is broken into imperceptible small molecule, freely expand It is dissipated in the air, the most free of a burden at last, absorb easily, equally distributed essential oil usage.You can contact by breathing, body surface, The actual power experiencing tea tree ethereal oil, and there is the effect of reality.During use, except tea tree ethereal oil that can be simple adds Outward it is also possible to allocate such as the essential oils such as lavender, grape fruit, cypress, peppermint into, strengthening antibacterial effect simultaneously improves soul impression.
Refined jasmine oil:There is obvious relaxation effect, can inspire enthusiasm, lift self-confidence, the anti-melancholy ability of strength Can make one in high spirits, forget worry.Pacify nerve, the impression in generation front simultaneously, set up a kind of self-confident, have optimism and spirit Cheerful and light-hearted sensation, contributes to regaining one's vigor, and it has lax and warm mood function simultaneously,
P-Cymene is to bacillus anthracis, Alpha-hemolytic streptococcus, B- Streptococcus hemolyticus, corynebacterium diphtheriae, bacillus pseudodiphthericus, lung class 10 kinds of Gram-positives such as diplococcus, staphylococcus aureus, Staphylococcus citreus, white Portugal Portugal coccus, hay bacillus are thermophilic Gas bacterium all has antibacterial action, also has bacteriostasis for multiple pathomycetes.
Not only fragrance, moreover it is possible to mosquito expelling, has contraction capilary to Peppermint essential oil simultaneously, excludes vivotoxin, improves wet Rash, tinea, releive itch, inflammation and burning, soft skin, eliminate blackhead, be beneficial to oily hair and skin quality, purify air And the effect refreshed oneself.
Equipment involved in the present invention, raw material and method, are the usual equipment using of the industry, raw material and method.
Beneficial effects of the present invention:
Emulsion paint in the present invention has that anti-aging, non-scale, nondiscolouring, weatherability be strong, nontoxic, tasteless, good leveling property, Easy working feature, washability, nontoxic, smell is pure and fresh, has health-care effect, is conducive to health, and it is adding in right amount Plus still be able to keep original intensity and quality after other function ingredients, negative aeroion not only can be discharged for a long time, purify empty Gas, beneficial to health;And can restraining and sterilizing bacteria, fragrant odour simultaneously, property is gentle, pure and fresh soothe the spirit, help hormone secretion, releive Anxiety, improve insomnia the effects such as, thus reaching alleviation stress, improve operating efficiency effect it is even more important that its not Harmful effect can be produced it is adaptable to each age groups to human body.
Specific embodiment
With reference to embodiment, the present invention is described in more detail.
Embodiment 1.
A kind of anion environmental protection emulsion paint containing marjoram natural extract, by the material group of following parts by weight Become:Polyvinyl acetate emulsion 15kg, water-base resin 12 kg, levelling agent 3 kg, carboxyethyl cellulose 6 kg, anion natural ore Material powder 3kg, surfactant 1 kg, sustained release agent 1.5 kg, thickener 1 kg, color agent 6 kg, deionized water 60 kg are sweet Marjoram essential oil 0.4kg, grapefruit essential oil 0.5kg, wheat malt essential oil 0.3kg, propolis essential oil 0.5kg, refined jasmine oil 0.3kg, Tea tree ethereal oil 0.5kg, P-Cymene 0.3kg, Peppermint essential oil 0.5kg, described anion natural mineral powder is tourmaline, group of the lanthanides Rare earth composite salt and titanium oxide by weight 4:3:3 mixture, wherein tourmaline are dravite and elbaite presses weight Amount compares 6:4 mixture, the color masterbatch of described color agent is respectively SL-P10, SL-P12, SL-A26, SL-M04, SL-B01 and SL- B02.
Wherein, described surfactant is polyoxyethylene groups ethers nonionic fluorocarbon surfactant.
Embodiment 2.
A kind of anion environmental protection emulsion paint containing marjoram natural extract, by the material group of following parts by weight Become:Polyvinyl acetate emulsion 20 kg, water-base resin 7 kg, levelling agent 5 kg, carboxyethyl cellulose 3 kg, anion natural ore Material powder 6kg, surfactant 2 kg, sustained release agent 1 kg, thickener 2 kg, color agent 3 kg, deionized water 80 kg, sweet horse Yu Lan essential oil 0.8kg, grapefruit essential oil 0.3kg, wheat malt essential oil 0.5kg, propolis essential oil 0.3kg, refined jasmine oil 0.5kg, tea Tree essential oil 0.3kg, P-Cymene 0.5kg, Peppermint essential oil 0.3kg, described anion natural mineral powder is tourmaline, group of the lanthanides is dilute Native composite salt and titanium oxide by weight 4:3:3 mixture, wherein tourmaline be dravite and elbaite by weight Ratio 6:4 mixture, the color masterbatch of described color agent is respectively SL-P10, SL-P12, SL-A26, SL-M04, SL-B01 and SL- B02.
Wherein, described surfactant is polyoxyethylene groups ethers nonionic fluorocarbon surfactant.
Embodiment 3.
A kind of anion environmental protection emulsion paint containing marjoram natural extract it is characterised in that:By following weight portion The material composition of number:Polyvinyl acetate emulsion 17 kg, water-base resin 9 kg, levelling agent 4 kg, carboxyethyl cellulose 5 kg, bear Ion natural mineral powder 4kg, surfactant 1 kg, sustained release agent 1.3 kg, thickener 1 kg, color agent 4 kg, deionization Water 70 kg, marjoram essential oil 0.7kg, grapefruit essential oil 0.4kg, wheat malt essential oil 0.4kg, propolis essential oil 0.4kg, jasmine Essential oil 0.4kg, tea tree ethereal oil 0.4kg, P-Cymene 0.4kg, Peppermint essential oil 0.3-0.5 part, described anion natural mineral matter Powder is tourmaline, lanthanide rare composite salt and titanium oxide by weight 4:3:3 mixture, wherein tourmaline are dravite With elbaite by weight 6:4 mixture, the color masterbatch of described color agent is respectively SL-P10, SL-P12, SL-A26, SL- M04, SL-B01 and SL-B02.
Wherein, described surfactant is polyoxyethylene groups ethers nonionic fluorocarbon surfactant.
Reference examples 1.
Hydroxyethyl cellulose 4kg, silicon class defoamer 2kg, butyl glycol ether 2kg, six phosphorus meta-acid sodium 1.8kg, bentonite 12kg, preservative 2.5kg, propane diols 2kg, ammoniacal liquor 1kg, deionized water 30kg.
Test the emulsion paint in this above-described embodiment using air ion static method of testing, anion burst size be 0/ m3.
Reference examples 2.
Acrylic emulsion 4kg, epoxy emulsion 3kg, silica 5kg, coalescents 1kg, cosolvent 2kg, dispersant 1.5kg, defoamer 1.5kg, thickener 2kg, mould inhibitor 1.5kg, preservative 1kg, deionized water 40kg.
Test the emulsion paint in this above-described embodiment using air ion static method of testing, anion burst size be 0/ m3.
Carry out contrast test through the present invention with generic latex paint, with reference to GB18582-2008 and GB/T9756-2009 standard Test, its main performance index such as following table:
Conclusion:Emulsion paint in the present invention and prior art(Reference examples 1 and reference examples 2)Compare hence it is evident that reducing latex VOC in paint(VOC)Content, contrast ratio is high, wash-resistant property is good.
(2)Purifying formaldehyde is tested:
According to the emulsion paint in above-described embodiment 1, embodiment 2 and embodiment 3 according to JC/T1074-2008《Room air Purification function coating material purifying property》The standard of regulation is tested:
In 51 m3The customized chest fully sealing in, by embodiment 1 in generic latex paint and the present invention, implement Emulsion paint in example 2 and embodiment 3 is criticized respectively and is scraped on four faces of chest, after emulsion paint is dried, sprays into 5 ml dense simultaneously Spend the formalin for 36%, when formalin is volatilized completely in airtight chest(About 30 minutes), carry out the first sub-sampling Then after 4 hours measure the content of formaldehyde, after 12 hours, after 24 hours, take sample to measure the content of formaldehyde in air respectively.
Measure the content of formaldehyde using phenol reagent method, its principle is:The formaldehyde of in the air and phenol reagent react Generate piperazine afterwards, piperazine is aoxidized by ferric ion in an acidic solution and forms glaucous compound, then further according to the depth of color, Colorimetric carries out quantitation, to obtain a result.
4 sub-samplings are respectively labeled as A1, A2, A3, A4, test data asks for an interview table 2.
Reference examples 1 Reference examples 2 Embodiment 1 Embodiment 2 Embodiment 3
A1( mg/ m3) 1907 1938 1821 1719 1783
A2( mg/ m3) 1879 1902 1627 1597 1691
A3( mg/ m3) 1726 1807 1360 1175 1279
A4( mg/ m3) 1620 1782 903 796 821
Conclusion:Emulsion paint in the embodiment of the present invention 1, embodiment 2 and embodiment 3 all can play good purifying formaldehyde Effect, with common emulsion paint(Reference examples 1 and reference examples 2)Compare, the present invention has certain advantage.
(3)Anion collecting test.
By common emulsion paint(Reference examples 1 and reference examples 2)With the embodiment of the present invention 1, embodiment 2 and and embodiment 3 in Emulsion paint brush respectively in 20 × 20cm2Plank on, dry, lie on grating type ion collectors, collector put into 0.4 m3Closed bin in, carry out follow-on test with still air ion tester, test result shows:The embodiment of the present invention 1, Embodiment 2 and and embodiment 3 in emulsion paint contrast generic latex paint anion average increase be 1217/scm3, and Sustained release negative aeroion, is more beneficial for purifying the air of a room for a long time;And common emulsion paint(Reference examples 1 and reference examples 2) Then do not possess the function of anion releasing.
(4)To the test improving the state of mind.
Main method is that emulsion paint uses volunteer to test, and recruits 30 people, is being brushed with above-mentioned enforcement 1, embodiment 2 and respectively It is detained 60 minutes in the room of emulsion paint in embodiment 3, SCL-90 questionnaire is completed according to the impression of itself(I.e.《Symptoms Self-assessment amount Table-SCL90》, it is one of foremost Mental health test scale in the world), by continuous 1 week using following the tracks of, to judge Actual efficacy effect in terms of putting forward battle array spirit for the present invention, wherein 2 people are noninductive to be subject to;3 people's impressions are general;25 people are had to feed back this product tool There is effect of significantly refreshing oneself, the power that can warn is concentrated, and efficient reaches 83.33% it was demonstrated that the present invention has in terms of stimulating effect There is preferable effect.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, common for art For technical staff, can also make other changes in different forms on the basis of the above description, here need not All of embodiment cannot be exhaustive, all any modifications within the spirit and principles in the present invention, made, equivalent replace Change, improve, be still included within protection scope of the present invention.

Claims (1)

1. a kind of anion environmental protection emulsion paint containing marjoram natural extract it is characterised in that:By following parts by weight Material composition:Polyvinyl acetate emulsion 15-20 part, water-base resin 7-12 part, levelling agent 3-5 part, carboxyethyl cellulose 3-6 Part, anion natural mineral powder 3-6 part, surfactant 1-2 part, sustained release agent 1-1.5 part, thickener 1-2 part, color agent 3- 6 parts, deionized water 60-80 part, marjoram essential oil 0.4-0.8 part, grapefruit essential oil 0.3-0.5 part, wheat malt essential oil 0.3- 0.5 part, propolis essential oil 0.3-0.5 part, refined jasmine oil 0.3-0.5 part, tea tree ethereal oil 0.3-0.5 part, P-Cymene 0.3-0.5 Part, Peppermint essential oil 0.3-0.5 part, described anion natural mineral powder is tourmaline, lanthanide rare composite salt and titanium oxide By weight 4:3:3 mixture, wherein tourmaline are dravite and elbaite by weight 6:4 mixture, described The color masterbatch of color agent is respectively SL-P10, SL-P12, SL-A26, SL-M04, SL-B01 and SL-B02, and described surfactant is Polyoxyethylene groups ethers nonionic fluorocarbon surfactant.
CN201410411481.5A 2014-08-20 2014-08-20 Anion environment-friendly latex paint containing sweet marjoram natural extract Active CN104177949B (en)

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CN1179754C (en) * 2002-07-08 2004-12-15 中国建筑材料科学研究院 Composition tourmaline powder able to effectively generate negative ions in air and its preparing process
KR20060055915A (en) * 2004-11-19 2006-05-24 한중바이오(주) Bio mortar for wallpaper and method for coating using the same
CN101781489B (en) * 2009-12-31 2012-03-14 潍坊三强集团有限公司 Method for producing interior wall healthcare latex paint by using lavender natural extract
CN102964946A (en) * 2012-11-15 2013-03-13 青岛保利康新材料有限公司 Green odorless latex paint for interior walls
CN103756520A (en) * 2013-12-23 2014-04-30 广东三和化工科技有限公司 Environment-friendly emulsion paint and preparation

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Inventor after: Liu Zhanchuan

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Inventor after: Mei Shaofeng

Inventor after: Liu Yanfei

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