CN106277374A - A kind of corrosion inhibiting and descaling agent being applicable to low-pressure boiler equipment - Google Patents

A kind of corrosion inhibiting and descaling agent being applicable to low-pressure boiler equipment Download PDF

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Publication number
CN106277374A
CN106277374A CN201610883262.6A CN201610883262A CN106277374A CN 106277374 A CN106277374 A CN 106277374A CN 201610883262 A CN201610883262 A CN 201610883262A CN 106277374 A CN106277374 A CN 106277374A
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China
Prior art keywords
parts
water
applicable
low
equipment
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CN201610883262.6A
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Chinese (zh)
Inventor
梁婵
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Guangxi University
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Guangxi University
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Priority to CN201610883262.6A priority Critical patent/CN106277374A/en
Publication of CN106277374A publication Critical patent/CN106277374A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • C02F5/08Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
    • C02F5/10Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
    • C02F5/105Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances combined with inorganic substances
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/02Non-contaminated water, e.g. for industrial water supply
    • C02F2103/023Water in cooling circuits

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)

Abstract

A kind of corrosion inhibiting and descaling agent being applicable to low-pressure boiler equipment, raw material and weight portion thereof are as follows: sodium xylene sulfonate 25~30 parts, poly-epoxy succinic acid 5~10 parts, vanadic acid sodium 3~8 parts, matrine 0.5~0.8 part, Tween 80 5~10 parts and benzyl alcohol 20~25 parts.Control industrial circulating cooling water system fouling and corrosion, effectively suppress growth of microorganism, it is ensured that the heat exchange efficiency of equipment and service life, not only can improve the recycling rate of waterused of water, saving water resource, and can greatly improve the integral status of recirculated cooling water.

Description

A kind of corrosion inhibiting and descaling agent being applicable to low-pressure boiler equipment
Technical field
The present invention relates to water treatment agent field, a kind of corrosion inhibiting and descaling agent being applicable to low-pressure boiler equipment.
Background technology
Recirculated cooling water is to use water sport in water for industrial use, in the industries such as petrochemical industry, electric power, iron and steel, metallurgy, circulation The consumption of cooling water accounts for the 50-90% of enterprise water use total amount.Owing to there being different salinity in former water, recirculated cooling water is concentrated to Certain multiple must discharge certain dense water, and supplementary new water makes the salinity in cooling water, pH value, organic concentration, suspension Thing content controls a rational allowed band, and water resources consumption is the biggest with the quantity of sewage discharge.Due to China's water Resource critical shortage, protection environmental demand and regulation increasingly stringent.Therefore, recirculated cooling water design is considered as not affecting technique Use water-saving and environmental protection new technique under condition as far as possible.Recirculated cooling water refers to be changed by heat exchanger heat-shift or direct contact After hot mode comes exchange media heat cooled tower cold water, recycle, with saving water resource.
Circulating water cooling treatment is to ensure that the equipment such as cooling tower, cold water board is in optimal running status, circulates cold But water processes and must effectively control microorganism species, the generation of suppression incrustation scale, the corrosion of prevention pipe-line equipment, and fouling can affect Heat exchange efficiency, source of consuming energy more, affect technological operation, corrosion can reduce service life of equipment, and there is potential safety hazard.Circulating cooling The process of water can be attributed to following four aspect: 1. removing oil removal: set up other filter device, other filter flow is generally recirculated water The 1~5% of amount, filter and remove suspended substances matter.2. control fouling;Soften desalination or add antisludging agent.3. control corrosion rate;Add resistance Dirt agent, makes metal surface form thin film and is covered by metal, thus completely cut off with corrosive medium, prevent metal erosion.4. Control microorganism: add biocide.
Large, medium and small boiler stops fouling and corrosion, chemical treatment method in useable stove, adds anticorrosion in boiler feed water Antisludging agent, reduces boiler water hardness demineralized water, reduces fouling and corrosion, and this method is simple and practical, receives praises from customers.And delay Erosion antisludging agent is of a great variety, it is common that compounding of some structure specilization compounds, and will be according to metal surface situation, corrosive medium The factors such as composition and ruuning situation carry out kind selection.
Summary of the invention
The present invention is directed to the deficiencies in the prior art, it is provided that a kind of corrosion inhibiting and descaling agent being applicable to low-pressure boiler equipment, reach Reduce the purpose in the service life of energy consumption, extension device.
To achieve these goals, present invention employs techniques below scheme:
A kind of corrosion inhibiting and descaling agent being applicable to low-pressure boiler equipment, raw material and weight portion thereof are as follows: sodium xylene sulfonate 25 ~30 parts, poly-epoxy succinic acid 5~10 parts, vanadic acid sodium 3~8 parts, matrine 0.5~0.8 part, Tween 80 5~10 parts and benzene Methanol 20~25 parts.
Compared with prior art, the beneficial effect that the present invention possesses:
Control industrial circulating cooling water system fouling and corrosion, effectively suppress growth of microorganism, it is ensured that the heat exchange effect of equipment Rate and service life, not only can improve the recycling rate of waterused of water, saving water resource, and can greatly improve recirculated cooling water Integral status.
Detailed description of the invention
Below by embodiment, technical scheme is further elaborated.
Embodiment 1
A kind of corrosion inhibiting and descaling agent being applicable to low-pressure boiler equipment, raw material and weight portion thereof are as follows: sodium xylene sulfonate 30 Part, poly-epoxy succinic acid 10 parts, vanadic acid sodium 8 parts, matrine 0.5 part, Tween 80 10 parts and benzyl alcohol 25 parts.
Embodiment 2
A kind of corrosion inhibiting and descaling agent being applicable to low-pressure boiler equipment, raw material and weight portion thereof are as follows: sodium xylene sulfonate 25 Part, poly-epoxy succinic acid 5 parts, vanadic acid sodium 3 parts, matrine 0.8 part, Tween 80 5 parts and benzyl alcohol 20 parts.
Embodiment 3
A kind of corrosion inhibiting and descaling agent being applicable to low-pressure boiler equipment, raw material and weight portion thereof are as follows: sodium xylene sulfonate 28 Part, poly-epoxy succinic acid 7 parts, vanadic acid sodium 5 parts, matrine 0.6 part, Tween 80 8 parts and benzyl alcohol 22 parts.
According to Code for design of industrial recirculating cooling water treatment GB50050-2007,
Carbon steel equipment heat-transfer area water side corrosion speed should be less than 0.075mm/a;
Equipment heat-transfer area water side dirtiness resistance value should be less than 3.44 × 10-4m2·K/W;
Equipment heat-transfer area water side adheres to speed and not should be greater than 15mg/cm2Month;
Total number of bacteria is less than 105Individual/milliliter;
Slime content is less than 5ml/m3
After weighing each raw material components mix homogeneously according to formula described in embodiment 3, add according to the addition of 100mg/L and close In the blood circulation of road, then monitoring above-mentioned water treatment efficiency index, result is as follows:
Carbon steel equipment heat-transfer area water side corrosion speed is 0.018mm/a, is better than standard-required;
Equipment heat-transfer area water side dirtiness resistance value is 1.99 × 10-5m2K/W, is better than standard-required;
It is 2.01mg/cm that equipment heat-transfer area water side adheres to speed2Month, it is better than standard-required;
Total number of bacteria is 8.9 × 107Individual/milliliter, is better than standard-required;
Slime content is 1.4ml/m3, it is better than standard-required.

Claims (1)

1. the corrosion inhibiting and descaling agent being applicable to low-pressure boiler equipment, it is characterised in that raw material and weight portion thereof are as follows:
Sodium xylene sulfonate 25~30 parts, poly-epoxy succinic acid 5~10 parts, vanadic acid sodium 3~8 parts, matrine 0.5~0.8 part, tell Temperature 805~10 parts and benzyl alcohol 20~25 parts.
CN201610883262.6A 2016-10-09 2016-10-09 A kind of corrosion inhibiting and descaling agent being applicable to low-pressure boiler equipment Pending CN106277374A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610883262.6A CN106277374A (en) 2016-10-09 2016-10-09 A kind of corrosion inhibiting and descaling agent being applicable to low-pressure boiler equipment

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610883262.6A CN106277374A (en) 2016-10-09 2016-10-09 A kind of corrosion inhibiting and descaling agent being applicable to low-pressure boiler equipment

Publications (1)

Publication Number Publication Date
CN106277374A true CN106277374A (en) 2017-01-04

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610883262.6A Pending CN106277374A (en) 2016-10-09 2016-10-09 A kind of corrosion inhibiting and descaling agent being applicable to low-pressure boiler equipment

Country Status (1)

Country Link
CN (1) CN106277374A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1435384A (en) * 2002-01-30 2003-08-13 北京化工大学 Corrosion-and scaling-inhibiting water treating agent
CN102453917A (en) * 2010-10-27 2012-05-16 中国石油化工股份有限公司 Corrosion inhibitor for carbon dioxide removing system and application thereof
CN104085220A (en) * 2014-07-05 2014-10-08 安徽索亚装饰材料有限公司 Corrosion and scale inhibition fountain solution and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1435384A (en) * 2002-01-30 2003-08-13 北京化工大学 Corrosion-and scaling-inhibiting water treating agent
CN102453917A (en) * 2010-10-27 2012-05-16 中国石油化工股份有限公司 Corrosion inhibitor for carbon dioxide removing system and application thereof
CN104085220A (en) * 2014-07-05 2014-10-08 安徽索亚装饰材料有限公司 Corrosion and scale inhibition fountain solution and preparation method thereof

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