CN104086125B - A kind of building board and preparation method thereof - Google Patents
A kind of building board and preparation method thereof Download PDFInfo
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- CN104086125B CN104086125B CN201410281182.4A CN201410281182A CN104086125B CN 104086125 B CN104086125 B CN 104086125B CN 201410281182 A CN201410281182 A CN 201410281182A CN 104086125 B CN104086125 B CN 104086125B
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- 238000002360 preparation method Methods 0.000 title abstract description 5
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 38
- 239000004088 foaming agent Substances 0.000 claims abstract description 31
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims abstract description 19
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims abstract description 19
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 19
- 239000000440 bentonite Substances 0.000 claims abstract description 19
- 229910000278 bentonite Inorganic materials 0.000 claims abstract description 19
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000004202 carbamide Substances 0.000 claims abstract description 19
- 235000013877 carbamide Nutrition 0.000 claims abstract description 19
- 239000004568 cement Substances 0.000 claims abstract description 19
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 19
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000003365 glass fiber Substances 0.000 claims abstract description 19
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims abstract description 19
- 229920000609 methyl cellulose Polymers 0.000 claims abstract description 19
- 239000001923 methylcellulose Substances 0.000 claims abstract description 19
- 229910052863 mullite Inorganic materials 0.000 claims abstract description 19
- 239000012188 paraffin wax Substances 0.000 claims abstract description 19
- 239000011347 resin Substances 0.000 claims abstract description 19
- 229920005989 resin Polymers 0.000 claims abstract description 19
- 239000010457 zeolite Substances 0.000 claims abstract description 19
- 239000003077 lignite Substances 0.000 claims abstract description 18
- 239000000203 mixture Substances 0.000 claims description 20
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 239000010459 dolomite Substances 0.000 claims description 2
- 229910000514 dolomite Inorganic materials 0.000 claims description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 55
- 238000009413 insulation Methods 0.000 abstract description 9
- 230000002265 prevention Effects 0.000 abstract description 4
- 239000004566 building material Substances 0.000 abstract description 2
- 238000005187 foaming Methods 0.000 description 26
- 238000010276 construction Methods 0.000 description 15
- 238000000034 method Methods 0.000 description 14
- 239000000758 substrate Substances 0.000 description 12
- 238000010438 heat treatment Methods 0.000 description 11
- 238000004321 preservation Methods 0.000 description 9
- -1 Maifanitum Substances 0.000 description 8
- 239000010881 fly ash Substances 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000012467 final product Substances 0.000 description 6
- 238000007667 floating Methods 0.000 description 6
- 238000003825 pressing Methods 0.000 description 6
- 230000007613 environmental effect Effects 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 150000001450 anions Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 230000002093 peripheral effect Effects 0.000 description 2
- 238000007664 blowing Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
Abstract
The invention belongs to building material field, be specifically related to building board of a kind of lightweight, insulation, high intensity and preparation method thereof.Environment protection architecture sheet material of the present invention is prepared from by following parts by weight of component: cement 5-10 part, paraffin 2-8 part, carbamide 7-13 part, sulfonated-pheno-formoldehyde resin 4-8 part, glass fibre 6-14 part, bentonite 8-15 part, methylcellulose 3-9 part, mullite 1-5 part, Maifanitum 2-5 part, zeolite 2-5 part, sulfonated-methyl brown coal 1-6 part, hydroxyethyl cellulose 4-15 part and foaming agent 0.5-1.5 part.Sheet material of the present invention has the performance of fabulous lightweight, insulation, fire prevention and high intensity, and its performance indications are far above country and Industry code requirements.
Description
Technical field
The invention belongs to building material field, be specifically related to environment protection architecture sheet material of a kind of lightweight, insulation, high intensity and preparation method thereof.
Background technology
Along with socioeconomic high speed development, increasing building is rised sheer from level ground, and presents the high level requirement to " building height, Form of Architecture and construction quality ".Wherein, building heat preservation is to reduce the measure that Indoor environment heat distributes to outdoor, has important effect to creating suitable indoor thermal environment with saving the energy, is also to construction quality important requirement and a guarantee simultaneously.
Building environmental practice, according to the difference of construction location, is broadly divided into building external structure and carries out and carry out two ways from building interior metope.Wherein, carrying out building heat preservation from periphery construction is the mode that current construction is generally sampled, and this mode mainly having benefited from peripheral construction can be uniformly carried out in the construction later stage.But the construction of building heat insulating exterior wall is substantially in the majority with site operation play, being typically employed in the exterior wall last time smears the mortar of bonding, patch benzene plate, linked network, thin-coat plaster etc., owing to this work progress numerous and diverse cycle is long, and inter-layer bonding force is poor, the maturation period making exterior wall differs greatly, the heat insulation function making exterior wall declines, and even affects service life.Therefore, adopt the mode of external wall construction that the weight of heat preservation plate material, resistance to compression and cracking resistance are had high requirement.Especially the glass-wall building quite favored now, its peripheral construction heat-insulating receives many restrictions especially.Therefore, the mode constructed by indoor heat insulating is also got more and more and is used.
But, the requirement identical with outdoor heat preservation construction, also require that the heat preservation plate material of its use has the performance of lightweight, insulation, high intensity, especially fire prevention and environmental-protecting performance are had higher requirement.
Therefore, for building heat preservation, no matter adopt which kind of form of construction work, all cut both ways, search to the bottom and must develop a kind of building board fully meeting the requirement of building heat preservation workability, make it have the performance of lightweight, insulation, fire prevention, high intensity concurrently, the requirement of environmental protection can also be met so that it is different construction requirements can be met according to operating mode simultaneously.
Summary of the invention
For this, the problem that the technical problem to be solved is in that in prior art building board and cannot meet the performance requirement such as environmental protection, lightweight, and then a kind of environment protection architecture sheet material that can be used for outdoor wall thermal insulating and indoor wall insulation is provided, described sheet material has the performances such as lightweight, insulation, high intensity concurrently, can meet the environmental requirement of indoor construction simultaneously.
For solving above-mentioned technical problem, environment protection architecture sheet material of the present invention, is prepared from by following parts by weight of component: cement 5-10 part, paraffin 2-8 part, carbamide 7-13 part, sulfonated-pheno-formoldehyde resin 4-8 part, glass fibre 6-14 part, bentonite 8-15 part, methylcellulose 3-9 part, mullite 1-5 part, Maifanitum 2-5 part, zeolite 2-5 part, sulfonated-methyl brown coal 1-6 part, hydroxyethyl cellulose 4-15 part and foaming agent 0.5-1.5 part.
Preferably, described environment protection architecture sheet material, is prepared from by following parts by weight of component: cement 6-8 part, paraffin 4-6 part, carbamide 9-12 part, sulfonated-pheno-formoldehyde resin 5-7 part, glass fibre 9-12 part, bentonite 10-13 part, methylcellulose 5-7 part, mullite 2-4 part, Maifanitum 3-4 part, zeolite 2.5-4 part, sulfonated-methyl brown coal 2-5 part, hydroxyethyl cellulose 6-11 part and foaming agent 0.7-1.2 part.
Preferred, described environment protection architecture sheet material, is prepared from by following parts by weight of component: cement 7 parts, 5 parts of paraffin, 10 parts of carbamide, sulfonated-pheno-formoldehyde resin 6 parts, glass fibre 10 parts, bentonite 11 parts, methylcellulose 6 parts, mullite 3 parts, Maifanitum 3.5 parts, 3 parts of zeolite, sulfonated-methyl brown coal 4 parts, hydroxyethyl cellulose 9 parts and foaming agent 1 part.
Described foaming agent is the mixture of one or more in sodium carbonate, calcium carbonate, dolomite class foaming agent.
Present invention also offers a kind of method preparing above-mentioned environment protection architecture sheet material, comprise the steps:
(1) take the foaming agent of described cement, flyash, mullite, Maifanitum, bentonite, zeolite, sulfonated-methyl brown coal and selected parts by weight 1/4-1/3 according to selected parts by weight, mix and sieve for subsequent use；
(2) taking described paraffin, carbamide, sulfonated-pheno-formoldehyde resin, glass fibre, methylcellulose, hydroxyethyl cellulose and residue foaming agent according to selected parts by weight, mixing is also heated to 100 DEG C of low-temp foamings carried out above reactions, standby；
(3) by the mixture mixing after the mixture of step (1) and step (2) low-temp foaming, heating carries out foaming process to 400-480 DEG C；
(4) pouring the material after foaming into mould, ram-jolt is floating, and the pressure that described material applies 0.8-1.0MPa carries out mold pressing 5-10s, and the demoulding obtains required sheet material base substrate；
(5) after being dried by described sheet material base substrate, natural curing at normal temperatures 12 hours, to obtain final product.
Further, in described step (3), described blowing temperature is 450 DEG C.
In described step (1), the consumption of described foaming agent is the 30% of selected parts by weight.
In described step (2), described low-temp foaming controls temperature and is 110-120 DEG C.
The invention also discloses a kind of environment protection architecture sheet material prepared according to said method, and disclose the application in building heat preservation field of the described environment protection architecture sheet material.
The technique scheme of the present invention has the advantage that compared to existing technology
1, environment protection architecture sheet material of the present invention is with cement, flyash, mullite, Maifanitum, bentonite, zeolite, paraffin, carbamide, sulfonated-pheno-formoldehyde resin, glass fibre, methylcellulose, hydroxyethyl cellulose and foaming agent for raw material, the sheet material prepared has the performance of fabulous lightweight, insulation, fire prevention and high intensity, and its performance indications are far above country and Industry code requirements；
2, environment protection architecture sheet material of the present invention has on the basis of many high-quality performances, amazing discovery has the function of sustainable release finite concentration negative oxygen ion, make its many requirement being possible not only to meet outdoor architecture heat preservation construction, simultaneously as indoor heat insulating only use, also it is entirely capable of meeting the requirement of its environmental-protecting performance；
3, building board of the present invention is by the original foam process rationally selecting to achieve at a lower temperature, not only making described sheet material have good performance, and energy consumption is relatively low simultaneously；
4, the method preparing sheet material of the present invention, adopts the mode that difference processed in originally respectively that added in batches by foaming agent so that described prepared sheet material has the character of porous, has been greatly reduced temperature and the energy consumption of foam process simultaneously.
Detailed description of the invention
Embodiment 1
Environment protection architecture sheet material described in the present embodiment is prepared from by following parts by weight of component:
Cement 5kg, paraffin 8kg, carbamide 7kg, sulfonated-pheno-formoldehyde resin 8kg, glass fibre 6kg, bentonite 15kg, methylcellulose 3kg, mullite 5kg, Maifanitum 2kg, zeolite 5kg, sulfonated-methyl brown coal 1kg, hydroxyethyl cellulose 15 and foaming agent 0.5kg.
Described in the present embodiment, environment protection architecture sheet material is prepared from by following steps:
(1) take the foaming agent of described cement, flyash, mullite, Maifanitum, bentonite, zeolite, sulfonated-methyl brown coal and selected weight 1/4 according to selected weight, mix and sieve for subsequent use；
(2) take described paraffin, carbamide, sulfonated-pheno-formoldehyde resin, glass fibre, methylcellulose, hydroxyethyl cellulose and residue foaming agent, mixing heating according to selected parts by weight and carry out low-temp foaming reaction to 110 DEG C, standby；
(3) by the mixture mixing after the mixture of step (1) and step (2) low-temp foaming, heating carries out foaming process to 400 DEG C；
(4) pouring the material after foaming into mould, ram-jolt is floating, and the pressure that described material applies 0.8-1.0MPa carries out mold pressing 5-10s, and the demoulding obtains required sheet material base substrate；
(5) after being dried by described sheet material base substrate, natural curing at normal temperatures 12 hours, to obtain final product.
Embodiment 2
Environment protection architecture sheet material described in the present embodiment is prepared from by following parts by weight of component:
Cement 10kg, paraffin 2kg, carbamide 13kg, sulfonated-pheno-formoldehyde resin 4kg, glass fibre 14kg, bentonite 8kg, methylcellulose 9kg, mullite 1kg, Maifanitum 5kg, zeolite 2kg, sulfonated-methyl brown coal 6kg, hydroxyethyl cellulose 4kg and foaming agent 1.5kg.
Described in the present embodiment, environment protection architecture sheet material is prepared from by following steps:
(1) take the foaming agent of described cement, flyash, mullite, Maifanitum, bentonite, zeolite, sulfonated-methyl brown coal and selected parts by weight 1/3 according to selected parts by weight, mix and sieve for subsequent use；
(2) take described paraffin, carbamide, sulfonated-pheno-formoldehyde resin, glass fibre, methylcellulose, hydroxyethyl cellulose and residue foaming agent, mixing heating according to selected parts by weight and carry out low-temp foaming reaction to 120 DEG C, standby；
(3) by the mixture mixing after the mixture of step (1) and step (2) low-temp foaming, heating carries out foaming process to 480 DEG C；
(4) pouring the material after foaming into mould, ram-jolt is floating, and the pressure that described material applies 0.8-1.0MPa carries out mold pressing 5-10s, and the demoulding obtains required sheet material base substrate；
(5) after being dried by described sheet material base substrate, natural curing at normal temperatures 12 hours, to obtain final product.
Embodiment 3
Environment protection architecture sheet material described in the present embodiment is prepared from by following parts by weight of component:
Cement 6kg, paraffin 6kg, carbamide 9kg, sulfonated-pheno-formoldehyde resin 7kg, glass fibre 9kg, bentonite 13kg, methylcellulose 5kg, mullite 4g, Maifanitum 3kg, zeolite 4kg, sulfonated-methyl brown coal 2kg, hydroxyethyl cellulose 11kg and foaming agent 0.7kg.
Described in the present embodiment, environment protection architecture sheet material is prepared from by following steps:
(1) take the foaming agent of described cement, flyash, mullite, Maifanitum, bentonite, zeolite, sulfonated-methyl brown coal and selected parts by weight 30% according to selected weight, mix and sieve for subsequent use；
(2) take described paraffin, carbamide, sulfonated-pheno-formoldehyde resin, glass fibre, methylcellulose, hydroxyethyl cellulose and residue foaming agent, mixing heating according to selected weight and carry out low-temp foaming reaction to 110 DEG C, standby；
(3) by the mixture mixing after the mixture of step (1) and step (2) low-temp foaming, heating carries out foaming process to 450 DEG C；
(4) pouring the material after foaming into mould, ram-jolt is floating, and the pressure that described material applies 0.8-1.0MPa carries out mold pressing 5-10s, and the demoulding obtains required sheet material base substrate；
(5) after being dried by described sheet material base substrate, natural curing at normal temperatures 12 hours, to obtain final product.
Embodiment 4
Environment protection architecture sheet material described in the present embodiment is prepared from by following parts by weight of component:
Cement 8kg, paraffin 4kg, carbamide 12kg, sulfonated-pheno-formoldehyde resin 5kg, glass fibre 12kg, bentonite 10kg, methylcellulose 7kg, mullite 2kg, Maifanitum 4kg, zeolite 2.5kg, sulfonated-methyl brown coal 5kg, hydroxyethyl cellulose 6kg and foaming agent 1.2kg.
Described in the present embodiment, environment protection architecture sheet material is prepared from by following steps:
(1) take the foaming agent of described cement, flyash, mullite, Maifanitum, bentonite, zeolite, sulfonated-methyl brown coal and selected weight 30% according to selected weight, mix and sieve for subsequent use；
(2) take described paraffin, carbamide, sulfonated-pheno-formoldehyde resin, glass fibre, methylcellulose, hydroxyethyl cellulose and residue foaming agent, mixing heating according to selected weight and carry out low-temp foaming reaction to 120 DEG C, standby；
(3) by the mixture mixing after the mixture of step (1) and step (2) low-temp foaming, heating carries out foaming process to 450 DEG C；
(4) pouring the material after foaming into mould, ram-jolt is floating, and the pressure that described material applies 0.8-1.0MPa carries out mold pressing 5-10s, and the demoulding obtains required sheet material base substrate；
(5) after being dried by described sheet material base substrate, natural curing at normal temperatures 12 hours, to obtain final product.
Embodiment 5
Environment protection architecture sheet material described in the present embodiment is prepared from by following parts by weight of component:
Cement 7kg, paraffin 5kg, carbamide 10kg, sulfonated-pheno-formoldehyde resin 6kg, glass fibre 10kg, bentonite 11kg, methylcellulose 6kg, mullite 3kg, Maifanitum 3.5kg, zeolite 3kg, sulfonated-methyl brown coal 4kg, hydroxyethyl cellulose 9kg and foaming agent 1kg.
Present invention also offers a kind of method preparing above-mentioned environment protection architecture sheet material, comprise the steps:
(1) take the foaming agent of described cement, flyash, mullite, Maifanitum, bentonite, zeolite, sulfonated-methyl brown coal and selected parts by weight 30% according to selected weight, mix and sieve for subsequent use；
(2) take described paraffin, carbamide, sulfonated-pheno-formoldehyde resin, glass fibre, methylcellulose, hydroxyethyl cellulose and residue foaming agent, mixing heating according to selected weight and carry out low-temp foaming reaction to 120 DEG C, standby；
(3) by the mixture mixing after the mixture of step (1) and step (2) low-temp foaming, heating carries out foaming process to 450 DEG C；
(4) pouring the material after foaming into mould, ram-jolt is floating, and the pressure that described material applies 0.8-1.0MPa carries out mold pressing 5-10s, and the demoulding obtains required sheet material base substrate；
(5) after being dried by described sheet material base substrate, natural curing at normal temperatures 12 hours, to obtain final product.
Embodiment 6
The raw material of building board described in the present embodiment is identical with embodiment 5, and it differs only in, and in described preparation method, directly carries out foaming process in 450 DEG C after first being mixed by each raw material, and step is identical thereafter.
Effect example
The sheet material prepared in above-described embodiment 1-6 is carried out performance test, detailed programs and index and sees following table.
And by the described building board 10*10cm size prepared, it is placed in 60L seal box, use read-only anion analyzer to measure negative ion concentration record in case after 24 hours.
Visible, building board of the present invention not only indices meets even above country and industry standard, simultaneously described sheet material can effective anion releasing, there is fabulous environmental-protecting performance.
Obviously, above-described embodiment is only for clearly demonstrating example, and is not the restriction to embodiment.For those of ordinary skill in the field, can also make other changes in different forms on the basis of the above description.Here without also cannot all of embodiment be given exhaustive.And the apparent change thus extended out or variation are still among the protection domain of the invention.
Claims (4)
1. a building board, it is characterized in that, following parts by weight of component be prepared from: cement 5-10 part, paraffin 2-8 part, carbamide 7-13 part, sulfonated-pheno-formoldehyde resin 4-8 part, glass fibre 6-14 part, bentonite 8-15 part, methylcellulose 3-9 part, mullite 1-5 part, Maifanitum 2-5 part, zeolite 2-5 part, sulfonated-methyl brown coal 1-6 part, hydroxyethyl cellulose 4-15 part and foaming agent 0.5-1.5 part.
2. building board according to claim 1, it is characterized in that, following parts by weight of component be prepared from: cement 6-8 part, paraffin 4-6 part, carbamide 9-12 part, sulfonated-pheno-formoldehyde resin 5-7 part, glass fibre 9-12 part, bentonite 10-13 part, methylcellulose 5-7 part, mullite 2-4 part, Maifanitum 3-4 part, zeolite 2.5-4 part, sulfonated-methyl brown coal 2-5 part, hydroxyethyl cellulose 6-11 part and foaming agent 0.7-1.2 part.
3. building board according to claim 1 and 2, it is characterized in that, following parts by weight of component be prepared from: cement 7 parts, 5 parts of paraffin, 10 parts of carbamide, sulfonated-pheno-formoldehyde resin 6 parts, glass fibre 10 parts, bentonite 11 parts, methylcellulose 6 parts, mullite 3 parts, Maifanitum 3.5 parts, 3 parts of zeolite, sulfonated-methyl brown coal 4 parts, hydroxyethyl cellulose 9 parts and foaming agent 1 part.
4. building board according to claim 1 and 2, it is characterised in that described foaming agent is the mixture of one or more in sodium carbonate, calcium carbonate, dolomite foaming agent.
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| CN201410281182.4A CN104086125B (en) | 2014-06-20 | 2014-06-20 | A kind of building board and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410281182.4A CN104086125B (en) | 2014-06-20 | 2014-06-20 | A kind of building board and preparation method thereof |
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| CN104086125A CN104086125A (en) | 2014-10-08 |
| CN104086125B true CN104086125B (en) | 2016-06-29 |
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| CN107602061A (en) * | 2016-03-11 | 2018-01-19 | 夏立中 | A kind of high-quality building template and preparation method thereof |
| CN106145804A (en) * | 2016-07-12 | 2016-11-23 | 广西南宁桂尔创环保科技有限公司 | A kind of novel environment friendly building board |
| CN106186866A (en) * | 2016-07-12 | 2016-12-07 | 广西南宁桂尔创环保科技有限公司 | A kind of building board of improvement |
| CN106187278A (en) * | 2016-07-12 | 2016-12-07 | 广西南宁桂尔创环保科技有限公司 | A kind of building panel |
| CN106146031A (en) * | 2016-07-12 | 2016-11-23 | 广西南宁桂尔创环保科技有限公司 | A kind of building board |
| CN106167374A (en) * | 2016-07-12 | 2016-11-30 | 广西南宁桂尔创环保科技有限公司 | A kind of environment protection architecture sheet material |
| CN106186867A (en) * | 2016-07-12 | 2016-12-07 | 广西南宁桂尔创环保科技有限公司 | A kind of high performance building board |
| CN106747135A (en) * | 2016-11-29 | 2017-05-31 | 郑佳丹 | A kind of environmental friendly material of antibacterial, waterproof |
| CN107053447B (en) * | 2017-05-23 | 2019-04-12 | 广西睿桂涵农业有限公司 | A kind of maintenance process of cement products |
| CN108468408B (en) * | 2018-03-07 | 2020-04-10 | 深圳市中饰南方建设工程有限公司 | Environment-friendly building composite board and manufacturing method thereof |
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| KR20130102745A (en) * | 2012-03-08 | 2013-09-23 | 주식회사 엔바이온 | Manufacturing of functional deorderizer using activated carbon made from waste tires powder |
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| CN101139189A (en) * | 2007-08-10 | 2008-03-12 | 陈忠平 | Vitreous pearlite inorganic composite heat-insulating material and method for making same |
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