CN104030731A - Silicon zirconium hard glaze and method for preparing color spray decorative ceramics under silicon zirconium hard glaze - Google Patents
Silicon zirconium hard glaze and method for preparing color spray decorative ceramics under silicon zirconium hard glaze Download PDFInfo
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- CN104030731A CN104030731A CN201410262620.2A CN201410262620A CN104030731A CN 104030731 A CN104030731 A CN 104030731A CN 201410262620 A CN201410262620 A CN 201410262620A CN 104030731 A CN104030731 A CN 104030731A
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- 239000007921 spray Substances 0.000 title claims abstract description 35
- UVGLBOPDEUYYCS-UHFFFAOYSA-N silicon zirconium Chemical compound [Si].[Zr] UVGLBOPDEUYYCS-UHFFFAOYSA-N 0.000 title claims abstract description 17
- 239000000919 ceramic Substances 0.000 title claims abstract description 12
- 238000000034 method Methods 0.000 title claims abstract description 9
- 229910052796 boron Inorganic materials 0.000 claims abstract description 14
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000010453 quartz Substances 0.000 claims abstract description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 6
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910021532 Calcite Inorganic materials 0.000 claims abstract description 6
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 6
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 6
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 6
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000002245 particle Substances 0.000 claims abstract description 6
- 239000000049 pigment Substances 0.000 claims abstract description 6
- 239000000454 talc Substances 0.000 claims abstract description 6
- 229910052623 talc Inorganic materials 0.000 claims abstract description 6
- 239000011787 zinc oxide Substances 0.000 claims abstract description 6
- 239000000463 material Substances 0.000 claims description 34
- 239000000203 mixture Substances 0.000 claims description 24
- 238000009472 formulation Methods 0.000 claims description 20
- 239000000758 substrate Substances 0.000 claims description 11
- GUBGYTABKSRVRQ-PICCSMPSSA-N D-Maltose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 claims description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 10
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 10
- 238000000498 ball milling Methods 0.000 claims description 10
- 229910052700 potassium Inorganic materials 0.000 claims description 10
- 239000011591 potassium Substances 0.000 claims description 10
- 239000004576 sand Substances 0.000 claims description 10
- 239000003674 animal food additive Substances 0.000 claims description 7
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 5
- 229930006000 Sucrose Natural products 0.000 claims description 5
- 235000011187 glycerol Nutrition 0.000 claims description 5
- 238000009413 insulation Methods 0.000 claims description 5
- 230000003647 oxidation Effects 0.000 claims description 5
- 238000007254 oxidation reaction Methods 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 239000005720 sucrose Substances 0.000 claims description 5
- 235000012222 talc Nutrition 0.000 claims description 5
- 239000000654 additive Substances 0.000 abstract description 3
- 230000000996 additive effect Effects 0.000 abstract description 3
- 238000005034 decoration Methods 0.000 abstract description 3
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 3
- 150000002500 ions Chemical class 0.000 abstract description 3
- 229910052793 cadmium Inorganic materials 0.000 abstract description 2
- 238000010304 firing Methods 0.000 abstract description 2
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 abstract 2
- 238000004090 dissolution Methods 0.000 abstract 2
- CNLWCVNCHLKFHK-UHFFFAOYSA-N aluminum;lithium;dioxido(oxo)silane Chemical compound [Li+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O CNLWCVNCHLKFHK-UHFFFAOYSA-N 0.000 abstract 1
- 239000000440 bentonite Substances 0.000 abstract 1
- 229910000278 bentonite Inorganic materials 0.000 abstract 1
- 229910052642 spodumene Inorganic materials 0.000 abstract 1
- 239000003086 colorant Substances 0.000 description 6
- 210000003298 dental enamel Anatomy 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 4
- 230000007547 defect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005187 foaming Methods 0.000 description 2
- 229910052573 porcelain Inorganic materials 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 208000003351 Melanosis Diseases 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 239000010977 jade Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
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- Glass Compositions (AREA)
- Adornments (AREA)
Abstract
The invention relates to silicon zirconium hard glaze which comprises the following components in percentage by weight: 55-70 percent of formula A, 30-45 percent of formula B, 40-45 percent of moisture, 0.3-1.2 percent of glaze additive and 5-10 percent of pigment, wherein the formula A comprises the following components in percentage by weight: 20-25 percent of potassium feldspar, 8-15 percent of aluminum oxide, 38-48 percent of Longyan particles, 20-25 percent of quartz and 0-2 percent of bentonite; the formula B comprises the following components in percentage by weight: 34-39 percent of potassium feldspar, 9-15 percent of calcite, 4-9 percent of zinc oxide, 5-10 percent of kaolin, 25-30 percent of quartz, 0-5 percent of spodumene, 0-2 percent of talc and 0-2 percent of boron clinker. The invention also provides a method for preparing the color spray decorative ceramics under silicon zirconium hard glaze. According to the method, the risk of lead-cadmium dissolution and heavy metal ion dissolution is reduced, a phenomenon that a pigment layer flows due to flow of the glaze layer in the firing process is avoided, and the decoration requirement is well met.
Description
Technical field
The present invention relates to the preparation method of color spray decorative ceramics under a kind of silicon zirconium hard glaze and silicon zirconium hard glaze.
Background technology
Pottery has the history of existing more than 5000 in China.Porcelain is one of greatness invention of China, and exquisite Chinese pottery was once enjoyed great prestige in the world.China is the first in the world large household porcelain production state and export State.
For a long time, household china lacks innovation at decoration technology technical elements, state of the art does not have obvious lifting for many years, goods are decorated still applique, the transfering printing process methods of adopting more, applique product on glaze, and wear resisting property is poor, be difficult to meet the requirement of cutlery to hardness of glaze surface, flower face lacks nature, send out a uncut jade returns genuine breath, and the stripping problem of heavy metal ion easily appears in and applique on glaze.Limited the outlet of faience, had a strong impact on the economic benefit of enterprise, be badly in need of a kind of new decoration technology of development, met the requirement of cutlery to hardness of glaze surface, General Promotion quality product, improves Business Economic Benefit.
Summary of the invention
The object of the present invention is to provide the preparation method of color spray decorative ceramics under a kind of silicon zirconium hard glaze and silicon zirconium hard glaze, to solve the problem and the defect that exist in above-mentioned technology.
For achieving the above object, the present invention by the following technical solutions:
A kind of silicon zirconium hard glaze, comprises that weight percent is A formulation material 55 ~ 70%, B formulation material 30 ~ 45%, moisture 40 ~ 45%, glaze feed additives 0.3 ~ 1.2%, pigment 5 ~ 10%; Wherein, A formulation material comprises weight percent: potassium felspar sand 20 ~ 25%, aluminum oxide 8 ~ 15%, Longyan particle 38 ~ 48%, quartz 20 ~ 25%, wilkinite 0 ~ 2%; B formulation material comprises weight percent: potassium felspar sand 34 ~ 39%, calcite 9 ~ 15%, zinc oxide 4 ~ 9%, kaolin 5 ~ 10%, quartz 25 ~ 30%, triphane 0 ~ 5%, talcum 0 ~ 2%, boron frit 0 ~ 2%.
Described glaze feed additives is malt sugar, glycerine or sucrose.
The present invention also provides the preparation method of color spray decorative ceramics under a kind of silicon zirconium hard glaze, and its method steps is:
S1: get A formula material, ball milling 18-22 hour, fineness be 325 mesh sieves tail over≤0.3%, the 180-200 order that sieves, for subsequent use;
S2: get B formula material, ball milling 20-26 hour, fineness be 325 mesh sieves tail over≤0.1%, 250 orders that sieve, for subsequent use;
S3: get the A formula 55 ~ 70% that S1 obtains, B formula 30 ~ 45%, moisture content 40 ~ 45%, glaze feed additives 0.3 ~ 1.2%, the pigment 5 ~ 10% that S2 obtains mixes, the color glaze that obtains preparing;
S4: by spray gun color spray on ceramic body or low temperature biscuiting base substrate for the color glaze preparing, adjust spray gun and compressed-air actuated pressure, the compressed air pressure of color spray is 0.4-0.45MPa, spray after lustful base substrate oven dry, soak glaze, after glazed body is dried, enter kiln oxidation and burn till 1280-1320 DEG C, insulation 20-30min, naturally cools to room temperature.
Compared with prior art, the present invention has following beneficial effect:
1. glaze feed additives adopts the additive of moisturizing class, as organic nontoxic safe raw materials such as malt sugar, glycerine, sucrose, adjust the physicals of color glaze, regulate the mutual matching problem between color glaze, cover-coat enamel, base substrate, improve the wetting property of colorant layer and cover-coat enamel, after color spray, when glazing, can not cause the glaze shrinkage freckle of goods, this class additive also has cohesive action simultaneously, improve the adhesive ability of colorant layer, while executing cover-coat enamel operation, avoid causing muddy stain, solved the defects such as the foaming in cover-coat enamel operation, quick-fried glaze, contracting glaze;
2. because chromonic layer is under glaze, reduced the stripping risk of Lead and cadmium and heavy metal ion, colorant layer, in sintering process, can not flow because of flowing of glaze layer, has greatly facilitated the requirement of decorating.
Embodiment
Below in conjunction with embodiment, the present invention is further illustrated.
Embodiment 1
The present embodiment discloses a kind of silicon zirconium hard glaze, comprises that weight percent is A formulation material 65%, B formulation material 35%, moisture 40%, malt sugar 1%, yellow material 8%; Wherein, A formulation material comprises weight percent: potassium felspar sand 20%, aluminum oxide 8%, Longyan particle 38%, quartz 22%, wilkinite 1%; B formulation material comprises weight percent: potassium felspar sand 34%, calcite 10%, zinc oxide 4%, kaolin 6%, quartz 26%, triphane 2%, talcum 1.5%, boron frit 0.5%.
Get A formula material, ball milling 18 hours, fineness is that 325 mesh sieves tail over 0.3%, 180 orders that sieve are for subsequent use; Get B formula material, ball milling 22 hours, fineness is that 325 mesh sieves tail over 0.05%, 250 orders that sieve are for subsequent use; Get A obtained above formula 65%, B formula 35%, moisture content 40%, malt sugar 1%, yellow material 8% and mix, the color glaze that obtains preparing; By spray gun color spray on ceramic body or low temperature biscuiting base substrate for the color glaze preparing, adjust spray gun and compressed-air actuated pressure, the compressed air pressure of color spray is 0.4MPa, spray gun air switch normal regulating, from the inside color spray of product edges, accomplish the effect of color gradient, spray after lustful base substrate oven dry, soak glaze, after glazed body is dried, enter kiln oxidation and burn till 1280 DEG C, insulation 25min, naturally cools to room temperature.
Product thermal-shock resistance prepared by the present embodiment reaches 180-20 DEG C of hydrothermal exchange and does not once split, glaze light, and colorant colour generation is full, and decorative effect is good, simple and unsophisticated, elegant, attractive in appearance.
Embodiment 2
The present embodiment discloses a kind of silicon zirconium hard glaze, comprises that weight percent is A formulation material 70%, B formulation material 30%, moisture content 42%, glycerine 0.3%, brown material 9%; Wherein, A formulation material comprises weight percent: potassium felspar sand 22%, aluminum oxide 10%, Longyan particle 45%, quartz 20%, wilkinite 0.5%; B formulation material comprises weight percent: potassium felspar sand 38%, calcite 12%, zinc oxide 5%, kaolin 8%, quartz 28%, triphane 5%, talcum 2%, boron frit 1%.
Get A formula material, ball milling 20 hours, fineness is that 325 mesh sieves tail over 0.2%, 200 orders that sieve are for subsequent use; Get B formula material, ball milling 26 hours, fineness is that 325 mesh sieves tail over 0.1%, 250 orders that sieve are for subsequent use; Get A obtained above formula 70%, B formula 30%, moisture content 42%, glycerine 0.3%, brown material 9% and mix, the color glaze that obtains preparing; By spray gun color spray on ceramic body or low temperature biscuiting base substrate for the color glaze preparing, adjust spray gun and compressed-air actuated pressure, the compressed air pressure of color spray is 0.4MPa, spray gun air switch normal regulating, from the inside color spray of product edges, accomplish the effect of color gradient, spray after lustful base substrate oven dry, soak glaze, after glazed body is dried, enter kiln oxidation and burn till 1280 DEG C, insulation 20min, naturally cools to room temperature.
Product thermal-shock resistance prepared by the present embodiment reaches 180-20 DEG C of hydrothermal exchange and does not once split, and produces once-firing qualification rate 85%, meets the processing requirement of the operations such as carrying operation.
Embodiment 3
The present embodiment discloses a kind of silicon zirconium hard glaze, comprises that weight percent is A formulation material 70%, B formulation material 30%, moisture content 45%, sucrose 1.2%, mixes colorant 9%; Wherein, A formulation material comprises weight percent: potassium felspar sand 25%, aluminum oxide 9%, Longyan particle 48%, quartz 24%, wilkinite 2%; B formulation material comprises weight percent: potassium felspar sand 39%, calcite 14%, zinc oxide 7%, kaolin 5%, quartz 27%, triphane 2%, talcum 1%, boron frit 1.5%.
Get A formula material, ball milling 22 hours, fineness is that 325 mesh sieves tail over 0.1%, 200 orders that sieve are for subsequent use; Get B formula material, ball milling 24 hours, fineness is that 325 mesh sieves tail over 0.08%, 250 orders that sieve are for subsequent use; Get A obtained above formula 70%, B formula 30%, moisture content 45%, sucrose 1.2%, mix colorant 9% and mix, the color glaze that obtains preparing; By spray gun color spray on ceramic body or low temperature biscuiting base substrate for the color glaze preparing, adjust spray gun and compressed-air actuated pressure, the compressed air pressure of color spray is 0.45MPa, spray after lustful base substrate oven dry, soak glaze, after glazed body is dried, enter kiln oxidation and burn till 1320 DEG C, insulation 30min, naturally cools to room temperature.
Product thermal-shock resistance prepared by the present embodiment reaches 180-20 DEG C of hydrothermal exchange and does not once split, and meets the requirement to hardness of glaze surface, has solved the defects such as the foaming in cover-coat enamel operation, quick-fried glaze, contracting glaze.
Claims (2)
1. a silicon zirconium hard glaze, is characterized in that, comprises that weight percent is A formulation material 55 ~ 70%, B formulation material 30 ~ 45%, moisture 40 ~ 45%, glaze feed additives 0.3 ~ 1.2%, pigment 5 ~ 10%; Wherein, A formulation material comprises weight percent: potassium felspar sand 20 ~ 25%, aluminum oxide 8 ~ 15%, Longyan particle 38 ~ 48%, quartz 20 ~ 25%, wilkinite 0 ~ 2%; B formulation material comprises weight percent: potassium felspar sand 34 ~ 39%, calcite 9 ~ 15%, zinc oxide 4 ~ 9%, kaolin 5 ~ 10%, quartz 25 ~ 30%, triphane 0 ~ 5%, talcum 0 ~ 2%, boron frit 0 ~ 2%; Described glaze feed additives is malt sugar, glycerine or sucrose.
2. a preparation method for color spray decorative ceramics under silicon zirconium hard glaze, is characterized in that, method steps is:
S1: get A formula material, ball milling 18-22 hour, fineness be 325 mesh sieves tail over≤0.3%, the 180-200 order that sieves, for subsequent use;
S2: get B formula material, ball milling 20-26 hour, fineness be 325 mesh sieves tail over≤0.1%, 250 orders that sieve, for subsequent use;
S3: get the A formula 55 ~ 70% that S1 obtains, B formula 30 ~ 45%, moisture content 40 ~ 45%, glaze feed additives 0.3 ~ 1.2%, the pigment 5 ~ 10% that S2 obtains mixes, the color glaze that obtains preparing;
S4: by spray gun color spray on ceramic body or low temperature biscuiting base substrate for the color glaze preparing, spray after lustful base substrate oven dry, soak glaze, after glazed body is dried, enter kiln oxidation and burn till 1280-1320 DEG C, insulation 20-30min, naturally cools to room temperature.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410262620.2A CN104030731B (en) | 2014-06-13 | 2014-06-13 | A kind of hard glaze and prepare the method for decorative ceramics with it |
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| CN201410262620.2A CN104030731B (en) | 2014-06-13 | 2014-06-13 | A kind of hard glaze and prepare the method for decorative ceramics with it |
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| CN104030731A true CN104030731A (en) | 2014-09-10 |
| CN104030731B CN104030731B (en) | 2016-03-09 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105502943A (en) * | 2015-12-25 | 2016-04-20 | 重庆鸽牌电瓷有限公司 | Electric porcelain brown glaze trademark glaze and preparation method thereof |
| CN110423142A (en) * | 2019-09-06 | 2019-11-08 | 济源市坤彤陶瓷科技开发有限公司 | A kind of silver figure glaze ceramic process |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005350327A (en) * | 2004-06-14 | 2005-12-22 | Inax Corp | Decorated ceramic body, its production method, and glaze preparation |
| CN101870593A (en) * | 2010-07-20 | 2010-10-27 | 唐山惠达陶瓷(集团)股份有限公司 | High-hardness self-cleaning glaze and preparation method thereof |
| CN102992813A (en) * | 2012-12-17 | 2013-03-27 | 四川科达节能技术有限公司 | High-temperature glaze coating, preparation method thereof, binder and using method of coating |
-
2014
- 2014-06-13 CN CN201410262620.2A patent/CN104030731B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005350327A (en) * | 2004-06-14 | 2005-12-22 | Inax Corp | Decorated ceramic body, its production method, and glaze preparation |
| CN101870593A (en) * | 2010-07-20 | 2010-10-27 | 唐山惠达陶瓷(集团)股份有限公司 | High-hardness self-cleaning glaze and preparation method thereof |
| CN102992813A (en) * | 2012-12-17 | 2013-03-27 | 四川科达节能技术有限公司 | High-temperature glaze coating, preparation method thereof, binder and using method of coating |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105502943A (en) * | 2015-12-25 | 2016-04-20 | 重庆鸽牌电瓷有限公司 | Electric porcelain brown glaze trademark glaze and preparation method thereof |
| CN110423142A (en) * | 2019-09-06 | 2019-11-08 | 济源市坤彤陶瓷科技开发有限公司 | A kind of silver figure glaze ceramic process |
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| CN104030731B (en) | 2016-03-09 |
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Denomination of invention: A hard glaze and a method for preparing decorative ceramics using it Effective date of registration: 20231214 Granted publication date: 20160309 Pledgee: China Co. truction Bank Corp Chaozhou branch Pledgor: Guangdong Songfa Ceramics Co.,Ltd. Registration number: Y2023980071819 |
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