CN104161041A - Bactericidal composition containing amino-oligosaccharin and hexaconazole - Google Patents
Bactericidal composition containing amino-oligosaccharin and hexaconazole Download PDFInfo
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- CN104161041A CN104161041A CN201410388895.0A CN201410388895A CN104161041A CN 104161041 A CN104161041 A CN 104161041A CN 201410388895 A CN201410388895 A CN 201410388895A CN 104161041 A CN104161041 A CN 104161041A
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- amino
- oligosaccharide
- azoles alcohol
- bactericidal composition
- hexaconazole
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- 239000000203 mixture Substances 0.000 title claims abstract description 28
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 17
- STMIIPIFODONDC-UHFFFAOYSA-N 2-(2,4-dichlorophenyl)-1-(1H-1,2,4-triazol-1-yl)hexan-2-ol Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(O)(CCCC)CN1C=NC=N1 STMIIPIFODONDC-UHFFFAOYSA-N 0.000 title abstract description 7
- 239000000375 suspending agent Substances 0.000 claims abstract description 18
- 239000004480 active ingredient Substances 0.000 claims abstract description 5
- 229920001542 oligosaccharide Polymers 0.000 claims description 55
- 150000003851 azoles Chemical class 0.000 claims description 52
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 51
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
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- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 241000235349 Ascomycota Species 0.000 description 3
- 241000221198 Basidiomycota Species 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 241000233866 Fungi Species 0.000 description 3
- 229920001732 Lignosulfonate Polymers 0.000 description 3
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 3
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- 229940082509 xanthan gum Drugs 0.000 description 3
- OILXMJHPFNGGTO-UHFFFAOYSA-N (22E)-(24xi)-24-methylcholesta-5,22-dien-3beta-ol Natural products C1C=C2CC(O)CCC2(C)C2C1C1CCC(C(C)C=CC(C)C(C)C)C1(C)CC2 OILXMJHPFNGGTO-UHFFFAOYSA-N 0.000 description 2
- RQOCXCFLRBRBCS-UHFFFAOYSA-N (22E)-cholesta-5,7,22-trien-3beta-ol Natural products C1C(O)CCC2(C)C(CCC3(C(C(C)C=CCC(C)C)CCC33)C)C3=CC=C21 RQOCXCFLRBRBCS-UHFFFAOYSA-N 0.000 description 2
- OQMZNAMGEHIHNN-UHFFFAOYSA-N 7-Dehydrostigmasterol Natural products C1C(O)CCC2(C)C(CCC3(C(C(C)C=CC(CC)C(C)C)CCC33)C)C3=CC=C21 OQMZNAMGEHIHNN-UHFFFAOYSA-N 0.000 description 2
- 241000255789 Bombyx mori Species 0.000 description 2
- 208000035240 Disease Resistance Diseases 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- DNVPQKQSNYMLRS-NXVQYWJNSA-N Ergosterol Natural products CC(C)[C@@H](C)C=C[C@H](C)[C@H]1CC[C@H]2C3=CC=C4C[C@@H](O)CC[C@]4(C)[C@@H]3CC[C@]12C DNVPQKQSNYMLRS-NXVQYWJNSA-N 0.000 description 2
- 230000002528 anti-freeze Effects 0.000 description 2
- 229960000892 attapulgite Drugs 0.000 description 2
- 239000003899 bactericide agent Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 210000000170 cell membrane Anatomy 0.000 description 2
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- 238000005516 engineering process Methods 0.000 description 2
- DNVPQKQSNYMLRS-SOWFXMKYSA-N ergosterol Chemical compound C1[C@@H](O)CC[C@]2(C)[C@H](CC[C@]3([C@H]([C@H](C)/C=C/[C@@H](C)C(C)C)CC[C@H]33)C)C3=CC=C21 DNVPQKQSNYMLRS-SOWFXMKYSA-N 0.000 description 2
- 230000014509 gene expression Effects 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- 230000006698 induction Effects 0.000 description 2
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- 231100000419 toxicity Toxicity 0.000 description 2
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- 239000000080 wetting agent Substances 0.000 description 2
- LYCAIKOWRPUZTN-NMQOAUCRSA-N 1,2-dideuteriooxyethane Chemical compound [2H]OCCO[2H] LYCAIKOWRPUZTN-NMQOAUCRSA-N 0.000 description 1
- 241001530056 Athelia rolfsii Species 0.000 description 1
- 108010022172 Chitinases Proteins 0.000 description 1
- 102000012286 Chitinases Human genes 0.000 description 1
- 108010001682 Dextranase Proteins 0.000 description 1
- 241000221785 Erysiphales Species 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 206010039509 Scab Diseases 0.000 description 1
- 229930182558 Sterol Natural products 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 238000005842 biochemical reaction Methods 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000017858 demethylation Effects 0.000 description 1
- 238000010520 demethylation reaction Methods 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000004720 fertilization Effects 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000003641 microbiacidal effect Effects 0.000 description 1
- 230000007269 microbial metabolism Effects 0.000 description 1
- 229940124561 microbicide Drugs 0.000 description 1
- 239000002855 microbicide agent Substances 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 230000035479 physiological effects, processes and functions Effects 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
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- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000820 toxicity test Toxicity 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a bactericidal composition containing amino-oligosaccharin and hexaconazole. The hexaconazole and amino-oligosaccharin are taken as active ingredients, and the weight ratio of the hexaconazole to amino-oligosaccharin is (20:1)-(1:8). The bactericidal composition is prepared into wettable powder or suspending agent, is used for controlling fungous diseases of crops and is obvious in synergistic effect, the control efficiency can be improved, the agricultural cost is reduced, the disease drug resistance is delayed, and the production requirement on agriculture is met.
Description
Technical field
The present invention relates to a kind of microbicide compositions, be specifically related to the bactericidal composition containing own azoles alcohol and amino-oligosaccharide.
Background technology
Own azoles alcohol, belongs to azoles fungicide, sterol demethylation inhibitor, and the disease that fungi especially Basidiomycota and Ascomycota are caused has protection and the therapeutic action of broad spectrum activity.Destroy and stop the biosynthesis of the cell membrane important composition composition ergosterol of germ, cause cell membrane not form, make germ death.There is interior suction, protection and therapeutic activity.Can effectively prevent and treat disease due to sac fungi, basidiomycetes and imperfect fungus, the disease especially Basidiomycetes and Ascomycetes being caused has excellent protection and eradicant action as powdery mildew, rust, scab, brown spot, anthracnose etc.
Amino-oligosaccharide is a kind of bactericide with resistant effect that microbial metabolism is extracted, growth to some germ has inhibitory action, as affect fungi steamed stuffed bun sprout, bringing out mycelia form morphs, in the born of the same parents of mycelia, biochemical reaction changes etc., the mechanism that inducing plant produces disease resistance is mainly to excite gene expression in plants, generation has chitinase, dextranase, guarantor's element and the PR albumen etc. of antibacterial action, there is the gene expression that suppresses germ simultaneously, the Physiology and biochemistry of mycelia is morphed, growth is suppressed, simultaneously can also stimulating growth.
This year, rice sheath blight disease generation was comparatively serious, and not plump paddy rate is increased, and thousand kernel weight reduces, general underproduction 5%-10%, seriously can reach 50%-70%, along with the popularization of short bar Multi spike cultivar, the raising of Planting Densities and Fertilization Level, has become an outstanding problem of rice high yield stable yields.Rice sheath blight disease mainly relies on for many years jinggangmeisu and prevents and treats, and makes disease produce larger pesticide resistance, causes dosage to strengthen, and preventive effect reduces.It is obvious that the control of rice sheath blight disease lacks synergistic effect, and cost is lower, the composition of medicine that the lasting period is grown.
Summary of the invention
Technical problem to be solved by this invention is, provides a kind of synergistic effect remarkable, can improve preventive effect, reduce agricultural cost, and delay the bactericidal composition containing amino-oligosaccharide and own azoles alcohol mixture that disease drug resistance produces, to meet the upper needs of producing of agricultural.
The present invention solves the problems of the technologies described above taked technical scheme: containing the bactericidal composition of amino-oligosaccharide and own azoles alcohol, taking own azoles alcohol and amino-oligosaccharide as active ingredient, the weight ratio of own azoles alcohol and amino-oligosaccharide is 20:1～1:8.
Above-mentioned bactericidal composition is prepared into wetting powder or suspending agent.
The adjuvant using in composition of the present invention comprises that dispersant, wetting agent, antifreeze, defoamer, thickener, carrier or other are of value to the material of active ingredient stable and drug effect performance in preparation, is all conventional in pesticidal preparations or allows the various compositions that use.
Described dispersant is selected from one or more in polycarboxylate, lauryl sodium sulfate, lignosulfonates, polyoxyethylene carboxylate, alkylphenol polyoxyethylene, neopelex, sodium hydroxyethyl cellulose, alkylnaphthalene sulfonate.
Described wetting agent is selected from one or more in spaonin powder, silkworm excrement or soapberry powder; Described antifreeze is selected from one or more in ethylene glycol, propane diols or glycerine; Described defoamer is selected from one or more of silicone oil, silicone compound, C10-20 saturated fat acid compounds.
Described thickener is selected from one or more of xanthan gum, polyvinyl alcohol, polyethylene glycol.
Described carrier is selected from one or more in kaolin, white carbon, attapulgite, deionized water.
Bactericidal composition provided by the present invention has the following advantages:
1, can overcome shortcoming, the scope of application that can widen medicament, the prolongation lasting period that single dose easily produces resistance, improve drug effect;
2, not only kept the many merits of bactericide, and the reduction of the dosage of mixture, drug effect significantly improves, and has reduced production cost;
3, bactericidal composition of the present invention has obvious synergistic effect after composite, can delay the pesticide resistance of germ, and rice sheath blight disease is had to good control efficiency.
4, bactericidal composition compatibility of the present invention and reasonable mixture ratio, can alleviate the toxic action to various natural enemies greatly, and the infringement to ecotope and less pollution, be conducive to protect person poultry safety.
Embodiment
In order to find the medicament desirable to rice sheath blight disease field efficacy, the characteristic that the present invention is based on own azoles alcohol and amino-oligosaccharide is further studied, inventor finds and proves to carry out composite taking own azoles alcohol and amino-oligosaccharide as active ingredient, make deposits yields disease resistance in amino-oligosaccharide induction, and prevent on basis that pathogen develops immunity to drugs, the characteristic of further utilizing own azoles alcohol to there is destruction and stop the biosynthesis of germ ergosterol to form, can produce obvious cooperative synergism effect preventing and treating in rice sheath blight disease, aspect other disease control, be mainly also to improve the control efficiency of own azoles alcohol and the prevention and treatment range of expansion disease by the induction of amino-oligosaccharide, reduce dosage, reduce use cost.
Below in conjunction with concrete example, technical scheme of the present invention and technique effect are described further, the percentage in embodiment is all weight percentage.
The method that the present invention adopts Toxicity Determination and field trial to combine.First by Toxicity Determination, the synergy ratio after clear and definite two kinds of medicaments are composite by a certain percentage, on this basis, then carries out field trial.
Evaluate the synergistic effect of pharmacy mix according to the co-toxicity coefficient method (CTC) of SunJohnson (1960), be that CTC≤80 are antagonism, 80<CTC<120 is summation action, and CTC >=120 are synergistic effect.
Table one: own azoles alcohol, amino-oligosaccharide and different proportioning thereof the toxicity test result to rice sheath blight disease
| Reagent agent | Proportioning | EC 50(mg/L) | Co-toxicity coefficient |
| Own azoles alcohol (A) | / | 1.1 | / |
| Amino-oligosaccharide (B) | / | 0.53 | / |
| A:B | 20:1 | 0.57 | 183.52 |
| A:B | 12:1 | 0.52 | 192.12 |
| A:B | 10:1 | 0.51 | 196.42 |
| A:B | 8:1 | 0.49 | 190.20 |
| A:B | 5:1 | 0.55 | 169.55 |
| A:B | 1:1 | 0.44 | 162.56 |
| A:B | 1:5 | 0.4 | 145.02 |
| A:B | 1:8 | 0.45 | 127.81 |
As seen from table, own azoles alcohol and amino-oligosaccharide co-toxicity coefficient within the scope of 20:1-1:8 is all greater than 120, and it has remarkable synergistic effect to rice sheath blight disease as seen.
The own azoles alcohol of embodiment 121% amino-oligosaccharide wetting powder
Own azoles alcohol 20%, amino-oligosaccharide 1%, polycarboxylate 8%, lauryl sodium sulfate 3%, spaonin powder 3%, kaolin supply 100%.Mix through air-flow crushing, make 21% own azoles alcohol amino-oligosaccharide wetting powder.
This formula is used for preventing and treating rice sheath blight disease, and using extension rate is 3000 times of sprayings, and after medicine, the preventive effect of 7 days is 86.5%.And the own azoles alcohol of single dose 20% wetting powder is pressed 1000 times of extension rates and 5% amino-oligosaccharide wetting powder by 1000 times of extension rates, uses the same method while using identical dose, after medicine, the preventive effect of 7 days is respectively 70.4% and 58.8%.
Embodiment 2
9% own azoles alcohol amino-oligosaccharide wetting powder
Own azoles alcohol 8%, amino-oligosaccharide 1%, polycarboxylate 5%, lauryl sodium sulfate 3%, white carbon 8%, kaolin supply 100%.Mix through air-flow crushing, make 9% own azoles alcohol amino-oligosaccharide wetting powder.
This formula is used for preventing and treating rice sheath blight disease, and using extension rate is 3000 times of sprayings, and after medicine, the preventive effect of 7 days is 71.3%.And the own azoles alcohol of single dose 8% wetting powder is pressed 1000 times of extension rates and 1% amino-oligosaccharide aqua by 1000 times of extension rates, uses the same method while using identical dose, after medicine, the preventive effect of 7 days is respectively 59.4% and 60.3%.The composite rear synergistic effect of own azoles alcohol and amino-oligosaccharide is obvious, to the preventive effect of banded sclerotial blight significantly better than single dose.
Embodiment 3
6% own azoles alcohol amino-oligosaccharide wetting powder
Own azoles alcohol 5%, amino-oligosaccharide 1%, silkworm excrement 5%, lignosulfonates 3%, white carbon 12%, attapulgite supply 100%.Mix through air-flow crushing, make 6% own azoles alcohol amino-oligosaccharide wetting powder.
This formula is used for preventing and treating rice sheath blight disease, and using extension rate is 2000 times of sprayings, and after medicine, the preventive effect of 7 days is 78.6%.And the own azoles alcohol of single dose 5% wetting powder is pressed 800 times of extension rates and 1% amino-oligosaccharide aqua by 800 times of extension rates, uses the same method while using identical dose, after medicine, the preventive effect of 7 days is respectively 56.3% and 46.9%.
Embodiment 4
15% own azoles alcohol amino-oligosaccharide wetting powder
Own azoles alcohol 10%, amino-oligosaccharide 5%, alkyl benzene sulfonate calcium salt 3%, lignosulfonates 5%, white carbon 10%, kaolin supply 100%.Mix through air-flow crushing, make 15% hexanol amino-oligosaccharide wetting powder.
This formula is used for preventing and treating rice sheath blight disease, and using extension rate is 3000 times of sprayings, and after medicine, the preventive effect of 7 days is 83.8%.And the own azoles alcohol of single dose 10% wetting powder is pressed 1000 times of extension rates and 5% amino-oligosaccharide wetting powder by 1000 times of extension rates, uses the same method while using identical dose, after medicine, the preventive effect of 7 days is respectively 62.8% and 61.7%.
Embodiment 5
13% own azoles alcohol amino-oligosaccharide suspending agent
Own azoles alcohol 12%, amino-oligosaccharide 1%, alkylphenol polyoxyethylene 2%, polyoxyethylene carboxylate 6%, DBSA 4%, silicone oil 0.1%, xanthan gum 0.3%, deionized water add to 100% and make 13% own azoles alcohol amino-oligosaccharide suspending agent.
This formula is used for preventing and treating rice sheath blight disease, and using extension rate is 3000 times of sprayings, and after medicine, the preventive effect of 7 days is 81.7%.And single dose 12% hexaconazole suspending agent is pressed 1000 times of extension rates and 1% amino-oligosaccharide suspending agent by 1000 times of extension rates, uses the same method while using identical dose, after medicine, the preventive effect of 7 days is respectively 67.8% and 61.3%.
Embodiment 6
2% own azoles alcohol amino-oligosaccharide suspending agent
Own azoles alcohol 1%, amino-oligosaccharide 1%, alkylphenol polyoxyethylene 2%, polyoxyethylene carboxylate 6%, DBSA 4%, silicone oil 0.1%, xanthan gum 0.3%, deionized water add to 100% and make 2% own azoles alcohol amino-oligosaccharide suspending agent.
This formula is used for preventing and treating rice sheath blight disease, and using extension rate is 2000 times of sprayings, and after medicine, the preventive effect of 7 days is 70.8%.And single dose 1% hexaconazole suspending agent is pressed 1000 times of extension rates and 1% amino-oligosaccharide aqua by 1000 times of extension rates, uses the same method while using identical dose, after medicine, the preventive effect of 7 days is respectively 61.3% and 57.4%.
Embodiment 7
6% own azoles alcohol amino-oligosaccharide suspending agent
Own azoles alcohol 1%, amino-oligosaccharide 5%, spaonin powder 2%, polyoxyethylene carboxylate 6%, neopelex 4%, sodium hydroxyethyl cellulose 0.1%, polyvinyl alcohol 0.4%, ethylene glycol 2%, deionized water add to 100% and make 6% own azoles alcohol amino-oligosaccharide suspending agent.
This formula is used for preventing and treating rice sheath blight disease, and using extension rate is 2000 times of sprayings, and after medicine, the preventive effect of 7 days is 73.5%.And single dose 1% hexaconazole suspending agent is pressed 800 times of extension rates and 5% amino-oligosaccharide suspending agent by 800 times of extension rates, uses the same method while using identical dose, after medicine, the preventive effect of 7 days is respectively 54.8% and 67.4%.
Embodiment 8
9% own azoles alcohol amino-oligosaccharide suspending agent
Own azoles alcohol 1%, amino-oligosaccharide 8%, soapberry powder 2%, polyoxyethylene carboxylate 6%, DBSA 4%, sodium hydroxyethyl cellulose 0.1%, polyvinyl alcohol 0.4%, glycerine 2%, deionized water add to 100% and make 9% own azoles alcohol amino-oligosaccharide suspending agent.
This formula is used for preventing and treating rice sheath blight disease, and using extension rate is 3000 times of sprayings, and after medicine, the preventive effect of 7 days is 71.5%.And the own azoles alcohol of single dose 1% wetting powder is pressed 1000 times of extension rates and 8% amino-oligosaccharide wetting powder by 1000 times of extension rates, uses the same method while using identical dose, after medicine, the preventive effect of 7 days is respectively 52.8% and 51.6%.
Embodiment 9
10% own azoles alcohol amino-oligosaccharide suspending agent
Own azoles alcohol 8%, amino-oligosaccharide 2%, soapberry powder 2%, polyoxyethylene carboxylate 6%, DBSA 4%, sodium hydroxyethyl cellulose 0.1%, polyvinyl alcohol 0.4%, glycerine 2%, deionized water add to 100% and make 10% own azoles alcohol amino-oligosaccharide suspending agent.
This formula is used for preventing and treating rice sheath blight disease, and using extension rate is 3000 times of sprayings, and after medicine, the preventive effect of 7 days is 82.5%.And the own azoles alcohol of single dose 8% wetting powder is pressed 1000 times of extension rates and 2% amino-oligosaccharide wetting powder by 1000 times of extension rates, uses the same method while using identical dose, after medicine, the preventive effect of 7 days is respectively 63.3% and 58.4%.
From above embodiment, can find out, cooperative synergism effect of the present invention is obvious, is all better than single dose, has improved diseases control rate, and rice sheath blight disease is had to good control efficiency.
Claims (2)
1. containing the bactericidal composition of amino-oligosaccharide and own azoles alcohol, it is characterized in that, taking own azoles alcohol and amino-oligosaccharide as active ingredient, the weight ratio of own azoles alcohol and amino-oligosaccharide is 20:1～1:8.
2. containing the bactericidal composition of amino-oligosaccharide and own azoles alcohol, it is characterized in that, described bactericidal composition is prepared into wetting powder or suspending agent.
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| CN201410388895.0A CN104161041B (en) | 2014-08-08 | 2014-08-08 | Containing the bactericidal composition of amino-oligosaccharide and own azoles alcohol |
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| CN201410388895.0A CN104161041B (en) | 2014-08-08 | 2014-08-08 | Containing the bactericidal composition of amino-oligosaccharide and own azoles alcohol |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104705324A (en) * | 2015-03-13 | 2015-06-17 | 黄业新 | Sterilizing composition containing zhongshengmycin and chitosan oligosaccharide |
| CN106172433A (en) * | 2016-07-25 | 2016-12-07 | 李祥英 | A kind of fluorine-containing thiazole pyrrole ethyl ketone and the composition pesticide of amino-oligosaccharide |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101816305A (en) * | 2010-05-09 | 2010-09-01 | 海南正业中农高科股份有限公司 | Bactericide pesticide composite containing oligochitosan |
| CN103947679A (en) * | 2014-05-15 | 2014-07-30 | 王和绥 | Pesticide for wheat pustulation period |
| CN103947668A (en) * | 2014-04-18 | 2014-07-30 | 北京明德立达农业科技有限公司 | Bactericidal composition and application thereof |
-
2014
- 2014-08-08 CN CN201410388895.0A patent/CN104161041B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101816305A (en) * | 2010-05-09 | 2010-09-01 | 海南正业中农高科股份有限公司 | Bactericide pesticide composite containing oligochitosan |
| CN103947668A (en) * | 2014-04-18 | 2014-07-30 | 北京明德立达农业科技有限公司 | Bactericidal composition and application thereof |
| CN103947679A (en) * | 2014-05-15 | 2014-07-30 | 王和绥 | Pesticide for wheat pustulation period |
Non-Patent Citations (2)
| Title |
|---|
| 刘天赵: ""5%氨基寡糖素水剂对晚稻纹枯病的防治研究"", 《广西植保》 * |
| 陈再廖: ""己唑醇等三唑类药剂防治水稻纹枯病的效果"", 《浙江农业科学》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104705324A (en) * | 2015-03-13 | 2015-06-17 | 黄业新 | Sterilizing composition containing zhongshengmycin and chitosan oligosaccharide |
| CN106172433A (en) * | 2016-07-25 | 2016-12-07 | 李祥英 | A kind of fluorine-containing thiazole pyrrole ethyl ketone and the composition pesticide of amino-oligosaccharide |
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| CN104161041B (en) | 2015-09-09 |
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