CN104085220A - Corrosion and scale inhibition fountain solution and preparation method thereof - Google Patents
Corrosion and scale inhibition fountain solution and preparation method thereof Download PDFInfo
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- CN104085220A CN104085220A CN201410318024.1A CN201410318024A CN104085220A CN 104085220 A CN104085220 A CN 104085220A CN 201410318024 A CN201410318024 A CN 201410318024A CN 104085220 A CN104085220 A CN 104085220A
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Abstract
The invention discloses a corrosion and scale inhibition fountain solution. The corrosion and scale inhibition fountain solution is characterized by being composed of the following raw materials, by weight, 2-10 parts of sucrose ester, 1-2 parts of liquid paraffin, 2-8 parts of lauramidopropyl hydroxy sulfoBetaine, 1-6 parts of sodium lauryl diphenyl ether disulfonate, 0.5-1.5 parts of dodecyldimethylamine oxide, 1-3 parts of zinc sulfate, 1-2 parts of sulfaguanidine, 0.5-1.5 parts of polyaspartic acid, 1-2 parts of polyepoxysuccinic acid, 0.5-1 part of isothiazolinone, 1-2 parts of sodium lactate, 5-10 additives and 30-50 parts of water. The corrosion and scale inhibition fountain solution has good scale inhibition and corrosion protection effects, lowers maintenance cost of a printing system, is low in ink consumption amount and good in printing effect, and meets the requirements of environmental protection and energy saving.
Description
Technical field
The present invention relates to printing plate-moistening liquid, be specifically related to a kind of corrosion-mitigation scale-inhibition fountain solution and preparation method thereof.
Background technology
Fountain solution is indispensable a kind of chemical assistant in color press printing process, and it forms uniform moisture film in forme blank parts, to resist the infiltration to blank parts of ink on picture and text, prevents dirty version.In printing process, be subject to the impact of water quality, in fountain solution, can generate undissolved, greasy calcium soap, cause on surface, occurring sediment at forme, damping roller, the ink of impact and the transmission of fountain solution with sprawl.Dirty fault is stained with in serious appearance.
Poly-aspartate, poly-epoxy succinic acid are water-soluble polymer, there is the characteristic of without phosphorus, nontoxic, nuisanceless and fully biodegradable, ion is had to extremely strong sequestering power, there is inhibition and scale inhibition double effects, the scaling salt classes such as calcium carbonate, calcium sulfate, barium sulfate, calcium phosphate are had to good scale inhibition effect.Meanwhile, its corrosion that there is peptizaiton and can effectively prevent hardware.
Summary of the invention
The object of this invention is to provide a kind of corrosion-mitigation scale-inhibition fountain solution.
The present invention is achieved by the following technical solutions:
A kind of corrosion-mitigation scale-inhibition fountain solution, is characterized in that its raw material by following weight parts forms: sucrose ester 2-10, atoleine 1-2, dodecanamide propyl hydroxy sulfo lycine 2-8, alkyl diphenyl ether disulphonic acid sodium 1-6, alkyl dimethyl amine oxide 0.5-1.5, zinc sulfate 1-3, sulphaguanidine 1-2, poly-aspartate 0.5-1.5, poly-epoxy succinic acid 1-2, OIT 0.5-1, sodium lactate 1-2, auxiliary agent 5-10, water 30-50.
Described auxiliary agent is made up of the raw material of following weight portion: glycerine 5-10, polyethylene glycol 2-8, glycine 0.5-1.5, citric acid 1-3, oleic acid 2-3, caryophyllus oil 0.2-1, rhamnose 0.2-1, Tea Polyphenols 0.3-1, sodium acid carbonate 1-3, natrium citricum 10-30, Tween 80 1-5, water 30-50; First that citric acid, natrium citricum is water-soluble, be heated to 50-60 DEG C, then add glycerine, polyethylene glycol, caryophyllus oil, oleic acid and sodium acid carbonate, stir 15min, add all the other raw materials after being cooled to room temperature, be stirred to completely and dissolve, after filtration and get final product.
Corrosion-mitigation scale-inhibition fountain solution according to claim 1, is characterized in that being made up of the raw material of following weight parts: sucrose ester 8, atoleine 1.5, dodecanamide propyl hydroxy sulfo lycine 6, alkyl diphenyl ether disulphonic acid sodium 5, alkyl dimethyl amine oxide 1, zinc sulfate 2, sulphaguanidine 1.5, poly-aspartate 1, poly-epoxy succinic acid 1.5, OIT 0.8, sodium lactate 1.5, auxiliary agent 8, water 40.
Described auxiliary agent is made up of the raw material of following weight portion: glycerine 7, polyethylene glycol 6, glycine 1, citric acid 2, oleic acid 1.5, caryophyllus oil 0.5, rhamnose 0.5, Tea Polyphenols 0.5, sodium acid carbonate 2, natrium citricum 18, Tween 80 3, water 40; First that citric acid, natrium citricum is water-soluble, be heated to 50-60 DEG C, then add glycerine, polyethylene glycol, caryophyllus oil, oleic acid and sodium acid carbonate, stir 15min, add all the other raw materials after being cooled to room temperature, be stirred to completely and dissolve, after filtration and get final product.
The preparation method of corrosion-mitigation scale-inhibition fountain solution according to claim 1, is characterized in that, comprises the following steps:
(1) take raw material by formula, in reactor, add water, sucrose ester, dodecanamide propyl hydroxy sulfo lycine, alkyl diphenyl ether disulphonic acid sodium, atoleine, alkyl dimethyl amine oxide are dropped in reactor, be heated to 60-80 DEG C, stir 10-15min;
(2) temperature is adjusted to 50-60 DEG C, adds sulfonic acid guanidine, poly-aspartate, poly-epoxy succinic acid, OIT and auxiliary agent 600-800rpm to stir 15-30min;
(3) be cooled to room temperature, add rest materials, be stirred to and dissolve completely, filtering and impurity removing matter gets product.
Advantage of the present invention is:
1. have good scale inhibition anticorrosion erosion effect, the dirt in can minimizing system, and effective service equipment, reduced the maintenance cost of print system.
2. save water and ink use amount, can reach rapidly ink-water balance, reduce paper material consumption.
3. main component gentleness is harmless, meets the requirement of safety and environmental protection.
Detailed description of the invention
Non-limiting examples of the present invention is as follows:
Embodiment 1: the preparation of fountain solution
A kind of corrosion-mitigation scale-inhibition fountain solution, is prepared from by the component raw material of following weight (kg): sucrose ester 8, atoleine 1.5, dodecanamide propyl hydroxy sulfo lycine 6, alkyl diphenyl ether disulphonic acid sodium 5, alkyl dimethyl amine oxide 1, zinc sulfate 2, sulphaguanidine 1.5, poly-aspartate 1, poly-epoxy succinic acid 1.5, OIT 0.8, sodium lactate 1.5, auxiliary agent 8, water 40;
Wherein, auxiliary agent is made up of the raw material of following weight (kg): glycerine 7, polyethylene glycol 6, glycine 1, citric acid 2, oleic acid 1.5, caryophyllus oil 0.5, rhamnose 0.5, Tea Polyphenols 0.5, sodium acid carbonate 2, natrium citricum 18, Tween 80 3, water 40; First that citric acid, natrium citricum is water-soluble, be heated to 50-60 DEG C, then add glycerine, polyethylene glycol, caryophyllus oil, oleic acid and sodium acid carbonate, stir 15min, add all the other raw materials after being cooled to room temperature, be stirred to completely and dissolve, after filtration and get final product.
Its preparation method comprises the following steps:
(1) take raw material by formula, in reactor, add water, sucrose ester, dodecanamide propyl hydroxy sulfo lycine, alkyl diphenyl ether disulphonic acid sodium, atoleine, alkyl dimethyl amine oxide are dropped in reactor, be heated to 60-80 DEG C, stir 10-15min;
(2) temperature is adjusted to 50-60 DEG C, adds sulfonic acid guanidine, poly-aspartate, poly-epoxy succinic acid, OIT and auxiliary agent 600-800rpm to stir 15-30min;
(3) be cooled to room temperature, add rest materials, be stirred to and dissolve completely, filtering and impurity removing matter gets product.
Embodiment 2: the test of fountain solution performance
1, water-pickup of ink
Fountain solution is major effect ink-water balance performance in printing process, and wherein water-pickup of ink is an important parameter.There is material impact to water-pickup of ink in the character of fountain solution.According to offset printing principle, in offset printing process, water-pickup of ink is feasible lower than 26%.
The mensuration of water-pickup of ink C: adopt gravimetric method.
By distilled water diluting to 3% for fountain solution described in embodiment 1, in container, once add the fountain solution after 50g black ink and 50g dilution, 100r/min leaves standstill 10min after stirring 1h, by unabsorbed fountain solution and ink multi_layer extraction, is calculated as follows water-pickup of ink:
Measurement result water-pickup of ink is 21.12%, far below 26% of limiting value, in normal range (NR), is conducive to print production.
2, the mensuration of corrosion inhibition
Adopt static steel weight-loss method to measure corrosion inhibition.At normal temperatures and pressures the Q235 steel disc having weighed is put into respectively to the running water that does not add fountain solution and add fountain solution (final concentration 3%) described in embodiment 1, steel disc surface area and running water volume ratio are 1:15, and the lacing film time is 7d.After lacing film finishes, wash away corrosion product, after cleaning up, dry up and weigh.Weight loss by steel disc before and after corrosion calculates inhibition efficiency, and formula is as follows:
△ W in formula
0---of poor quality before and after blank solution lacing film;
△ W---the solution lacing film front and back that add fountain solution are of poor quality
Recording inhibition efficiency is 52.08%, and corrosion resistance is good, is applicable to practical application.
Claims (3)
1. a corrosion-mitigation scale-inhibition fountain solution, is characterized in that its raw material by following weight parts forms: sucrose ester 2-10, atoleine 1-2, dodecanamide propyl hydroxy sulfo lycine 2-8, alkyl diphenyl ether disulphonic acid sodium 1-6, alkyl dimethyl amine oxide 0.5-1.5, zinc sulfate 1-3, sulphaguanidine 1-2, poly-aspartate 0.5-1.5, poly-epoxy succinic acid 1-2, OIT 0.5-1, sodium lactate 1-2, auxiliary agent 5-10, water 30-50;
Described auxiliary agent is made up of the raw material of following weight portion: glycerine 5-10, polyethylene glycol 2-8, glycine 0.5-1.5, citric acid 1-3, oleic acid 2-3, caryophyllus oil 0.2-1, rhamnose 0.2-1, Tea Polyphenols 0.3-1, sodium acid carbonate 1-3, natrium citricum 10-30, Tween 80 1-5, water 30-50; First that citric acid, natrium citricum is water-soluble, be heated to 50-60 DEG C, then add glycerine, polyethylene glycol, caryophyllus oil, oleic acid and sodium acid carbonate, stir 15min, add all the other raw materials after being cooled to room temperature, be stirred to completely and dissolve, after filtration and get final product.
2. corrosion-mitigation scale-inhibition fountain solution according to claim 1, is characterized in that being made up of the raw material of following weight parts: sucrose ester 8, atoleine 1.5, dodecanamide propyl hydroxy sulfo lycine 6, alkyl diphenyl ether disulphonic acid sodium 5, alkyl dimethyl amine oxide 1, zinc sulfate 2, sulphaguanidine 1.5, poly-aspartate 1, poly-epoxy succinic acid 1.5, OIT 0.8, sodium lactate 1.5, auxiliary agent 8, water 40;
Described auxiliary agent is made up of the raw material of following weight portion: glycerine 7, polyethylene glycol 6, glycine 1, citric acid 2, oleic acid 1.5, caryophyllus oil 0.5, rhamnose 0.5, Tea Polyphenols 0.5, sodium acid carbonate 2, natrium citricum 18, Tween 80 3, water 40; First that citric acid, natrium citricum is water-soluble, be heated to 50-60 DEG C, then add glycerine, polyethylene glycol, caryophyllus oil, oleic acid and sodium acid carbonate, stir 15min, add all the other raw materials after being cooled to room temperature, be stirred to completely and dissolve, after filtration and get final product.
3. the preparation method of corrosion-mitigation scale-inhibition fountain solution according to claim 1, is characterized in that, comprises the following steps:
(1) take raw material by formula, in reactor, add water, sucrose ester, dodecanamide propyl hydroxy sulfo lycine, alkyl diphenyl ether disulphonic acid sodium, atoleine, alkyl dimethyl amine oxide are dropped in reactor, be heated to 60-80 DEG C, stir 10-15min;
(2) temperature is adjusted to 50-60 DEG C, adds sulfonic acid guanidine, poly-aspartate, poly-epoxy succinic acid, OIT and auxiliary agent 600-800rpm to stir 15-30min;
(3) be cooled to room temperature, add rest materials, be stirred to and dissolve completely, filtering and impurity removing matter gets product.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104908474A (en) * | 2015-06-16 | 2015-09-16 | 合肥启华环保科技有限公司 | Corrosion-resistant mold-proof fountain solution and preparation method thereof |
CN106277374A (en) * | 2016-10-09 | 2017-01-04 | 广西大学 | A kind of corrosion inhibiting and descaling agent being applicable to low-pressure boiler equipment |
CN107336538A (en) * | 2017-07-07 | 2017-11-10 | 合肥新意境材料有限责任公司 | A kind of corrosion-mitigation scale-inhibition fountain solution of the konjac glucomannan of carragheen containing κ compounding and preparation method thereof |
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US5282892A (en) * | 1991-07-04 | 1994-02-01 | Heidelberger Druckmaschinen Ag | Dampening-solution concentrate and dampening solution and method of use thereof in the offset printing process |
CN1297016A (en) * | 1999-11-11 | 2001-05-30 | 富士胶片株式会社 | Dumping processing solution composition for lithography |
CN101805067A (en) * | 2009-02-17 | 2010-08-18 | 上海洗霸科技有限公司 | Phosphorus-free green composite corrosion and scale inhibitor |
CN103694773A (en) * | 2013-12-26 | 2014-04-02 | 青岛中科菲力工程技术研发有限公司 | Cleaning agent for printing damping roller |
CN103786460A (en) * | 2014-01-16 | 2014-05-14 | 合肥环照高分子材料厂 | Alcohol-free environment-friendly fountain solution and preparation method thereof |
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2014
- 2014-07-05 CN CN201410318024.1A patent/CN104085220A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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US5282892A (en) * | 1991-07-04 | 1994-02-01 | Heidelberger Druckmaschinen Ag | Dampening-solution concentrate and dampening solution and method of use thereof in the offset printing process |
CN1297016A (en) * | 1999-11-11 | 2001-05-30 | 富士胶片株式会社 | Dumping processing solution composition for lithography |
CN101805067A (en) * | 2009-02-17 | 2010-08-18 | 上海洗霸科技有限公司 | Phosphorus-free green composite corrosion and scale inhibitor |
CN103694773A (en) * | 2013-12-26 | 2014-04-02 | 青岛中科菲力工程技术研发有限公司 | Cleaning agent for printing damping roller |
CN103786460A (en) * | 2014-01-16 | 2014-05-14 | 合肥环照高分子材料厂 | Alcohol-free environment-friendly fountain solution and preparation method thereof |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104908474A (en) * | 2015-06-16 | 2015-09-16 | 合肥启华环保科技有限公司 | Corrosion-resistant mold-proof fountain solution and preparation method thereof |
CN106277374A (en) * | 2016-10-09 | 2017-01-04 | 广西大学 | A kind of corrosion inhibiting and descaling agent being applicable to low-pressure boiler equipment |
CN107336538A (en) * | 2017-07-07 | 2017-11-10 | 合肥新意境材料有限责任公司 | A kind of corrosion-mitigation scale-inhibition fountain solution of the konjac glucomannan of carragheen containing κ compounding and preparation method thereof |
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Application publication date: 20141008 |