Ethylene-propylene diene reclaimed rubber modifying asphalt rust-inhibiting paint
Technical field
The present invention relates to a kind of coating, particularly a kind of regenerated rubber modified oil pitch rust-inhibiting paint.
Background technology
Pitch is with a long history as coating, China in early days with the byproduct tar of coking plant, producer gas plant brush inland river wooden boat, timber, bamboo fence etc. are carried with anticorrosion in river.Due to the development of synthetic resins, new coating continues to bring out in recent years.But because bituminous varnish has special performance, add the advantages such as aboundresources, cheap, easy construction, still occupy so far certain status.
The bituminous varnish of manufacturing coating is mainly rock asphalt, petroleum pitch and coal tar pitch three classes.Rock asphalt glossiness is high, and matter is hard, and energy and Vegetable oil lipoprotein well merge, and this veriety is best, and still, price is higher.Tar-bitumen is the byproduct that coke-oven plant, producer gas plant obtain in the time manufacturing coke gas, and coal tar pitch is because containing a large amount of phenol and benzene, and toxicity is very large, and taste is very smelly, very large to workmen's murder by poisoning.The toxicity of petroleum pitch is little, there is no smell, people is safe from harm substantially, but antiseptic property does not have coal tar pitch good.
The fusing point that pitch is not fixed, low temperature is brittle cracking, and high temperature trickling, so pitch can not do separately coating, must pass through modification.
Traditional bituminous varnish has four kinds, and the one, dry vegetable oil modifying asphalt paint; The 2nd, rosin derivative modifying asphalt paint; The 3rd, synthetic modifying asphalt paint, synthetic resins comprises epoxy resin, polystyrene resin, resol, aminoresin, isocyanate resin; The 4th, the bituminous varnish that has unfilled bitumen to make.
The bituminous varnish of dry vegetable oil modification, typical dry vegetable oil is as oleum lini, perilla oil, cannabis oil and tung oil, and the dry vegetable oil of this class is because hold at high price, and cost compare is high, so this class bituminous varnish has seldom been seen in the market.
At home on market, epoxy coal tar pitch paint, because it has good water-fast, alkaline-resisting, chemical proofing, has very strong adhesion property to metal, still very in fashion at present.But this product is because adopting thickness coal-tar pitch, it is containing benzene, containing phenol, and toxicity is very large, and pungency is also very large, very large to workmen's Health hazard.
At present, the rust-inhibiting paint kind using on domestic market has alcohol acid antirust paint, phenolic antirust paint, epoxy anti-rust paint, inorganic zinc silicate rust-inhibiting paint, highly-chlorinated polyethylene rust-inhibiting paint, chlorinated polyvinyl chloride rust-inhibiting paint, transformant conversion and prevention paint of rust, epoxy coal tar pitch rust-inhibiting paint.
Summary of the invention
The object of the invention is the shortcoming in order to overcome above-mentioned background technology, provide one to utilize ethylene-propylene diene reclaimed rubber modifying asphalt filmogen, development one sprays dry, has remarkable rustless property, to the low murder by poisoning of people, rust-inhibiting paint with low cost and preparation method thereof.
Technical scheme of the present invention is: a kind of Ethylene Propylene Terpolymer regeneration untreated rubber modifying asphalt rust-inhibiting paint and preparation method thereof, and its moiety and weight proportion are as follows:
Ethylene Propylene Terpolymer regeneration rubber modified oil pitch solution: 20 ~ 40 weight parts
Aliphatic solvents: 5` ~ 15 weight part organobentonite: 0.5 ~ 1 weight part
Dispersion agent: 0.1 ~ 0.5 weight part tinting pigment: 3 ~ 25 weight parts
Ground barium sulfate: 25 ~ 45 weight part hexafluorophosphoric acid calcium powders: 5 ~ 10 weight parts
Triethyl aluminum: 0.2 ~ 1 mass parts rare earth composite drier: 0.3 ~ 0.8 mass parts;
Described Ethylene Propylene Terpolymer regeneration rubber modified oil pitch solution is to be prepared from by petroleum pitch, Ethylene Propylene Terpolymer regeneration rubber, chloroparaffin and aliphatic solvents processing; Its moiety of described petroleum pitch and weight proportion are:
oil content40%~60%, resin 15%~30%,
pitch earth matter10%~30%, bitumencarb 2%~3%; Described Ethylene Propylene Terpolymer reclaimed rubber contains one can be for the unsaturated double-bond of sulfuration, described unsaturated double-bond is provided by one of ethylidene norbornene (ENB) or dicyclopentadiene (DCPD), described petroleum pitch also contains unsaturated double-bond, in manufacturing processed by adding rare earth composite drier and triethyl aluminum, absorb airborne Sauerstoffatom, realize solvent evaporates and oxidation cross-linked dual dry.
A kind of Ethylene Propylene Terpolymer regeneration untreated rubber modifying asphalt rust-inhibiting paint and preparation method thereof, its preparation method carries out according to following steps:
(1) Ethylene Propylene Terpolymer regeneration rubber solution manufacturing method: adopt chloroparaffin and aliphatic hydrocarbon mixed solvent to make Ethylene Propylene Terpolymer regeneration rubber solvent; The two weight blending ratio is: chloroparaffin: aliphatic solvents=1:1, and according to the part by weight of Ethylene Propylene Terpolymer regeneration rubber: mixed solvent=60:40, soaked overnight, micelle is partly dissolved and is softened; Then use atomized ash sand mill, grind together, with high speed dispersor 1200 ~ 1400r/min dispersion 20 ~ 30 minutes, grind according to this high speed dispersion 2 ~ 3 roads; Micelle is broken, and is finally dissolved into resin solution;
(2) bituminous solution preparation: according to aliphatic solvents: pitch=40:60 part by weight, aliphatic solvents is added in the container with stirring and heating unit thereof, heat while stirring, drop into 1/2nd of above-mentioned pitch simultaneously, after pitch dissolves completely, drop into again remaining pitch, after dissolving, make solids content and be 60% Ethylene Propylene Terpolymer regeneration rubber modified oil pitch solution;
(3) according to pitch: the solids ratios of Ethylene Propylene Terpolymer regeneration rubber=1:1 ~ 1.5, mix, high speed dispersion 25 ~ 30 minutes, for subsequent use;
(4) Ethylene Propylene Terpolymer regeneration untreated rubber modifying asphalt rust-inhibiting paint preparation method is as follows:
1. drop into successively in order described weight proportion solvent: Ethylene Propylene Terpolymer regeneration rubber modified oil pitch solution, Ethylene Propylene Terpolymer regeneration rubber liquid, aliphatic solvents, organobentonite, dispersion agent, triethyl aluminum;
2. start high speed dispersor, middling speed 500 ~ 800r/min, disperses 10 ~ 15 minutes; Then tinting pigment, ground barium sulfate, hexafluorophosphoric acid calcium powder are slowly dropped in dispersion limit in limit;
3. after feeding intake, rate of dispersion is promoted to 1200 ~ 1400r/min, disperses 30 ~ 40 minutes;
4. then go up sand mill and grind, mesh-of-grind≤40 μ m;
5. add rare earth composite drier, stir 10 ~ 20 minutes, filter and package.
The invention has the beneficial effects as follows: the present invention by adding rare earth composite drier and triethyl aluminum, absorbs airborne Sauerstoffatom in manufacturing processed, realize solvent evaporates and oxidation cross-linked dual dry.The antirust priming-finishing integrated rust protection paint of product ethylene-propylene diene reclaimed rubber modifying asphalt of the present invention can form tough and tensile coating after doing solid work, and coating has good elasticity and has the features such as good snappiness, wear resistance, shock-resistance; Product of the present invention is antirust except can be applicable to traditional plain metal, is also applicable to the petroleum pipe line antirust, anti-corrosive under severe environment.
Embodiment
Illustrate as follows to of the present invention further describing:
Example 1: a kind of ethylene-propylene diene reclaimed rubber modifying asphalt rust-proofing primer of rust
The ethylene-propylene diene reclaimed rubber modifying asphalt rust-proofing primer proportioning table of table 1 rust:
Above-mentioned preparation method comprises the following steps:
(1) Ethylene Propylene Terpolymer regeneration rubber solution manufacturing method: adopt the mixed solvent of trichloropropane and 200# aliphatic solvents to make Ethylene Propylene Terpolymer regeneration rubber solvent, the two blending ratio is, trichloropropane: 200# aliphatic solvents=1:1 weight ratio, according to the part by weight of Ethylene Propylene Terpolymer regeneration rubber: mixed solvent=60:40, soaked overnight, micelle is partly dissolved and is softened; Then use atomized ash sand mill, grind together, with high speed dispersor 1200 ~ 1400r/min dispersion 20 ~ 30 minutes, grind according to this high speed dispersion 2 ~ 3 roads; Micelle is broken, and is then dissolved into resin state;
(2) bituminous solution preparation: according to 200# aliphatic solvents: 10# petroleum pitch=40:60 part by weight, aliphatic solvents is added in the container with stirring and heating unit thereof, heat while stirring, drop into 1/2nd of above-mentioned pitch simultaneously, after pitch dissolves completely, drop into again remaining pitch, after dissolving, make solids content and be 60% Ethylene Propylene Terpolymer regeneration rubber modifying asphalt solution;
(3) according to pitch: the solids ratios of Ethylene Propylene Terpolymer regeneration rubber=1:1 ~ 1.5, mix, high speed dispersion 25 ~ 30 minutes, for subsequent use;
(4) painting method:
1. according to table one proportioning table, drop into successively in order Ethylene Propylene Terpolymer regeneration rubber modifying asphalt solution, 200# aliphatic solvents oil, organobentonite, dispersion agent;
2. start high speed dispersor, middling speed 500 ~ 800r/min, disperses 10 ~ 15 minutes; Then red iron oxide, ground barium sulfate, hexafluorophosphoric acid calcium powder, triethyl aluminum are slowly dropped in dispersion limit in limit;
3. after feeding intake, rate of dispersion is promoted to 1200 ~ 1400r/min, disperses 30 ~ 40 minutes;
4. then go up sand mill and grind, mesh-of-grind≤40 μ m;
5. add rare earth composite drier, stir 10 ~ 20 minutes, filter and package.
The technology of the present invention product performance and technical indicator, see the following form 2.
Table 2 the technology of the present invention product performance technical indicator
As can be seen from Table 2, this invention product has following feature:
1. excellent physical and mechanical properties the technology of the present invention product ethylene-propylene diene reclaimed rubber modifying asphalt rust-proofing primer can form tough and tensile coating after doing solid work, and coating has good elasticity and has the features such as good snappiness, wear resistance, shock-resistance.
2. not only with low cost, and excellent chemical-resistant and antiseptic property ethylene-propylene diene reclaimed rubber modifying asphalt rust-inhibiting primer coating have excellent chemical-resistant, the long period of soaking of the chemical such as acid-and base-resisting highly, salt, salt fog, aliphatic hydrocarbon.
3. the technology of the present invention product is antirust except can be applicable to traditional plain metal, is also applicable to the petroleum pipe line antirust, anti-corrosive under severe environment.
Example 2: a kind of antirust paint for priming paint and top lacquer of ethylene-propylene diene reclaimed rubber modifying asphalt of grey
The antirust paint for priming paint and top lacquer component proportion of the ethylene-propylene diene reclaimed rubber modifying asphalt table of table 3 grey:
Above-mentioned preparation method comprises the following steps:
(1) Ethylene Propylene Terpolymer regeneration rubber solution manufacturing method: adopt trichloropropane and 200# aliphatic hydrocarbon mixed solvent to make Ethylene Propylene Terpolymer regeneration rubber solvent.The two blending ratio is, trichloropropane: 200# aliphatic solvents=1:1 weight ratio, and according to the part by weight of Ethylene Propylene Terpolymer regeneration rubber: mixed solvent=60:40, soaked overnight, micelle is partly dissolved and is softened; Then use atomized ash sand mill, grind together, with high speed dispersor 1200 ~ 1400r/min dispersion 20 ~ 30 minutes, grind according to this high speed dispersion 2 ~ 3 roads; Micelle is broken, and is then dissolved into resin state;
(2) bituminous solution preparation: according to 200# aliphatic solvents: 10# petroleum pitch=40:60 part by weight, aliphatic solvents is added in the container with stirring and heating unit thereof, heat while stirring, drop into 1/2nd of above-mentioned pitch simultaneously, after pitch dissolves completely, drop into again remaining 10# petroleum pitch, after dissolving, make solids content and be 60% Ethylene Propylene Terpolymer regeneration rubber modifying asphalt solution;
(3) according to 10# petroleum pitch: the solids ratios of Ethylene Propylene Terpolymer regeneration rubber=1:1 ~ 1.5, mixes.High speed dispersion 25 ~ 30 minutes, for subsequent use;
(4) painting method:
1. according to above-mentioned composition, drop into successively in order Ethylene Propylene Terpolymer regeneration rubber modifying asphalt solution, 200# aliphatic solvents oil, organobentonite, dispersion agent;
2. start high speed dispersor, middling speed 500 ~ 800r/min, disperses 10 ~ 15 minutes; Then rutile titanium white powder, ground barium sulfate, hexafluorophosphoric acid calcium powder, triethyl aluminum are slowly dropped in dispersion limit in limit;
3. after feeding intake, rate of dispersion is promoted to 1200 ~ 1400r/min, disperses 30 ~ 40 minutes;
4. then go up sand mill and grind, mesh-of-grind≤40 μ m;
5. add rare earth composite drier, stir 10 ~ 20 minutes, filter and package.
The technology of the present invention product performance and technical indicator, see the following form 2.
Table 4 the technology of the present invention product performance technical indicator
As can be seen from Table 4, this invention product has following feature:
1. the excellent antirust priming-finishing integrated rust protection paint of physical and mechanical properties the technology of the present invention product ethylene-propylene diene reclaimed rubber modifying asphalt can form tough and tensile coating after doing solid work, and coating has good elasticity and has the features such as good snappiness, wear resistance, shock-resistance.
2. not only with low cost, and excellent chemical-resistant and antiseptic property ethylene-propylene diene reclaimed rubber modifying asphalt priming-finishing integrated rust protection paint coating have excellent chemical-resistant, the long period of soaking of the chemical such as acid-and base-resisting highly, salt, salt fog, aliphatic hydrocarbon.
3. the technology of the present invention product is antirust except can be applicable to traditional plain metal, is also applicable to the petroleum pipe line antirust, anti-corrosive under severe environment.