CN104018638A - Granite veneer stone and manufacturing method thereof - Google Patents
Granite veneer stone and manufacturing method thereof Download PDFInfo
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- CN104018638A CN104018638A CN201410286951.XA CN201410286951A CN104018638A CN 104018638 A CN104018638 A CN 104018638A CN 201410286951 A CN201410286951 A CN 201410286951A CN 104018638 A CN104018638 A CN 104018638A
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Abstract
The invention discloses a granite veneer stone and a preparation method thereof. The granite veneer stone is characterized in that a protective layer is a nano fluorocarbon paint; a color grain granite coating consists of particles and a continuous phase emulsion; each particle consists of a GTS colloidal solution and a colorful base paint; the preparation method comprises the following steps: firstly coating a seal primer on a base material, then coating the color grain granite coating on the seal primer, then coating the nano fluorocarbon paint on the seal primer again, and drying to form a granite veneer stone finished product.
Description
Technical field
The present invention relates to man-made stone field, more particularly, it relates to a kind of granite facing stone and preparation method thereof.
Background technology
At present, building wall, when carrying out granite decoration, or adopts natural granite stone material directly to stick on building wall surface, or adopts multicolor finish to be sprayed on composite sheet material, then composite sheet material is pasted to the surface at building.
While adopting lithotome to decorate, because lithotome is heavier, make transportation and construction very difficult, and the exploitation of lithotome is unfavorable for to the protection of ecology and environment; While adopting multicolor finish to be sprayed on composite sheet material, such facing stone style is unstable, and feel is poor, and because coating is exposed in external environment condition, through wet by the rain and burnt by the sun, very easily causes coating to fade, and the color duration is too short.
Summary of the invention
The deficiency existing for prior art, the object of the present invention is to provide a kind of granite facing stone, and it is light that this granite facing stone has material, transportation, easy construction, and style is stable, the feature that feel is smooth, moist.
For achieving the above object, the invention provides following technical scheme: a kind of granite facing stone, comprise base material, be coated in the elastic coating on base material, the coloured middle level of roller coat on elastic coating, the effect layer that lathe work flower hilllock spray painting is formed on coloured middle level, and be coated in the topping on effect layer, it is characterized in that, described topping is nano-fluorine carbon paint; Described lathe work flower hilllock coating is comprised of particle and continuous phase emulsion; Described particle is comprised of GTS colloidal solution and colorful base paint; Wherein,
The deionized water that described colorful base paint is 42%～45% by mass fraction, 0.6% dispersing agent, 0.1% wetting agent, 0.2～0.4% defoamer, 0.8% inorganic mineral gel, 0～2% rutile titanium white powder, 10～18% 4000 order kaolin, 0.7% cellulose, 0.2～0.3% AMP-95,0.6% coalescents, 0.4% propane diols, 26～38% organosilicon-modified acrylic elastic emulsion, 15% protection glue, and 0.1～0.8% form to come ash;
The deionized water that described GTS colloidal solution is 93.5% by mass fraction, and 6.5% GTS powder constituent;
The organic-silicon-modified synthetic emulsion that described continuous phase emulsion is 75% by mass fraction, 3.9% coalescents Texanol, 3.3% propane diols, 0.6% anticorrisive agent and 17.2% deionized water form.
The present invention is further set to, the deionized water that described colorful base paint is 40% by mass fraction, 0.6% dispersing agent; 0.1% wetting agent,, 0.2% defoamer; 0.8% inorganic mineral gel, 2% rutile titanium white powder, 10% 4000 order kaolin; 0.7% cellulose, 0.2% AMP-95,0.6% coalescents Texanol; 0.4% propane diols; 29% organosilicon-modified acrylic elastic emulsion, 15% protection glue, and 0.4% form to come ash.
By adopting technique scheme, by inorganic mineral gel, kaolin, rutile titanium white powder is the inorganic main body of artificial granite, made granite facing stone effect is true to nature, by organosilicon-modified acrylic elastic emulsion, it is main filmogen, add again the lathe work that other auxiliary agents are made to spend the effect layer of hilllock coating formation to there is feel exquisiteness, smooth, the feature that hot strength is large, and the same base material of this effect layer, elastic coating, coloured middle level and topping are the same, all organic by lightweight, inorganic material is made, compare the feature that lithotome has light weight, thereby easily transportation, construction, on effect layer, apply the topping that one deck consists of nano-fluorine carbon paint, can effectively protect effect layer not to be subject to external interference, the for example impact of ultraviolet ray and acid rain, make style shape, and the color of coating is very stable, be difficult for destroyed.
The present invention is further set to, and comprises the following steps:
(1) to take the base material that polyester fiber is main material, carry out smooth, dry processing, use high-quality cracking resistance seal coat comprehensively evenly brushing in the one side of base material, and standing and drying;
(2), after the seal coat of high-quality cracking resistance described in (1) bone dry, at its surface roller coating elastic coating, this elastic coating be take polymeric acrylic acid elastic emulsion and is made as film forming matter;
(3), after elastic coating bone dry described in (2), on its surface, evenly roller coat coloured silk is joined priming paint together, forms coloured middle level;
(4), after the bone dry of coloured middle level described in (3), at its colour grain painted colored hilllock of surperficial continuous uniform coating, form effect layer;
(5), after effect layer bone dry described in (4), at its surface spraying nano-fluorine carbon paint, form topping.
By adopting technique scheme, using polyester fiber as base material, can strengthen the hot strength of granite facing stone, at base material, simultaneously coat the effect that high-quality cracking resistance seal coat plays water-fast, acid and alkali-resistance, mildew resistant moistureproof; The elastic coating that the polymeric acrylic acid elastic emulsion of take is made as film forming matter can play and strengthen feel, the effect of compensation temperature variation to the stress of granite facing stone generation; On elastic coating, roller coat coloured silk is joined the color effect that priming paint can strengthen granite facing stone; The effect layer surface spraying nano-fluorine carbon paint forming at lathe work flower hilllock coating, as topping, can effectively protect effect layer not to be subject to external interference, makes its style shape, style color prolonged constant.
The present invention is further set to, and described lathe work flower hilllock coating, after the first pass spraying of surface, coloured middle level and bone dry, sprays second time again.
The present invention is further set to, and the consumption of described high-quality cracking resistance seal coat is 0.1～0.15kg/m
2; The thickness of described elastic coating is 1.2mm; The thickness in described coloured middle level is 0.15mm; The thickness of described effect layer is 0.2mm; The thickness of described topping is 0.1mm.。
By adopting technique scheme; the colour grain painted colored hilllock coating of twice can be in order to be effective layer feel fine and smooth; outward appearance is true to nature; not only effect is true to nature by above-mentioned thickness, produced granite facing stone to be set; and thickness is very thin; in protection effect layer, representing of impact effect layer outward appearance not again.
The present invention is further set to, and comprises the following steps:
(1) preparation of GTS colloidal solution: GTS powder is slowly added in deionized water, and the speed Centrifugal dispersion 30min with 1500r/min, obtains GTS colloidal solution;
(2) preparation of colorful base paint: by deionized water, dispersing agent, wetting agent, defoamer, and inorganic mineral gel adds in dispersion tank the speed Centrifugal dispersion 1-2min with 300-400r/min successively, add successively subsequently rutile titanium white powder, 4000 order kaolin are with cellulose, keep rotating speed to continue Centrifugal dispersion 5-10min, then add AMP-95, and slowly rotating speed is increased to 1000-1500r/min in reinforced process, continue to disperse 30min, finally add successively coalescents Texanol, propane diols, organosilicon-modified acrylic elastic emulsion, protection glue, and to come ash, keep current rotating speed 5min, obtain colorful base paint,
(3) preparation of continuous phase emulsion: organic-silicon-modified synthetic emulsion is added in dispersion tank to the speed Centrifugal dispersion 5min with 300-500r/min, subsequently by the coalescents Texanol being pre-mixed, propane diols, anticorrisive agent and deionized water add in dispersion tank, keep current rotating speed 5min, obtain continuous phase emulsion;
(4) granulation: the colorful base paint in (2) is joined in the GTS colloidal solution in (1), select as required the screen cloth of different pore size to carry out granulation, obtain particle;
(5) lathe work flower hilllock coating finished product: the continuous phase emulsion in (3) is joined in the particle in (4), after fully mixing, obtain finished product lathe work flower hilllock coating.
By adopting technique scheme, first by deionized water, dispersing agent, wetting agent G-396, defoamer, and inorganic mineral gel adds in dispersion tank the speed Centrifugal dispersion 1-2min with 300-400r/min successively, can in advance the inorganic mineral gel of colloidal be scatter in advance, to avoid caking, then add rutile titanium white powder, 4000 order kaolin are with cellulose, after Centrifugal dispersion, become the artificial granite main body of homogeneous phase, cellulose has strengthened the intensity of inorganic artificial granite main body, adding organosilicon-modified acrylic elastic emulsion is main filmogen again, and other auxiliary agents, make the colorful base paint forming that high intensity and toughness can be provided after moulding, after colorful base paint is mixed with GTS colloid, according to client's requirement, carry out granulation, form like this ability that particle just has very strong artificial granite, and light weight, intensity is high, after the particle of making is mixed with continuous phase emulsion, obtain the lathe work flower hilllock coating of mobility, so just can be by spray gun special, lathe work flower hilllock spray painting is surperficial in coloured middle level.
The present invention is further set to: in the preparation process of GTS colloidal solution, temperature is controlled at 30-40 ℃.
The present invention is further set to: in the preparation process of colorful base paint, temperature is 25 ℃, and relative humidity is 40%-60%.
The present invention is further set to: by adding thickener, the viscosity of described colorful base paint can be controlled in 100-120KU.
The present invention is further set to: in the coating finished product step of lathe work flower hilllock, temperature is 25 ℃, and relative humidity is 40%-60%, and incorporation time is within 1-5h.
By adopting technique scheme, temperature is controlled at 30-40 ℃, and GTS colloidal solution has best mixed performance like this, can too stickyly not cause caking, also can not lose viscosity; In the preparation of colorful base paint, by 25 ℃ of temperature control bits, relative humidity is 40%-60%, and its viscosity of colorful base paint of producing is like this 90KU, meets the demand in most of market on the market; By adding thickener, the viscosity that improves colorful base paint can increase granulation particle size out, thereby meets the demand of particular client; In the step of lathe work flower hilllock coating finished product, temperature is 25 ℃, and relative humidity is 40%-60%, and incorporation time is within 1-5h, thereby the lathe work of producing flower hilllock paint viscosity is 4000-9000mpa.s, is also modal use viscosity scope on market.
The specific embodiment
Understanding for the ease of those skilled in the art, is described in further detail the present invention below in conjunction with specific embodiment.
A kind of granite facing stone, comprise base material, be coated in the elastic coating on base material, the coloured middle level of roller coat on elastic coating, the effect layer that lathe work flower hilllock spray painting is formed on coloured middle level, and be coated in the topping on effect layer, and it is characterized in that, described topping is nano-fluorine carbon paint; Described lathe work flower hilllock coating comprises particle and continuous phase emulsion; Described particle comprises GTS colloidal solution and colorful base paint; Wherein,
The deionized water that described colorful base paint is 42%～45% by mass fraction, 0.6% dispersing agent, 0.1% wetting agent, 0.2～0.4% defoamer, 0.8% inorganic mineral gel, 0～2% rutile titanium white powder, 10～18% 4000 order kaolin, 0.7% cellulose, 0.2～0.3% AMP-95,0.6% coalescents, 0.4% propane diols, 26～38% organosilicon-modified acrylic elastic emulsion, 15% protection glue, and 0.1～0.8% form to come ash;
The deionized water that described GTS colloidal solution is 93.5% by mass fraction, and 6.5% GTS powder constituent;
The organic-silicon-modified synthetic emulsion that described continuous phase emulsion is 75% by mass fraction, 3.9% coalescents Texanol, 3.3% propane diols, the FE-15 anticorrisive agent of 0.6 % and 17.2% deionized water form.
The classes of agents of using, the model of raw material and the detailed proportioning of consumption:
Table 1, GTS colloidal solution proportioning.
Table 2, colorful base paint proportioning.
Table 3, continuous phase emulsion.
Table 4, nano-fluorine carbon paint proportioning.
Embodiment 1:
The preparation process of lathe work flower hilllock coating:
(1) preparation of GTS colloidal solution: GTS powder is slowly added in deionized water, and the speed Centrifugal dispersion 30min with 1500r/min, obtains GTS colloidal solution, and wherein GTS powder quality percentage is 93.5%, and the mass percent of deionized water is 6.5%;
(2) preparation of colorful base paint: the deionized water that is 40% by the mass percent that accounts for overall colorful base paint, 0.6% dispersing agent 120V, 0.1% wetting agent G-396, 0.2% defoamer G-298, and 0.8% inorganic mineral gel adds in dispersion tank the speed Centrifugal dispersion 1min with 300r/min successively, add successively subsequently 10% 4000 order kaolin with 0.7% cellulose HS-30000, keep rotating speed to continue Centrifugal dispersion 5min, then add 0.2% AMP-95, and slowly rotating speed is increased to 1000r/min in reinforced process, continue to disperse 30min, last 0.6% the coalescents Texanol of adding successively, 0.4% propane diols, 31.3% organosilicon-modified acrylic elastic emulsion, 15% protection glue, and 0.1% to come ash G399, keep current rotating speed 5min, obtain colorful base paint,
(3) preparation of continuous phase emulsion: add in dispersion tank the speed Centrifugal dispersion 5min with 300r/min by accounting for organic-silicon-modified synthetic emulsion that whole continuous phase quality of the emulsion percentage is 75%, subsequently by 3.9% the coalescents Texanol being pre-mixed, 3.3% propane diols, 0.6% FE-15 anticorrisive agent and 17.2% deionized water add in dispersion tank, keep current rotating speed 5min, obtain continuous phase emulsion;
(4) granulation: the colorful base paint in (2) is joined in the GTS colloidal solution in (1), the quality proportioning of colorful base paint and GTS colloidal solution is 2:3, select as required the screen cloth of different pore size to carry out granulation, such as 35 eye mesh screens, obtain the particle that particle diameter is 500 μ m;
(5) lathe work flower hilllock coating finished product: the continuous phase emulsion in (3) is joined in the particle in (4), and the quality proportioning of continuous phase emulsion and particle is 2:3, fully mixes after 1 hour, obtains finished product lathe work flower hilllock coating.
The preparation process of granite facing stone:
(1) to take, the base material that polyester fiber is main material fully cleans, smooth, dry processing, when clean, use the cleaning agent of PH=8, keep environment temperature: T=5 ℃, then use high-quality cracking resistance seal coat evenly to brush the one side at base material comprehensively, and standing and drying, the consumption of high-quality cracking resistance seal coat is 0.1kg/m
2;
(2) after the seal coat of high-quality cracking resistance described in (1) bone dry, at its surface roller coating elastic coating, this elastic coating be take polymeric acrylic acid elastic emulsion and is made as film forming matter, and this elastic coating thickness is 1.2mm;
(3) after elastic coating bone dry described in (2), on its surface, evenly roller coat coloured silk is joined priming paint together, forms coloured middle level, and the thickness in coloured middle level is 0.15mm;
(4) after the bone dry of coloured middle level described in (3), at its colour grain painted colored hilllock of surperficial continuous uniform coating, after spraying first pass, standing and drying, then sprays second time, forms effect layer, and the thickness of this effect layer is 0.2mm;
(5) after effect layer bone dry described in (4); at its surface spraying nano-fluorine carbon paint; its proportioning is: 35% dimethylbenzene; 10% butyl acetate, 0.3% Disponer 904s(Ricinate), 0.3% Levaslip 432(silicone levelling agent); 0.4% defoamer 635; and the nano combined fluorocarbon resin of 54% solvent-borne type, forming topping, the thickness of this topping is 0.1mm.
Here, in granite facing stone preparation process, high-quality cracking resistance seal coat that step (1) is used adopts the seal coat of autonomous production, has acid and alkali-resistance, water-fast, moisture resistance feature.
Table 5 is each component and preparation process and the condition of embodiment 1 lathe work flower hilllock coating.
Table 6 is preparation process and the condition of embodiment 1 granite facing stone.
Embodiment 2:
Table 7 is each component and preparation process and the condition of embodiment 2 lathe work flower hilllock coating.
Table 8 is preparation process and the condition of embodiment 1 granite facing stone.
Embodiment 3:
Table 9 is each component and preparation process and the condition of embodiment 3 lathe work flower hilllock coating.
Table 10 is preparation process and the condition of embodiment 3 granite facing stones.
Claims (10)
1. a granite facing stone, comprise base material, be coated in the elastic coating on base material, the coloured middle level of roller coat on elastic coating, the effect layer that lathe work flower hilllock spray painting is formed on coloured middle level, and be coated in the topping on effect layer, and it is characterized in that, described topping is nano-fluorine carbon paint; Described lathe work flower hilllock coating is comprised of particle and continuous phase emulsion; Described particle is comprised of GTS colloidal solution and colorful base paint; Wherein,
The deionized water that described colorful base paint is 42%～45% by mass fraction, 0.6% dispersing agent, 0.1% wetting agent, 0.2～0.4% defoamer, 0.8% inorganic mineral gel, 0～2% rutile titanium white powder, 10～18% 4000 order kaolin, 0.7% cellulose, 0.2～0.3% AMP-95,0.6% coalescents, 0.4% propane diols, 26～38% organosilicon-modified acrylic elastic emulsion, 15% protection glue, and 0.1～0.8% form to come ash;
The deionized water that described GTS colloidal solution is 93.5% by mass fraction, and 6.5% GTS powder constituent;
The organic-silicon-modified synthetic emulsion that described continuous phase emulsion is 75% by mass fraction, 3.9% coalescents Texanol, 3.3% propane diols, 0.6% anticorrisive agent and 17.2% deionized water form.
2. granite facing stone according to claim 1; it is characterized in that; the deionized water that described colorful base paint is 40% by mass fraction; 0.6% dispersing agent; 0.1% wetting agent,, 0.2% defoamer; 0.8% inorganic mineral gel; 2% rutile titanium white powder, 10% 4000 order kaolin, 0.7% cellulose; 0.2% AMP-95; 0.6% coalescents Texanol, 0.4% propane diols, 29% organosilicon-modified acrylic elastic emulsion; 15% protection glue, and 0.4% form to come ash.
3. a preparation method for granite facing stone, prepares described granite facing stone as claimed in claim 1, it is characterized in that comprising the following steps:
To take the base material that polyester fiber is main material, carry out smooth, dry processing, use high-quality cracking resistance seal coat comprehensively evenly brushing in the one side of base material, and standing and drying;
After the seal coat of high-quality cracking resistance described in (1) bone dry, at its surface roller coating elastic coating, this elastic coating be take polymeric acrylic acid elastic emulsion and is made as film forming matter;
After elastic coating bone dry described in (2), on its surface, evenly roller coat coloured silk is joined priming paint together, forms coloured middle level;
After the bone dry of coloured middle level described in (3), at its colour grain painted colored hilllock of surperficial continuous uniform coating, form effect layer;
After effect layer bone dry described in (4), at its surface spraying nano-fluorine carbon paint, form topping.
4. granite facing stone preparation method according to claim 3, is characterized in that, described lathe work flower hilllock coating, after the first pass spraying of surface, coloured middle level and bone dry, sprays second time again.
5. granite facing stone preparation method according to claim 4, is characterized in that, the consumption of described high-quality cracking resistance seal coat is 0.1～0.15kg/m
2; The thickness of described elastic coating is 1.2mm; The thickness in described coloured middle level is 0.15mm; The thickness of described effect layer is 0.2mm.
6. granite facing stone preparation method according to claim 3, is characterized in that, the preparation method of described lathe work flower hilllock coating comprises the following steps:
The preparation of GTS colloidal solution: GTS powder is slowly added in deionized water, and the speed Centrifugal dispersion 30min with 1500r/min, obtains GTS colloidal solution;
The preparation of colorful base paint: by deionized water, dispersing agent, wetting agent, defoamer, and inorganic mineral gel adds in dispersion tank the speed Centrifugal dispersion 1-2min with 300-400r/min successively, add successively subsequently rutile titanium white powder, 4000 order kaolin are with cellulose, keep rotating speed to continue Centrifugal dispersion 5-10min, then add AMP-95, and slowly rotating speed is increased to 1000-1500r/min in reinforced process, continue to disperse 30min, finally add successively coalescents Texanol, propane diols, organosilicon-modified acrylic elastic emulsion, protection glue, and to come ash, keep current rotating speed 5min, obtain colorful base paint,
The preparation of continuous phase emulsion: organic-silicon-modified synthetic emulsion is added in dispersion tank to the speed Centrifugal dispersion 5min with 300-500r/min, subsequently by the coalescents Texanol being pre-mixed, propane diols, anticorrisive agent and deionized water add in dispersion tank, keep current rotating speed 5min, obtain continuous phase emulsion;
Granulation: the colorful base paint in (2) is joined in the GTS colloidal solution in (1), select as required the screen cloth of different pore size to carry out granulation, obtain particle;
Lathe work flower hilllock coating finished product: the continuous phase emulsion in (3) is joined in the particle in (4), after fully mixing, obtain finished product lathe work flower hilllock coating.
7. granite facing stone preparation method according to claim 6, is characterized in that, in the preparation process of GTS colloidal solution, temperature is controlled at 30-40 ℃.
8. granite facing stone preparation method according to claim 6, is characterized in that, in the preparation process of colorful base paint, temperature is 25 ℃, and relative humidity is 40%-60%.
9. granite facing stone preparation method according to claim 8, is characterized in that, by adding thickener, the viscosity of described colorful base paint can be controlled in 100-120KU.
10. granite facing stone preparation method according to claim 6, is characterized in that, in the coating finished product step of lathe work flower hilllock, temperature is 25 ℃, and relative humidity is 40%-60%, and incorporation time is within 1-5h.
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