CN104119034A - Aqueous sand-based paint and preparation method thereof - Google Patents
Aqueous sand-based paint and preparation method thereof Download PDFInfo
- Publication number
- CN104119034A CN104119034A CN201310150055.6A CN201310150055A CN104119034A CN 104119034 A CN104119034 A CN 104119034A CN 201310150055 A CN201310150055 A CN 201310150055A CN 104119034 A CN104119034 A CN 104119034A
- Authority
- CN
- China
- Prior art keywords
- water
- sand
- base coating
- husky base
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention discloses an aqueous sand-based paint which comprises the following compositions by weight: 500-600 parts of 120-160 mesh sand, 200-300 parts of 60-80 mesh sand, 100-200 parts of 30-50 mesh sand, 25-40 parts of organosilicon modified styrene acrylic emulsion, 1.5-3 parts of cellulose, 0.5-2 parts of a multifunctional additive, 2-8 parts of ethylene glycol, 3-13 parts of a film-forming agent, 0.2-1 part of a thickening agent and 50-200 parts of water. The specifically proportional sand with different meshes is used as an aggregate of the aqueous sand-based paint to match with other materials, stain resistance and impact resistance are improved compared with a traditional paint, and the aqueous sand-based paint is strong in three-dimensional sense and good in simulation effect, and is more suitable for internal walls of buildings due to the rough feel.
Description
Technical field
The invention belongs to paint field, be specifically related to the husky base coating of a kind of water-based.
Background technology
At present, on the wall of some buildingss, spray stone-like coating to build the decorative effect that exactly likes marble, grouan etc., it is a kind of ideal material that substitutes lithotome decorative cover, can overcome the restriction that lithotome is subject to natural crystal, color and figure line heterogeneity after decorating, also cannot renovate exploitation processing difficulties, expensive shortcoming.The spraying effect of stone-like coating is solemnly elegant, the texture of enriching that can fully represent lithotome, there is extremely strong sticking power, high rigidity, rich texture, cost economic, good weathering resistance simultaneously, also have fire prevention, acid and alkali-resistance, anti-pollution, nontoxic, tasteless, adopt natural rubble to represent the long-term features such as texture attractive in appearance of the will never fade maintenance body of wall of color.But traditional stone-like coating has that effect is single, stereoscopic sensation is poor, surperficial vulnerable to pollution, easily be full of cracks, the poor shortcoming of weathering resistance.
Summary of the invention
In order to solve the problems of the technologies described above, the invention provides the husky base coating of a kind of water-based.
The husky base coating of water-based provided by the invention, the composition that contains following parts by weight:
Sand, 120 ~ 160 orders 500 ~ 600;
Sand, 60 ~ 80 orders 200 ~ 300;
Sand, 30 ~ 50 orders 100 ~ 200;
Organic-silicon-modified benzene emulsion 25 ~ 40;
Mierocrystalline cellulose 1.5 ~ 3;
Multifunctional assistant 0.5 ~ 2;
Ethylene glycol 2 ~ 8;
Film coalescence aid 3 ~ 13;
Thickening material 0.2 ~ 1;
Water 50 ~ 200.
Preferably, the husky base coating of described water-based also contains the composition of following parts by weight: sterilant 0.5 ~ 2.5.
Preferably, the husky base coating of above-mentioned water-based, the composition that contains following parts by weight:
Sand, 120 ~ 160 orders 530 ~ 580;
Sand, 60 ~ 80 orders 220 ~ 260;
Sand, 30 ~ 50 orders 130 ~ 170;
Organic-silicon-modified benzene emulsion 25 ~ 30;
Mierocrystalline cellulose 2 ~ 3;
Multifunctional assistant 1 ~ 1.5;
Ethylene glycol 3.5 ~ 6.5;
Film coalescence aid 3 ~ 7;
Thickening material 0.5 ~ 0.8;
Water 100 ~ 150.
Preferably, the SiO in described sand
2content is more than 75wt%.
Preferably, described sand is SiO
2content is 78wt%~85wt%.
As optimal technical scheme, described organic-silicon-modified benzene emulsion is prepared by the following method:
1) water intaking, vinylbenzene, methyl methacrylate, butyl acrylate, methacrylic acid, with response type organosilicon, Sodium dodecylbenzene sulfonate and Nonyl pheno, the reactive emulsifier of two keys, stir under room temperature, obtains pre-emulsion;
2) respectively sodium bicarbonate and Potassium Persulphate are made into the aqueous solution, preferably, the concentration of sodium bicarbonate and persulfate aqueous solution is 1 ~ 3%;
3) get 1/3 pre-emulsion, sodium hydrogen carbonate solution and 1/3 potassium persulfate solution mix, and heat 75 ~ 80 ℃, are not reacted to and reflux, and start to drip remaining pre-emulsion and remaining potassium persulfate solution, and cooling, with ammoniacal liquor adjust pH to 7 ~ 8, is filtered discharging.
Preferably, described Mierocrystalline cellulose is hydroxy ethyl fiber, Vltra tears or methylcellulose gum.Be preferably hydroxy ethyl fiber.
Preferably, described multifunctional assistant is multifunctional assistant AMP-95, multifunctional assistant HT-95 or multifunctional assistant DL-96.Be preferably multifunctional assistant AMP-95.
Preferably, described film coalescence aid is alcohol ester 12 film coalescence aid.
The preparation method who the invention provides the husky base coating of a kind of above-mentioned water-based, step is as follows:
According to the described Mierocrystalline cellulose that measures, be added to the water, after stirring, add multifunctional assistant, film coalescence aid, ethylene glycol, again stir, add organic-silicon-modified benzene emulsion, stir, sand adds successively according to the descending order of order number, stirs, and finally adds thickening material.
The present invention also provides the preparation method of the husky base coating of a kind of above-mentioned water-based, and step is as follows:
According to the described Mierocrystalline cellulose that measures, be added to the water, after stirring, add multifunctional assistant, sterilant, film coalescence aid, ethylene glycol, again stir, add organic-silicon-modified benzene emulsion, stir, sand adds successively according to the descending order of order number, stirs, and finally adds thickening material.
The present invention can reach following effect:
1, the sand of the different meshes of the designed specified proportion of the present invention becomes to coordinate with other as the aggregate of coating, all increase, and stereoscopic sensation is strong compared with the contamination resistance of traditional coating and shock-resistance, and simulated effect is good, and its harsh feeling is applicable to inner wall of building more.
2, the present invention finds to adopt SiO
2content, at the sand of 78wt%~85wt%, has obtained the husky base coating of effect excellence, and its stability, splitting resistance, weathering resistance etc. are all obviously better than existing coating.And because this sand can adopt the drift-sand in uneven desert, storehouse, be conducive to reduce costs (husky aboundresources), save quartz sand, and be conducive to desertification control.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described, can be implemented, but illustrated embodiment is not as a limitation of the invention so that those skilled in the art can better understand the present invention also.
In following examples, organic-silicon-modified benzene emulsion is prepared by the following method:
1) in reactor, add water 56g, vinylbenzene 40g, methyl methacrylate 5g, butyl acrylate 40g, methacrylic acid 5g, Sodium dodecylbenzene sulfonate 4.5g, Nonyl pheno 1.5g, SILICON-2(are with the response type organosilicon of two keys) 4g and reactive emulsifier (V-20S) 2g, under room temperature, stir, pre-emulsification 1h, obtains pre-emulsion.
2) respectively 0.2g sodium bicarbonate and 0.6g Potassium Persulphate are made into the aqueous solution of concentration 2%.
3), in the four-hole bottle of agitator, thermometer, prolong and dropping funnel is housed, add 1/3 pre-emulsion, 10g sodium hydrogen carbonate solution, 20g potassium persulfate solution.
4) heating is 75 ~ 80 ℃, is not reacted to and refluxes, and starts to drip remaining pre-emulsion and 40g potassium persulfate solution, and 3h drips off, and guarantees that pre-emulsion drips off prior to initiator potassium persulfate solution, and cooling, with ammoniacal liquor adjust pH to 7 ~ 8, is filtered discharging.
Medicine | Specification | The place of production |
Vinylbenzene | Chemical pure | Chemical Reagent Co., Ltd., Sinopharm Group |
Methyl methacrylate | Chemical pure | Chemical Reagent Co., Ltd., Sinopharm Group |
Butyl acrylate | Chemical pure | Chemical Reagent Co., Ltd., Sinopharm Group |
SILICON-2(is with the response type organosilicon of two keys) | Technical grade | The loyal Fine Chemical Co., Ltd in Shanghai |
Sodium dodecylbenzene sulfonate | Analytical pure | Chemical Reagent Co., Ltd., Sinopharm Group |
Nonyl pheno | Analytical pure | Chemical Reagent Co., Ltd., Sinopharm Group |
Reactive emulsifier (V-20S) | Technical grade | The loyal Fine Chemical Co., Ltd in Shanghai |
Potassium Persulphate | Analytical pure | Chemical Reagent Co., Ltd., Sinopharm Group |
Sodium bicarbonate | Chemical pure | Chemical Reagent Co., Ltd., Sinopharm Group |
Ammoniacal liquor | Chemical pure | Chemical Reagent Co., Ltd., Sinopharm Group |
Distilled water | Self-control | ? |
Embodiment 1
The component prescription of the husky base coating of water-based of the present embodiment is as follows:
Sand, 120 ~ 160 order 600g;
Sand, 60 ~ 80 order 280g;
Sand, 30 ~ 50 order 100g;
Organic-silicon-modified benzene emulsion 25g;
Vltra tears 1.5g;
Multifunctional assistant AMP-95 1g;
Ethylene glycol 8g;
Alcohol ester 12 film coalescence aid 8g;
Thickening material ASE-60 0.2g;
Water 150g.
Wherein, the drift-sand that the sand that the present embodiment is used is uneven desert, storehouse, after measured SiO in this drift-sand
2content is at 78wt%~85wt%.The drift-sand in uneven desert, storehouse is separated according to order number, standby.
The preparation method of the husky base coating of above-mentioned water-based:
Getting Natvosol is added to the water, stir 10min(rotating speed 500rad/min) after, add successively multifunctional assistant AMP-95, alcohol ester 12 film coalescence aid and ethylene glycol, stir 10min(rotating speed 800rad/min) after, then add silicone modified styrene-acrylate emulsion, stir 10 min(rotating speed 800rad/min), sand is added by the descending order of order number, and high-speed stirring 45 minutes (rotating speed 1000rad/min), finally adds thickening material, stir, obtain.
The overall performance of the husky base coating of water-based detects according to < < JG-T24-2000 SAND SLURRY SYNTHETIC EMULSION ARCHITECTURAL COATINGS > >, and result is as following table:
Shock-resistance: carry out with reference to the shock-resistant assay method of GB/T1732-93 paint film, test with QCJ type paint film impactor.
The husky base coating of water-based of the present embodiment: shock strength reaches 42 kg.cm,
Contamination resistance: undertaken by building coating coating contamination resistance experimental technique GB/T 9780-2005 regulation.
The husky base coating of water-based of the present embodiment, contamination resistance reaches 1 grade.
Abrasion resistance: GB/T 9266-1988 building coating abrasion resistance
The husky base coating of water-based of the present embodiment: abrasion resistance reaches more than 1000 times.
The husky base coating of the water-based properties of the present embodiment is good, and its harsh feeling is applicable to inner wall of building more, and after application, stereoscopic sensation is strong, sense of touch is true, simulated effect good.
Embodiment 2
The component prescription of the husky base coating of water-based of the present embodiment is as follows:
Sand, 120 ~ 160 order 530g;
Sand, 60 ~ 80 order 260g;
Sand, 30 ~ 50 order 150g;
Organic-silicon-modified benzene emulsion 30g;
Natvosol, molecular weight 60,000 2g;
Multifunctional assistant AMP-95 1g;
Ethylene glycol 5g;
Alcohol ester 12 film coalescence aid 7g;
Thickening material ASE-60 0.5g;
Sterilant C-15 1g;
Water 150g.
Wherein, sand is the drift-sand in uneven desert, storehouse, after measured SiO in this drift-sand
2content is at 78wt%~85wt%.The drift-sand in uneven desert, storehouse is separated according to order number, standby.
The preparation method of the husky base coating of above-mentioned water-based:
Getting Natvosol is added to the water, stir 10min(rotating speed 500rad/min) after, add successively multifunctional assistant AMP-95, sterilant C-15, alcohol ester 12 film coalescence aid and ethylene glycol, stir 10min(rotating speed 800rad/min) after, then add silicone modified styrene-acrylate emulsion, stir 10 min(rotating speed 800rad/min), sand is added by the descending order of order number, and high-speed stirring 45 minutes (rotating speed 1000rad/min), finally adds thickening material, stir, obtain.
The overall performance of the husky base coating of water-based detects according to < < JG-T24-2000 SAND SLURRY SYNTHETIC EMULSION ARCHITECTURAL COATINGS > >, and result is as following table:
Shock-resistance: carry out with reference to the shock-resistant assay method of GB/T1732-93 paint film, test with QCJ type paint film impactor.
The husky base coating of water-based of the present embodiment: shock strength reaches 52 kg.cm,
Contamination resistance: undertaken by building coating coating contamination resistance experimental technique GB/T 9780-2005 regulation.
The husky base coating of water-based of the present embodiment, contamination resistance reaches 1 grade.
Abrasion resistance: GB/T 9266-1988 building coating abrasion resistance.
The husky base coating of water-based of the present embodiment: abrasion resistance reaches more than 1500 times.
The husky base coating of the water-based properties of the present embodiment is good, and its harsh feeling is applicable to inner wall of building more, and after application, stereoscopic sensation is strong, sense of touch is true, simulated effect good.
Embodiment 3
The component prescription of the husky base coating of water-based of the present embodiment is as follows:
Sand, 120 ~ 160 order 580g;
Sand, 60 ~ 80 order 220g;
Sand, 30 ~ 50 order 130g;
Organic-silicon-modified benzene emulsion 25g;
Natvosol, molecular weight 60,000 3g;
Multifunctional assistant AMP-95 1.5g;
Ethylene glycol 6.5g;
Alcohol ester 12 film coalescence aid 3g;
Sterilant C-15 1.5g;
Thickening material ASE-60 0.2g;
Water 100g.
Wherein, sand is the drift-sand in uneven desert, storehouse, after measured SiO in this drift-sand
2content is at 78wt%~85wt%.The drift-sand in uneven desert, storehouse is separated according to order number, standby.
The preparation method of the husky base coating of above-mentioned water-based:
Getting Natvosol is added to the water, stir 10min(rotating speed 500rad/min) after, add successively multifunctional assistant AMP-95, alcohol ester 12 film coalescence aid, sterilant C-15 and ethylene glycol, stir 10min(rotating speed 800rad/min) after, then add silicone modified styrene-acrylate emulsion, stir 10 min(rotating speed 800rad/min), sand is added by the descending order of order number, and high-speed stirring 45 minutes (rotating speed 1000rad/min), finally adds thickening material, stir, obtain.
The overall performance of the husky base coating of water-based detects according to < < JG-T24-2000 SAND SLURRY SYNTHETIC EMULSION ARCHITECTURAL COATINGS > >, and result is as following table:
Shock-resistance: carry out with reference to the shock-resistant assay method of GB/T1732-93 paint film, test with QCJ type paint film impactor.
The husky base coating of water-based of the present embodiment: shock strength reaches 50 kg.cm,
Contamination resistance: undertaken by building coating coating contamination resistance experimental technique GB/T 9780-2005 regulation.
The husky base coating of water-based of the present embodiment, contamination resistance reaches 1 grade.
Abrasion resistance: GB/T 9266-1988 building coating abrasion resistance.
The husky base coating of water-based of the present embodiment: abrasion resistance reaches more than 1500 times.
The husky base coating of the water-based properties of the present embodiment is good, and its harsh feeling is applicable to inner wall of building more, and after application, stereoscopic sensation is strong, sense of touch is true, simulated effect good.
Embodiment 4
The component prescription of the husky base coating of water-based of the present embodiment is as follows:
Sand, 120 ~ 160 order 550g;
Sand, 60 ~ 80 order 200g;
Sand, 30 ~ 50 order 200g;
Organic-silicon-modified benzene emulsion 30g;
Vltra tears, molecular weight 60,000 2g;
Multifunctional assistant HT-95 2g;
Ethylene glycol 3.5g;
Alcohol ester 12 film coalescence aid 13g;
Sterilant C-15 0.5g;
Thickening material ASE-60 0.3g;
Water 80g.
Wherein, sand is the drift-sand in uneven desert, storehouse, after measured SiO in this drift-sand
2content is at 78wt%~85wt%.The drift-sand in uneven desert, storehouse is separated according to order number, standby.
The preparation method of the husky base coating of above-mentioned water-based:
Getting Vltra tears is added to the water, stir 10min(rotating speed 500rad/min) after, add successively multifunctional assistant HT-95,, sterilant C-15, alcohol ester 12 film coalescence aid and ethylene glycol, stir 10min(rotating speed 800rad/min) after, then add silicone modified styrene-acrylate emulsion, stir 10 min(rotating speed 800rad/min), sand is added by the descending order of order number, and high-speed stirring 45 minutes (rotating speed 1000rad/min), finally adds thickening material, stir, obtain.
The overall performance of the husky base coating of water-based detects according to < < JG-T24-2000 SAND SLURRY SYNTHETIC EMULSION ARCHITECTURAL COATINGS > >, and result is as following table:
Shock-resistance: carry out with reference to the shock-resistant assay method of GB/T1732-93 paint film, test with QCJ type paint film impactor.
The husky base coating of water-based of the present embodiment: shock strength reaches 41 kg.cm,
Contamination resistance: undertaken by building coating coating contamination resistance experimental technique GB/T 9780-2005 regulation.
The husky base coating of the present embodiment, contamination resistance reaches 1 grade.
Abrasion resistance: GB/T 9266-1988 building coating abrasion resistance.
The husky base coating of water-based of the present embodiment: abrasion resistance reaches more than 1000 times.
The husky base coating of the water-based properties of the present embodiment is good, and its harsh feeling is applicable to inner wall of building more, and after application, stereoscopic sensation is strong, sense of touch is true, simulated effect good.
Embodiment 5
The component prescription of the husky base coating of water-based of the present embodiment is as follows:
Sand, 120 ~ 160 order 510g;
Sand, 60 ~ 80 order 300g;
Sand, 30 ~ 50 order 150g;
Organic-silicon-modified benzene emulsion 28g;
Vltra tears, molecular weight 60,000 2g;
Multifunctional assistant AMP-95 0.5g;
Ethylene glycol 2g;
Alcohol ester 12 film coalescence aid 5g;
Sterilant C-15 2.5g;
Thickening material ASE-60 1g;
Water 200g.
Wherein, sand is the drift-sand in uneven desert, storehouse, after measured SiO in this drift-sand
2content is at 78wt%~85wt%.The drift-sand in uneven desert, storehouse is separated according to order number, standby.
The preparation method of the husky base coating of above-mentioned water-based:
Getting Vltra tears is added to the water, stir 10min(rotating speed 500rad/min) after, add successively multifunctional assistant AMP-95, alcohol ester 12 film coalescence aid, sterilant C-15 and ethylene glycol, stir 10min(rotating speed 800rad/min) after, then add silicone modified styrene-acrylate emulsion, stir 10 min(rotating speed 800rad/min), sand is added by the descending order of order number, and high-speed stirring 45 minutes (rotating speed 1000rad/min), finally adds thickening material, stir, obtain.
The overall performance of the husky base coating of water-based detects according to < < JG-T24-2000 SAND SLURRY SYNTHETIC EMULSION ARCHITECTURAL COATINGS > >, and result is as following table:
Shock-resistance: carry out with reference to the shock-resistant assay method of GB/T1732-93 paint film, test with QCJ type paint film impactor.
The husky base coating of water-based of the present embodiment: shock strength reaches 45 kg.cm,
Contamination resistance: undertaken by building coating coating contamination resistance experimental technique GB/T 9780-2005 regulation.
The husky base coating of water-based of the present embodiment, contamination resistance reaches 1 grade.
The husky base coating of water-based of the present embodiment: abrasion resistance reaches more than 1000 times.
The husky base coating of the water-based properties of the present embodiment is good, and its harsh feeling is applicable to inner wall of building more, and after application, stereoscopic sensation is strong, sense of touch is true, simulated effect good.
Comparative example 1
The component prescription of the coating of this comparative example is as follows:
Quartz sand, 700g;
Benzene emulsion 150g;
Natvosol 12g;
Multifunctional assistant 3g;
Ethylene glycol 6;
Film coalescence aid 15g;
Thickening material 0.05;
Water 130g
Wherein, the sand that this comparative example is used is Shijiazhuang Qing Ta board colorful quartz sands.
The preparation method of the husky base coating of above-mentioned water-based:
Getting Natvosol is added to the water, stir 10min(rotating speed 500rad/min) after, add successively multifunctional assistant AMP-95, alcohol ester 12 film coalescence aid and ethylene glycol, stir 10min(rotating speed 800rad/min) after, then add benzene emulsion, stir 10 min(rotating speed 800rad/min), add quartz sand, high-speed stirring 45 minutes (rotating speed 1000rad/min), finally adds thickening material, stir, obtain.
Overall performance detects according to < < JG-T24-2000 SAND SLURRY SYNTHETIC EMULSION ARCHITECTURAL COATINGS > >, and result is as following table:
Shock-resistance: carry out with reference to the shock-resistant assay method of GB/T1732-93 paint film, test with QCJ type paint film impactor.
The husky base coating of water-based of this comparative example: shock strength is 31 kg.cm,
Contamination resistance: undertaken by building coating coating contamination resistance experimental technique GB/T 9780-2005 regulation.
The husky base coating of water-based of this comparative example, contamination resistance reaches 2 grades.
Abrasion resistance: GB/T 9266-1988 building coating abrasion resistance
The husky base coating of water-based of this comparative example: abrasion resistance is 600 left and right.
The above embodiment is only the preferred embodiment for absolutely proving that the present invention lifts, and protection scope of the present invention is not limited to this.Being equal to that those skilled in the art do on basis of the present invention substitutes or conversion, all within protection scope of the present invention.Protection scope of the present invention is as the criterion with claims.
Claims (10)
1. the husky base coating of water-based, is characterized in that the composition that contains following parts by weight:
Sand, 120 ~ 160 orders 500 ~ 600;
Sand, 60 ~ 80 orders 200 ~ 300;
Sand, 30 ~ 50 orders 100 ~ 200;
Organic-silicon-modified benzene emulsion 25 ~ 40;
Mierocrystalline cellulose 1.5 ~ 3;
Multifunctional assistant 0.5 ~ 2;
Ethylene glycol 2 ~ 8;
Film coalescence aid 3 ~ 13;
Thickening material 0.2 ~ 1;
Water 50 ~ 200.
2. the husky base coating of water-based according to claim 1, is characterized in that, the husky base coating of described water-based also contains the composition of following parts by weight: sterilant 0.5 ~ 2.5.
3. the husky base coating of water-based according to claim 1, is characterized in that the composition that contains following parts by weight:
Sand, 120 ~ 160 orders 530 ~ 580;
Sand, 60 ~ 80 orders 220 ~ 260;
Sand, 30 ~ 50 orders 130 ~ 170;
Organic-silicon-modified benzene emulsion 25 ~ 30;
Mierocrystalline cellulose 2 ~ 3;
Multifunctional assistant 1 ~ 1.5;
Ethylene glycol 3.5 ~ 6.5;
Film coalescence aid 3 ~ 7;
Thickening material 0.5 ~ 0.8;
Sterilant 1 ~ 1.5
Water 100 ~ 150.
4. according to the husky base coating of the water-based described in claim 1 ~ 3 any one, it is characterized in that the SiO in described sand
2content is more than 75wt%.
5. the husky base coating of water-based according to claim 4, is characterized in that, described sand is SiO
2content is 78wt%~85wt%.
6. according to the husky base coating of the water-based described in claim 1 ~ 3 any one, it is characterized in that, described organic-silicon-modified benzene emulsion is prepared by the following method:
1) water intaking, vinylbenzene, methyl methacrylate, butyl acrylate, methacrylic acid, with response type organosilicon, Sodium dodecylbenzene sulfonate and Nonyl pheno, the reactive emulsifier of two keys, stir under room temperature, obtains pre-emulsion;
2) respectively sodium bicarbonate and Potassium Persulphate are made into the aqueous solution;
3) get 1/3 pre-emulsion, sodium hydrogen carbonate solution and 1/3 potassium persulfate solution mix, and heat 75 ~ 80 ℃, are not reacted to and reflux, and start to drip remaining pre-emulsion and remaining potassium persulfate solution, and cooling, with ammoniacal liquor adjust pH to 7 ~ 8, is filtered discharging.
7. according to the husky base coating of the water-based described in claim 1 ~ 3 any one, it is characterized in that, described Mierocrystalline cellulose is hydroxy ethyl fiber, Vltra tears or methylcellulose gum.
8. according to the husky base coating of water-based described in claim 1 ~ 3 any one, it is characterized in that, described multifunctional assistant is multifunctional assistant AMP-95, multifunctional assistant HT-95 or multifunctional assistant DL-96.
9. according to the husky base coating of water-based described in claim 1 ~ 3 any one, it is characterized in that, described film coalescence aid is alcohol ester 12 film coalescence aid.
10. the preparation method of the husky base coating of water-based claimed in claim 1, is characterized in that, step is as follows:
According to the described Mierocrystalline cellulose that measures, be added to the water, after stirring, add multifunctional assistant, film coalescence aid, ethylene glycol, again stir, add organic-silicon-modified benzene emulsion, stir, sand adds successively according to the descending order of order number, stirs, and finally adds thickening material.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310150055.6A CN104119034B (en) | 2013-04-26 | 2013-04-26 | Husky base coating of a kind of water-based and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310150055.6A CN104119034B (en) | 2013-04-26 | 2013-04-26 | Husky base coating of a kind of water-based and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104119034A true CN104119034A (en) | 2014-10-29 |
CN104119034B CN104119034B (en) | 2016-04-13 |
Family
ID=51764704
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201310150055.6A Expired - Fee Related CN104119034B (en) | 2013-04-26 | 2013-04-26 | Husky base coating of a kind of water-based and preparation method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN104119034B (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105295578A (en) * | 2015-11-30 | 2016-02-03 | 桂林市和鑫防水装饰材料有限公司 | Silicone-modified styrene-acrylic emulsion coating and preparation method thereof |
CN106082794A (en) * | 2016-06-28 | 2016-11-09 | 郭舒洋 | A kind of preparation method of the true mineral varnish of high durable |
CN112500725A (en) * | 2020-12-10 | 2021-03-16 | 深圳广田高科新材料有限公司 | Novel inorganic environment-friendly bone paste modeling paint and preparation method thereof |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002088215A2 (en) * | 2001-04-30 | 2002-11-07 | Basf Corporation, Please See General Appointment Of Representative | Sandable, self-healable coating compositions and a process of using the same |
CN102492085A (en) * | 2011-12-06 | 2012-06-13 | 扬州大学 | Organosilicon-modified styrene-acrylic architectural waterproof latex and preparation method thereof |
CN102702908A (en) * | 2012-06-26 | 2012-10-03 | 吉林科龙建筑节能科技股份有限公司 | Environment-friendly building outer wall simulated tile coating and preparation method thereof |
CN102850861A (en) * | 2012-08-31 | 2013-01-02 | 芜湖县双宝建材有限公司 | Brick paint and preparation method thereof |
CN102876143A (en) * | 2012-08-31 | 2013-01-16 | 芜湖县双宝建材有限公司 | Marble paint and preparation method thereof |
CN102977253A (en) * | 2012-11-06 | 2013-03-20 | 中科院广州化学有限公司 | Silicone modified acrylate hybrid emulsion and preparation method and application thereof |
-
2013
- 2013-04-26 CN CN201310150055.6A patent/CN104119034B/en not_active Expired - Fee Related
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002088215A2 (en) * | 2001-04-30 | 2002-11-07 | Basf Corporation, Please See General Appointment Of Representative | Sandable, self-healable coating compositions and a process of using the same |
CN102492085A (en) * | 2011-12-06 | 2012-06-13 | 扬州大学 | Organosilicon-modified styrene-acrylic architectural waterproof latex and preparation method thereof |
CN102702908A (en) * | 2012-06-26 | 2012-10-03 | 吉林科龙建筑节能科技股份有限公司 | Environment-friendly building outer wall simulated tile coating and preparation method thereof |
CN102850861A (en) * | 2012-08-31 | 2013-01-02 | 芜湖县双宝建材有限公司 | Brick paint and preparation method thereof |
CN102876143A (en) * | 2012-08-31 | 2013-01-16 | 芜湖县双宝建材有限公司 | Marble paint and preparation method thereof |
CN102977253A (en) * | 2012-11-06 | 2013-03-20 | 中科院广州化学有限公司 | Silicone modified acrylate hybrid emulsion and preparation method and application thereof |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105295578A (en) * | 2015-11-30 | 2016-02-03 | 桂林市和鑫防水装饰材料有限公司 | Silicone-modified styrene-acrylic emulsion coating and preparation method thereof |
CN106082794A (en) * | 2016-06-28 | 2016-11-09 | 郭舒洋 | A kind of preparation method of the true mineral varnish of high durable |
CN112500725A (en) * | 2020-12-10 | 2021-03-16 | 深圳广田高科新材料有限公司 | Novel inorganic environment-friendly bone paste modeling paint and preparation method thereof |
CN112500725B (en) * | 2020-12-10 | 2022-05-27 | 深圳广田高科新材料有限公司 | Inorganic environment-friendly bone paste modeling paint and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
CN104119034B (en) | 2016-04-13 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN105331231B (en) | A kind of energy-saving ring fidelity stone-type composite dope and preparation method thereof and construction method | |
CN102533038B (en) | Natural stone paint | |
CN102617104B (en) | Inorganic powder sandy paint and production method thereof | |
CN102492102B (en) | Silicon-containing acrylic-acid-modified epoxy ester resin and paint thereof | |
CN106608943A (en) | One-component acrylic ester matte core-shell emulsions with good anti-water-white performance and preparation method and application thereof | |
CN102964514A (en) | Preparation method of polyacrylate emulsion containing silicon, fluorine and phosphate group | |
CN102643385B (en) | Organic silicon-acrylic ester copolymer emulsion and preparation and application thereof | |
CN103627272B (en) | Liquid rock particles of artificial granite sand textured coating | |
CN110540783B (en) | Matte water-in-water base paint, preparation method and matte water-in-water coating | |
CN106543347A (en) | Pure third true mineral varnish emulsion of a kind of resistant and preparation method thereof | |
CN105086536A (en) | Special high-performance emulsion paint for building external wall | |
CN103642344A (en) | Texture multicolor coating and preparation method thereof | |
CN104402301A (en) | Lightweight pottery sand stone-like paint and preparation method thereof | |
CN104119034A (en) | Aqueous sand-based paint and preparation method thereof | |
CN104556831A (en) | Really stone paint | |
CN104072662B (en) | The artificial color sand preparation preparation method of color sand acrylic resin modified, artificial | |
CN104119033A (en) | Aqueous sand-based paint and preparation method thereof | |
CN106478861A (en) | A kind of modified aqueous acrylic acid resin and the method preparing manually color sand using it | |
CN105778595A (en) | Fire retardant coating for buildings | |
CN104530890B (en) | Water-based acrylate fireproof coating and preparation method thereof | |
CN105219198B (en) | A kind of heat-insulating, fire-preventing stone-like coating | |
CN105802306A (en) | Preparation method of building fireproof coating | |
CN103274635B (en) | A kind of facing mortar | |
CN105062291A (en) | Preparation method of fireproof coating | |
CN105062288A (en) | Fireproof corrosion resistant coating |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160413 |