CN104173203B - Low-irritation skin massage product - Google Patents

Low-irritation skin massage product Download PDF

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Publication number
CN104173203B
CN104173203B CN201310203812.1A CN201310203812A CN104173203B CN 104173203 B CN104173203 B CN 104173203B CN 201310203812 A CN201310203812 A CN 201310203812A CN 104173203 B CN104173203 B CN 104173203B
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skin
massage
low stimulation
agent
cellulose
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CN104173203A (en
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江磊
宋伟东
洪晓鹏
暴朝霞
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Beiersdorf AG
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Beiersdorf AG
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Abstract

The invention discloses a cosmetic composition for low-irritation massage, which comprises massage particles, modified cellulose, an emollient, a surfactant and water. The invention also relates to a method for massaging the skin by applying the cosmetic composition for low-irritation massage and to the use of the cosmetic composition for low-irritation massage for the production of a product for massaging the skin.

Description

A kind of low stimulation skin massaging product
Technical field
The present invention relates to a kind of bath products, are more particularly to a kind of low stimulation cosmetic composition for massage, it includes Granule for massage, modified fibre, emollient, surfactant and suitable water.
Background technology
Cosmetic composition for massage is a kind of common cleansing skin product, can provide effective massaging feel simultaneously With good cleaning ability.The purpose of cosmetic composition for massage is to promote blood to follow by cleaning the physical stimulation of object Ring, increases thermal energy, and dispelling fatigue allows whole body to be in the state loosened completely；And/or by removing surface extra on cuticula Dead cell is so that skin surface is smooth.
However, common cosmetic composition for massage there is a problem of one it is universal, that is, carrying out the same of massage rubbing When can carry out offending excessive friction sense to skin tape and even tingling sensation or scratch sense, this tingling sensation is typically due to wherein exist Granule for massage cause.In personal frosted product, usually there is water-insoluble polymerization in water base or non-aqueous medium or emulsion Object material.But frosting product easily makes dry skin, the insoluble polymer in aqueous medium is scratched during use Sense, and can further stimulate skin and generate dry sensation.For the frosted product being present in non-aqueous medium i.e. oil medium For, although oil medium can help somewhat to reduce friction, sense is scratched in mitigation, but still is not enough to mitigate these mills The too strong scratch effect of article.
It has been proposed that should have in frosted product compared under low-shearing force can collapsibility insoluble polymer material, this A bit can collapsibility material can slightly reduce during use scratch sense；However, for some, even if non-water base In medium or emulsion, rubbing action is still too strong.
Someone further suggests that emollient is added（For example, glycerine etc.）It can be to a certain extent although emollient is added It reduces scratch sense or alleviates tingling sensation, but its effect and not ideal enough, require still to have quite apart from ideal user experience Gap.
Therefore, there is still a need for further improved cosmetic composition for massage products in the prior art, are being enough to realize While increasing thermal energy, dispelling fatigue and/or eliminate skin surface dead cell, make the effect of skin smooth, also have acceptable Physics sense of touch, that is, have reduce scratch sense or tingling sensation.
Invention content
Unless otherwise specified, all percentages used herein are with the total weight of composition.
The all components used in the present invention should be that skin is acceptable, i.e., will not cause when the skin with people is in contact Unsuitable toxicity, incompatibility, unstability and allergic reaction etc..
Term " cosmetic composition for massage " used herein refers to the composition for being intended for personal nursing, can The effect of physical massage effect and/or removing surface dead cell needed for object is provided.
The first purpose of the invention is to provide a kind of cosmetic composition for massage, it is enough to provide and increases thermal energy, disappears Except fatigue and/or the effect eliminated skin surface dead cell, make skin smooth, and there is acceptable physics sense of touch, that is, has There is the irritation of reduction（Scratch sense or tingling sensation）.
The present inventor passes through a large number of experiments, it was unexpectedly found that：Modified cellulose can effectively mitigate massage and apply some make up Composition can bring significant effect to the scratch sense of skin or tingling sensation or even a small amount of modified cellulose.The present inventor It has furthermore been found that in the cosmetic composition for massage product containing granule for massage, by modified cellulose and emollient and table Face activating agent combination is, it can be achieved that the user experience more significantly improved：Granular sensation obviously weakens, and has apparent lubrication and skin softening effect Fruit significantly reduces the tingling sensation of skin, is also reduced to the irritation of skin.Said combination, while realizing massage functions, Bring apparent lubrication and skin softening effect.
Therefore, it is based on above-mentioned discovery, in the first aspect, the present invention provides a kind of low stimulations to massage the combination that applies some make up Object, it includes following components by weight：
A) 50.0~90.0% granule for massage；
B) 0.1~5.0% modified cellulose;
C) 0.1~20.0% emollient；
D) 0.1~10.0% surfactant；With
E) suitable water.
It is the particulate material that can play massage or rubbing action for the granule for massage in the present composition, it can Include with variously-shaped and surface characteristic particle to be the combination of any one or more of substance as known in the art. These particles can use as it is, without by hydrophobically modified, being including but not limited to derived from those of a variety of materials, including Derived from those of inorganic, organic, natural and synthesis source.Illustrative granule for massage is based on polyethylene or poly- ammonia The granule for massage of ester, the granule for massage based on natural nerkel powder or shell powder and the bead made of wax；And clay（Such as Kaolin, bentonite etc.）, silica, zeolite, or mixtures thereof or derivative.More specifically, the non-limiting examples of these materials Including almond coarse powder, alumina, aluminium oxide, titanium dioxide, mica, odium stearate, alumina silicate, attapulgite, calcium carbonate, sulfuric acid Calcium, diatomite, iron oxide, montmorillonite, lagoriolite, talcum and tricalcium phosphate etc..
Can be cellulose derivative, including alkylcellulose, hydroxyl alkane for the modified cellulose in the present composition Base cellulose ether, carboxyl alkyl cellulose ether etc..Preferred modified fibre is known as methylcellulose（MC）, ethyl cellulose（EC）、 Carboxymethyl cellulose（CMC）, hydroxyethyl cellulose（HEC）, hydroxypropyl methyl cellulose（HPMC）.
Can be petroleum base fatty acid ester, ethyoxyl alkyl esters, ethoxy for the emollient in the present composition The aliphatic ester and PEGylated poly- silica of or mixtures thereof base aliphatic ester, aliphatic alcohols, polysiloxane-based and PEGization Alkanes.
Can be selected from anion surfactant, amphoteric ion surface for the surfactant in the present composition One kind in activating agent and nonionic surfactant or its arbitrary combination.
Exceptionally except above-mentioned necessary group, low stimulation cosmetic composition for massage of the invention can also not damage effect of the present invention Optionally include one or more in following components in the range of fruit.These components include activating agent, adjuvant, additive Deng, such as activating agent（Such as antiseptic, anti-acne activating agent, vitamin, anti wrinkling agent, anti-skin atrophy and skin repair activity It is agent, the agent of skin barrier repairing activity, the smooth activating agent of non-steroidal cosmetic, skin lightening agent, sun-screening agent, sebum inhibitor, anti-oxidant Agent etc.）, moisturizer, viscosity modifier and thickener, pH adjusting agent, dyestuff, organic solvent or diluent, freshener, essence with And pigment etc..These components and its amount can suitably be selected according to the actual needs of product, and be added to the combination of the present invention In object.
The composition of the present invention can be made into any suitable form suitable for using, such as, but not limited to following form： Emulsion, face cream, cream, facial mask, essence etc..
Second object of the present invention is to provide a kind of method preparing cosmetic composition for massage of the present invention, The method includes mixing each component in the cosmetic composition for massage, stir and required shape is further made Formula.
Another aspect of the present invention is related to a kind of method of massaging skin, including to a effective amount of present invention of dermal administration Low stimulation cosmetic composition for massage.
The invention further relates to the low stimulation cosmetic composition for massage to prepare the purposes in skin massaging product.It can profit With the low stimulation cosmetic composition for massage, various forms of skin massaging products are made according to required purpose.
The invention further relates to modified celluloses for mitigating scratch sense or shouting pain of the cosmetic composition for massage to skin The purposes of sense.
The content of granule for massage is in one specific aspect of the present invention, the low stimulation cosmetic composition for massage 50.0~80.0%, preferably 55%~75%, 60%~78%, 65.0~75.0%, more preferably 70.0%.
In terms of in the present invention, another is specific, modified cellulose contains in the low stimulation cosmetic composition for massage Amount is 0.3~3.0%, preferably 0.35~2.0%, 0.4~1.0%, more preferably 0.45%.
In terms of in the present invention, another is specific, the content of emollient is in the low stimulation cosmetic composition for massage 1.0~20.0%, preferably 1.5~15.0%, 2.0~13.0%, 3.0~10.0%, 3.5~8.0%, more preferably 5.0%.
The content of surfactant in one specific aspect of the present invention, the low stimulation cosmetic composition for massage Be 0.3~5.0%, preferably 0.3~3.0%, 0.35~2.0%, 0.4~1.0%, more preferably 0.45%.
In terms of in the present invention, another is specific, granule for massage is chlorination in the low stimulation cosmetic composition for massage Any one of sodium, sodium carbonate, sodium bicarbonate, sodium sulphate, niter cake and sugar or its any mixture.
In terms of in the present invention, another is specific, the modified cellulose in the low stimulation cosmetic composition for massage is Alkylcellulose, hydroxyalkyl cellulose ether or carboxyl alkyl cellulose ether.In some preferred embodiments, the modified fibre Element is methylcellulose（MC）, ethyl cellulose（EC）, carboxymethyl cellulose（CMC）, hydroxyethyl cellulose（HEC）And hydroxypropyl Methylcellulose（HPMC）Any one of or its any mixture.
Emollient is PEG-50 oxen in one specific aspect of the present invention, the low stimulation cosmetic composition for massage Oleoresin, apricot kernel oil PEG-8 esters, double-PEG-15 methyl ether dimethicones, PEG/PPG-25/25 poly dimethyl silicon Any one of oxygen alkane and hydrolysis Jojoba esters or its any mixture.
In terms of in the present invention, another is specific, surfactant is the moon in the low stimulation cosmetic composition for massage Any one of ionic surface active agent, amphoteric surfactant and nonionic surfactant or its any mixture.More In preferred embodiment, the anion surfactant is any in poly alkyl alcohol ether sulfate, aliphatic alcohol sulfate Kind or its any mixture；The amphoteric surfactant is preferably betaines；The nonionic surfactant is preferably Hydrogenated castor oils.
In a preferred embodiment, low stimulation cosmetic composition for massage of the invention contains suitable perfume (or spice) Essence.
In an especially preferred embodiment, low stimulation cosmetic composition for massage of the invention includes by weight The following components of meter is composed of the following components：
A) 70.0% NaCl;
B) 0.45% carboxymethyl cellulose；
C) 2.4% glycerine；
D) 5.0% PEG/PPG-25/25 dimethyl silicone polymers；
E) 0.45% Cremophor RH40；With
F) suitable water.
In an especially preferred embodiment, low stimulation cosmetic composition for massage of the invention includes by weight The following components of meter is composed of the following components：
A) 70.0% NaCl;
B) 0.45% carboxymethyl cellulose；
C) 2.4% glycerine；
D) 5.0% PEG/PPG-25/25 dimethyl silicone polymers；
E) 0.45% Cremophor RH40；
F) suitable essence；With
G) suitable water.
The low stimulation cosmetic composition for massage of the present invention can be made any product form suitable for using, such as but It is not limited to the forms such as creams, facial mask, emulsion, face cream, essence, emulsifiable paste, cake soap.In a preferred embodiment, of the invention Low stimulation cosmetic composition for massage be massage scrub cream form.
In some preferred embodiments, in addition low stimulation cosmetic composition for massage of the invention also contains following It is one or more in component：Activating agent（Antibacterial agent and antifungal agent, anti-acne activating agent, vitamin, anti wrinkling agent, anti-skin It is skin atrophy and skin repair activating agent, the agent of skin barrier repairing activity, the smooth activating agent of non-steroidal cosmetic, skin lightening agent, sun-proof Agent, sebum inhibitor and antioxidant etc.）, moisturizer, viscosity modifier and thickener, pH adjusting agent, dyestuff, organic solvent Or diluent, freshener, essence and pigment.
Specific implementation mode
I necessity components
A.Granule for massage
Granule for massage used in this invention can be the combination of any one or more of substance as known in the art, packet It includes with variously-shaped and surface characteristic particle.Illustrative granule for massage is the massage based on polyethylene or polyurethane Grain, the granule for massage based on natural nerkel powder or shell powder and the bead made of wax；And clay（Such as it is kaolin, swollen Moisten soil etc.）, silica, the mineral such as zeolite, or mixtures thereof or derivative.The non-limiting examples of these materials include that almond is thick Powder, silica, talcum, calcite, float stone, alumina, aluminium oxide, titanium dioxide, mica, odium stearate, alumina silicate, attapulgite, Calcium carbonate, calcium sulfate, diatomite, iron oxide, montmorillonite, lagoriolite and tricalcium phosphate etc.；The shell of crushing, such as apricot Core and walnut shell；Oatmeal；Polymer such as polyethylene and polypropylene bead；Microwax bead；Deng.In addition, particularly preferred Granule for massage can also be inorganic salts, such as sodium chloride, sodium carbonate, sodium bicarbonate, sodium sulphate, niter cake；And carbohydrate, example If monosaccharide includes glucose, fructose and galactolipin；Disaccharide includes sucrose（Such as the sucrose of sugarcane and beet sources）, maltose, fibre Tie up disaccharides and lactose；And polysaccharide includes amylose, amylopectin, glycogen, dextrin etc..Specifically the example of polysaccharide includes：(a) Xanthan gum, a kind of heteroglycan can be with trade name KELPROL and KELTROL F（CP KELCO companies）It sells, and with trade name RHODOPOL23 and RHODIACARE T（RHODIA companies）It sells；（b）Carboxymethyl starch, it is worth mentioning at this point that AVEBE companies The product that trade name PERFECTAMYL GEL45 and PERFECTAMYL GEL MB are sold；（c）Hydroxypropul starch, such as The product that GRAIN PROCSSING companies are sold with trade name ZEINA B860；And（d）Agar.
B.Modified cellulose
The modified cellulose for including in the low stimulation cosmetic composition for massage of the present invention can be cellulose derivative, Including alkylcellulose, hydroxyalkyl cellulose ether, carboxyl alkyl cellulose ether etc..Preferred modified fibre is known as methylcellulose （MC）, ethyl cellulose（EC）, carboxymethyl cellulose（CMC）, hydroxyethyl cellulose（HEC）, hydroxypropyl methyl cellulose （HPMC）.
C.Emollient
It can be petroleum base fatty acid ester, ethyoxyl alkyl esters, ethoxylated fatty to be suitable for the invention emollient Or mixtures thereof acid esters, aliphatic alcohols, polysiloxane-based and PEGylated aliphatic ester and PEGylated polysiloxane-based.It is suitable Petroleum based emollient includes or mixtures thereof the hydrocarbon of a length of 16-32 carbon atom of chain, the petroleum base hydrocarbon packet with the chain length Include mineral oil and vaseline；Applicable fatty acid ester emollient includes C12-C28Aliphatic acid, preferably C16-C22Saturated fatty acid and short Chain（C1-C8, preferably C1-C3）Emollient derived from single hydroxyl alcohol, the representative examples of these esters includes methyl palmitate, hard Resin acid methyl esters, dodecyl isopropyl ester, myristyl isopropyl ester, cetyl isopropyl ester and cetyl diethyl acetamidomalonate；It is applicable in Fatty acid ester emollient further include by long-chain fatty alcohol（C12-C28, preferably C12-C16）And short chain fatty acids（Such as lactic acid）Shape At ester；Applicable ethyoxyl alkyl esters emollient includes C12-C22Ethoxylated fatty acid ester, average degree of ethoxylation It is about 2 to about 30, the preferably described ethoxylated fatty alcohol ester emollient is selected from ethyoxyl dodecyl ester, cetyl ester and tristearin Acid esters, the preferred alkyl ethoxylate base ester are that ethoxylated dodecyl base ester, ethoxylated hexadecyl base ester, ethoxylation are hard Resin acid ester etc..
In addition, available emollient can also include the following in the present invention：（a）Silicone oil and its modifier, such as directly Chain and cricoid dimethyl silicone polymer；Amino, alkyl, alkaryl and aryl silicone oil；（b）Grease type, including natural oil lipid, Such as jojoba oil, soybean oil, sunflower oil, rice bran oil, avocado oil, apricot kernel oil, olive oil, sesame oil, persic oil, castor oil, Coconut oil, ermine oil；Cocoa butter；Butter（Fat）, lard；Above-mentioned oils adds the hardening oils that hydrogen obtains；And the glycerine one of synthesis Ester, diglyceride and triglycerides, such as myristic acid glyceride and 2 ethyl hexanoic acid glyceride；（c）Wax class, such as cohune Palmitic acid wax, spermaceti, beeswax, lanolin and its derivative；（d）Hydrophobic plant extract；（e）Hydro carbons, such as atoleine（Paraffin Oil）, vaseline, microwax, ceresine, squalene and mineral oil；（f）Higher fatty acids, such as lauric acid, myristic acid, palm Acid, stearic acid, oleic acid, linoleic acid, leukotrienes, lanoceric acid, isostearic acid, arachidonic acid and polyunsaturated fatty acid；（g） Higher alcohol, such as laruyl alcohol, cetanol, stearyl alcohol, oleyl alcohol, cholesterol；（h）Esters, such as Octanoic acid, hexadecyl ester, lactic acid nutmeg Ester, cetyl lactate, nutmeg calculate isopropyl ester, isopropyl palmitate, adipic acid isopropyl ester, butyl stearate, decyl oleate, different Stearic acid cholesteryl ester, lactic acid alkyl ester, citric acid alkyl esters and winestone acid alkyl ester；（i）Essential oil and its extract, such as peppermint Oil, jasmin oil, camphorated oil, bitter orange oil, turpentine oil, cinnamon oil, bergamot oil, citrus unshiu Marcovitch oil, calamus oil, pine tar, Lavender oil, laurel, caryophyllus oil, cypress oil, eucalyptus oil, lemon oil, thyme linaloe oil, peppermint oil, attar of rose, Salvia japonica Oil, sesame oil, ginger oil, basil, juniper berry oil, lemongrass oil, rosemary oil, bois de rose oil, avocado oil, grapefruit, grape pip Oil, myrrh oil, cucumber oil, water fennel oil, pot marigold oil, linden flower oil, three-coloured amaranth red oil, algal oil, ginkgo oil, symphysis caul-fat, can It can oil, neroli oil, green tea oil, menthol, cineole, evening primrose oil, camphorated oil etc..
Particularly preferred emollient is PEGylated aliphatic ester and PEGylated polysiloxane-based and natural oil, spy It is not PEG-50 sher butters, apricot kernel oil PEG-8 esters, double-PEG-15 methyl ether dimethicones, PEG/PPG-25/ Any one of 25 dimethyl silicone polymers and hydrolysis Jojoba esters or its any mixture.
D.Surfactant
The surfactant for including in the low stimulation cosmetic composition for massage of the present invention can be selected from anion table One kind in face activating agent, zwitterionic surfactant and nonionic surfactant or its arbitrary combination.
The low stimulation cosmetic composition for massage of the present invention includes to account for composition weight 0.3%~5.0%, preferably 0.3 ~3.0%, 0.35~2.0%, 0.4~1.0%, more preferable 0.45% surfactant.The surfactant can be composition Bring cleaning action and frothing capacity.
Anionic surfactant component includes not only common anion surfactant, further includes the pH in composition It is the zwitterionic surfactant or combination thereof of the coupling part of anionic property down.It is suitable for the invention combination The example of anion surfactant in object includes but not limited to sulfate, sulfonate, sarcosinate and sarcosine derivative. Preferred anion surfactant is poly alkyl alcohol ether sulfate and aliphatic alcohol sulfate.Non-limiting example is lauryl sulphur Sour ammonium, cocoyl ammonium sulfate, lauryl potassium sulfate, cocoyl potassium sulfate, NaLS, lauryl sodium sulfate, 12 Alkylsurfuric acid ammonium, sodium cocosulfate, lauryl sulfate monoethanolamine, cocoyl diethanolamine, lauryl sulfate diethyl Hydramine, triethanolamine lauryl sulfate, lauryl sulfate triethylamine and its mixture, particularly preferably Texapon Special, NaLS, polyoxyethylene lauryl ether ammonium sulfate, polyoxyethylene lauryl ether ammonium sulfate, polyoxyethylene lauryl ether sulphur Sour sodium, polyoxyethylene lauryl ether potassium sulfate, polyoxyethylene lauryl ether diethanolamine, polyoxyethylene lauryl ether sulfuric acid Diethanol amine, polyoxyethylene lauryl ether sulfuric acid triethanolamine, polyoxyethylene lauryl ether sulfuric acid triethylamine and its mixture.Sulphur The example of the anion surfactant of hydrochlorate includes such as tridecyl benzene sulfonate, neopelex, lauryl Sulfosuccinate etc..The example of sarcosine and sarcosine derivative includes sodium lauryl sarcosinate, cocoyl sarcosine, cocounut oil Base sarcosine and its mixture, wherein it is preferred that sodium lauryl sarcosinate.
Be suitable for the invention it is low stimulation cosmetic composition for massage amphoteric surfactant be it is known in the art that Those can be used for the substance in skin nursing, as described in following patent document：United States Patent (USP) 5,104,646, United States Patent (USP) 5, 106,609.These amphoteric surfactantes include the surfactant of secondary aliphatic amine and tertiary amines derived object, wherein the fat Race's group can be the group of linear chain or branched chain, and one in the aliphatic group can contain about 8-18 carbon atom, Another may include a kind of anionic hydrophilic group such as carboxyl, sulfonic acid with, sulfate radical, phosphate radical or phosphonate radical.Suitable for this The amphoteric surfactant of invention further includes the surface-active of the derivative as aliphatic quaternary ammonium, quaternary phosphines and season sulfonium compound Agent, one of aliphatic group contain about 8-18 carbon atom, another may include a kind of anionic hydrophilic group such as carboxylic Base, sulfonic acid with, sulfate radical, phosphate radical or phosphonate radical.Preferably betaines zwitterionic compound, including alkyl betaines Alkali, sulfobetaines, amidoalkyl betaine, amidosulfo betaines, hydroxyl sulfo betaine and its mixture, especially It is cocoamidopropyl, Cocamidopropyl hydroxyl sulfo betaine, coco dimethyl carboxymethyl glycine betaine, coconut palm Oily dimethyl sulfopropyl betaine, stearyl dimethyl sulfopropyl glycine betaine.
It is known in this field to be suitable for the invention the nonionic surfactant of low stimulation cosmetic composition for massage , such as the compound with hydrophobic group and hydrogen atoms, such as the polyoxyethylene ether of alkyl phenol, aliphatic alcohol polyethenoxy Ether, span classes, tween classes etc..Particularly preferred nonionic surfactant is hydrogenated castor oils, especially PEG-40 hydrogenations Castor oil.
II.Optional components
The low stimulation cosmetic composition for massage of the present invention can also within the scope of the effect of the invention optionally Including one or more in following components.These components include activating agent, adjuvant, additive etc., such as activating agent（Such as Antiseptic, anti-acne activating agent, vitamin, anti wrinkling agent, anti-skin atrophy and skin repair activating agent, skin barrier repairing activity Agent, the smooth activating agent of non-steroidal cosmetic, skin lightening agent, sun-screening agent, sebum inhibitor, antioxidant etc.）, moisturizer, viscosity tune Save agent and thickener, pH adjusting agent, dyestuff, organic solvent or diluent, freshener, essence and pigment etc..These components and Its amount can suitably be selected according to the actual needs of product, and be added in the composition of the present invention.
Antiseptic includes antibacterial agent and antifungal activity agent, such as Beta-lactam medicine, quinolone medicine, the third sand of ring Star, Norfloxacin, tetracycline, erythromycin, triclosan etc..
Anti-acne activating agent can be used for being effectively treated Disseminated acne, the chronic disease of pilosebaceous follicle.Useful anti-powder The non-limiting example for piercing activating agent includes keratolytic, such as salicylic acid, 5- MEXORYL SAMs and 4- methoxyl group water The salicyclic acid derivatives of poplar acid；Resorcinol；Retinol and its derivative；The D- and l-amino acid and its derivative of sulfur-bearing and Salt, especially its N- acetyl derivative.
Anti-wrinkle, anti-skin atrophy and skin repair activating agent can be used for supplement or the recovery of epidermis.By promote and It keeps excoriative and accepts as unavoidable process, these activating agents usually can provide required skin nursing effect, these activating agents Non-limiting example includes vitamin, minerals and skin-nourishing object, such as vitamin A. D. E and K, vitamin C；Magnesium, calcium, Copper, zinc and other metals；Retinene, retinol, retinyl ester such as retinoic acid ester, retinyl palmitate and Vitamin A propionate Retinyl ester；Vitamin B complex compound（Such as niacinamide and niacin）；Etc..
Skin barrier repairing activity agent is the skin care active that those can repair and supplement the natural water-proof function of epidermis Agent.The non-limiting example of skin barrier repairing activity agent includes lipoid, such as cholesterol described in European patent 556957, Ceramide, sucrose ester and quasi- ceramide；Ascorbic acid；Biotin；Phosphatide；Etc..
The smooth activating agent of non-steroidal cosmetic can be effectively used for preventing or treating scytitis.It can enhance skin appearance benefit Place, such as can help to more uniform acceptable skin quality and color.The smooth activating agent of non-steroidal cosmetic it is non-limiting Example includes propanoic derivatives, acetogenin, fenamic acid derivatives etc..
Skin lightening agent can reduce the amount of melanin in skin, or provide this effect by other mechanism.It can be used for this hair The non-limiting example of skin lightening agent in bright include aloe extract, Alpha-Glyceryl-L- ascorbic acid, ammonium lactate, glycolic, Hydroquinone, 4-hydroxyanisol etc..
Sun-screening agent can provide sun-proof result for skin.Various sun-screening agents be disclosed in such as United States Patent (USP) 5087445, 5073372, in 5073371 etc..The non-limiting example of the sun-screening agent of composition for use in the present invention is octyl methoxyl base meat Cinnamic acid ester and butyl methoxy benzoylmethane, 2- Parsol MCXs, 2- ethylhexyls-N, N- diformazan Base P aminobenzoates, p-aminobenzoic acid, 2-PHENYLBENZIMIDAZOLE-5-SULFONIC ACID, oxybenzone etc..
The sebum that sebum inhibitor can be used for reducing sebaceous glands generates.The non-limiting example packet of available sebum inhibitor Include hydroxy Al chloride, corticosteroid, dehydroactic acid and its salt, dichlorophenyl imidazoles dioxolanes etc..
The non-limiting example of antioxidant includes workable ascorbic acid and its salt, aliphatic acid ascorbic acid, anti-bad Hematic acid derivative（Such as magnesium ascorbyl phosphate, STAY-C 50, sorbic acid acid ascorbyl ester）, tocopherol, tocopherol Acetic acid esters, other esters of tocopherol, butylated hydroxybenzoic acid and its salt, 6- hydroxyl -2,5,7,8- tetramethyl benzo dihydros Pyrans -2- carboxylic acids（It is sold with trade name " Trolox "）, gallic acid and its Arrcostab（Especially propylgallate）, uric acid And its salt and Arrcostab, sorbic acid and its salt, lipoic acid, amine（Such as N, N- diethylhydroxylamine, aminoguanidine）, sulfhydryl compound （Such as glutathione）, Dihydroxyfumaric acid and its salt, arginine glycine betaine, nordihydroguaiaretic acid, flavonoids, rely ammonia Acid, proline, silymarin, grape skin extract, Rosmarinus officinalis extract.
For the present invention low stimulation cosmetic composition for massage optional viscosity modifier and thickener usually with In low stimulation cosmetic composition for massage of the effective quantity for the present invention so that overall viscosity is suitable for product purpose.It is this viscous The specific non-limiting example for spending conditioning agent and thickener includes sodium chloride, sodium sulphate and its mixture.
III production methods
The low stimulation cosmetic composition for massage of the present invention can be by any known or other be effectively adapted to provide for Prepared by the technology of cosmetic composition for massage, massaged on condition that resulting composition provides low stimulation as described in the present invention Performance.The method for preparing the low stimulation cosmetic composition for massage of the present invention includes conventional preparation and hybrid technology.For example, The method as described in United States Patent (USP) 5837661 can be referred to.
IV application methods
On the other hand, the present invention also provides a kind of method massaged skin, the method includes to skin Using the low stimulation cosmetic composition for massage of a effective amount of present invention.Specifically, the low stimulation massage of the present invention Cosmetic compositions are used with the usual manner of massaging skin.
V purposes
The invention further relates to purposes of the low stimulation cosmetic composition for massage in preparing skin massaging product.This Invention further relates to modified cellulose for mitigating cosmetic composition for massage to the scratch sense of skin or the purposes of tingling sensation.This Inventors discovered through research that modified cellulose can effectively mitigate scratch sense or shouting pain of the cosmetic composition for massage to skin Sense or even a small amount of modified cellulose can bring significant effect.Present inventors have further discovered that containing granule for massage In cosmetic composition for massage product, by modified cellulose with emollient and surfactant package, it can be achieved that significantly improving User experience：Granular sensation obviously weakens, and has apparent lubrication and skin softening effect, is significantly reduced to the tingling sensation of skin, to skin The irritation of skin also reduces.
Embodiment
It is the non-limiting example of the low stimulation cosmetic composition for massage of the present invention below.These embodiments provide It is solely for the purpose of illustration, and should not be construed as limitation of the invention.It will be understood by those skilled in the art that can not depart from On the basis of the spirit and scope of the present invention, many changes and adjustment are carried out to the present invention.In the specification and following of the present invention In example, unless stated otherwise, all concentration is all weight percent.
Embodiment 1-4
Following example 1-4 is related to the low stimulation cosmetic composition for massage with different granule for massage.Specifically, Embodiment 1-4 is related separately to salt grain (NaCl), sugared grain (sucrose), cellulose family inclusion enclave（Main group is as cellulose, dimension life Element）With agar inclusion enclave（Main group is as agar, pigment）The composition of granule for massage existing for form.Concrete composition is seen below Table.Salt used is purchased from Tianjin Development Zone sea light chemical pharmaceutical factory, 50 μm~3mm of grain size.
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4
NaCl 70.0 - - -
Sucrose - 70.0 - -
Cellulose family inclusion enclave - - 70.0 -
Agar inclusion enclave - - - 70.0
Carboxymethyl cellulose 0.45 0.45 0.45 0.45
Glycerine 2.4 2.4 2.4 2.4
Cremophor RH40 0.45 0.45 0.45 0.45
Essence In right amount In right amount In right amount In right amount
Water In right amount In right amount In right amount In right amount
Preparation method：
1）Modified cellulose is added in glycerine and is stirred, fully soaks, then adds it in water under fast stirring It is complete to swelling（Transparent colloid is without solid particle）, obtain base-material；
2）Stirring in Cremophor RH40 is added in essence to be then added in base-material, then thereto to uniform Granule for massage and remaining water is added, is stirred for uniform.
In addition, being prepared for the composition in following embodiment by this technique.
Embodiment 5-8
Following example 5-8 is related to the low stimulation cosmetic composition for massage with different modified celluloses.It is specific and Speech, embodiment 5-8 are related separately to containing methylcellulose, carboxymethyl cellulose, hydroxyethyl cellulose and hydroxypropyl methyl fiber The composition of the modified cellulose of prime form.These modified celluloses are solid-state fine powder, under the conditions of intensively stirred Clear viscous gel is formed after being dissolved in water.
Embodiment 9-15
Following example 9-15 is related to the low stimulation cosmetic composition for massage with different surfaces activating agent.It is specific and Speech, following example 9-15 relate separately to anion surfactant（Laureth sodium sulfovinate, laruyl alcohol sodium sulfovinate, Amphoteric surfactant（Lauroylamidopropyl betaine, lauryl hydroxyl sulfo betaine）And nonionic surfactant （Tween60, Span60, PEG-40 rilanit special）.
Embodiment 16-20
Following example 1 6-20 is related to the low stimulation cosmetic composition for massage with different emollients.Specifically, The emollient that following example 1 6-20 is related separately to is PEG-50 sher butters, apricot kernel oil PEG-8 esters, double-PEG-15 methyl Ether dimethyl silicone polymer, PEG/PPG-25/25 dimethyl silicone polymers, hydrolysis Jojoba esters etc..
Embodiment 21-24
Following example 2 1-24 is related to the low stimulation cosmetic composition for massage with different NaCl contents.It is specific and Speech, the NaCl contents that following example 2 1-24 is related separately to are：30.0%, 50.0 %, 70.0% and 90.0%.
Embodiment 21 Embodiment 22 Embodiment 23 Embodiment 24
NaCl 30.0 50.0 70.0 90.0
Carboxymethyl cellulose 0.45 0.45 0.45 0.45
Glycerine 2.4 2.4 2.4 2.4
Cremophor RH40 0.45 0.45 0.45 0.45
Essence In right amount In right amount In right amount In right amount
Water In right amount In right amount In right amount In right amount
Preferred embodiment 25
Exemplary preferred embodiment of the following example 25 as the present invention is provided.Meanwhile being prepared for product as a comparison Comparative example, difference does not only contain carboxymethyl cellulose in it compared with the product of embodiment 25.
Effect assessment
Estimation flow
It every time before assessment product, is first washed one's hands with mild shower cream, is begun the evaluation at again after hand is 3 minutes dry.
1）Evaluate appearance, smell and viscosity
1.1 pour into 10ml products in 50ml beakers the appearance for observing product, and hear perfume (or spice)；
1.2 are soaked hand with 38 degree of warm water；
1.3 overturning wrists remove water extra on hand in 3 seconds（It not swing one's arm）；
1.4 take 1ml products in the palm of the hand, do not add water it is in one's hands in, both hands are looped rubbing 15s（60bpm）, so as to
Spreadability is evaluated,
Evaluate the skin sense during rubbing；
2）Continue rubbing both hands of quickly looping, the back of the hand is also rubbed with the hands and arrived（The palm of the hand 5 seconds, left hand are carried on the back 5 seconds, and the right hand is carried on the back 5 seconds, 180bpm）
The second assessment foam；
3）With 38 degree of warm water washing both hands；
After punching 10 seconds, skin sense is evaluated；
Front and back rubbing both hands 10s（60bpm）；
4）With towel both hands；
5）It waits for 10 seconds, after hand is dry, evaluates skin sense at once；
Touch the back of the hand 10s（45bpm）；
6）Skin sense is evaluated after 3 minutes；
Touch the back of the hand 10s（45bpm）.
Each sample is washed by 12 people examination, is respectively washed twice, i.e. 24 person-times/sample.Comparing result is as shown in the table：
The evaluation result of embodiment 5-8：
As can be seen from the above table, compared with other modified celluloses, use carboxymethyl cellulose so that product in all respects It performs better than.
The evaluation result of embodiment 16-20：
As can be seen from the above table, compared with other emollients, make product using PEG/PPG-25/25 dimethyl silicone polymers It performs better than in all respects.
The evaluation result of embodiment 21-24：
As can be seen from the above table, when NaCl contents are 70.0%, product performs better than in all respects.
The evaluation result of embodiment 25 and the evaluation result of comparative example：
As can be seen from the above results, it compared with the product for not containing modified cellulose in the prior art, is preferably implemented Example 25 significantly reduces the tingling sensation of skin, and has better product texture and more moist overall process use feeling.

Claims (14)

1. a kind of low stimulation skin massaging product, it includes following components by weight：
A) 50.0~90.0% granule for massage；
B) 0.1~5.0% modified cellulose；
C) 0.1~20.0% emollient；
D) 0.1~10.0% surfactant；With
E) suitable water,
The wherein described granule for massage be any one of sodium chloride, sodium carbonate, sodium bicarbonate, sodium sulphate, niter cake and sugar or Its any mixture and the emollient are PEG-50 sher butters, apricot kernel oil PEG-8 esters, double-PEG-15 methyl ethers are poly- Any one of dimethyl siloxane, PEG/PPG-25/25 dimethyl silicone polymers, hydrolysis Jojoba esters or its arbitrary mixing Object, and the modified cellulose is selected from the group of alkylcellulose, hydroxyalkyl cellulose ether, carboxyl alkyl cellulose ether.
2. low stimulation skin massaging product according to claim 1, wherein the content of the granule for massage be 50.0~ 80.0%.
3. low stimulation skin massaging product according to claim 1 or 2, wherein the content of the modified cellulose is 0.3 ~3.0%.
4. low stimulation skin massaging product according to claim 1 or 2, wherein the content of the emollient be 1.0~ 20.0%.
5. low stimulation skin massaging product according to claim 1 or 2, wherein the content of the surfactant is 0.3 ~5.0%.
6. the low stimulation skin massaging product stated according to claims 1 or 2, wherein the modified cellulose be methylcellulose, Any one of ethyl cellulose, carboxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl methyl cellulose or its arbitrary mixing Object.
7. low stimulation skin massaging product according to claim 1 or 2, wherein the surfactant is anionic surface Any one of activating agent, amphoteric surfactant, nonionic surfactant or its any mixture.
8. low stimulation skin massaging product according to claim 7, wherein the anion surfactant is fatty alcohol Any one of polyethers sulfate, aliphatic alcohol sulfate or its any mixture；The amphoteric surfactant is selected from glycine betaine Class；The nonionic surfactant is selected from hydrogenated castor oils.
9. low stimulation skin massaging product according to claim 1, it includes by weight following components or by by weight Following components composition：
A) 70.0% NaCl；
B) 0.45% carboxymethyl cellulose；
C) 2.4% glycerine；
D) 5.0% PEG/PPG-25/25 dimethyl silicone polymers；
E) 0.45% Cremophor RH40；With
F) suitable water.
10. low stimulation skin massaging product according to claim 1 or 2 also includes suitable essence.
11. low stimulation skin massaging product according to claim 1 or 2, for the form of massage scrub cream.
12. low stimulation skin massaging product according to claim 1 or 2 also includes one kind or more in following components Kind：Antibacterial agent and antifungal agent, anti-acne activating agent, vitamin, anti wrinkling agent, anti-skin atrophy and skin repair activating agent, The agent of skin barrier repairing activity, the smooth activating agent of non-steroidal cosmetic, skin lightening agent, sun-screening agent, sebum inhibitor, antioxidant, Moisturizer, viscosity modifier, pH adjusting agent, dyestuff, organic solvent or diluent, freshener, essence and pigment.
13. low stimulation skin massaging product according to claim 12, wherein the viscosity modifier is thickener.
14. a kind of method of massaging skin includes the low stimulation to any one of a effective amount of claim 1 to 13 of dermal administration Skin massaging product.
CN201310203812.1A 2013-05-28 2013-05-28 Low-irritation skin massage product Expired - Fee Related CN104173203B (en)

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CN107648060A (en) * 2017-09-24 2018-02-02 长沙华晨生物科技有限公司 A kind of facial mask without preservative
CN107929096A (en) * 2017-11-02 2018-04-20 宁波凯斯宝玛卫厨有限公司 A kind of mildy wash
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