CN105950017A - Rust-proof asphalt paint for bottom of special container - Google Patents
Rust-proof asphalt paint for bottom of special container Download PDFInfo
- Publication number
- CN105950017A CN105950017A CN201610414594.XA CN201610414594A CN105950017A CN 105950017 A CN105950017 A CN 105950017A CN 201610414594 A CN201610414594 A CN 201610414594A CN 105950017 A CN105950017 A CN 105950017A
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- China
- Prior art keywords
- rust
- proof
- solvent
- container
- activator
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D195/00—Coating compositions based on bituminous materials, e.g. asphalt, tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses rust-proof asphalt paint for the bottom of a special container. A high-quality refined solvent and high-quality road asphalt are selected; meanwhile, rust-proof wax and an additive with the good plasticization performance are added, organic bentonite, heavy calcium powder and the like are matched, the suitable viscosity is adjusted so that spot construction can be convenient, and after the solvent is volatilized, a black light protective film with the long-term corrosion-proof and harsh-resistant conditions are formed in the bottom of the special container. The rust-proof deadline is at least 5 years or above, cost is reduced, the service life of the container is prolonged, and meanwhile it can be guaranteed that the rust-proof asphalt paint has the good corrosion-proof and rust-proof performance at the temperature of -30 DEG C to 100 DEG C; the rust-proof asphalt paint has the excellent corrosion resistance, the solvent is environmentally friendly and safe, hazardous substances such as heavy metal are not contained in the product, storing is convenient, construction is simple, and performance is stable.
Description
Technical field
The present invention relates to C09D coating composition in IPC classification, in particular for the asphalt caulk that container base is antirust.
Background technology
Generally asphalt caulk is with Colophonium and coal tar as primary raw material, adds the organic solvents such as diluent, modifying agent, drier
Composition.The proportioning of primary raw material is typically different because weather, temperature, use environment are different, and the use of modifying agent presses demand not
Add together.Its characteristic includes: thermostability is poor, and drying time is short, and favorable anti-corrosion effect has excellent weather resistance；It is applicable to height
Warm, wet, chemical, air pollution and seashore salinity high be prone to the iron structure of corrosive environment, electrified railway system, boats and ships,
Bridge and all kinds of zinc-plated equipment iron pipe, wave plate, the protective coating of zinc-plated steel frame structure, be used for underground piping antiseptic project.
The container of China in 1994 has exceeded the Korea S being known as " container kingdom " at that time, and the container of China is to fly
Fast speed development, China has been the container production big country ranked the first in the world at present.Container is international transport
With the specific purpose tool of logistics, the overwhelming majority is steel structure.Owing to the transport of container is to travel to and fro between land and ocean,
Require have stronger anticorrosive property and temperature-change resistance (-40～70 DEG C), the most also require good decorative property, invariant color, not powder
Change, wear-resistant, damage resistant, impact resistance etc., and be amenable to the test of mal-condition.Container industry requires container drip
In the blue or green paint antirust time limit of more than at least 3 years, the jump in temperature of 40-70 DEG C can be stood, environment is had and well adapts to
Property, it is possible to stand the test of mal-condition.This just protection to the metal structure being in harsh corrosive environment propose more
High requirement, including container base, general standard requirement, container Colophonium underframe paint spraying thickness typically require be
200μm。
Inland container bitumastic is all based on solvent based coating at present, and it contains substantial amounts of organic volatile
VOC (Volatile Organic Compounds), these organic volatile great majority are inflammable and explosive noxious substance, no
Only polluting environment, the waste energy, and workman's construction environment is severe, serious harm workmen's is healthy, to the mankind
Multiple harm is brought with environment.Such as Chinese invention patent application CN200510136609.2 discloses a kind of for metal
Structural member and the etch-proof long-acting anticorrosive metal paint of hardware and manufacturing process thereof, by modified high-molecular organic compound
Coal tar pitch, organic polymer resin, antirust agent and auxiliary agent are blended, agitated, grind, adjust and add firming agent after viscosity
Forming, it has extremely excellent extra-weather-proof performance and decay resistance, can become rusty at band, operation under the conditions of band water, band greasy dirt,
Can be widely applied to the antiseptic projects such as the hardware under various environment, building, underground engineering and boats and ships.But this technical side
Case application effect is still to be tested.
It is correspondingly improved technical scheme and also has a small amount of open, such as:
Chinese patent application 201210005168.2 Guangzhou Jointas Chemical Co., Ltd. and South China Science & Engineering University disclose a kind of collection
Vanning underframe aqueous imitates Colophonium anticorrosive coating and preparation method thereof, and by weight percentage, its raw material is by following components structure
Become: tap water 5-13%, aqueous acrylic emulsion 46-62%, rust resisting pigment 10-15%, body constitution filler 15-22%,
Anti-settling agent 0.6-1.0%, wetting dispersing agent A 0.05-0.2%, wetting dispersing agent BOT0.2-1.0%, coalescents 4-6%,
Defoamer 0.1-0.3%, pH adjusting agent 0.2-0.4%, salt spray resistance auxiliary agent 0.4-0.8%, anti-sudden strain of a muscle rust agent 0.1-0.2% and
Thickening agent 0.1-0.7%.Similar product is through overtesting, and it is difficult to reach to spray thickness requirement.
Summary of the invention
It is an object of the invention to provide antirust asphalt caulk bottom a kind of special container, this coating environment-protecting asepsis, low cost, execute
Work is simple, rust-proof life limit for length, it is simple at the surface direct spraying processed.
The purpose of the present invention will be realized by techniques below measure: formula is:
Refined low abnormal smells from the patient solvent: 5-30%
70# road asphalt: 10-40%
Rust-proofing wax: 1-10%
Base oil: 0.2-5%
Plasticizer: 0.2-5%
Organobentonite: 0.2-5%
Activator: 0.2-5%
Dicalcium powder: 10-40%
The step of preparation method includes:
The most in a kettle., Colophonium is added in solvent-refined oil, heat and be sufficiently stirred for, temperature 90 ± 10 DEG C, stirring
Time 2 h, double product detects, chemically examine qualified after carry out next step again.
8. being preheated in drying room by rust-proofing wax, after it becomes liquid, slowly put into, temperature controls at 55-65 DEG C,
Mixing time 25-35 minute.
Putting into base oil and plasticizer the most successively, temperature controls at 55-65 DEG C, stirs 25-35 minute.
10. slowly putting into organobentonite above reactor, meanwhile, agitator need to ceaselessly stir in batches, and temperature controls
At 55-65 DEG C, mixing time 25-35 minute.
Putting into activator, the amount of input need to be accurate in units of g, and activator can occur chemistry anti-with organobentonite
Should, during this, temperature controls at 55-65 DEG C, mixing time 45-55 minute.
Put into dicalcium powder, stir, be cooled to room temperature, complete preparation.
Especially, refined low abnormal smells from the patient solvent is D60, and base oil is No. 10 machinery oil, and plasticizer is adipic acid two
Pungent fat, activator is the ethanol of 95%.
Advantages of the present invention and effect: select refining solvent and the road asphalt of high-quality, add rust-proofing wax, plasticising simultaneously
The additive of better performances, coordinates with organobentonite, dicalcium powder etc., adjusts suitable viscosity, to facilitate scene
Construction, forms the protection of the black bright of long-term anticorrosion and resistance to harsh conditions in container base after solvent volatilization
Film.The antirust time limit of more than at least 5 years can be provided, reduce cost, extend the service life of container, energy simultaneously
Enough ensure, under conditions of-30 DEG C and 100 DEG C, still there is preferable anti-rust and corrosionproperties, possess the anticorrosive property of excellence,
Solvent Environmental Safety, product is without harmful substances such as heavy metals, and it is convenient to store, and construction is simple, stable performance.
Detailed description of the invention
The principle of the invention is, selects refining solvent and the road asphalt of high-quality, adds rust-proofing wax, plasticising performance relatively simultaneously
Good additive, coordinates with organobentonite, dicalcium powder etc., adjusts suitable viscosity, to facilitate the construction at scene,
Form the protecting film of the black bright of long-term anticorrosion and resistance to harsh conditions in container base after solvent volatilization.
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1: formula is:
Refined low abnormal smells from the patient solvent: 25%
70# road asphalt: 32%
Rust-proofing wax: 3%
Base oil: 1%
Plasticizer: 1%
Organobentonite: 2%
Activator: 1%
Dicalcium powder: 35%
The step of preparation method includes:
The most in a kettle., Colophonium is added in solvent-refined oil, heat and be sufficiently stirred for, temperature 90 ± 10 DEG C, stirring
Time 2 h, double product detects, chemically examine qualified after carry out next step again.
2. being preheated in drying room by rust-proofing wax, after it becomes liquid, slowly put into, temperature controls at 55-65 DEG C,
Mixing time 25-35 minute.
Putting into base oil and plasticizer the most successively, temperature controls at 55-65 DEG C, stirs 25-35 minute.
4. slowly putting into organobentonite above reactor, meanwhile, agitator need to ceaselessly stir in batches, and temperature controls
At 55-65 DEG C, mixing time 25-35 minute.
5. putting into activator, the amount of input need to be accurate in units of g, and activator can occur chemistry anti-with organobentonite
Should, during this, temperature controls at 55-65 DEG C, mixing time 45-55 minute.
6. put into dicalcium powder, stir, be cooled to room temperature, complete preparation.
In aforementioned, refined low abnormal smells from the patient solvent is D60, and base oil is No. 10 machinery oil, and plasticizer is adipic acid two
Pungent fat, activator is the ethanol of 95%.
In the present embodiment, preparing the asphalt caulk index of quality is:
| Detection project | Control standard |
| Outward appearance | Black non transparent liquid |
| Proportion (15/4 DEG C) | 1.2±0.2 |
| Thixotropy | 4.5↑ |
| Salt spray test (hour) | 1000↑ |
| Interior fluidity (μm) | 600↑ |
| Tolerance to cold (-40 DEG C) | Flawless |
| Thermostability (100 DEG C) | No sag |
In the present invention, the basic outward appearance of asphalt caulk and workability all can reach the requirement of container base paint, coating
Surface drying time is short, and impact resistance, acid resistance, alkali resistance, salt fog resistance etc. the farthest surpass industry standard, and this product is described
Product are with a wide range of applications on container.Its property indices is all up to state standards.
Above example is described in detail embodiments of the present invention, but this is only to facilitate the example that understands and lift, should
It is considered to be limitation of the scope of the invention.Equally, any person of ordinary skill in the field all can be according to the skill of the present invention
Art scheme and the description of preferred embodiment thereof, make various possible equivalent and change or replace, but all these change or replacement
All should belong to the protection domain of the claims in the present invention.
Claims (2)
1. antirust asphalt caulk bottom special container, it is characterised in that formula is:
Refined low abnormal smells from the patient solvent: 5-30%
70# road asphalt: 10-40%
Rust-proofing wax: 1-10%
Base oil: 0.2-5%
Plasticizer: 0.2-5%
Organobentonite: 0.2-5%
Activator: 0.2-5%
Dicalcium powder: 10-40%
The step of preparation method includes:
The most in a kettle., Colophonium is added in solvent-refined oil, heat and be sufficiently stirred for, temperature 90 ± 10 DEG C, stirring
Time 2 h, double product detects, chemically examine qualified after carry out next step again；
2. being preheated in drying room by rust-proofing wax, after it becomes liquid, slowly put into, temperature controls at 55-65 DEG C,
Mixing time 25-35 minute；
Putting into base oil and plasticizer the most successively, temperature controls at 55-65 DEG C, stirs 25-35 minute；
4. slowly putting into organobentonite above reactor, meanwhile, agitator need to ceaselessly stir in batches, and temperature controls
At 55-65 DEG C, mixing time 25-35 minute；
5. putting into activator, the amount of input need to be accurate in units of g, and activator can occur chemistry anti-with organobentonite
Should, during this, temperature controls at 55-65 DEG C, mixing time 45-55 minute；
6. put into dicalcium powder, stir, be cooled to room temperature, complete preparation.
2. the asphalt caulk antirust for container base as claimed in claim 1, it is characterised in that: refined low abnormal smells from the patient is molten
Agent is D60, and base oil is No. 10 machinery oil, and plasticizer is adipic acid dibutyl ester, and activator is the ethanol of 95%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610414594.XA CN105950017B (en) | 2016-06-14 | 2016-06-14 | Special container bottom antirust asphalt caulk |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610414594.XA CN105950017B (en) | 2016-06-14 | 2016-06-14 | Special container bottom antirust asphalt caulk |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105950017A true CN105950017A (en) | 2016-09-21 |
| CN105950017B CN105950017B (en) | 2019-03-01 |
Family
ID=56906390
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610414594.XA Active CN105950017B (en) | 2016-06-14 | 2016-06-14 | Special container bottom antirust asphalt caulk |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105950017B (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6270462A (en) * | 1985-09-25 | 1987-03-31 | Kawasaki Steel Corp | Bituminous corrosion-preventive composition for structural material |
| CN101319104A (en) * | 2008-06-20 | 2008-12-10 | 中国矿业大学(北京) | Composite suspension agent of alcohol based dry powder paint, preparation method and prepared paint thereof |
| CN102618044A (en) * | 2011-01-27 | 2012-08-01 | 中科合成油技术有限公司 | Antirust wax |
| CN103013334A (en) * | 2012-11-28 | 2013-04-03 | 天长市开林化工有限公司 | Asphalt anticorrosive paint applied to hull bottoms |
| CN103881574A (en) * | 2013-11-08 | 2014-06-25 | 东南大学 | Antirust varnish |
| CN104087173A (en) * | 2014-07-24 | 2014-10-08 | 苏州吉人漆业有限公司 | Ethylene propylene diene monomer regenerated rubber modified asphalt anti-rust paint |
-
2016
- 2016-06-14 CN CN201610414594.XA patent/CN105950017B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6270462A (en) * | 1985-09-25 | 1987-03-31 | Kawasaki Steel Corp | Bituminous corrosion-preventive composition for structural material |
| CN101319104A (en) * | 2008-06-20 | 2008-12-10 | 中国矿业大学(北京) | Composite suspension agent of alcohol based dry powder paint, preparation method and prepared paint thereof |
| CN102618044A (en) * | 2011-01-27 | 2012-08-01 | 中科合成油技术有限公司 | Antirust wax |
| CN103013334A (en) * | 2012-11-28 | 2013-04-03 | 天长市开林化工有限公司 | Asphalt anticorrosive paint applied to hull bottoms |
| CN103881574A (en) * | 2013-11-08 | 2014-06-25 | 东南大学 | Antirust varnish |
| CN104087173A (en) * | 2014-07-24 | 2014-10-08 | 苏州吉人漆业有限公司 | Ethylene propylene diene monomer regenerated rubber modified asphalt anti-rust paint |
Non-Patent Citations (1)
| Title |
|---|
| 李子东等: "《胶黏剂助剂 第二版》", 30 June 2009 * |
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| Publication number | Publication date |
|---|---|
| CN105950017B (en) | 2019-03-01 |
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