CN110577692A - composite filling particles for preparing polyethylene corrugated pipe outer sleeve layer and preparation method - Google Patents
composite filling particles for preparing polyethylene corrugated pipe outer sleeve layer and preparation method Download PDFInfo
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- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
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- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
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- C08J2323/04—Homopolymers or copolymers of ethene
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- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
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Abstract
The invention provides composite filler particles for preparing an outer sleeve layer of a polyethylene corrugated pipe, which comprise the following raw materials in parts by weight: 100 parts of biomass calcium carbonate shell powder; 8-15 parts of high-density polyethylene; 1-3 parts of needle-shaped wollastonite; 1-2 parts of pyrophyllite fine powder; 1-2 parts of an antioxidant; 1-5 parts of an impact modifier; 0.1-0.5 part of stearic acid; 2-8 parts of paraffin; 0.5-2 parts of a dispersing agent. The advantages are that: the biomass calcium carbonate shell powder is biogenic calcium carbonate, and the inorganic component is formed by biological mineralization under the regulation and control of organic matters and is better symbiotic with the organic matters. The wollastonite and pyrophyllite fine powder in the reinforcing filler is a functional clay mineral, is non-toxic and harmless, and improves the mechanical and thermal chemical stability of the corrugated pipe product to a greater extent and prolongs the service cycle of the corrugated pipe product.
Description
Technical Field
the invention belongs to the field of organic and inorganic composite material processing and preparation and corresponding application, and particularly relates to a high-strength, wear-resistant and corrosion-resistant composite filler particle for preparing a polyethylene corrugated pipe outer sleeve layer and a preparation method thereof, wherein the composite filler particle is prepared from biomass solid waste resources, namely shells.
background
Currently, the environment and resources are two major problems of social concern at present, and the green environmental protection concepts of energy saving, consumption reduction and the like gradually enter the daily production and life of people, and the environmental protection problems of 'water and water co-generation', 'air purification', 'garbage classification', 'green disposal and treatment of solid waste resources' and the like gradually become the research focus of the scientific researchers. In the case of the traditional plastics industry, the "white pollution" problem that occurs with traditional plastics has an immeasurable negative impact on the ecological environment, given that they are more difficult to degrade. On the other hand, as the source materials of the traditional polymer are mainly petroleum, and the petroleum is a nonrenewable resource, along with a large amount of development and complex reaction to generate a series of derivative products, the petroleum resource is gradually reduced and simultaneously generates a large amount of harmful products, which bring immeasurable harm to the natural environment on which people live, so that the environmental problems of greenhouse effect, haze and the like gradually puzzle people's life.
Because of the corrugated structure and the design of PE material, the high-density polyethylene (HDPE) corrugated pipe has strong pressure resistance, good chemical stability, low-temperature resistance, bending resistance, impact resistance and convenient construction performance, and is widely applied to municipal engineering, underground embedding and drainage and pollution discharge of residential districts, pre-buried pipelines of highways, irrigation and water delivery of farmland, drainage of waterlogging, chemical engineering, mine fluid delivery and the like. The HDPE double-wall corrugated pipe is a pipe with an outer wall with an annular structure and a smooth inner wall, and is firstly developed in Germany in the early 80 s. The production process and the use technology are mature, and the method has been greatly popularized and applied in developed countries such as Europe and America and the like due to the excellent performance and the relatively economic cost. However, at present, with the serious pollution of underground water, especially the improvement of the requirement of alkaline resistance and acid-alkali resistance of underground pipeline materials in saline-alkali land areas, the corrugated pipe is supplemented with functional filling particles as a filler in the manufacturing process of the corrugated pipe so as to improve the application performance of the end product of the corrugated pipe. Meanwhile, due to the addition of the functional filling particles with lower cost, the usage amount of the polyethylene raw material with higher value in unit volume of the corrugated pipe is greatly reduced, so that the excellent performance of the terminal product is realized, and the environmental protection and green industrial requirements of plastic reduction, plastic reduction and resource saving are realized, thereby having obvious economic and social benefits.
Shells, the substance composition of which is mainly biological calcium carbonate, mainly show calcite or aragonite or the combination form of the two. However, at present, shells, especially mother mussels for culturing pearls, are in fact dumped randomly after the pearls are collected, so that a large amount of land resources are occupied, the appearance is influenced, and meanwhile, serious negative effects are brought to the environment. At present, the national requirements for green treatment and disposal of solid waste resources are gradually upgraded, and particularly from the aspects of recycling and green utilization of shell solid waste resources, environmental protection, improvement of corrugated pipe material application performance, reduction of plastics and reduction of plastics, biomass calcium carbonate shell powder, pyrophyllite fine powder, wollastonite and the like are taken as composite fillers to perform physicochemical reinforcement on a PE carrier, and the composite materials are applied to preparation of PE corrugated pipe outer sleeves to improve the mechanical properties, chemical corrosion resistance and the like of the PE corrugated pipe outer sleeves.
Disclosure of Invention
The invention provides a high-strength, wear-resistant and corrosion-resistant composite filling particle applied to preparation of an outer sleeve layer of a polyethylene corrugated pipe and a preparation method thereof, aiming at the current situation of disposal of biological shell solid waste.
the invention aims to be realized by the following scheme: the composite filler particles for preparing the outer sleeve layer of the polyethylene corrugated pipe comprise the following raw materials in parts by weight:
100 parts of biomass calcium carbonate shell powder
8-15 parts of high-density polyethylene
1-3 parts of needle-shaped wollastonite
1-2 parts of pyrophyllite micro-fine powder
1-2 parts of antioxidant
1-5 parts of impact modifier
0.1-0.5 part of stearic acid
2-8 parts of paraffin
0.5-2 parts of a dispersing agent.
Further, the feed comprises the following raw materials in parts by weight:
100 parts of biomass calcium carbonate shell powder
8-10 parts of high-density polyethylene
1-3 parts of needle-shaped wollastonite
1-2 parts of pyrophyllite micro-fine powder
1-2 parts of antioxidant
3-5 parts of impact modifier
0.3-0.5 part of stearic acid
5-8 parts of paraffin
1-2 parts of a dispersing agent.
Further, the dispersant is a PE wax.
A preparation method of composite filling particles for preparing an outer sleeve layer of a polyethylene corrugated pipe comprises the following preparation procedures:
The first step is as follows: cleaning biological shells to remove outer-layer sludge, drying, and then preparing biomass calcium carbonate shell powder with a certain particle size through mechanical crushing and deep grinding, wherein the particle size of the powder is 1000-1250 meshes;
The second step is that: placing the biomass calcium carbonate shell powder, the needle-shaped wollastonite, the chopped carbon fibers and the pyrophyllite micropowder into a high-speed mixer for high-speed mixing and dispersing, wherein the temperature of a high-speed mixed material system needs to reach 120-150 ℃, and obtaining composite powder;
The third step: putting the composite powder obtained in the step two, stearic acid and a silane coupling agent into a high-speed mixer according to a ratio for high-speed mixing and modification to obtain modified powder;
The fourth step: and (3) placing the modified powder obtained in the third step, high-density polyethylene, PE wax, antioxidant and impact modifier in a high-speed mixer according to a certain proportion for high-speed mixing until the mixture is fully plasticized and becomes semi-slurry paste, and extruding and granulating by a double screw to obtain the composite filling particles for preparing the outer sleeve layer of the polyethylene corrugated pipe.
Further, in the first step, the shell is first washed with water only to remove the remaining dirt on the outer layer surface without performing mechanical polishing removal or alkali removal of the brown or black horny layer on the shell surface, and the brown or black horny layer on the shell surface is retained.
further, in the second step, the high-speed mixing time is 20-50 min, the temperature is 120-150 ℃, and the stirring speed is 600-800 r/min.
Further, in the third step, the high-speed mixing time is 15-30 min, the temperature is 110-160 ℃, and the speed is 600-800 r/min.
further, in the fourth step, the high-speed mixing time is 10-40 min, the temperature is 130-170 ℃, and the speed is 600-800 r/min.
The invention has the beneficial effects that:
1. The invention adopts the composite type reinforced filler, and can be uniformly distributed in the filling particles through dispersion and modification treatment.
2. the biomass calcium carbonate shell powder is biogenic calcium carbonate, and the inorganic component is formed by biological mineralization under the regulation and control of organic matters and is better symbiotic with the organic matters. Wollastonite and pyrophyllite fine powder are preferably used as functional clay minerals in the reinforcing filler system, so that the reinforcing filler system is non-toxic and harmless, the mechanical, thermal and chemical stability of corrugated pipe products is improved to a greater extent, and the service life of the corrugated pipe is finally prolonged.
3. The composite filling particle can be used as a composite filling particle for products of underground embedded drainage and pollution discharge, highway embedded pipelines, farmland irrigation water delivery and drainage pipelines, and is used for improving the service performance of the terminal corrugated pipeline material.
Detailed Description
The invention is further illustrated by the following specific examples:
Embodiment 1, the composite filler particles for preparing the outer jacket layer of the polyethylene corrugated pipe of the present invention comprise the following raw materials by weight:
100 parts of biomass calcium carbonate shell powder
8-15 parts of high-density polyethylene
1-3 parts of needle-shaped wollastonite
1-2 parts of pyrophyllite micro-fine powder
1-2 parts of antioxidant
1-5 parts of impact modifier
0.1-0.5 part of stearic acid
2-8 parts of paraffin
0.5-2 parts of a dispersing agent.
The composite filler particles for preparing the outer sleeve layer of the polyethylene corrugated pipe comprise the following preferred raw materials in parts by weight:
100 parts of biomass calcium carbonate shell powder
8-10 parts of high-density polyethylene
1-3 parts of needle-shaped wollastonite
1-2 parts of pyrophyllite micro-fine powder
1-2 parts of antioxidant
3-5 parts of impact modifier
0.3-0.5 part of stearic acid
5-8 parts of paraffin
1-2 parts of a dispersing agent.
A composite filler particle for preparing the external jacket of polyethylene corrugated pipe features that the dispersing agent is PE wax.
a preparation method of composite filling particles for preparing an outer sleeve layer of a polyethylene corrugated pipe comprises the following preparation procedures:
The first step is as follows: cleaning biological shells to remove outer-layer sludge, drying, and then preparing biomass calcium carbonate shell powder with a certain particle size through mechanical crushing and deep grinding, wherein the particle size of the powder is 1000-1250 meshes;
The second step is that: placing the biomass calcium carbonate shell powder, the needle-shaped wollastonite, the chopped carbon fibers and the pyrophyllite micropowder into a high-speed mixer for high-speed mixing and dispersing, wherein the temperature of a high-speed mixed material system needs to reach 120-150 ℃, and obtaining composite powder;
The third step: putting the composite powder obtained in the step two, stearic acid and a silane coupling agent into a high-speed mixer according to a ratio for high-speed mixing and modification to obtain modified powder;
The fourth step: and (3) placing the modified powder obtained in the third step, high-density polyethylene, PE wax, antioxidant and impact modifier in a high-speed mixer according to a certain proportion for high-speed mixing until the mixture is fully plasticized and becomes semi-slurry paste, and extruding and granulating by a double screw to obtain the composite filling particles for preparing the outer sleeve layer of the polyethylene corrugated pipe.
In the first step, shells are washed by water to remove residual dirt on the surface of an outer layer, and the brown or black cuticle on the surfaces of the shells is not required to be removed by mechanical polishing or alkali liquor, so that the brown or black cuticle on the surfaces of the shells is retained.
In the second step, the high-speed mixing time is 20-50 min, the temperature is 120-150 ℃, and the stirring speed is 600-800 r/min.
A preparation method of composite filling particles for preparing an outer sleeve layer of a polyethylene corrugated pipe comprises the third step, wherein the high-speed mixing time is 15-30 min, the temperature is 110-160 ℃, and the speed is 600-800 r/min.
A preparation method of composite filling particles for preparing an outer sleeve layer of a polyethylene corrugated pipe comprises the fourth step of mixing at a high speed for 10-40 min at the temperature of 130-170 ℃ at the speed of 600-800 r/min.
example 2, a method for preparing composite filler particles for a polyethylene corrugated pipe jacket layer, (1) weighing 2 parts of acicular wollastonite, 3 parts of pyrophyllite micropowder and 100 parts of biomass calcium carbonate shell powder respectively, placing the weighed materials into a high-speed mixer, mixing at a high speed and dispersing for 40 min, wherein the mixing speed is 800r/min, and the mixing temperature is 120 ℃, so as to obtain dispersed powder;
(2) Putting the dispersed powder obtained in the step (1) and 0.3 part of stearic acid into a high-speed mixer for high-speed mixing and modification, wherein the mixing time is 30 min, the mixing speed is 800r/min, and the mixing temperature is 120-130 ℃, so as to obtain modified powder;
(3) And (3) mixing the modified powder obtained in the step (2) with 10 parts of high-density polyethylene, 8 parts of paraffin, 0.8 part of PE wax, 0.5 part of antioxidant and 1 part of impact resistance agent in a high-speed mixer at a high speed for 20 min, wherein the mixing speed is 800r/min, the mixing temperature is 140-150 ℃, and extruding and granulating through a double screw after uniform mixing to obtain the corrugated pipe outer sleeve layer filling particles.
example 3, a method for preparing composite filler particles for a polyethylene corrugated pipe jacket layer,
(1) respectively weighing 3 parts of acicular wollastonite, 4 parts of pyrophyllite micropowder and 100 parts of biomass calcium carbonate shell powder, placing the mixture in a high-speed mixer for high-speed mixing and dispersing, wherein the mixing time is 40 min, the mixing speed is 800r/min, and the mixing temperature is 120 ℃, so as to obtain dispersed powder;
(2) putting the dispersed powder obtained in the step (1) and 0.5 part of stearic acid into a high-speed mixer for high-speed mixing and modification, wherein the mixing time is 30 min, the mixing speed is 800r/min, and the mixing temperature is 120-130 ℃, so as to obtain modified powder;
(3) And (3) placing the modified powder obtained in the step (2), 15 parts of high-density polyethylene, 2 parts of paraffin, 0.5 part of PE wax, 1 part of antioxidant and 0.5 part of impact resistance agent into a high-speed mixer for high-speed mixing, wherein the mixing time is 20 min, the mixing speed is 800r/min, the mixing temperature is 140-150 ℃, and extruding and granulating through a double screw after uniform mixing to obtain the corrugated pipe outer sleeve layer filling particles.
example 4 preparation method of composite filler particles for preparing outer jacket layer of polyethylene corrugated pipe
(1) Respectively weighing 1 part of acicular wollastonite, 5 parts of pyrophyllite micropowder and 100 parts of biomass calcium carbonate shell powder, placing the weighed materials in a high-speed mixer for high-speed mixing and dispersing, wherein the mixing time is 40 min, the mixing speed is 800r/min, and the mixing temperature is 120 ℃, so as to obtain dispersed powder;
(2) Putting the dispersed powder obtained in the step (1) and 0.3 part of stearic acid into a high-speed mixer for high-speed mixing and modification, wherein the mixing time is 30 min, the mixing speed is 800r/min, and the mixing temperature is 120-130 ℃, so as to obtain modified powder;
(3) And (3) placing the modified powder obtained in the step (2), 8 parts of high-density polyethylene, 8 parts of paraffin, 1 part of PE wax, 0.8 part of antioxidant and 2 parts of impact resistance agent into a high-speed mixer for high-speed mixing, wherein the mixing time is 20 min, the mixing speed is 800r/min, the mixing temperature is 140-150 ℃, and after uniform mixing, carrying out twin-screw extrusion granulation to obtain the corrugated pipe outer sleeve layer filling particles.
In the tensile property test experiment, the prepared particles filled in the outer sleeve layer of the corrugated pipe are subjected to injection molding to prepare a sample strip to be detected, and the tensile property of the sample strip is tested according to the national standard GB/TI040 plastic tensile test method. The test results are shown in table 1.
TABLE 1 results of the detection and analysis of examples 2-4 and commercially available comparative samples
Sample name | tensile Strength (MPa) |
example 2 | 32.5 |
Example 3 | 34.9 |
Example 4 | 31.8 |
Comparative example | 24.4 |
as can be seen from the tensile property detection results of the samples of examples 2 to 4 and the comparative example in Table 1, the tensile properties of the samples of examples 2 to 4 are obviously superior to those of the comparative example, which shows that the samples of examples 2 to 4 have superior tensile strength. The invention takes the fibrous filler as the composite type reinforcing component, and compared with calcium carbonate which is used as the reinforcing effect, the composite type corrugated pipe outer sleeve material has the obvious characteristic of reinforcing the mechanical property of the corrugated pipe outer sleeve material.
Although the present invention has been described with reference to preferred embodiments, it will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, and various changes in form and details may be made within the scope of the appended claims.
Claims (8)
1. the utility model provides a compound packing particle of preparation polyethylene bellows overcoat layer which characterized in that: the feed comprises the following raw materials in parts by weight:
100 parts of biomass calcium carbonate shell powder
8-15 parts of high-density polyethylene
1-3 parts of needle-shaped wollastonite
1-2 parts of pyrophyllite micro-fine powder
1-2 parts of antioxidant
1-5 parts of impact modifier
0.1-0.5 part of stearic acid
2-8 parts of paraffin
0.5-2 parts of a dispersing agent.
2. The composite filler particle for preparing the outer jacket layer of the polyethylene corrugated pipe as claimed in claim 1, wherein: the feed comprises the following preferred raw materials in parts by weight:
100 parts of biomass calcium carbonate shell powder
8-10 parts of high-density polyethylene
1-3 parts of needle-shaped wollastonite
1-2 parts of pyrophyllite micro-fine powder
1-2 parts of antioxidant
3-5 parts of impact modifier
0.3-0.5 part of stearic acid
5-8 parts of paraffin
1-2 parts of a dispersing agent.
3. The composite filler particle for preparing the outer jacket layer of the polyethylene corrugated pipe as claimed in claim 1, wherein: the dispersant is PE wax.
4. A preparation method of composite filling particles for preparing an outer sleeve layer of a polyethylene corrugated pipe is characterized by comprising the following steps of: the preparation method comprises the following preparation procedures:
the first step is as follows: cleaning biological shells to remove outer-layer sludge, drying, and then preparing biomass calcium carbonate shell powder with a certain particle size through mechanical crushing and deep grinding, wherein the particle size of the powder is 1000-1250 meshes;
The second step is that: placing the biomass calcium carbonate shell powder, the needle-shaped wollastonite, the chopped carbon fibers and the pyrophyllite micropowder into a high-speed mixer for high-speed mixing and dispersing, wherein the temperature of a high-speed mixed material system needs to reach 120-150 ℃, and obtaining composite powder;
The third step: putting the composite powder obtained in the step two, stearic acid and a silane coupling agent into a high-speed mixer according to a ratio for high-speed mixing and modification to obtain modified powder;
The fourth step: and (3) placing the modified powder obtained in the third step, high-density polyethylene, PE wax, antioxidant and impact modifier in a high-speed mixer according to a certain proportion for high-speed mixing until the mixture is fully plasticized and becomes semi-slurry paste, and extruding and granulating by a double screw to obtain the composite filling particles for preparing the outer sleeve layer of the polyethylene corrugated pipe.
5. The method for preparing the composite filler particles for the outer jacket layer of the polyethylene corrugated pipe as claimed in claim 4, wherein: in the first step, the shell is washed with water to remove the residual dirt on the outer layer surface without mechanical polishing or alkali solution removal of the brown or black horny layer on the shell surface, and the brown or black horny layer on the shell surface is retained.
6. The method for preparing the composite filler particles for the outer jacket layer of the polyethylene corrugated pipe as claimed in claim 4, wherein: in the second step, the high-speed mixing time is 20-50 min, the temperature is 120-150 ℃, and the stirring speed is 600-800 r/min.
7. The method for preparing the composite filler particles for the outer jacket layer of the polyethylene corrugated pipe as claimed in claim 4, wherein: in the third step, the high-speed mixing time is 15-30 min, the temperature is 110-160 ℃, and the speed is 600-800 r/min.
8. The method for preparing the composite filler particles for the outer jacket layer of the polyethylene corrugated pipe as claimed in claim 4, wherein: in the fourth step, the high-speed mixing time is 10-40 min, the temperature is 130-170 ℃, and the speed is 600-800 r/min.
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Cited By (1)
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CN113635509A (en) * | 2021-08-13 | 2021-11-12 | 常州丰锦塑胶科技有限公司 | Foaming process of compression-resistant heat-insulating pipe |
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CN108774757A (en) * | 2018-06-21 | 2018-11-09 | 浙江工业大学温州科学技术研究院 | A kind of composite filled particle and its preparation method and application being used to prepare high strength non-woven fabric |
CN108841112A (en) * | 2018-07-16 | 2018-11-20 | 浙江工业大学温州科学技术研究院 | A kind of high intensity biological shell calcium carbonate and the compound particle of polyvinyl chloride and preparation method thereof |
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