CN106747135A - A kind of environmental friendly material of antibacterial, waterproof - Google Patents

A kind of environmental friendly material of antibacterial, waterproof Download PDF

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Publication number
CN106747135A
CN106747135A CN201611067611.3A CN201611067611A CN106747135A CN 106747135 A CN106747135 A CN 106747135A CN 201611067611 A CN201611067611 A CN 201611067611A CN 106747135 A CN106747135 A CN 106747135A
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China
Prior art keywords
parts
antibacterial
waterproof
environmental friendly
friendly material
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CN201611067611.3A
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Chinese (zh)
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郑佳丹
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Individual
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Priority to CN201611067611.3A priority Critical patent/CN106747135A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/06Aluminous cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/27Water resistance, i.e. waterproof or water-repellent materials

Abstract

The present invention discloses the environmental friendly material of a kind of antibacterial, waterproof, including the raw material that following parts by weight are matched:20 30 parts of nano silver antimicrobials, 9 11 parts of sulfonated-pheno-formoldehyde resin, 60 70 parts of polyvinyl alcohol, 50 70 parts of bentonite, 0.5 1.5 parts of cupric sulfate pentahydrate, 10 14 parts of mullite, 0.1 0.3 parts of calcium stearate, 10 20 parts of higher aliphatic acids waterproofing agent, 0.3 0.9 parts of 1010 antioxidant, 10 20 parts of Tissuemat E, 100 150 parts of sulphate aluminium cement, 15 19 parts of glass fibre, 10 16 parts of zeolite, 46 parts of epoxy resin, 100 150 parts of water;Effectively, waterproof is effective, health environment-friendly for the antibacterial, the environmental friendly material antibacterial of waterproof.

Description

A kind of environmental friendly material of antibacterial, waterproof
Technical field
The present invention relates to a kind of antibacterial, the environmental friendly material of waterproof.
Background technology
New material refers to some materials newly-developed or researching and developing, having preeminent performance, with than traditional material more It is excellent performance.New material technology is then according to the will of people, is processed by physical study, design of material, material, tests and comment A series of research process such as valency, create the technology of the new material that can meet various needs.
The history that composite material is used can trace back to ancient times.The straw continued to use from ancient times to the present strengthens clay and has used Upper century-old armored concrete is formed by two kinds of Material claddings.The forties in 20th century, because of aircraft industry the need for, developed glass Glass fibre reinforced plastics (are commonly called as fiberglass), and composite this title is occurred in that from this.After the fifties, carbon is developed successively The high intensity such as fiber, graphite fibre and boron fibre and high modulus fibre.Occur in that aramid fiber and silicon carbide fibre the seventies.This A little high intensity, high modulus fibre can be with the metals such as nonmetal basal body or aluminium, magnesium, titanium such as synthetic resin, carbon, graphite, ceramics, rubber Matrix is combined, the composite that composition differs from one another.
The specific strength of superhigh molecular weight polyethylene fibers ranks first place in various fibers, especially its anti-chemical reagent Erosion performance and ageing resistace are excellent.It also has excellent high frequency sonar permeability and resistance to corrosion seawater, many countries The high frequency sonar dome of naval vessels is manufactured with it, detecting a mine, the clearance ability of naval vessels has been substantially increased, good green wood has been thought at home Expect that the composite material of exploitation represents the higher level of the country.Except in military field, in automobile making, shipbuilding, medical treatment The field such as apparatus, athletic sports appliance superhigh molecular weight polyethylene fibers also have broad application prospects.The fiber is once appearance Just cause great interest and the attention of World Developed Countries.
But antibacterial now, the antibacterial effect of the environmental friendly material of waterproof are general, and waterproof effect is general, and unhealthy ring Protect.
The content of the invention
In view of this, this is to provide a kind of antibacterial effectively with goal of the invention, and waterproof is effective, the antibacterial of health environment-friendly, waterproof Environmental friendly material.
In order to solve the above-mentioned technical problem, the technical scheme is that:
The environmental friendly material of a kind of antibacterial, waterproof, including the raw material that following parts by weight are matched:Nano silver antimicrobials 20- 30 parts, sulfonated-pheno-formoldehyde resin 9-11 parts, polyvinyl alcohol 60-70 parts, bentonite 50-70 parts, cupric sulfate pentahydrate 0.5-1.5 parts, Mullite 10-14 parts, calcium stearate 0.1-0.3 parts, 10-20 parts of higher aliphatic acids waterproofing agent, 1010 antioxidant 0.3-0.9 Part, Tissuemat E 10-20 parts, sulphate aluminium cement 100-150 parts, glass fibre 15-19 parts, zeolite 10-16 parts, epoxy resin 4-6 parts, water 100-150 parts.
Further, a kind of described antibacterial, the environmental friendly material of waterproof, including the raw material that following parts by weight are matched: 20 parts of nano silver antimicrobials, 9 parts of sulfonated-pheno-formoldehyde resin, 60 parts of polyvinyl alcohol, 50 parts of bentonite, 0.5 part of cupric sulfate pentahydrate, not Come 10 parts of stone, 0.1 part of calcium stearate, 10 parts of higher aliphatic acids waterproofing agent, 0.3 part of 1010 antioxidant, 10 parts of Tissuemat E, sulphur 100 parts of aluminate cement, 15 parts of glass fibre, 10 parts of zeolite, 4 parts of epoxy resin, 100 parts of water.
Further, a kind of described antibacterial, the environmental friendly material of waterproof, including the raw material that following parts by weight are matched: 30 parts of nano silver antimicrobials, 11 parts of sulfonated-pheno-formoldehyde resin, 70 parts of polyvinyl alcohol, 70 parts of bentonite, 1.5 parts of cupric sulfate pentahydrate, 14 parts of mullite, 0.3 part of calcium stearate, 20 parts of higher aliphatic acids waterproofing agent, 0.9 part of 1010 antioxidant, 20 parts of Tissuemat E, 150 parts of sulphate aluminium cement, 19 parts of glass fibre, 16 parts of zeolite, 6 parts of epoxy resin, 150 parts of water.
Further, a kind of described antibacterial, the environmental friendly material of waterproof, including the raw material that following parts by weight are matched: 25 parts of nano silver antimicrobials, 10 parts of sulfonated-pheno-formoldehyde resin, 65 parts of polyvinyl alcohol, 60 parts of bentonite, 1 part of cupric sulfate pentahydrate, not Come 12 parts of stone, 0.2 part of calcium stearate, 15 parts of higher aliphatic acids waterproofing agent, 0.6 part of 1010 antioxidant, 15 parts of Tissuemat E, sulphur 125 parts of aluminate cement, 17 parts of glass fibre, 13 parts of zeolite, 5 parts of epoxy resin, 125 parts of water.
A kind of antibacterial, the preparation method of the environmental friendly material of waterproof are as follows:
1) 13 parts of 60 parts of bentonite, 12 parts of mullite, 125 parts of sulphate aluminium cement, 17 parts of glass fibre and zeolite is taken to put Enter grinder, grinding particle diameter is 400 mesh, standby;
2) by nano silver antimicrobials 25 parts put into step 1) in, be placed in a centrifuge, temperature be 25 DEG C at, rotating speed is 2000r/min, centrifugation rotates 35min, obtains antibacterial composite soil;
3) 10 parts of sulfonated-pheno-formoldehyde resin, 65 parts of polyvinyl alcohol are taken and are added to step 2) in antibacterial composite soil, be heated to Foaming treatment is carried out after 500 DEG C;
4) step 3) in mixture add 15 parts of higher aliphatic acids waterproofing agent, be placed in and 10min stirred in mixer, stir Speed is mixed for 250r/min, 25 DEG C are cooled to;
5) 1 part of cupric sulfate pentahydrate, 0.2 part of calcium stearate, 0.6 part of 1010 antioxidant, 15 parts of Tissuemat E, epoxy resin are taken 5 parts, 125 parts of water be just added on mixer, rotating speed is 150r/min, and the time is 30min, and temperature is 200 DEG C;
6) by step 4) in mixture be added to step 5) in mixed liquor in, Hybrid Heating is to 400 DEG C;
7) by step 6) in mixture pour into mould, you can obtain the environmental friendly material of antibacterial, waterproof.
The technology of the present invention effect major embodiment is in the following areas:By rice silver antibacterial agent, sulfonated-pheno-formoldehyde resin, polyethylene Alcohol, bentonite, cupric sulfate pentahydrate, mullite, calcium stearate, higher aliphatic acids waterproofing agent, 1010 antioxidant, Tissuemat E, Sulphate aluminium cement, glass fibre, zeolite, epoxy resin, water, make antibacterial, the environmental friendly material of waterproof has antibiotic property and anti- Aqueous property, with good environmental benefit, meets national requirements.
Specific embodiment
Embodiment 1
The environmental friendly material of a kind of antibacterial, waterproof, including the raw material that following parts by weight are matched:Nano silver antimicrobials 20 Part, 9 parts of sulfonated-pheno-formoldehyde resin, 60 parts of polyvinyl alcohol, 50 parts of bentonite, 0.5 part of cupric sulfate pentahydrate, 10 parts of mullite, tristearin 0.1 part of sour calcium, 10 parts of higher aliphatic acids waterproofing agent, 0.3 part of 1010 antioxidant, 10 parts of Tissuemat E, sulphate aluminium cement 100 Part, 15 parts of glass fibre, 10 parts of zeolite, 4 parts of epoxy resin, 100 parts of water.
A kind of antibacterial, the preparation method of the environmental friendly material of waterproof are as follows:
1) 10 parts of 50 parts of bentonite, 10 parts of mullite, 100 parts of sulphate aluminium cement, 15 parts of glass fibre and zeolite is taken to put Enter grinder, grinding particle diameter is 400 mesh, standby;
2) by nano silver antimicrobials 20 parts put into step 1) in, be placed in a centrifuge, temperature be 25 DEG C at, rotating speed is 2000r/min, centrifugation rotates 35min, obtains antibacterial composite soil;
3) 9 parts of sulfonated-pheno-formoldehyde resin, 60 parts of polyvinyl alcohol are taken and are added to step 2) in antibacterial composite soil, be heated to Foaming treatment is carried out after 500 DEG C;
4) step 3) in mixture add 10 parts of higher aliphatic acids waterproofing agent, be placed in and 10min stirred in mixer, stir Speed is mixed for 250r/min, 25 DEG C are cooled to;
5) 0.5 part of cupric sulfate pentahydrate, 0.1 part of calcium stearate, 0.3 part of 1010 antioxidant, 10 parts of Tissuemat E, asphalt mixtures modified by epoxy resin are taken 4 parts of fat, 100 parts of water are just added on mixer, and rotating speed is 150r/min, and the time is 30min, and temperature is 200 DEG C;
6) by step 4) in mixture be added to step 5) in mixed liquor in, Hybrid Heating is to 400 DEG C;
7) by step 6) in mixture pour into mould, you can obtain the environmental friendly material of antibacterial, waterproof.
Embodiment 2
The environmental friendly material of a kind of antibacterial, waterproof, including the raw material that following parts by weight are matched:Nano silver antimicrobials 30 Part, 11 parts of sulfonated-pheno-formoldehyde resin, 70 parts of polyvinyl alcohol, 70 parts of bentonite, 1.5 parts of cupric sulfate pentahydrate, 14 parts of mullite, tristearin 0.3 part of sour calcium, 20 parts of higher aliphatic acids waterproofing agent, 0.9 part of 1010 antioxidant, 20 parts of Tissuemat E, sulphate aluminium cement 150 Part, 19 parts of glass fibre, 16 parts of zeolite, 6 parts of epoxy resin, 150 parts of water.
A kind of antibacterial, the preparation method of the environmental friendly material of waterproof are as follows:
1) 16 parts of 70 parts of bentonite, 14 parts of mullite, 150 parts of sulphate aluminium cement, 19 parts of glass fibre and zeolite is taken to put Enter grinder, grinding particle diameter is 400 mesh, standby;
2) by nano silver antimicrobials 30 parts put into step 1) in, be placed in a centrifuge, temperature be 25 DEG C at, rotating speed is 2000r/min, centrifugation rotates 35min, obtains antibacterial composite soil;
3) 11 parts of sulfonated-pheno-formoldehyde resin, 70 parts of polyvinyl alcohol are taken and are added to step 2) in antibacterial composite soil, be heated to Foaming treatment is carried out after 500 DEG C;
4) step 3) in mixture add 20 parts of higher aliphatic acids waterproofing agent, be placed in and 10min stirred in mixer, stir Speed is mixed for 250r/min, 25 DEG C are cooled to;
5) 1.5 parts of cupric sulfate pentahydrate, 0.3 part of calcium stearate, 0.9 part of 1010 antioxidant, 20 parts of Tissuemat E, asphalt mixtures modified by epoxy resin are taken 6 parts of fat, 150 parts of water are just added on mixer, and rotating speed is 150r/min, and the time is 30min, and temperature is 200 DEG C;
6) by step 4) in mixture be added to step 5) in mixed liquor in, Hybrid Heating is to 400 DEG C;
7) by step 6) in mixture pour into mould, you can obtain the environmental friendly material of antibacterial, waterproof.
Embodiment 3
The environmental friendly material of a kind of antibacterial, waterproof, including the raw material that following parts by weight are matched:Nano silver antimicrobials 25 Part, 10 parts of sulfonated-pheno-formoldehyde resin, 65 parts of polyvinyl alcohol, 60 parts of bentonite, 1 part of cupric sulfate pentahydrate, 12 parts of mullite, stearic acid 0.2 part of calcium, 15 parts of higher aliphatic acids waterproofing agent, 0.6 part of 1010 antioxidant, 15 parts of Tissuemat E, sulphate aluminium cement 125 Part, 17 parts of glass fibre, 13 parts of zeolite, 5 parts of epoxy resin, 125 parts of water.
A kind of antibacterial, the preparation method of the environmental friendly material of waterproof are as follows:
1) 13 parts of 60 parts of bentonite, 12 parts of mullite, 125 parts of sulphate aluminium cement, 17 parts of glass fibre and zeolite is taken to put Enter grinder, grinding particle diameter is 400 mesh, standby;
2) by nano silver antimicrobials 25 parts put into step 1) in, be placed in a centrifuge, temperature be 25 DEG C at, rotating speed is 2000r/min, centrifugation rotates 35min, obtains antibacterial composite soil;
3) 10 parts of sulfonated-pheno-formoldehyde resin, 65 parts of polyvinyl alcohol are taken and are added to step 2) in antibacterial composite soil, be heated to Foaming treatment is carried out after 500 DEG C;
4) step 3) in mixture add 15 parts of higher aliphatic acids waterproofing agent, be placed in and 10min stirred in mixer, stir Speed is mixed for 250r/min, 25 DEG C are cooled to;
5) 1 part of cupric sulfate pentahydrate, 0.2 part of calcium stearate, 0.6 part of 1010 antioxidant, 15 parts of Tissuemat E, epoxy resin are taken 5 parts, 125 parts of water be just added on mixer, rotating speed is 150r/min, and the time is 30min, and temperature is 200 DEG C;
6) by step 4) in mixture be added to step 5) in mixed liquor in, Hybrid Heating is to 400 DEG C;
7) by step 6) in mixture pour into mould, you can obtain the environmental friendly material of antibacterial, waterproof.
Experimental example
It is experimental group to choose the sheet material manufactured by 100 pieces of antibacterials of the invention, the environmental friendly material of waterproof, chooses 100 pieces Sheet material manufactured by common environmental friendly material is control group, the environment-friendly materials size one that experimental group and control group are used Sample, and thickness is all 20cm, and result is recorded after the test, its experimental result is as follows:
SGS synthesis macromolecular material antifungal activity moulds do not grow Formaldehyde≤0.045mm/m3 Buildings waterproof grade
Experimental group 100% 95% 1 grade
Control group 3% 1% 3 grades
Learnt by experimental result, effectively, waterproof is effective, healthy ring for antibacterial of the invention, the environmental friendly material antibacterial of waterproof Protect.
The technology of the present invention effect major embodiment is in the following areas:By rice silver antibacterial agent, sulfonated-pheno-formoldehyde resin, polyethylene Alcohol, bentonite, cupric sulfate pentahydrate, mullite, calcium stearate, higher aliphatic acids waterproofing agent, 1010 antioxidant, Tissuemat E, Sulphate aluminium cement, glass fibre, zeolite, epoxy resin, water, make antibacterial, the environmental friendly material of waterproof has antibiotic property and anti- Aqueous property, with good environmental benefit, meets national requirements.
Certainly, it is more than representative instance of the invention, in addition, the present invention can also have other various specific implementations The technical scheme that mode, all use equivalents or equivalent transformation are formed, all falls within the scope of protection of present invention.

Claims (4)

1. the environmental friendly material of a kind of antibacterial, waterproof, it is characterised in that:Raw material including following parts by weight proportioning:Nano Silver Antiseptic 20-30 parts, sulfonated-pheno-formoldehyde resin 9-11 parts, polyvinyl alcohol 60-70 parts, bentonite 50-70 parts, cupric sulfate pentahydrate 0.5-1.5 parts, mullite 10-14 parts, calcium stearate 0.1-0.3 parts, 10-20 parts of higher aliphatic acids waterproofing agent, 1010 antioxygens Agent 0.3-0.9 parts, Tissuemat E 10-20 parts, sulphate aluminium cement 100-150 parts, glass fibre 15-19 parts, zeolite 10-16 Part, epoxy resin 4-6 parts, water 100-150 parts.
2. the environmental friendly material of antibacterial as claimed in claim 1, waterproof, it is characterised in that:Including following parts by weight proportioning Raw material:20 parts of nano silver antimicrobials, 9 parts of sulfonated-pheno-formoldehyde resin, 60 parts of polyvinyl alcohol, 50 parts of bentonite, cupric sulfate pentahydrate 0.5 part, 10 parts of mullite, 0.1 part of calcium stearate, 10 parts of higher aliphatic acids waterproofing agent, 0.3 part of 1010 antioxidant, polyethylene 10 parts of wax, 100 parts of sulphate aluminium cement, 15 parts of glass fibre, 10 parts of zeolite, 4 parts of epoxy resin, 100 parts of water.
3. the environmental friendly material of antibacterial as claimed in claim 1, waterproof, it is characterised in that:Including following parts by weight proportioning Raw material:30 parts of nano silver antimicrobials, 11 parts of sulfonated-pheno-formoldehyde resin, 70 parts of polyvinyl alcohol, 70 parts of bentonite, cupric sulfate pentahydrate 1.5 parts, 14 parts of mullite, 0.3 part of calcium stearate, 20 parts of higher aliphatic acids waterproofing agent, 0.9 part of 1010 antioxidant, polyethylene 20 parts of wax, 150 parts of sulphate aluminium cement, 19 parts of glass fibre, 16 parts of zeolite, 6 parts of epoxy resin, 150 parts of water.
4. the environmental friendly material of antibacterial as claimed in claim 1, waterproof, it is characterised in that:Including following parts by weight proportioning Raw material:25 parts of nano silver antimicrobials, 10 parts of sulfonated-pheno-formoldehyde resin, 65 parts of polyvinyl alcohol, 60 parts of bentonite, cupric sulfate pentahydrate 1 part, 12 parts of mullite, 0.2 part of calcium stearate, 15 parts of higher aliphatic acids waterproofing agent, 0.6 part of 1010 antioxidant, Tissuemat E 15 parts, 125 parts of sulphate aluminium cement, 17 parts of glass fibre, 13 parts of zeolite, 5 parts of epoxy resin, 125 parts of water.
CN201611067611.3A 2016-11-29 2016-11-29 A kind of environmental friendly material of antibacterial, waterproof Pending CN106747135A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021184286A1 (en) * 2020-03-19 2021-09-23 江苏朗悦新材料科技有限公司 Environment-friendly sheet material and preparation method therefor

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CN104086212A (en) * 2014-06-20 2014-10-08 林学芹 Environment-friendly building board and preparation method thereof
CN104086210A (en) * 2014-06-20 2014-10-08 林学芹 Improved environment-friendly building board and preparation method thereof
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CN104086125A (en) * 2014-06-20 2014-10-08 林学芹 Building board and preparation method thereof
CN104086212A (en) * 2014-06-20 2014-10-08 林学芹 Environment-friendly building board and preparation method thereof
CN104086210A (en) * 2014-06-20 2014-10-08 林学芹 Improved environment-friendly building board and preparation method thereof
CN106145804A (en) * 2016-07-12 2016-11-23 广西南宁桂尔创环保科技有限公司 A kind of novel environment friendly building board

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Cited By (1)

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WO2021184286A1 (en) * 2020-03-19 2021-09-23 江苏朗悦新材料科技有限公司 Environment-friendly sheet material and preparation method therefor

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Application publication date: 20170531