CN104045962A - 一种适于电镀的增强abs树脂组合物及其制备方法与应用 - Google Patents

一种适于电镀的增强abs树脂组合物及其制备方法与应用 Download PDF

Info

Publication number
CN104045962A
CN104045962A CN201410240548.3A CN201410240548A CN104045962A CN 104045962 A CN104045962 A CN 104045962A CN 201410240548 A CN201410240548 A CN 201410240548A CN 104045962 A CN104045962 A CN 104045962A
Authority
CN
China
Prior art keywords
abs resin
temperature
electroplating
district
resin combination
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201410240548.3A
Other languages
English (en)
Other versions
CN104045962B (zh
Inventor
何超雄
王亮
程庆
袁绍彦
付锦锋
陈日平
王林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kingfa Science and Technology Co Ltd
Original Assignee
Kingfa Science and Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kingfa Science and Technology Co Ltd filed Critical Kingfa Science and Technology Co Ltd
Priority to CN201410240548.3A priority Critical patent/CN104045962B/zh
Publication of CN104045962A publication Critical patent/CN104045962A/zh
Application granted granted Critical
Publication of CN104045962B publication Critical patent/CN104045962B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00—Making granules
    • B29B9/12—Making granules characterised by structure or composition
    • B29B9/14—Making granules characterised by structure or composition fibre-reinforced
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00—Mixing; Kneading
    • B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
    • B29B7/58—Component parts, details or accessories; Auxiliary operations
    • B29B7/72—Measuring, controlling or regulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00—Making granules
    • B29B9/12—Making granules characterised by structure or composition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
    • B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/92—Measuring, controlling or regulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00—Mixing; Kneading
    • B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
    • B29B7/34—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices
    • B29B7/38—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary
    • B29B7/46—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00—Making granules
    • B29B9/02—Making granules by dividing preformed material
    • B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92009—Measured parameter
    • B29C2948/92266—Mechanical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92323—Location or phase of measurement
    • B29C2948/92485—Start-up, shut-down or parameter setting phase; Emergency shut-down; Material change; Test or laboratory equipment or studies
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92504—Controlled parameter
    • B29C2948/9258—Velocity
    • B29C2948/9259—Angular velocity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92504—Controlled parameter
    • B29C2948/92704—Temperature
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92504—Controlled parameter
    • B29C2948/92761—Mechanical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92819—Location or phase of control
    • B29C2948/92857—Extrusion unit
    • B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
    • B29C2948/92895—Barrel or housing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92819—Location or phase of control
    • B29C2948/92857—Extrusion unit
    • B29C2948/92904—Die; Nozzle zone
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92819—Location or phase of control
    • B29C2948/9298—Start-up, shut-down or parameter setting phase; Emergency shut-down; Material change; Test or laboratory equipment or studies

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Electroplating Methods And Accessories (AREA)

Abstract

本发明公开了一种适于电镀的增强ABS树脂组合物，按重量百分比计，包括如下组分：85%～96%ABS树脂；3%～10%碳纤维；0.1%～1.0%分散剂；0.01%～1.0%润滑剂；0.1%～1.0%主抗氧剂；0.5%～2.0%辅助抗氧剂；本发明的适于电镀的增强ABS树脂组合物能降低塑料电镀制件的线性热膨胀系数，其线性热膨胀系数比普通ABS树脂减小50%以上，能较好满足塑料电镀制件的性能要求；本发明采用碳纤维能增强ABS树脂的导电性，可有效增加ABS树脂与电镀层的结合力，能缩短电镀前期的预处理时间，提高电镀生产的加工效率，更有利于电镀生产；本发明的适于电镀的增强ABS树脂组合物具有高力学强度，且尺寸稳定性好。

Description

一种适于电镀的增强ABS树脂组合物及其制备方法与应用
技术领域
本发明涉及高分子领域，特别涉及一种适于电镀的增强ABS树脂组合物及其制备方法与应用。
背景技术
近年来，塑料电镀已被广泛应用在塑料零件的装饰上，而ABS塑料是塑料电镀制件中应用最广的一种。ABS塑料是丙烯腈(A)、丁二烯(B)、苯乙烯(S)的三元共聚物。对电镀级ABS塑料来说，丁二烯的含量对电镀影响很大，一般应控制在18%～23%，与电镀层的结合力最好。但是由于ABS塑料是非导体，所以在电镀前必须在ABS塑料附上导电层，这需要经过粗化、中和、敏化、活化、化学镀等几个步骤，处理过程比较复杂。另外，由于ABS塑料的刚性强度不高，对于一些高力学强度要求的塑料电镀制件，如电镀汽车门拉手和电视机支撑底座等塑料电镀制件，普通ABS塑料基材难以满足越来越高的塑料电镀制品性能要求。因此有必要开发一种既与镀层有良好结合力，又具有高力学强度的ABS树脂组合物。
发明内容
为了克服现有技术的不足与缺陷，本发明的首要目的是提供一种具有低线性热膨胀系数、与镀层有良好结合力，且有高力学强度的适于电镀的增强ABS树脂组合物。
本发明的另一目的在于提供上述适于电镀的增强ABS树脂组合物的制备方法。
本发明的另一目的在于提供上述适于电镀的增强ABS树脂组合物的用途。
本发明通过如下技术方案予以实现：
一种适于电镀的增强ABS树脂组合物，按重量百分比计，包括如下组分：
ABS树脂           85%~96%；
碳纤维             3%~10%；
分散剂             0.1%~1.0%；
润滑剂             0.01%~1.0%；
主抗氧剂           0.1%~1.0%；
辅助抗氧剂         0.5%~2.0%。
优选地，所述ABS树脂（丙烯腈-丁二烯-苯乙烯树脂），可以通过常规制备方法制得，优选为乳液法合成制备方法：将苯乙烯单体和丙烯腈与聚丁二烯胶乳进行乳液接枝共聚，另外苯乙烯单体和丙烯腈单体进行共聚生成SAN，然后两者掺合可得ABS树脂。
优选地，所述碳纤维为碳纤维短切原丝，纤维直径为6~10μm，长度为3~12mm。
优选地，所述分散剂为白矿油，所述润滑剂为N,N'-亚乙基双硬脂酰胺。
优选地，所述主抗氧剂为受阻酚类抗氧剂；所述辅助抗氧剂为亚磷酸酯类抗氧剂；所述主抗氧剂优选为四[β-（3, 5-二叔丁基-4-羟基苯基）丙酸]季茂四醇脂；所述辅助抗氧剂优选为三[2, 4-二叔丁基苯基]亚磷酸酯。
一种上述适于电镀的增强ABS树脂组合物的制备方法，包括如下步骤：
a）按重量配比称取ABS树脂、分散剂、润滑剂、主抗氧剂和辅助抗氧剂，在高速搅拌混料机中混合均匀后送入双螺杆挤出机中；
b）碳纤维通过双螺杆挤出机的侧喂系统加入，经双螺杆挤出机熔融挤出、造粒，即得适于电镀的增强ABS树脂组合物。
步骤a）中所述ABS树脂、分散剂、润滑剂、主抗氧剂和辅助抗氧剂在高速搅拌混料机中的投料混合方式可以为同时投料混合，也可以单独通过计量喂料器进入高速搅拌混料机，
步骤b）中碳纤维通过双螺杆挤出机的侧喂系统是在双螺杆的第六区加入。
所述双螺杆挤出机的喂料转速为200~350 rpm；所述双螺杆挤出机的各段螺杆温度从加料口到机头的温度为：一区温度80~120oC、二区温度140~160oC、三区温度200~210oC、四区温度210~220oC、五区温度220~230oC、六区温度220~230oC、七区温度220~230oC、八区温度220~230oC、九区温度220~230oC、机头温度240oC；所述螺杆转速为250~400rpm。
上述适于电镀的增强ABS树脂组合物的制备方法得到的适于电镀的增强ABS树脂组合物在塑料电镀制件中的应用。
本发明与现有技术相比，具有如下有益效果：
1）本发明的适于电镀的增强ABS树脂组合物能降低塑料电镀制件的线性热膨胀系数，其线性热膨胀系数比普通ABS树脂减小50%以上，能较好满足塑料电镀制件的性能要求；
2）本发明采用碳纤维能增强ABS树脂的导电性，可有效增加ABS树脂与电镀层的结合力，能缩短电镀前期的预处理时间，提高电镀生产的加工效率，更有利于电镀生产；
3）本发明的适于电镀的增强ABS树脂组合物具有高力学强度，且尺寸稳定性好。
具体实施方式
下面通过具体实施方式来进一步说明本发明，以下实施例为本发明较佳的实施方式，但本发明的实施方式并不受下述实施例的限制。
现对实施例及对比例所用的原材料做如下说明，但不限于这些材料：
所述ABS树脂为奇美PA-727；
所述碳纤维为短切碳纤维；
所述分散剂为白矿油；
所述润滑剂为N,N'-亚乙基双硬脂酰胺；
所述主抗氧剂为四四[β-（3, 5-二叔丁基-4-羟基苯基）丙酸]季茂四醇脂，辅助抗氧剂为三[2, 4-二叔丁基苯基]亚磷酸酯。
实施例1~6及对比例1~2：
按表1中的重量百分比称取好ABS树脂、分散剂、润滑剂、主抗氧剂和辅助抗氧剂，在高速搅拌混料机中混合均匀或单独通过计量喂料器进入双螺杆挤出机中，其中碳纤维通过双螺杆挤出机的侧喂系统在螺杆第六区加入；将上述混合物料送入双螺杆挤出机中，双螺杆挤出机的各段螺杆温度从加料口到机头的温度分别优选为一区温度80oC、二区温度140oC、三区温度200oC、四区温度210oC、五区温度220oC、六区温度230oC、七区温度220oC、八区温度230oC、九区温度230oC、机头温度230oC，螺杆转速优选为350rpm，双螺杆挤出机的长径比为40，在双螺杆挤出机的输送和剪切作用下，充分熔融塑化、捏合混炼、经机头挤出、拉条、冷却、切粒、干燥，最后包装，即得适于电镀的增强ABS树脂组合物；并测定其线性热膨胀系数、百格测试结果以及各力学性能，具体测试数据列于表1中。
表1   实施例1~6及对比例1~2中各组成的具体配比（重量百分比）及其测试性能结果
　 实施例1 实施例2 实施例3 实施例4 实施例5 实施例6 对比例1 对比例2
ABS树脂 96 93 90 92 90 85 100 79
碳纤维 3 5 7 8 10 10 0 20
分散剂 0.1 0.5 0.5 0.5 0.7 1.0 0 0.1
润滑剂 0.1 0.4 0.5 0.6 0.6 1.0 0 0.1
主抗氧剂 0.3 0.4 0.5 0.5 0.4 1.0 0 0.3
辅助抗氧剂 0.5 0.7 1.5 1.8 1.2 2.0 0 0.5
拉伸强度(mPa) 51 69 76 85 90 92 39 113
弯曲强度(mPa) 69 87 97 104 110 116 63 151
弯曲模量(mPa) 3620 4350 5310 5650 6300 6520 2160 7950
IZOD缺口冲击强度(kJ/m2) 16 13 10 8 6 5 23 3
线性热膨胀系数(μm/(m·℃)) 49 47 43 41 38 37 99 28
百格测试结果 2 2 0 1 0 1 2 5
各项性能测试方法：
拉伸强度按ISO 527标准进行测试，试样为Ⅰ型试样，测试设备为德国Zwick公司的拉伸试验机Z020。
弯曲强度按ISO 178标准进行测试，试样尺寸为4mm×10mm×80mm，测试设备为德国Zwick Roell公司的弯曲试验机Z005。
悬臂梁缺口冲击强度按照ISO 180标准进行测试，试样尺寸为4mm×10mm×80mm，缺口深度为2mm。测试设备为德国Zwick Roell公司的冲击试验机HIT5.5P。
线性热膨胀系数按GB/T 1036标准测试，测试温度范围-40~40℃。测试设备为热机械分析仪TMA Q400。
将实施例1~6和对比例1~2得到适于电镀的增强ABS树脂组合物进行电镀，并按GB/T 9286标准进行百格测试实验，百格测试结果为3M胶带撕落的格数。

Claims (8)

1.一种适于电镀的增强ABS树脂组合物，其特征在于，按重量百分比计，包括如下组分：
ABS树脂           85%~96%；
碳纤维             3%~10%；
分散剂             0.1%~1.0%；
润滑剂             0.01%~1.0%；
主抗氧剂           0.1%~1.0%；
辅助抗氧剂         0.5%~2.0%。
2.根据权利要求1所述的适于电镀的增强ABS树脂组合物，其特征在于：所述碳纤维为碳纤维短切原丝，纤维直径为6~10μm，长度为3~12mm。
3.根据权利要求1所述的适于电镀的增强ABS树脂组合物，其特征在于：所述分散剂为白矿油，所述润滑剂为N,N'-亚乙基双硬脂酰胺。
4.根据权利要求1所述的适于电镀的增强ABS树脂组合物，其特征在于：所述主抗氧剂为受阻酚类抗氧剂；所述辅助抗氧剂为亚磷酸酯类抗氧剂；所述主抗氧剂优选为四[β-（3, 5-二叔丁基-4-羟基苯基）丙酸]季茂四醇脂；所述辅助抗氧剂优选为三[2, 4-二叔丁基苯基]亚磷酸酯。
5.如权利要求1~4任一项所述的适于电镀的增强ABS树脂组合物的制备方法，包括如下步骤：
a）按重量配比称取ABS树脂、分散剂、润滑剂、主抗氧剂和辅助抗氧剂，在高速搅拌混料机中混合均匀后送入双螺杆挤出机中；
b）碳纤维通过双螺杆挤出机的侧喂系统加入，经双螺杆挤出机熔融挤出、造粒，即得适于电镀的增强ABS树脂组合物。
6.根据权利要求5所述的适于电镀的增强ABS树脂组合物的制备方法，其特征在于：步骤b）所述碳纤维通过双螺杆挤出机的侧喂系统是在双螺杆的第六区加入。
7.根据权利要求5所述的适于电镀的增强ABS树脂组合物的制备方法，其特征在于：所述双螺杆挤出机的喂料转速为200~350 rpm；所述双螺杆挤出机的各段螺杆温度从加料口到机头的温度为：一区温度80~120oC、二区温度140~160oC、三区温度200~210oC、四区温度210~220oC、五区温度220~230oC、六区温度220~230oC、七区温度220~230oC、八区温度220~230oC、九区温度220~230oC、机头温度240oC；所述螺杆转速为250~400rpm。
8.如权利要求5所述的适于电镀的增强ABS树脂组合物的制备方法得到的适于电镀的增强ABS树脂组合物在塑料电镀制件中的应用。
CN201410240548.3A 2014-05-30 2014-05-30 一种适于电镀的增强abs树脂组合物及其制备方法与应用 Active CN104045962B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410240548.3A CN104045962B (zh) 2014-05-30 2014-05-30 一种适于电镀的增强abs树脂组合物及其制备方法与应用

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410240548.3A CN104045962B (zh) 2014-05-30 2014-05-30 一种适于电镀的增强abs树脂组合物及其制备方法与应用

Publications (2)

Publication Number Publication Date
CN104045962A true CN104045962A (zh) 2014-09-17
CN104045962B CN104045962B (zh) 2019-03-29

Family

ID=51499379

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410240548.3A Active CN104045962B (zh) 2014-05-30 2014-05-30 一种适于电镀的增强abs树脂组合物及其制备方法与应用

Country Status (1)

Country Link
CN (1) CN104045962B (zh)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111040368A (zh) * 2019-12-20 2020-04-21 广州市聚赛龙工程塑料股份有限公司 一种低线性膨胀系数的abs合金材料及其制备方法和应用
CN111500043A (zh) * 2020-04-13 2020-08-07 金发科技股份有限公司 一种聚碳酸酯合金材料及其制备方法和应用

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1513028A (zh) * 2001-05-31 2004-07-14 ������������ʽ���� 镀覆基材用树脂组合物及使用该组合物的树脂成型品及镀成零件
CN1772798A (zh) * 2005-08-03 2006-05-17 北京纳盛通新材料科技有限公司 一种导电塑料及其加工方法、加工装置
CN102504471A (zh) * 2011-12-02 2012-06-20 四川长虹电器股份有限公司 Abs/玻璃纤维复合材料及其制备方法
CN103421270A (zh) * 2012-05-25 2013-12-04 上海杰事杰新材料(集团)股份有限公司 一种abs材料及其制备方法
CN103483761A (zh) * 2013-09-17 2014-01-01 安徽科聚新材料有限公司 一种纤维增强abs材料及其制备方法
CN103740082A (zh) * 2013-12-28 2014-04-23 重庆普利特新材料有限公司 一种ul94-5va级的高性能阻燃增强pc/abs共混材料及其制备方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1513028A (zh) * 2001-05-31 2004-07-14 ������������ʽ���� 镀覆基材用树脂组合物及使用该组合物的树脂成型品及镀成零件
CN1772798A (zh) * 2005-08-03 2006-05-17 北京纳盛通新材料科技有限公司 一种导电塑料及其加工方法、加工装置
CN102504471A (zh) * 2011-12-02 2012-06-20 四川长虹电器股份有限公司 Abs/玻璃纤维复合材料及其制备方法
CN103421270A (zh) * 2012-05-25 2013-12-04 上海杰事杰新材料(集团)股份有限公司 一种abs材料及其制备方法
CN103483761A (zh) * 2013-09-17 2014-01-01 安徽科聚新材料有限公司 一种纤维增强abs材料及其制备方法
CN103740082A (zh) * 2013-12-28 2014-04-23 重庆普利特新材料有限公司 一种ul94-5va级的高性能阻燃增强pc/abs共混材料及其制备方法

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111040368A (zh) * 2019-12-20 2020-04-21 广州市聚赛龙工程塑料股份有限公司 一种低线性膨胀系数的abs合金材料及其制备方法和应用
CN111500043A (zh) * 2020-04-13 2020-08-07 金发科技股份有限公司 一种聚碳酸酯合金材料及其制备方法和应用
CN111500043B (zh) * 2020-04-13 2022-03-29 金发科技股份有限公司 一种聚碳酸酯合金材料及其制备方法和应用

Also Published As

Publication number Publication date
CN104045962B (zh) 2019-03-29

Similar Documents

Publication Publication Date Title
CN103013089B (zh) 一种阻燃玻纤增强pc/abs复合材料及其制备方法
CN103059547A (zh) 一种电镀pc/abs合金材料及其制备方法
CN103525088A (zh) 一种聚苯硫醚复合材料及其制备方法
CN103382302A (zh) 一种红磷阻燃尼龙组合物及其制备方法
CN104448803B (zh) 无卤阻燃长纤维增强尼龙6复合材料及其制备方法
CN107083030A (zh) 一种低翘曲高强度玻纤增强pbt/asa合金材料及其制备方法
CN103772885A (zh) 一种消光pc/abs汽车仪表盘材料及其制备方法
CN110283384A (zh) 一种高光泽高强度玄武岩增强聚丙烯复合材料及制备方法
CN103756240A (zh) 一种耐应力发白abs复合材料及其制备方法和应用
CN110372988A (zh) 一种abs/pok复合材料及其制备方法
CN102993651A (zh) 玻璃纤维增强聚对苯二甲酸丁二醇酯复合材料及其制备方法
CN103483816A (zh) 一种碳纤增强聚酰亚胺复合材料及其制备方法
CN104497532A (zh) 一种无卤阻燃高光泽高玻纤增强pc材料及其制备方法
CN104045963B (zh) 一种适于电镀的玻纤增强高光abs树脂组合物及其制备方法与应用
CN102040829B (zh) 高速铁路系统用玻璃纤维增强尼龙材料及其制备方法
CN102942736B (zh) 一种高玻纤含量增强聚丙烯材料及其制备方法
CN102617974A (zh) 一种abs/埃洛石复合材料及其制备方法
CN104356585A (zh) 高性能连续碳纤维增强abs复合材料及其制备方法
CN104045962A (zh) 一种适于电镀的增强abs树脂组合物及其制备方法与应用
CN103755881A (zh) 聚苯硫醚与聚酰胺的相容剂、含该相容剂的聚苯硫醚/聚酰胺复合材料及其制备方法
CN103709710B (zh) 加工性能优异的pc/abs合金材料及其制备方法
CN106633776B (zh) 一种适合门把手用电镀pc/abs合金材料及其制备方法
CN106893250B (zh) 一种吹塑用高熔体强度、良外观的abs树脂组合物
CN103540124A (zh) 一种耐磨热塑性树脂复合材料及其制备方法
CN102618027A (zh) 一种耐长期高温热老化pa6材料及其制备方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant