CN104100064A - Metal face overlay stone and production method thereof - Google Patents
Metal face overlay stone and production method thereof Download PDFInfo
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- CN104100064A CN104100064A CN201410328496.5A CN201410328496A CN104100064A CN 104100064 A CN104100064 A CN 104100064A CN 201410328496 A CN201410328496 A CN 201410328496A CN 104100064 A CN104100064 A CN 104100064A
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Abstract
The invention discloses a metal face overlay stone comprising a base material, an elastic coating, a colored intermediate layer, an effect layer and a protective layer. The base materials is coated with the elastic coating, the colored intermediate layer is arranged on the elastic layer by roller coating, the effect layer is formed by spraying multicolor metallic paint on the colored intermediate layer, and the effect layer is coated with the protective layer. The protective layer is nano fluorocarbon paint, the multicolor metallic paint is composed of slurry and 10-15% of multicolor metal power and 45-59% of nano fluorocarbon resin by mass, and the slurry is composed of, by mass, 20-28% of xylene, 8-15% of butyl acetate, 8% of 20% CAB, 0.7% of Levaslip432, 0.4-1% of Disponer904s, 0.6-0.8% of Aisponer912, 0.6-1% of Defom6500 and 2% of 201p. The metal face overlay stone has the advantages of convenience in transportation and construction, stable patterns, smooth hand feeling and fineness and smoothness.
Description
Technical field
The present invention relates to a kind of man-made stone field, more particularly, it relates to a kind of metal face overlay stone and preparation method thereof.
Background technology
At present, building wall, when carrying out metal finishing, or adopts metal material directly to stick on building wall surface, or adopts metallic paint to be sprayed on composite sheet material, then composite sheet material is pasted to the surface at building.
While adopting metal to decorate, because metal is heavier, make transportation and construction very difficult, cost is higher, and metal material easily corrodes; While adopting metallic paint to be sprayed on composite sheet material, such facing stone style is unstable, and feel is poor, and because coating is exposed in external environment condition, through wet by the rain and burnt by the sun, very easily causes coating to fade, and the color duration is too short.
Summary of the invention
The deficiency existing for prior art, the object of the present invention is to provide a kind of metal face overlay stone, and it is light that this metal face overlay stone has material, transportation, easy construction, and style is stable, the feature that feel is smooth, moist.
For achieving the above object; the invention provides following technical scheme: a kind of illusion-colour metal face overlay stone; comprise base material; be coated in the elastic coating on base material; the coloured middle level of roller coat on elastic coating; illusion-colour metallic paint is sprayed on to the effect layer forming on coloured middle level; and be coated in the topping on effect layer; described topping is nano-fluorine carbon paint; described illusion-colour metallic paint consists of slurry, illusion-colour metal powder and fluorine carbon-nano resin; the mass fraction of illusion-colour metal powder is 10% ~ 15%, and the mass fraction of fluorine carbon-nano resin is 45% ~ 59%.
The dimethylbenzene that slurry is 20% ~ 28% by metal quality mark, 8% ~ 15% acetate butyl, the CAB that 8% concentration is 20%, the Disponer 904s of 0.7% Levaslip 432,0.4% ~ 1%, 0.6% ~ 0.8% Aisponer 912, the 201p of 0.6% ~ 1% Defom 6500,2% forms.
The present invention is further set to: described illusion-colour metallic paint is comprised of slurry, 10% illusion-colour metal powder and 46% fluorine carbon-nano resin; Slurry comprises that mass fraction is 21% dimethylbenzene, 10% acetate butyl, and the CAB that 8% concentration is 20%, the Disponer 904s of 0.7% Levaslip 432,0.7%, the 201p of the Defom 6500,2% of 0.7% Aisponer 912,0.9% forms.
By adopting technique scheme, by inorganic mineral gel, kaolin, rutile titanium white powder is imitative metal inorganic main body, made metal face overlay stone effect is true to nature, by organosilicon-modified acrylic elastic emulsion, it is main filmogen, add again the effect layer that illusion-colour metallic paint that other auxiliary agents make forms to there is feel exquisiteness, smooth, the feature that hot strength is large, and the same base material of this effect layer, elastic coating, coloured middle level and topping are the same, all organic by lightweight, inorganic material is made, compare the feature that metal material has light weight, thereby easily transportation, construction, on effect layer, apply the topping that one deck consists of nano-fluorine carbon paint, can effectively protect effect layer not to be subject to external interference, make its color very stable.
Preparation method, preparation as described in one of claim 1 or 2 illusion-colour metal face overlay stone, it is characterized in that: comprise the following steps:
(1) to take the base material that polyester fiber is main material, carry out smooth, dry processing, use high-quality cracking resistance seal coat comprehensively evenly brushing in the one side of base material, and standing and drying;
(2), after the seal coat of high-quality cracking resistance described in (1) bone dry, at its surface roller coating elastic coating, this elastic coating be take polymeric acrylic acid elastic emulsion and is made as film forming matter;
(3), after elastic coating bone dry described in (2), on its surface, evenly roller coat coloured silk is joined priming paint together, forms coloured middle level;
(4), after the bone dry of coloured middle level described in (3), at its surperficial continuous uniform spraying illusion-colour metallic paint, form effect layer;
(5), after effect layer bone dry described in (4), at its surface spraying nano-fluorine carbon paint, form topping.
By adopting technique scheme, using polyester fiber as base material, can strengthen the hot strength of metal face overlay stone, at base material, simultaneously coat the effect that high-quality cracking resistance seal coat plays water-fast, acid and alkali-resistance, mildew resistant moistureproof; The elastic coating that the polymeric acrylic acid elastic emulsion of take is made as film forming matter can play and strengthen feel, the effect of compensation temperature variation to the stress of metal face overlay stone generation; On elastic coating, roller coat is just joined the color effect that priming paint can strengthen metal face overlay stone; The effect layer surface spraying nano-fluorine carbon paint forming at illusion-colour metallic paint, as topping, can effectively protect effect layer not to be subject to external interference, makes its color very stable.
The present invention is further set to: described illusion-colour metallic paint, after the first pass spraying of surface, coloured middle level and bone dry, sprays second time again.
The present invention is further set to: the consumption of described high-quality cracking resistance seal coat is 0.1～0.15kg/m
2; The thickness of described elastic coating is 1.2mm; The thickness in described coloured middle level is 0.15mm; The thickness of described effect layer is 0.2mm
By adopting technique scheme; the spraying illusion-colour metallic paint of twice can be in order to be effective layer feel fine and smooth; outward appearance is true to nature; not only effect is true to nature by above-mentioned thickness, produced illusion-colour metal face overlay stone to be set; and thickness is very thin; in protection effect layer, representing of impact effect layer outward appearance not again.
The preparation method of illusion-colour metallic paint comprises the following steps: add successively the CAB of dimethylbenzene, acetate butyl, 20% concentration to disperse in dispersion tank, jitter time is 5-10min, until complete transparent in graininess; Add again Levaslip 432, Disponer 904s, Aisponer 912, and Defom 6500, and 201p makes slurry to carrying out high speed dispersion in dispersion tank; Illusion-colour metal powder is slowly joined in slurry, and its medium speed can not be higher than 900r/min, and jitter time is 10-15min; After all raw materials scatter completely, add fluorine carbon-nano resin agitating even, obtain illusion-colour metallic paint.
By adopting technique scheme, add successively the CAB of dimethylbenzene, acetate butyl, 20% concentration to disperse in dispersion tank, jitter time is 5-10min, until complete transparent in graininess; Add again Levaslip 432, Disponer 904s, Aisponer 912, and Defom 6500, and 201p makes slurry to carrying out high speed dispersion in dispersion tank; Illusion-colour metal powder is slowly joined in slurry, and its medium speed can not be higher than 900r/min, and jitter time is 10-15min; After all raw materials scatter completely, add fluorine carbon-nano resin agitating even, obtain illusion-colour metallic paint; Wherein the CAB of 20% concentration is first molten in advance, illusion-colour metal powder is brewed in advance, with high-grade illusion-colour metal powder modulation of all kinds, do not add mill base, finished product has 3 kinds of above illusion-colour metal powders substantially, construction is process high-temperature baking on the synthetic polyester fiber of my door, again with the protection of fluorine carbon-nano finish, become paint film to there is impayable guarantor's chromatic effect, and other auxiliary agents, make the illusion-colour metallic paint forming that high intensity and toughness can be provided after moulding, the ability of very strong imitative metal, and also light weight, intensity are high; Obtain after the illusion-colour metallic paint of mobility, by spray gun special, illusion-colour metallic paint is sprayed on to surface, coloured middle level.
The present invention is further set to: in the preparation process of illusion-colour metallic paint, temperature is 25 ℃, and relative humidity is 40%-60%.
The present invention is further set to: by adding thickener, the viscosity of described illusion-colour metallic paint can be controlled in 100-120KU.
By adopting technique scheme, in the preparation of illusion-colour metallic paint, by 25 ℃ of temperature control bits, relative humidity is 40%-60%, and its viscosity of illusion-colour metallic paint of producing is like this 90KU, meets on the market the demand in most of market and the demand that meets particular client; In the step of illusion-colour metallic paint finished product, temperature is 25 ℃, and relative humidity is 40%-60%, and incorporation time is within 1-5h, thereby the illusion-colour metallic paint viscosity of producing is 4000-9000mpa.s, is also modal use viscosity scope on market.
The specific embodiment
Understanding for the ease of those skilled in the art, is described in further detail the present invention below in conjunction with specific embodiment.
A kind of illusion-colour metal face overlay stone; comprise base material; be coated in the elastic coating on base material; the coloured middle level of roller coat on elastic coating, is sprayed on illusion-colour metallic paint the effect layer forming on coloured middle level, and is coated in the topping on effect layer; described topping is nano-fluorine carbon paint; described illusion-colour metallic paint consists of slurry, illusion-colour metal powder and fluorine carbon-nano resin, and the mass fraction of illusion-colour metal powder is 10% ~ 15%, and the mass fraction of fluorine carbon-nano resin is 45% ~ 59%.
The dimethylbenzene that slurry is 20% ~ 28% by metal quality mark, 8% ~ 15% acetate butyl, the CAB that 8% concentration is 20%, the Disponer 904s of 0.7% Levaslip 432,0.4% ~ 1%, 0.6% ~ 0.8% Aisponer 912, the 201p of 0.6% ~ 1% Defom 6500,2%.
The detailed proportioning of the classes of agents of using, raw material and consumption:
1. illusion-colour metallic paint proportioning:
Dimethylbenzene 20% ~ 28%;
Acetate butyl 8% ~ 15%;
20%CAB 8%；
Levaslip 432 0.7%；
Aisponer 912 0.6%~0.8%；
Defom 6500 0.6%~1% ；
201p 2%；
Disponer 904 0.4%~1%；
Illusion-colour metal powder 10% ~ 15%;
Fluorine carbon-nano resin 45% ~ 59%.
Nano-fluorine carbon paint proportioning:
Dimethylbenzene 35～40%
Butyl acetate 10～15%
Disponer 904s(Ricinate) 0.3～0.5%
Levaslip 432(silicone levelling agent) 0.3～0.5%
Defoamer 635 0.4～0.7%
The nano combined fluorocarbon resin 50～55% of solvent-borne type.
Embodiment 1: the preparation process of illusion-colour metallic paint:
The preparation process of illusion-colour metallic paint: add successively the CAB of dimethylbenzene, acetate butyl, 20% concentration to disperse in dispersion tank, jitter time is 5-10min, until complete transparent in graininess; Add again Levaslip 432, Disponer 904s, Aisponer 912, and Defom 6500, and 201p makes slurry to carrying out high speed dispersion in dispersion tank; Illusion-colour metal powder is slowly added in the slurry making, its medium speed can not be higher than 900r/min, and jitter time is 10-15min; After all raw materials scatter completely, add fluorine carbon-nano resin agitating even, obtain illusion-colour metallic paint.
3. the preparation process of metal face overlay stone:
(1) to take, the base material that polyester fiber is main material fully cleans, smooth, dry processing, when clean, use the cleaning agent of PH=8, keep environment temperature: T=5 ℃, then use high-quality cracking resistance seal coat evenly to brush the one side at base material comprehensively, and standing and drying, the consumption of high-quality cracking resistance seal coat is 0.1kg/m
2;
(2) after the seal coat of high-quality cracking resistance described in (1) bone dry, at its surface roller coating elastic coating, this elastic coating be take polymeric acrylic acid elastic emulsion and is made as film forming matter, and this elastic coating thickness is 1.2mm;
(3) after elastic coating bone dry described in (2), on its surface, evenly roller coat coloured silk is joined priming paint together, forms coloured middle level, and the thickness in coloured middle level is 0.15mm;
(4) after the bone dry of coloured middle level described in (3), at its surperficial continuous uniform spraying illusion-colour metallic paint, after spraying first pass, standing and drying, then sprays second time, forms effect layer, and the thickness of this effect layer is 0.2mm;
(5) after effect layer bone dry described in (4); at its surface spraying nano-fluorine carbon paint; its proportioning is: 35% dimethylbenzene; 10% butyl acetate, 0.3% Disponer 904s(Ricinate), 0.3% Levaslip 432(silicone levelling agent); 0.4% defoamer 635; and the nano combined fluorocarbon resin of 54% solvent-borne type, forming topping, the thickness of this topping is 0.1mm.
Here, in metal face overlay stone preparation process, high-quality cracking resistance seal coat that step (1) is used adopts the seal coat of autonomous production, has acid and alkali-resistance, water-fast, moisture resistance feature.
Embodiment 1.
The proportioning of illusion-colour metallic paint:
Dimethylbenzene 21%;
Acetate butyl 10%;
20%CAB 8%；
Levaslip 432 0.7% ；
Disponer 904 0.7%；
Aisponer 912 0.7%；
Defom 6500 0.9% ；
201p 2%；
Illusion-colour metal powder 10%;
Fluorine carbon-nano resin 46%.
Operating process and condition:
1. add successively dimethylbenzene, acetate butyl, 20% CAB to disperse 5-10min, to complete transparent in graininess, then add 4.5.6.7.8 high speed dispersion;
2. add again Levaslip 432, Disponer 904s, Aisponer 912, and Defom 6500, and 201p makes slurry to carrying out high speed dispersion in dispersion tank; Illusion-colour metal powder is slowly added in the slurry making, its medium speed can not be higher than 900r/min, and jitter time is 10-15min;
3. prefabricated metal paste is slowly added, rotating speed can not, higher than 900r/min, disperse 10-15 minute.
The preparation process of metal face overlay stone and condition in embodiment 2:
(1) to take, the base material that polyester fiber is main material fully cleans, smooth, dry processing, when clean, use the cleaning agent of PH=8, keep environment temperature: T=5 ℃, then use high-quality cracking resistance seal coat evenly to brush the one side at base material comprehensively, and standing and drying, the consumption of high-quality cracking resistance seal coat is 0.1kg/m
2;
(2) after the seal coat of high-quality cracking resistance described in (1) bone dry, at its surface roller coating elastic coating, this elastic coating be take polymeric acrylic acid elastic emulsion and is made as film forming matter, and this elastic coating thickness is 1.2mm;
(3) after elastic coating bone dry described in (2), on its surface, evenly roller coat coloured silk is joined priming paint together, forms coloured middle level, and the thickness in coloured middle level is 0.15mm;
(4) after the bone dry of coloured middle level described in (3), at its surperficial continuous uniform spraying illusion-colour metallic paint, after spraying first pass, standing and drying, then sprays second time, forms effect layer, and the thickness of this effect layer is 0.2mm;
(5) after effect layer bone dry described in (4); at its surface spraying nano-fluorine carbon paint; its proportioning is: 35% dimethylbenzene; 10% butyl acetate, 0.3% Disponer 904s(Ricinate), 0.3% Levaslip 432(silicone levelling agent); 0.4% defoamer 635; and the nano combined fluorocarbon resin of 54% solvent-borne type, forming topping, the thickness of this topping is 0.1mm.
Embodiment 2.
The proportioning of illusion-colour metallic paint
Dimethylbenzene 23%;
Acetate butyl 8%;
20%CAB 8%；
Levaslip 432 0.7% ；
Disponer 904 0.5 %；
Aisponer 912 0.8%；
Defom 6500 1% ；
201p 2%；
Illusion-colour metal powder 11%;
Fluorine carbon-nano resin 45%.
Operating process and condition:
1. add successively dimethylbenzene, acetate butyl, 20% CAB to disperse 5-10min, to complete transparent in graininess, then add 4.5.6.7.8 high speed dispersion;
2. add again Levaslip 432, Disponer 904s, Aisponer 912, and Defom 6500, and 201p makes slurry to carrying out high speed dispersion in dispersion tank; Illusion-colour metal powder is slowly added in the slurry making, its medium speed can not be higher than 900r/min, and jitter time is 10-15min;
3. prefabricated metal paste is slowly added, rotating speed can not, higher than 900r/min, disperse 10-15 minute.
The preparation process of metal face overlay stone and condition in embodiment 2:
(1) to take, the base material that polyester fiber is main material fully cleans, smooth, dry processing, when clean, use the cleaning agent of PH=8, keep environment temperature: T=5 ℃, then use high-quality cracking resistance seal coat evenly to brush the one side at base material comprehensively, and standing and drying, the consumption of high-quality cracking resistance seal coat is 0.1kg/m
2;
(2) after the seal coat of high-quality cracking resistance described in (1) bone dry, at its surface roller coating elastic coating, this elastic coating be take polymeric acrylic acid elastic emulsion and is made as film forming matter, and this elastic coating thickness is 1.2mm;
(3) after elastic coating bone dry described in (2), on its surface, evenly roller coat coloured silk is joined priming paint together, forms coloured middle level, and the thickness in coloured middle level is 0.15mm;
(4) after the bone dry of coloured middle level described in (3), at its surperficial continuous uniform spraying illusion-colour metallic paint, after spraying first pass, standing and drying, then sprays second time, forms effect layer, and the thickness of this effect layer is 0.2mm;
(5) after effect layer bone dry described in (4); at its surface spraying nano-fluorine carbon paint; its proportioning is: 35% dimethylbenzene; 10% butyl acetate, 0.3% Disponer 904s(Ricinate), 0.3% Levaslip 432(silicone levelling agent); 0.4% defoamer 635; and the nano combined fluorocarbon resin of 54% solvent-borne type, forming topping, the thickness of this topping is 0.1mm.
Embodiment 3.
The proportioning of illusion-colour metallic paint:
Dimethylbenzene 21%;
Acetate butyl 9%;
20%CAB 8%；
Levaslip 432 0.7% ；
Disponer 904 0.5 %；
Aisponer 912 0.8%；
Defom 6500 1%
201p 2%；
Illusion-colour metal powder 10%;
Fluorine carbon-nano resin 47%.
Operating process and condition:
1. add successively dimethylbenzene, acetate butyl, 20% CAB to disperse 5-10min, to complete transparent in graininess, then add 4.5.6.7.8 high speed dispersion;
2. add again Levaslip 432, Disponer 904s, Aisponer 912, and Defom 6500, and 201p makes slurry to carrying out high speed dispersion in dispersion tank; Illusion-colour metal powder is slowly added in the slurry making, its medium speed can not be higher than 900r/min, and jitter time is 10-15min;
3. prefabricated metal paste is slowly added, rotating speed can not, higher than 900r/min, disperse 10-15 minute.
Preparation process and the condition of the metal face overlay stone in embodiment 3:
(1) to take, the base material that polyester fiber is main material fully cleans, smooth, dry processing, when clean, use the cleaning agent of PH=8, keep environment temperature: T=5 ℃, then use high-quality cracking resistance seal coat evenly to brush the one side at base material comprehensively, and standing and drying, the consumption of high-quality cracking resistance seal coat is 0.1kg/m
2;
(2) after the seal coat of high-quality cracking resistance described in (1) bone dry, at its surface roller coating elastic coating, this elastic coating be take polymeric acrylic acid elastic emulsion and is made as film forming matter, and this elastic coating thickness is 1.2mm;
(3) after elastic coating bone dry described in (2), on its surface, evenly roller coat coloured silk is joined priming paint together, forms coloured middle level, and the thickness in coloured middle level is 0.15mm;
(4) after the bone dry of coloured middle level described in (3), at its surperficial continuous uniform spraying illusion-colour metallic paint, after spraying first pass, standing and drying, then sprays second time, forms effect layer, and the thickness of this effect layer is 0.2mm;
(5) after effect layer bone dry described in (4); at its surface spraying nano-fluorine carbon paint; its proportioning is: 35% dimethylbenzene; 10% butyl acetate, 0.3% Disponer 904s(Ricinate), 0.3% Levaslip 432(silicone levelling agent); 0.4% defoamer 635; and the nano combined fluorocarbon resin of 54% solvent-borne type, forming topping, the thickness of this topping is 0.1mm.
The above is only the preferred embodiment of the present invention, and protection scope of the present invention is also not only confined to above-described embodiment, and all technical schemes belonging under thinking of the present invention all belong to protection scope of the present invention.It should be pointed out that for those skilled in the art, some improvements and modifications without departing from the principles of the present invention, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (8)
1. an illusion-colour metal face overlay stone, comprise base material, be coated in the elastic coating on base material, the coloured middle level of roller coat on elastic coating, illusion-colour metallic paint is sprayed on to the effect layer forming on coloured middle level, and be coated in the topping on effect layer, and it is characterized in that: described topping is nano-fluorine carbon paint, described illusion-colour metallic paint consists of slurry, illusion-colour metal powder and fluorine carbon-nano resin; The mass fraction of illusion-colour metal powder is 10% ~ 15%, and the mass fraction of fluorine carbon-nano resin is 45% ~ 59%;
The dimethylbenzene that described slurry is 20% ~ 28% by metal quality mark, 8% ~ 15% acetate butyl, 8% concentration is 20% CAB, 0.7% Levaslip 432,0.4% ~ 1% Disponer 904s, the 201p of the Defom 6500,2% of 0.6% ~ 0.8% Aisponer 912,0.6% ~ 1% forms.
2. illusion-colour metal face overlay stone according to claim 1, is characterized in that: described illusion-colour metallic paint is comprised of slurry, 10% illusion-colour metal powder and 46% fluorine carbon-nano resin; Slurry comprises that mass fraction is 21% dimethylbenzene, 10% acetate butyl, and the CAB that 8% concentration is 20%, the Disponer 904s of 0.7% Levaslip 432,0.7%, the 201p of the Defom 6500,2% of 0.7% Aisponer 912,0.9% forms.
3. a preparation method for illusion-colour metal face overlay stone, prepares illusion-colour metal face overlay stone as described in one of claim 1 or 2, it is characterized in that: comprise the following steps:
To take the base material that polyester fiber is main material, carry out smooth, dry processing, use high-quality cracking resistance seal coat comprehensively evenly brushing in the one side of base material, and standing and drying;
After the seal coat of high-quality cracking resistance described in (1) bone dry, at its surface roller coating elastic coating, this elastic coating be take polymeric acrylic acid elastic emulsion and is made as film forming matter;
After elastic coating bone dry described in (2), on its surface, evenly roller coat coloured silk is joined priming paint together, forms coloured middle level;
After the bone dry of coloured middle level described in (3), at its surperficial continuous uniform spraying illusion-colour metallic paint, form effect layer;
After effect layer bone dry described in (4), at its surface spraying nano-fluorine carbon paint, form topping.
4. metal face overlay stone preparation method according to claim 3, is characterized in that: described illusion-colour metallic paint, after the first pass spraying of surface, coloured middle level and bone dry, sprays second time again.
5. metal face overlay stone preparation method according to claim 3, is characterized in that: the consumption of described high-quality cracking resistance seal coat is 0.1～0.15kg/m
2; The thickness of described elastic coating is 1.2mm; The thickness in described coloured middle level is 0.15mm; The thickness of described effect layer is 0.2mm.
6. a preparation method for illusion-colour metallic paint, slurry preparation: add successively the CAB of dimethylbenzene, acetate butyl, 20% concentration to disperse in dispersion tank, jitter time is 5-10min, until complete transparent in graininess; Add again Levaslip 432, Disponer 904s, Aisponer 912, and Defom 6500, and 201p makes slurry to carrying out high speed dispersion in dispersion tank; Illusion-colour metal powder is slowly joined in slurry, and its medium speed can not be higher than 900r/min, and jitter time is 10-15min; After all raw materials scatter completely, add fluorine carbon-nano resin agitating even, obtain illusion-colour metallic paint.
7. illusion-colour metallic paint preparation method according to claim 6, is characterized in that, in the preparation process of illusion-colour metallic paint, temperature is 25 ℃, and relative humidity is 40%-60%.
8. illusion-colour metallic paint preparation method according to claim 7, is characterized in that, by adding thickener, the viscosity of described illusion-colour metallic paint can be controlled in 100-120KU.
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| CN108864838A (en) * | 2017-05-10 | 2018-11-23 | 四川海聚环保科技有限责任公司 | Imitative metal lagging and production technology |
| CN109057217A (en) * | 2018-07-25 | 2018-12-21 | 四川海聚环保科技有限责任公司 | A kind of imitation stone decorative panel and production technology |
| CN109098378A (en) * | 2018-07-25 | 2018-12-28 | 四川海聚环保科技有限责任公司 | A kind of imitative metal lagging and production technology |
| CN109898767A (en) * | 2019-01-28 | 2019-06-18 | 宁波华宝石节能科技股份有限公司 | The preparation method of three-dimensional shiny surface stone decoration board |
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Denomination of invention: Magic color metal facing stone Effective date of registration: 20201229 Granted publication date: 20160824 Pledgee: Bank of China Limited by Share Ltd. Jiaojiang branch Taizhou City Branch Pledgor: ZHEJIANG TAIJI COATINGS Co.,Ltd. Registration number: Y2020330001289 |