CN104017411A - Paint flame retardant for wood furniture - Google Patents
Paint flame retardant for wood furniture Download PDFInfo
- Publication number
- CN104017411A CN104017411A CN201410300118.6A CN201410300118A CN104017411A CN 104017411 A CN104017411 A CN 104017411A CN 201410300118 A CN201410300118 A CN 201410300118A CN 104017411 A CN104017411 A CN 104017411A
- Authority
- CN
- China
- Prior art keywords
- paint
- wood furniture
- flame retardant
- retardant
- furniture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003063 flame retardant Substances 0.000 title claims abstract description 32
- 239000002023 wood Substances 0.000 title claims abstract description 28
- 239000003973 paint Substances 0.000 title abstract description 17
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract description 11
- KJRCEJOSASVSRA-UHFFFAOYSA-N propane-2-thiol Chemical compound CC(C)S KJRCEJOSASVSRA-UHFFFAOYSA-N 0.000 claims abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 5
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 30
- MPNXSZJPSVBLHP-UHFFFAOYSA-N 2-chloro-n-phenylpyridine-3-carboxamide Chemical compound ClC1=NC=CC=C1C(=O)NC1=CC=CC=C1 MPNXSZJPSVBLHP-UHFFFAOYSA-N 0.000 claims description 12
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 claims description 12
- -1 dimethyl butyrate Chemical compound 0.000 claims description 12
- RIFGWPKJUGCATF-UHFFFAOYSA-N ethyl chloroformate Chemical compound CCOC(Cl)=O RIFGWPKJUGCATF-UHFFFAOYSA-N 0.000 claims description 12
- 229910052760 oxygen Inorganic materials 0.000 claims description 12
- 239000001301 oxygen Substances 0.000 claims description 12
- MBGGBVCUIVRRBF-UHFFFAOYSA-N sulfinpyrazone Chemical compound O=C1N(C=2C=CC=CC=2)N(C=2C=CC=CC=2)C(=O)C1CCS(=O)C1=CC=CC=C1 MBGGBVCUIVRRBF-UHFFFAOYSA-N 0.000 claims description 11
- 235000019439 ethyl acetate Nutrition 0.000 claims description 10
- 229960003329 sulfinpyrazone Drugs 0.000 claims description 10
- 230000000694 effects Effects 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 abstract description 2
- SNPLKNRPJHDVJA-ZETCQYMHSA-N D-panthenol Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCCO SNPLKNRPJHDVJA-ZETCQYMHSA-N 0.000 abstract description 2
- HCBIBCJNVBAKAB-UHFFFAOYSA-N Procaine hydrochloride Chemical compound Cl.CCN(CC)CCOC(=O)C1=CC=C(N)C=C1 HCBIBCJNVBAKAB-UHFFFAOYSA-N 0.000 abstract description 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 abstract description 2
- 230000003993 interaction Effects 0.000 abstract description 2
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 abstract 1
- 238000010304 firing Methods 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 7
- 230000006378 damage Effects 0.000 description 4
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
Abstract
The invention relates to a paint flame retardant for wood furniture and belongs to the technical field of flame-retardant articles. The paint flame retardant is prepared from the following raw materials: water, endo-1,7,7-trimethylbicyclo[2.2.1]heptane-2-olacetate, isopropyl mercaptan, (R)-(+)-2,4-dihydroxy-N-(3--hydroxypropyl)-3,3-dimethylbutyramide, 2-isopropyl-5-methyl-cyclohexanol, 1-(4-fluorophenyl)-4-[4-(4-chlorophenyl)-4-hydroxy-1-piperidinyl]-1-butanone, p-aminobenzoic-2-diethylamino-ethyl ester hydrochloride and the like. According to the paint flame retardant for wood furniture, by virtue of the interactions between the relevant chemical components and in combination with the use of paint wooden furniture, the paint flame retardant can be used for effectively preventing wooden furniture from firing and the spread of fire and has an excellent flame-retardant effect and unnecessary life casualties and property losses are reduced for the public.
Description
Technical field
The present invention relates to a kind of wood furniture and paint fire retardant, belong to fire-retardant articles for use technical field.
background technology
In various disasters, fire is the most often, threaten the most at large one of major casualty of public security and social development.And the indispensable wood materials articles for use such as furniture that exist in buildings, once presence of fire, the inflammableness itself having will be impelled fire rapid spread, bring great lives and properties harm to the public.
Summary of the invention
The object of the invention is to solve wood furniture that above-mentioned prior art exists paint cannot be fire-retardant deficiency, provide a kind of wood furniture of good flame retardation effect to paint fire retardant.
Wood furniture is painted fire retardant, special character is to be prepared from by the raw material of following weight part proportioning: 75 parts, water, interior type-1, 7, 7-trimethylammonium two encircles [2.2.1] heptane-2-alcohol acetic ester 28-32 part, isopropyl mercaptan 15-18 part, (R)-(+)-2, 4-dihydroxyl-N-(3-hydroxypropyl)-3, 3-amide dimethyl butyrate 22-25 part, 2-sec.-propyl-5-methyl-cyclohexanol 20-22 part, 1-(4-fluorophenyl)-4-[4-(4-chloro-phenyl-)-4-hydroxyl-piperidino]-1-butanone 10-12 part, para-amino benzoic acid-2-diethylin carbethoxy hydrochloride 8-10 part, (2-carbamyl oxygen ethyl) trimethyl ammonium chloride 4-6 part, sulfinpyrazone 1-2 part.
Preparation method of the present invention: add pure water, add while stirring interior type-1,7,7-trimethylammonium two encircles [2.2.1] heptane-2-alcohol acetic ester, isopropyl mercaptan, continues to be stirred to and is uniformly dispersed, and is then heated to 55-65 DEG C; Slowly add (R)-(+)-2,4-dihydroxyl-N-(3-hydroxypropyl)-3,3-amide dimethyl butyrate, stirs and makes it to dissolve; After add successively 2-sec.-propyl-5-methyl-cyclohexanol, 1-(4-fluorophenyl)-4-[4-(4-chloro-phenyl-)-4-hydroxyl-piperidino]-1-butanone, para-amino benzoic acid-2-diethylin carbethoxy hydrochloride, (2-carbamyl oxygen ethyl) trimethyl ammonium chloride, sulfinpyrazone, stir; Be cooled to 30-35 DEG C, stir and leave standstill 20 minutes, obtain this wood furniture and paint fire retardant.
This wood furniture is painted fire retardant, utilize interaction between related chemical constituents, influence each other, the use that coordinates wood furniture to paint, effectively prevent the on fire of wood furniture, stop fire spread to expand, there is splendid flame retardant effect, for the public reduces unnecessary life casualty and property damage.
Embodiment
Below provide the specific embodiment of the present invention, be used for the present invention to be further described.In the present invention, if no special instructions, each raw material is all taking working substance content as 100%.
In following examples and comparative example, raw material introduction:
Interior type-1,7,7-trimethylammonium two encircles [2.2.1] heptane-2-alcohol acetic ester, and CAS accession number is: 76-49-3;
Isopropyl mercaptan, CAS accession number is: 75-33-2;
(R)-(+)-2,4-dihydroxyl-N-(3-hydroxypropyl)-3,3-amide dimethyl butyrate, CAS accession number is: 81-13-0;
2-sec.-propyl-5-methyl-cyclohexanol, CAS accession number is: 89-78-1;
1-(4-fluorophenyl)-4-[4-(4-chloro-phenyl-)-4-hydroxyl-piperidino]-1-butanone, CAS accession number is: 52-86-8;
Para-amino benzoic acid-2-diethylin carbethoxy hydrochloride, CAS accession number is: 51-05-8;
(2-carbamyl oxygen ethyl) trimethyl ammonium chloride, CAS accession number is: 51-83-2;
Sulfinpyrazone, CAS accession number is: 57-96-5.
Embodiment 1
Weigh: water 75kg, interior type-1,7,7-trimethylammonium two encircles [2.2.1] heptane-2-alcohol acetic ester 30kg, isopropyl mercaptan 18kg, (R)-(+)-2,4-dihydroxyl-N-(3-hydroxypropyl)-3,3-amide dimethyl butyrate 22kg, 2-sec.-propyl-5-methyl-cyclohexanol 22kg, 1-(4-fluorophenyl)-4-[4-(4-chloro-phenyl-)-4-hydroxyl-piperidino]-1-butanone 12kg, para-amino benzoic acid-2-diethylin carbethoxy hydrochloride 9kg, (2-carbamyl oxygen ethyl) trimethyl ammonium chloride 4kg, sulfinpyrazone 2kg.
The present embodiment wood furniture is painted the preparation method of fire retardant: add pure water, add while stirring interior type-1,7,7-trimethylammonium two encircles [2.2.1] heptane-2-alcohol acetic ester, isopropyl mercaptan, continues to be stirred to be uniformly dispersed, and is then heated to 55-65 DEG C; Slowly add (R)-(+)-2,4-dihydroxyl-N-(3-hydroxypropyl)-3,3-amide dimethyl butyrate, stirs and makes it to dissolve; After add successively 2-sec.-propyl-5-methyl-cyclohexanol, 1-(4-fluorophenyl)-4-[4-(4-chloro-phenyl-)-4-hydroxyl-piperidino]-1-butanone, para-amino benzoic acid-2-diethylin carbethoxy hydrochloride, (2-carbamyl oxygen ethyl) trimethyl ammonium chloride, sulfinpyrazone, stir; Be cooled to 30-35 DEG C, stir and leave standstill 20 minutes, obtain this wood furniture and paint fire retardant.
Embodiment 2
Weigh: water 75kg, interior type-1,7,7-trimethylammonium two encircles [2.2.1] heptane-2-alcohol acetic ester 32kg, isopropyl mercaptan 17kg, (R)-(+)-2,4-dihydroxyl-N-(3-hydroxypropyl)-3,3-amide dimethyl butyrate 25kg, 2-sec.-propyl-5-methyl-cyclohexanol 21kg, 1-(4-fluorophenyl)-4-[4-(4-chloro-phenyl-)-4-hydroxyl-piperidino]-1-butanone 10kg, para-amino benzoic acid-2-diethylin carbethoxy hydrochloride 10kg, (2-carbamyl oxygen ethyl) trimethyl ammonium chloride 6kg, sulfinpyrazone 1.5kg.
The present embodiment wood furniture is painted the preparation method of fire retardant with embodiment 1.
Embodiment 3
Weigh: water 75kg, interior type-1,7,7-trimethylammonium two encircles [2.2.1] heptane-2-alcohol acetic ester 28kg, isopropyl mercaptan 15kg, (R)-(+)-2,4-dihydroxyl-N-(3-hydroxypropyl)-3,3-amide dimethyl butyrate 23kg, 2-sec.-propyl-5-methyl-cyclohexanol 20kg, 1-(4-fluorophenyl)-4-[4-(4-chloro-phenyl-)-4-hydroxyl-piperidino]-1-butanone 11kg, para-amino benzoic acid-2-diethylin carbethoxy hydrochloride 8kg, (2-carbamyl oxygen ethyl) trimethyl ammonium chloride 5kg, sulfinpyrazone 1kg.
The present embodiment wood furniture is painted the preparation method of fire retardant with embodiment 1.
Comparative example 1
Weigh: water 75kg, interior type-1,7,7-trimethylammonium two encircles [2.2.1] heptane-2-alcohol acetic ester 30kg, isopropyl mercaptan 18kg, (R)-(+)-2,4-dihydroxyl-N-(3-hydroxypropyl)-3,3-amide dimethyl butyrate 22kg, 2-sec.-propyl-5-methyl-cyclohexanol 22kg, para-amino benzoic acid-2-diethylin carbethoxy hydrochloride 9kg, (2-carbamyl oxygen ethyl) trimethyl ammonium chloride 4kg.
This comparative example wood furniture is painted the preparation method of fire retardant: add pure water, add while stirring interior type-1,7,7-trimethylammonium two encircles [2.2.1] heptane-2-alcohol acetic ester, isopropyl mercaptan, continues to be stirred to be uniformly dispersed, and is then heated to 55-65 DEG C; Slowly add (R)-(+)-2,4-dihydroxyl-N-(3-hydroxypropyl)-3,3-amide dimethyl butyrate, stirs and makes it to dissolve; After add successively 2-sec.-propyl-5-methyl-cyclohexanol, para-amino benzoic acid-2-diethylin carbethoxy hydrochloride, (2-carbamyl oxygen ethyl) trimethyl ammonium chloride, stir; Be cooled to 30-35 DEG C, stir and leave standstill 20 minutes, obtain this wood furniture and paint fire retardant.
Comparative example 2
Weigh: water 75kg, (R)-(+)-2,4-dihydroxyl-N-(3-hydroxypropyl)-3,3-amide dimethyl butyrate 22kg, 2-sec.-propyl-5-methyl-cyclohexanol 22kg, 1-(4-fluorophenyl)-4-[4-(4-chloro-phenyl-)-4-hydroxyl-piperidino]-1-butanone 12kg, para-amino benzoic acid-2-diethylin carbethoxy hydrochloride 9kg, (2-carbamyl oxygen ethyl) trimethyl ammonium chloride 4kg, sulfinpyrazone 2kg.
This comparative example wood furniture is painted the preparation method of fire retardant: add pure water, be heated to 55-65 DEG C; Slowly add (R)-(+)-2,4-dihydroxyl-N-(3-hydroxypropyl)-3,3-amide dimethyl butyrate, stirs and makes it to dissolve; After add successively 2-sec.-propyl-5-methyl-cyclohexanol, 1-(4-fluorophenyl)-4-[4-(4-chloro-phenyl-)-4-hydroxyl-piperidino]-1-butanone, para-amino benzoic acid-2-diethylin carbethoxy hydrochloride, (2-carbamyl oxygen ethyl) trimethyl ammonium chloride, sulfinpyrazone, stir; Be cooled to 30-35 DEG C, stir and leave standstill 20 minutes, obtain this wood furniture and paint fire retardant.
Test case
Embodiment and comparative example are tested, and concrete data are in table 1.
Wood furniture is painted the flame retardant properties test chart of fire retardant
| ? | UL-94 flame retardant rating, (1.6mm) | LOI，% |
| Embodiment 1 | VO | 34.6 |
| Embodiment 2 | VO | 33.4 |
| Embodiment 3 | VO | 33.7 |
| Comparative example 1 | VO | 24.5 |
| Comparative example 2 | NR | 7.5 |
It is better that wood furniture of the present invention is painted thermotolerance and the flame retardant resistance of fire retardant, and preparation technology is simple, and product cost is low, the good combination property of product.This fire retardant does not move, does not separate out, is not extracted in wood furniture paint, is easy to be uniformly dispersed, and good weatherability, persistence is good, when heat, does not decompose.
In the time of wood furniture paint application, use this wood furniture to paint fire retardant simultaneously, do not produce any impact to painting the performance itself having, and its anti-flaming function section having effectively prevents that fiery residence from spreading by the diffusion of wood furniture, fire extinguishing in time, reduces loss of life and personal injury and property damage.
Claims (1)
1. wood furniture is painted fire retardant, it is characterized in that: the raw material by following weight part proportioning is prepared from: 75 parts, water, interior type-1, 7, 7-trimethylammonium two encircles [2.2.1] heptane-2-alcohol acetic ester 28-32 part, isopropyl mercaptan 15-18 part, (R)-(+)-2, 4-dihydroxyl-N-(3-hydroxypropyl)-3, 3-amide dimethyl butyrate 22-25 part, 2-sec.-propyl-5-methyl-cyclohexanol 20-22 part, 1-(4-fluorophenyl)-4-[4-(4-chloro-phenyl-)-4-hydroxyl-piperidino]-1-butanone 10-12 part, para-amino benzoic acid-2-diethylin carbethoxy hydrochloride 8-10 part, (2-carbamyl oxygen ethyl) trimethyl ammonium chloride 4-6 part, sulfinpyrazone 1-2 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410300118.6A CN104017411B (en) | 2014-06-27 | 2014-06-27 | Wood furniture paints fire retardant |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410300118.6A CN104017411B (en) | 2014-06-27 | 2014-06-27 | Wood furniture paints fire retardant |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104017411A true CN104017411A (en) | 2014-09-03 |
| CN104017411B CN104017411B (en) | 2015-12-02 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410300118.6A Active CN104017411B (en) | 2014-06-27 | 2014-06-27 | Wood furniture paints fire retardant |
Country Status (1)
| Country | Link |
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| CN (1) | CN104017411B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104312234A (en) * | 2014-09-29 | 2015-01-28 | 滁州斯迈特复合材料有限公司 | Flame retardant for computer mainboard |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6613391B1 (en) * | 2000-01-27 | 2003-09-02 | Henry Gang | Flame inhibiting and retarding chemical process and system for general use on multiple solid surfaces |
| CN101659824A (en) * | 2008-08-28 | 2010-03-03 | 上海富臣化工有限公司 | Nano flame retardant emulsion paint and method for preparing same |
| CN102993894A (en) * | 2012-07-07 | 2013-03-27 | 苏州萃智新技术开发有限公司 | Composite flame retardant for phenolic paint |
| CN103849192A (en) * | 2012-11-29 | 2014-06-11 | 大连飞马文仪家俱有限公司 | Paint containing silver ion antibacterial agent and red phosphorus |
| CN103849194A (en) * | 2012-11-29 | 2014-06-11 | 大连飞马文仪家俱有限公司 | Flame retardant paint containing aluminium hydroxide |
-
2014
- 2014-06-27 CN CN201410300118.6A patent/CN104017411B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6613391B1 (en) * | 2000-01-27 | 2003-09-02 | Henry Gang | Flame inhibiting and retarding chemical process and system for general use on multiple solid surfaces |
| CN101659824A (en) * | 2008-08-28 | 2010-03-03 | 上海富臣化工有限公司 | Nano flame retardant emulsion paint and method for preparing same |
| CN102993894A (en) * | 2012-07-07 | 2013-03-27 | 苏州萃智新技术开发有限公司 | Composite flame retardant for phenolic paint |
| CN103849192A (en) * | 2012-11-29 | 2014-06-11 | 大连飞马文仪家俱有限公司 | Paint containing silver ion antibacterial agent and red phosphorus |
| CN103849194A (en) * | 2012-11-29 | 2014-06-11 | 大连飞马文仪家俱有限公司 | Flame retardant paint containing aluminium hydroxide |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104312234A (en) * | 2014-09-29 | 2015-01-28 | 滁州斯迈特复合材料有限公司 | Flame retardant for computer mainboard |
| CN104312234B (en) * | 2014-09-29 | 2016-03-23 | 滁州斯迈特复合材料有限公司 | Computer main board fire retardant |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104017411B (en) | 2015-12-02 |
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Effective date of registration: 20190103 Address after: 310000 Daan village, Bei Zhuang village, Chong Xian street, Yuhang District, Hangzhou, Zhejiang Patentee after: ZHEJIANG GENZO FURNITURE MANUFACTURING Co.,Ltd. Address before: 239000 No. 12, Shuixi village, Shuikou Town, Shuikou Town, Lai An county, Chuzhou, Anhui Patentee before: Liu Xinxia |
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Effective date of registration: 20240110 Address after: No. 109 Shunda Road, Yangshuwan Industrial Park, Luoshe Town, Deqing County, Huzhou City, Zhejiang Province, 313200 Patentee after: Zhejiang Guanchen Tianhe Intelligent Furniture Co.,Ltd. Address before: 310000 Daan village, Bei Zhuang village, Chong Xian street, Yuhang District, Hangzhou, Zhejiang Patentee before: ZHEJIANG GENZO FURNITURE MANUFACTURING Co.,Ltd. |