CN109279845A - A kind of environmental friendly material of antibacterial, waterproof - Google Patents
A kind of environmental friendly material of antibacterial, waterproof Download PDFInfo
- Publication number
- CN109279845A CN109279845A CN201710636889.6A CN201710636889A CN109279845A CN 109279845 A CN109279845 A CN 109279845A CN 201710636889 A CN201710636889 A CN 201710636889A CN 109279845 A CN109279845 A CN 109279845A
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- antibacterial
- waterproof
- environmental friendly
- friendly material
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/06—Aluminous cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00017—Aspects relating to the protection of the environment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/2092—Resistance against biological degradation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention discloses the environmental friendly material of a kind of antibacterial, waterproof, the raw material including following parts by weight proportion: 20-30 parts of nano silver antimicrobials, 9-11 parts of sulfonated-pheno-formoldehyde resin, 60-70 parts of polyvinyl alcohol, 50-70 parts of bentonite, 0.5-1.5 parts of cupric sulfate pentahydrate, 10-14 parts of mullite, 0.1-0.3 parts of calcium stearate, 10-20 parts of higher aliphatic acids waterproofing agent, 0.3-0.9 parts of 1010 antioxidant, 10-20 parts of polyethylene wax, 100-150 parts of sulphate aluminium cement, 15-19 parts of glass fibre, 10-16 parts of zeolite, 4-6 parts of epoxy resin, 100-150 parts of water；The antibacterial, the environmental friendly material antibacterial of waterproof are effective, and waterproof is effective, health environment-friendly.
Description
Technical field
The present invention relates to the environmental friendly materials of a kind of antibacterial, waterproof.
Background technique
New material refers to some materials newly-developed or researching and developing, having preeminent performance, has more than traditional material
For excellent performance.New material technology is then the will according to people, is commented by physical study, design of material, material processing, test
A series of research process such as valence, create the technology for being able to satisfy the new material of various needs.
The history that composite material uses can trace back to ancient times.The straw continued to use from ancient times to the present enhances clay and has used
The armored concrete of upper a century is formed by two kinds of Material claddings.In the 1940s, having developed glass because of the needs of aircraft industry
Glass fibre reinforced plastics (are commonly called as glass reinforced plastic), this title of composite material occur from this.After the fifties, carbon is developed successively
The high intensity such as fiber, graphite fibre and boron fibre and high modulus fibre.There is aramid fiber and silicon carbide fibre in the seventies.This
Some high-intensitive, high modulus fibres can be with the metals such as nonmetal basal bodies or aluminium, magnesium, titanium such as synthetic resin, carbon, graphite, ceramics, rubber
Matrix is compound, constitutes composite material with their own characteristics.
The specific strength of ultra high molecular weight polyethylene fiber ranks first place in various fibers, especially its anti-chemical reagent
Erosion performance and anti-aging property are excellent.It also has excellent high frequency sonar permeability and resistance to corrosion seawater, many countries
The high frequency sonar dome for having manufactured naval vessels with it substantially increases detecting a mine, the clearance ability of naval vessels, thinks good green wood at home
The composite material of material exploitation represents domestic higher level.Except in military field, in automobile manufacture, shipbuilding, medical treatment
The fields such as instrument, athletic sports appliance ultra high molecular weight polyethylene fiber also has broad application prospects.The fiber is once appearance
Just cause great interest and the attention of World Developed Countries.
But the antibacterial effect of the environmental friendly material of antibacterial, waterproof now is general, and waterproof effect is general, and unhealthy ring
It protects.
Summary of the invention
In view of this, this is to provide with goal of the invention, a kind of antibacterial is effective, and waterproof is effective, antibacterial, the waterproof of health environment-friendly
Environmental friendly material.
In order to solve the above-mentioned technical problem, the technical scheme is that
The environmental friendly material of a kind of antibacterial, waterproof, the raw material including following parts by weight proportion: nano silver antimicrobials 20-
30 parts, 9-11 parts of sulfonated-pheno-formoldehyde resin, 60-70 parts of polyvinyl alcohol, 50-70 parts of bentonite, 0.5-1.5 parts of cupric sulfate pentahydrate,
10-14 parts of mullite, 0.1-0.3 parts of calcium stearate, 10-20 parts of higher aliphatic acids waterproofing agent, 1010 antioxidant 0.3-0.9
Part, 10-20 parts of polyethylene wax, 100-150 parts of sulphate aluminium cement, 15-19 parts of glass fibre, 10-16 parts of zeolite, epoxy resin
4-6 parts, 100-150 parts of water.
Further, the environmental friendly material of a kind of antibacterial, waterproof, the raw material including following parts by weight proportion:
20 parts of nano silver antimicrobials, 9 parts of sulfonated-pheno-formoldehyde resin, 60 parts of polyvinyl alcohol, 50 parts of bentonite, 0.5 part of cupric sulfate pentahydrate, not
Come 10 parts of stone, 0.1 part of calcium stearate, 10 parts of higher aliphatic acids waterproofing agent, 0.3 part of 1010 antioxidant, 10 parts of polyethylene wax, sulphur
100 parts of aluminate cement, 15 parts of glass fibre, 10 parts of zeolite, 4 parts of epoxy resin, 100 parts of water.
Further, the environmental friendly material of a kind of antibacterial, waterproof, the raw material including following parts by weight proportion:
30 parts of nano silver antimicrobials, 11 parts of sulfonated-pheno-formoldehyde resin, 70 parts of polyvinyl alcohol, 70 parts of bentonite, 1.5 parts of cupric sulfate pentahydrate,
14 parts of mullite, 0.3 part of calcium stearate, 20 parts of higher aliphatic acids waterproofing agent, 0.9 part of 1010 antioxidant, 20 parts of polyethylene wax,
150 parts of sulphate aluminium cement, 19 parts of glass fibre, 16 parts of zeolite, 6 parts of epoxy resin, 150 parts of water.
Further, the environmental friendly material of a kind of antibacterial, waterproof, the raw material including following parts by weight proportion:
25 parts of nano silver antimicrobials, 10 parts of sulfonated-pheno-formoldehyde resin, 65 parts of polyvinyl alcohol, 60 parts of bentonite, 1 part of cupric sulfate pentahydrate, not
Come 12 parts of stone, 0.2 part of calcium stearate, 15 parts of higher aliphatic acids waterproofing agent, 0.6 part of 1010 antioxidant, 15 parts of polyethylene wax, sulphur
125 parts of aluminate cement, 17 parts of glass fibre, 13 parts of zeolite, 5 parts of epoxy resin, 125 parts of water.
A kind of environmental friendly material of antibacterial, waterproof the preparation method is as follows:
1) 60 parts of bentonite, 12 parts of mullite, 125 parts of sulphate aluminium cement, 17 parts of glass fibre and 13 parts of zeolite is taken to put
Into grinder, grinding partial size is 400 mesh, spare；
2) 25 parts of nano silver antimicrobials are put into step 1), is placed in a centrifuge, in the case where temperature is 25 DEG C, revolving speed is
2000r/min, centrifugation rotation 35min, obtains antibacterial composite soil；
3) 10 parts of sulfonated-pheno-formoldehyde resin, 65 parts of the polyvinyl alcohol antibacterial composite soils being added in step 2) are taken, is heated to
Foaming processing is carried out after 500 DEG C；
4) 15 parts of higher aliphatic acids waterproofing agent is added in the mixture in step 3), is placed in blender and stirs 10min, stirs
Mixing speed is 250r/min, is cooled to 25 DEG C；
5) 1 part of cupric sulfate pentahydrate, 0.2 part of calcium stearate, 0.6 part of 1010 antioxidant, 15 parts of polyethylene wax, epoxy resin are taken
5 parts, 125 parts of water are just added on mixing machine, revolving speed 150r/min, time 30min, and temperature is 200 DEG C；
6) mixture in step 4) is added in the mixed liquor in step 5), Hybrid Heating is to 400 DEG C；
7) mixture in step 6) is poured into mold, the environmental friendly material of antibacterial, waterproof can be obtained.
The technology of the present invention effect major embodiment is in the following areas: passing through rice silver antibacterial agent, sulfonated-pheno-formoldehyde resin, polyethylene
Alcohol, bentonite, cupric sulfate pentahydrate, mullite, calcium stearate, higher aliphatic acids waterproofing agent, 1010 antioxidant, polyethylene wax,
Sulphate aluminium cement, glass fibre, zeolite, epoxy resin, water make antibacterial, the environmental friendly material of waterproof has antibiotic property and anti-
Aqueous property has good environmental benefit, meets national requirements.
Specific embodiment
Embodiment 1
The environmental friendly material of a kind of antibacterial, waterproof, the raw material including following parts by weight proportion: nano silver antimicrobials 20
Part, 9 parts of sulfonated-pheno-formoldehyde resin, 60 parts of polyvinyl alcohol, 50 parts of bentonite, 0.5 part of cupric sulfate pentahydrate, 10 parts of mullite, tristearin
0.1 part of sour calcium, 10 parts of higher aliphatic acids waterproofing agent, 0.3 part of 1010 antioxidant, 10 parts of polyethylene wax, sulphate aluminium cement 100
Part, 15 parts of glass fibre, 10 parts of zeolite, 4 parts of epoxy resin, 100 parts of water.
A kind of environmental friendly material of antibacterial, waterproof the preparation method is as follows:
1) 50 parts of bentonite, 10 parts of mullite, 100 parts of sulphate aluminium cement, 15 parts of glass fibre and 10 parts of zeolite is taken to put
Into grinder, grinding partial size is 400 mesh, spare；
2) 20 parts of nano silver antimicrobials are put into step 1), is placed in a centrifuge, in the case where temperature is 25 DEG C, revolving speed is
2000r/min, centrifugation rotation 35min, obtains antibacterial composite soil；
3) 9 parts of sulfonated-pheno-formoldehyde resin, 60 parts of the polyvinyl alcohol antibacterial composite soils being added in step 2) are taken, is heated to
Foaming processing is carried out after 500 DEG C；
4) 10 parts of higher aliphatic acids waterproofing agent is added in the mixture in step 3), is placed in blender and stirs 10min, stirs
Mixing speed is 250r/min, is cooled to 25 DEG C；
5) 0.5 part of cupric sulfate pentahydrate, 0.1 part of calcium stearate, 0.3 part of 1010 antioxidant, 10 parts of polyethylene wax, asphalt mixtures modified by epoxy resin are taken
4 parts of rouge, 100 parts of water be just added on mixing machine, revolving speed 150r/min, time 30min, temperature be 200 DEG C；
6) mixture in step 4) is added in the mixed liquor in step 5), Hybrid Heating is to 400 DEG C；
7) mixture in step 6) is poured into mold, the environmental friendly material of antibacterial, waterproof can be obtained.
Embodiment 2
The environmental friendly material of a kind of antibacterial, waterproof, the raw material including following parts by weight proportion: nano silver antimicrobials 30
Part, 11 parts of sulfonated-pheno-formoldehyde resin, 70 parts of polyvinyl alcohol, 70 parts of bentonite, 1.5 parts of cupric sulfate pentahydrate, 14 parts of mullite, tristearin
0.3 part of sour calcium, 20 parts of higher aliphatic acids waterproofing agent, 0.9 part of 1010 antioxidant, 20 parts of polyethylene wax, sulphate aluminium cement 150
Part, 19 parts of glass fibre, 16 parts of zeolite, 6 parts of epoxy resin, 150 parts of water.
A kind of environmental friendly material of antibacterial, waterproof the preparation method is as follows:
1) 70 parts of bentonite, 14 parts of mullite, 150 parts of sulphate aluminium cement, 19 parts of glass fibre and 16 parts of zeolite is taken to put
Into grinder, grinding partial size is 400 mesh, spare；
2) 30 parts of nano silver antimicrobials are put into step 1), is placed in a centrifuge, in the case where temperature is 25 DEG C, revolving speed is
2000r/min, centrifugation rotation 35min, obtains antibacterial composite soil；
3) 11 parts of sulfonated-pheno-formoldehyde resin, 70 parts of the polyvinyl alcohol antibacterial composite soils being added in step 2) are taken, is heated to
Foaming processing is carried out after 500 DEG C；
4) 20 parts of higher aliphatic acids waterproofing agent is added in the mixture in step 3), is placed in blender and stirs 10min, stirs
Mixing speed is 250r/min, is cooled to 25 DEG C；
5) 1.5 parts of cupric sulfate pentahydrate, 0.3 part of calcium stearate, 0.9 part of 1010 antioxidant, 20 parts of polyethylene wax, asphalt mixtures modified by epoxy resin are taken
6 parts of rouge, 150 parts of water be just added on mixing machine, revolving speed 150r/min, time 30min, temperature be 200 DEG C；
6) mixture in step 4) is added in the mixed liquor in step 5), Hybrid Heating is to 400 DEG C；
7) mixture in step 6) is poured into mold, the environmental friendly material of antibacterial, waterproof can be obtained.
Embodiment 3
The environmental friendly material of a kind of antibacterial, waterproof, the raw material including following parts by weight proportion: nano silver antimicrobials 25
Part, 10 parts of sulfonated-pheno-formoldehyde resin, 65 parts of polyvinyl alcohol, 60 parts of bentonite, 1 part of cupric sulfate pentahydrate, 12 parts of mullite, stearic acid
0.2 part of calcium, 15 parts of higher aliphatic acids waterproofing agent, 0.6 part of 1010 antioxidant, 15 parts of polyethylene wax, sulphate aluminium cement 125
Part, 17 parts of glass fibre, 13 parts of zeolite, 5 parts of epoxy resin, 125 parts of water.
A kind of environmental friendly material of antibacterial, waterproof the preparation method is as follows:
1) 60 parts of bentonite, 12 parts of mullite, 125 parts of sulphate aluminium cement, 17 parts of glass fibre and 13 parts of zeolite is taken to put
Into grinder, grinding partial size is 400 mesh, spare；
2) 25 parts of nano silver antimicrobials are put into step 1), is placed in a centrifuge, in the case where temperature is 25 DEG C, revolving speed is
2000r/min, centrifugation rotation 35min, obtains antibacterial composite soil；
3) 10 parts of sulfonated-pheno-formoldehyde resin, 65 parts of the polyvinyl alcohol antibacterial composite soils being added in step 2) are taken, is heated to
Foaming processing is carried out after 500 DEG C；
4) 15 parts of higher aliphatic acids waterproofing agent is added in the mixture in step 3), is placed in blender and stirs 10min, stirs
Mixing speed is 250r/min, is cooled to 25 DEG C；
5) 1 part of cupric sulfate pentahydrate, 0.2 part of calcium stearate, 0.6 part of 1010 antioxidant, 15 parts of polyethylene wax, epoxy resin are taken
5 parts, 125 parts of water are just added on mixing machine, revolving speed 150r/min, time 30min, and temperature is 200 DEG C；
6) mixture in step 4) is added in the mixed liquor in step 5), Hybrid Heating is to 400 DEG C；
7) mixture in step 6) is poured into mold, the environmental friendly material of antibacterial, waterproof can be obtained.
Experimental example
Choosing plate manufactured by the environmental friendly material of 100 pieces of antibacterials of the invention, waterproof is experimental group, chooses 100 pieces
Plate manufactured by common environmental friendly material is control group, environment-friendly materials size one used in experimental group and control group
Sample, and thickness is all 20cm, record is as a result, its experimental result is as follows after the test:
| SGS synthesis high molecular material antifungal activity mould does not grow | Formaldehyde≤0.045mm/m3 | Buildings waterproof grade | |
| Experimental group | 100% | 95% | 1 grade |
| Control group | 3% | 1% | 3 grades |
It is learnt by experimental result, antibacterial of the invention, the environmental friendly material antibacterial of waterproof are effective, and waterproof is effective, healthy ring
It protects.
The technology of the present invention effect major embodiment is in the following areas: passing through rice silver antibacterial agent, sulfonated-pheno-formoldehyde resin, polyethylene
Alcohol, bentonite, cupric sulfate pentahydrate, mullite, calcium stearate, higher aliphatic acids waterproofing agent, 1010 antioxidant, polyethylene wax,
Sulphate aluminium cement, glass fibre, zeolite, epoxy resin, water make antibacterial, the environmental friendly material of waterproof has antibiotic property and anti-
Aqueous property has good environmental benefit, meets national requirements.
Certainly, above is representative instance of the invention, and in addition to this, the present invention can also have other a variety of specific implementations
Mode, all technical solutions formed using equivalent substitution or equivalent transformation, is all fallen within the scope of protection of present invention.
Claims (4)
1. the environmental friendly material of a kind of antibacterial, waterproof, it is characterised in that: the raw material including following parts by weight proportion: nano silver
20-30 parts of antibacterial agent, 9-11 parts of sulfonated-pheno-formoldehyde resin, 60-70 parts of polyvinyl alcohol, 50-70 parts of bentonite, cupric sulfate pentahydrate
0.5-1.5 parts, 10-14 parts of mullite, 0.1-0.3 parts of calcium stearate, 10-20 parts of higher aliphatic acids waterproofing agent, 1010 antioxygens
0.3-0.9 parts of agent, 10-20 parts of polyethylene wax, 100-150 parts of sulphate aluminium cement, 15-19 parts of glass fibre, zeolite 10-16
Part, 4-6 parts of epoxy resin, 100-150 parts of water.
2. the environmental friendly material of antibacterial as described in claim 1, waterproof, it is characterised in that: matched including following parts by weight
Raw material: 20 parts of nano silver antimicrobials, 9 parts of sulfonated-pheno-formoldehyde resin, 60 parts of polyvinyl alcohol, 50 parts of bentonite, cupric sulfate pentahydrate
0.5 part, 10 parts of mullite, 0.1 part of calcium stearate, 10 parts of higher aliphatic acids waterproofing agent, 0.3 part of 1010 antioxidant, polyethylene
10 parts of wax, 100 parts of sulphate aluminium cement, 15 parts of glass fibre, 10 parts of zeolite, 4 parts of epoxy resin, 100 parts of water.
3. the environmental friendly material of antibacterial as described in claim 1, waterproof, it is characterised in that: matched including following parts by weight
Raw material: 30 parts of nano silver antimicrobials, 11 parts of sulfonated-pheno-formoldehyde resin, 70 parts of polyvinyl alcohol, 70 parts of bentonite, cupric sulfate pentahydrate
1.5 parts, 14 parts of mullite, 0.3 part of calcium stearate, 20 parts of higher aliphatic acids waterproofing agent, 0.9 part of 1010 antioxidant, polyethylene
20 parts of wax, 150 parts of sulphate aluminium cement, 19 parts of glass fibre, 16 parts of zeolite, 6 parts of epoxy resin, 150 parts of water.
4. the environmental friendly material of antibacterial as described in claim 1, waterproof, it is characterised in that: matched including following parts by weight
Raw material: 25 parts of nano silver antimicrobials, 10 parts of sulfonated-pheno-formoldehyde resin, 65 parts of polyvinyl alcohol, 60 parts of bentonite, cupric sulfate pentahydrate
1 part, 12 parts of mullite, 0.2 part of calcium stearate, 15 parts of higher aliphatic acids waterproofing agent, 0.6 part of 1010 antioxidant, polyethylene wax
15 parts, 125 parts of sulphate aluminium cement, 17 parts of glass fibre, 13 parts of zeolite, 5 parts of epoxy resin, 125 parts of water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710636889.6A CN109279845A (en) | 2017-07-20 | 2017-07-20 | A kind of environmental friendly material of antibacterial, waterproof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710636889.6A CN109279845A (en) | 2017-07-20 | 2017-07-20 | A kind of environmental friendly material of antibacterial, waterproof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109279845A true CN109279845A (en) | 2019-01-29 |
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ID=65185099
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710636889.6A Pending CN109279845A (en) | 2017-07-20 | 2017-07-20 | A kind of environmental friendly material of antibacterial, waterproof |
Country Status (1)
| Country | Link |
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| CN (1) | CN109279845A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2021184286A1 (en) * | 2020-03-19 | 2021-09-23 | 江苏朗悦新材料科技有限公司 | Environment-friendly sheet material and preparation method therefor |
| CN114804741A (en) * | 2022-05-28 | 2022-07-29 | 河南蓝翎环科防水材料有限公司 | Rapidly solidified bentonite waterproof protective material and preparation method thereof |
-
2017
- 2017-07-20 CN CN201710636889.6A patent/CN109279845A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2021184286A1 (en) * | 2020-03-19 | 2021-09-23 | 江苏朗悦新材料科技有限公司 | Environment-friendly sheet material and preparation method therefor |
| CN114804741A (en) * | 2022-05-28 | 2022-07-29 | 河南蓝翎环科防水材料有限公司 | Rapidly solidified bentonite waterproof protective material and preparation method thereof |
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Application publication date: 20190129 |
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| WD01 | Invention patent application deemed withdrawn after publication |