CN104031454B - Family's wall paint fire retardant - Google Patents
Family's wall paint fire retardant Download PDFInfo
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- CN104031454B CN104031454B CN201410286058.7A CN201410286058A CN104031454B CN 104031454 B CN104031454 B CN 104031454B CN 201410286058 A CN201410286058 A CN 201410286058A CN 104031454 B CN104031454 B CN 104031454B
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Abstract
The present invention relates to family's wall paint fire retardant, belong to fire-retardant articles for use field.It is by following raw material [(2E)-3,7-dimethyl-octa-2,6-dialkylene] (4E, 8E)-5,9,13-trimethylammonium 14 carbon-4,8,12-triolefin acid esters, 2,6,6,8-tetramethyl-three ring [5.3.1.0] undecane-8-alcohol, N4-(6-methoxyl group-8-quinolyl)-1-pentamethylene diamine diphosphate, endoxan, 2-[2-[4-[(4-chloro-phenyl-)-phenmethyl] piperazine-1-base] oxyethyl group] ethanol etc. is prepared from.This family's wall paint fire retardant, utilize the interaction between related chemical constituents, influence each other, mix with wall paint and use, family's body of wall can stop propagation of flame to be burnt while attractive in appearance, there is splendid flame retardant effect, the fire attack time be can effectively increase, loss of life and personal injury and property damage reduced.
Description
Technical field
The present invention relates to a kind of family wall paint fire retardant, belong to fire-retardant articles for use field.
Background technology
Fire-fighting work is a social job, and it relates to all trades and professions, huge numbers of families.And family fire increases year by year, and cause a tremendous loss of lives, the dead group of group even occurs and hinders accident, therefore, number of ways is prevented fires, and especially the enhancing of family's material of construction fire-proof function is very necessary, and it is an effective way wherein that family's wall paint has flame retardant effect.
Summary of the invention
The object of the invention is to solve the deficiency that family's wall paint that above-mentioned prior art exists cannot be fire-retardant, a kind of family's wall paint fire retardant of good flame retardation effect is provided.
Family's wall paint fire retardant, special character is to be prepared from by the raw material of following weight: 85 parts, water, [(2E)-3, 7-dimethyl-octa-2, 6-dialkylene] (4E, 8E)-5, 9, 13-trimethylammonium 14 carbon-4, 8, 12-triolefin acid esters 28-30 part, 2, 6, 6, 8-tetramethyl-three ring [5.3.1.0] undecane-8-alcohol 24-26 part, N4-(6-methoxyl group-8-quinolyl)-1-pentamethylene diamine diphosphate 18-20 part, endoxan 12-15 part, 2-[2-[4-[(4-chloro-phenyl-)-phenmethyl] piperazine-1-base] oxyethyl group] ethanol 10-12 part, hexichol hydroxy methyl acetate 6-8 part, (R)-4-[2-(methylamino-)-1-hydroxyethyl]-1, 2-dihydroxy-benzene hydrochloride 2-4 part, 3-[[(4, 5-dihydro-1H-imidazoles-2-base) methyl] (4-tolyl) amino] phenol 1-2 part.
Preparation method of the present invention: by pure water, [(2E)-3, 7-dimethyl-octa-2, 6-dialkylene] (4E, 8E)-5, 9, 13-trimethylammonium 14 carbon-4, 8, 12-triolefin acid esters, endoxan, 2-[2-[4-[(4-chloro-phenyl-)-phenmethyl] piperazine-1-base] oxyethyl group] ethanol adds stirring and dissolving in reactor 1, by 2, 6, 6, 8-tetramethyl-three ring [5.3.1.0] undecane-8-alcohol, N4-(6-methoxyl group-8-quinolyl)-1-pentamethylene diamine diphosphate, hexichol hydroxy methyl acetate, (R)-4-[2-(methylamino-)-1-hydroxyethyl]-1, 2-dihydroxy-benzene hydrochloride, 3-[[(4, 5-dihydro-1H-imidazoles-2-base) methyl] (4-tolyl) amino] phenol stirring and dissolving in reactor 2, mixture in reactor 2 is joined gradually in reactor 1, abundant stirring 20-30 minute, 1-2 hour is left standstill again in the water bath with thermostatic control of 60 DEG C, required family's wall paint fire retardant can be obtained.
This family's wall paint fire retardant, utilize the interaction between related chemical constituents, influence each other, mix with wall paint and use, family's body of wall can stop propagation of flame to be burnt while attractive in appearance, there is splendid flame retardant effect, the fire attack time be can effectively increase, loss of life and personal injury and property damage reduced.
Embodiment
Below provide the specific embodiment of the present invention, be used for being further described the present invention.In the present invention, if no special instructions, each raw material all in working substance content for 100%.
In following examples and comparative example, raw material introduction:
[(2E)-3,7-dimethyl-octa-2,6-dialkylene] (4E, 8E)-5,9,13-trimethylammonium 14 carbon-4,8,12-triolefin acid esters, CAS accession number is: 51-77-4;
2,6,6,8-tetramethyl-three ring [5.3.1.0] undecane-8-alcohol, CAS accession number is: 77-53-2;
N4-(6-methoxyl group-8-quinolyl)-1-pentamethylene diamine diphosphate, CAS accession number is: 63-45-6;
Endoxan, CAS accession number is: 50-18-0;
2-[2-[4-[(4-chloro-phenyl-)-phenmethyl] piperazine-1-base] oxyethyl group] ethanol, CAS accession number is: 68-88-2;
Hexichol hydroxy methyl acetate, CAS accession number is: 76-89-1;
(R)-4-[2-(methylamino-)-1-hydroxyethyl]-1,2-dihydroxy-benzene hydrochloride, CAS accession number is: 55-31-2;
3-[[(4,5-dihydro-1H-imidazoles-2-base) methyl] (4-tolyl) is amino] phenol, CAS accession number is: 50-60-2.
Embodiment 1
Weigh: water 85kg, [(2E)-3, 7-dimethyl-octa-2, 6-dialkylene] (4E, 8E)-5, 9, 13-trimethylammonium 14 carbon-4, 8, 12-triolefin acid esters 30kg, 2, 6, 6, 8-tetramethyl-three ring [5.3.1.0] undecane-8-alcohol 25kg, N4-(6-methoxyl group-8-quinolyl)-1-pentamethylene diamine diphosphate 20kg, endoxan 12kg, 2-[2-[4-[(4-chloro-phenyl-)-phenmethyl] piperazine-1-base] oxyethyl group] ethanol 11kg, hexichol hydroxy methyl acetate 8kg, (R)-4-[2-(methylamino-)-1-hydroxyethyl]-1, 2-dihydroxy-benzene hydrochloride 4kg, 3-[[(4, 5-dihydro-1H-imidazoles-2-base) methyl] (4-tolyl) amino] phenol 2kg.
This embodiment family wall paint fire retardant preparation method: by pure water, [(2E)-3, 7-dimethyl-octa-2, 6-dialkylene] (4E, 8E)-5, 9, 13-trimethylammonium 14 carbon-4, 8, 12-triolefin acid esters, endoxan, 2-[2-[4-[(4-chloro-phenyl-)-phenmethyl] piperazine-1-base] oxyethyl group] ethanol adds stirring and dissolving in reactor 1, by 2, 6, 6, 8-tetramethyl-three ring [5.3.1.0] undecane-8-alcohol, N4-(6-methoxyl group-8-quinolyl)-1-pentamethylene diamine diphosphate, hexichol hydroxy methyl acetate, (R)-4-[2-(methylamino-)-1-hydroxyethyl]-1, 2-dihydroxy-benzene hydrochloride, 3-[[(4, 5-dihydro-1H-imidazoles-2-base) methyl] (4-tolyl) amino] phenol stirring and dissolving in reactor 2, mixture in reactor 2 is joined gradually in reactor 1, abundant stirring 20-30 minute, 1-2 hour is left standstill again in the water bath with thermostatic control of 60 DEG C, required family's wall paint fire retardant can be obtained.
Embodiment 2
Weigh: water 85kg, [(2E)-3, 7-dimethyl-octa-2, 6-dialkylene] (4E, 8E)-5, 9, 13-trimethylammonium 14 carbon-4, 8, 12-triolefin acid esters 28kg, 2, 6, 6, 8-tetramethyl-three ring [5.3.1.0] undecane-8-alcohol 26kg, N4-(6-methoxyl group-8-quinolyl)-1-pentamethylene diamine diphosphate 19kg, endoxan 14kg, 2-[2-[4-[(4-chloro-phenyl-)-phenmethyl] piperazine-1-base] oxyethyl group] ethanol 12kg, hexichol hydroxy methyl acetate 7kg, (R)-4-[2-(methylamino-)-1-hydroxyethyl]-1, 2-dihydroxy-benzene hydrochloride 2kg, 3-[[(4, 5-dihydro-1H-imidazoles-2-base) methyl] (4-tolyl) amino] phenol 1.5kg.
The preparation method of this family's wall paint fire retardant is with embodiment 1.
Embodiment 3
Weigh: water 85kg, [(2E)-3, 7-dimethyl-octa-2, 6-dialkylene] (4E, 8E)-5, 9, 13-trimethylammonium 14 carbon-4, 8, 12-triolefin acid esters 29kg, 2, 6, 6, 8-tetramethyl-three ring [5.3.1.0] undecane-8-alcohol 24kg, N4-(6-methoxyl group-8-quinolyl)-1-pentamethylene diamine diphosphate 18kg, endoxan 15kg, 2-[2-[4-[(4-chloro-phenyl-)-phenmethyl] piperazine-1-base] oxyethyl group] ethanol 10kg, hexichol hydroxy methyl acetate 6kg, (R)-4-[2-(methylamino-)-1-hydroxyethyl]-1, 2-dihydroxy-benzene hydrochloride 3kg, 3-[[(4, 5-dihydro-1H-imidazoles-2-base) methyl] (4-tolyl) amino] phenol 1kg.
The preparation method of this family's wall paint fire retardant is with embodiment 1.
Comparative example 1
Weigh: water 85kg, [(2E)-3, 7-dimethyl-octa-2, 6-dialkylene] (4E, 8E)-5, 9, 13-trimethylammonium 14 carbon-4, 8, 12-triolefin acid esters 30kg, 2, 6, 6, 8-tetramethyl-three ring [5.3.1.0] undecane-8-alcohol 25kg, N4-(6-methoxyl group-8-quinolyl)-1-pentamethylene diamine diphosphate 20kg, endoxan 12kg, (R)-4-[2-(methylamino-)-1-hydroxyethyl]-1, 2-dihydroxy-benzene hydrochloride 4kg, 3-[[(4, 5-dihydro-1H-imidazoles-2-base) methyl] (4-tolyl) amino] phenol 2kg.
This comparative example family wall paint fire retardant preparation method: by pure water, [(2E)-3, 7-dimethyl-octa-2, 6-dialkylene] (4E, 8E)-5, 9, 13-trimethylammonium 14 carbon-4, 8, 12-triolefin acid esters, endoxan adds stirring and dissolving in reactor 1, by 2, 6, 6, 8-tetramethyl-three ring [5.3.1.0] undecane-8-alcohol, N4-(6-methoxyl group-8-quinolyl)-1-pentamethylene diamine diphosphate, (R)-4-[2-(methylamino-)-1-hydroxyethyl]-1, 2-dihydroxy-benzene hydrochloride, 3-[[(4, 5-dihydro-1H-imidazoles-2-base) methyl] (4-tolyl) amino] phenol stirring and dissolving in reactor 2, mixture in reactor 2 is joined gradually in reactor 1, abundant stirring 20-30 minute, 1-2 hour is left standstill again in the water bath with thermostatic control of 60 DEG C, required family's wall paint fire retardant can be obtained.
Comparative example 2
Weigh: water 85kg, 2,6,6,8-tetramethyl-three ring [5.3.1.0] undecane-8-alcohol 25kg, N4-(6-methoxyl group-8-quinolyl)-1-pentamethylene diamine diphosphate 20kg, endoxan 12kg, 2-[2-[4-[(4-chloro-phenyl-)-phenmethyl] piperazine-1-base] oxyethyl group] ethanol 11kg, hexichol hydroxy methyl acetate 8kg, 3-[[(4,5-dihydro-1H-imidazoles-2-base) methyl] (4-tolyl) is amino] phenol 2kg.
This comparative example family wall paint fire retardant preparation method: by pure water, endoxan, 2-[2-[4-[(4-chloro-phenyl-)-phenmethyl] piperazine-1-base] oxyethyl group] ethanol adds stirring and dissolving in reactor 1, by 2, 6, 6, 8-tetramethyl-three ring [5.3.1.0] undecane-8-alcohol, N4-(6-methoxyl group-8-quinolyl)-1-pentamethylene diamine diphosphate, hexichol hydroxy methyl acetate, 3-[[(4, 5-dihydro-1H-imidazoles-2-base) methyl] (4-tolyl) amino] phenol stirring and dissolving in reactor 2, mixture in reactor 2 is joined gradually in reactor 1, abundant stirring 20-30 minute, 1-2 hour is left standstill again in the water bath with thermostatic control of 60 DEG C, required family's wall paint fire retardant can be obtained.
Test case
Test embodiment and comparative example, concrete data are in table 1.
The flame retardant properties test chart of family's wall paint fire retardant
| UL-94 flame retardant rating, (1.6mm) | LOI，% | |
| Embodiment 1 | VO | 29.5 |
| Embodiment 2 | VO | 29.2 |
| Embodiment 3 | VO | 28.8 |
| Comparative example 1 | VO | 21.3 |
| Comparative example 2 | NR | 8.5 |
Thermotolerance and the flame retardant resistance of family of the present invention wall paint fire retardant are better, and preparation technology is simple, and product cost is low, the good combination property of product.
Family of the present invention wall paint fire retardant, not containing rare elements, flame retardant properties is good, do not move in wall paint, do not separate out, be not extracted, be easy to be uniformly dispersed, good weatherability, persistence is good, the opacifying power of wall paint, sticking power, viscosity, fineness are not all affected, and the fire retardant on body of wall has long-term flame retardant resistance.
Claims (1)
1. family's wall paint fire retardant, it is characterized in that being prepared from by the raw material of following weight: 85 parts, water, [(2E)-3, 7-dimethyl-octa-2, 6-dialkylene] (4E, 8E)-5, 9, 13-trimethylammonium 14 carbon-4, 8, 12-triolefin acid esters 28-30 part, 2, 6, 6, 8-tetramethyl-three ring [5.3.1.0] undecane-8-alcohol 24-26 part, N4-(6-methoxyl group-8-quinolyl)-1-pentamethylene diamine diphosphate 18-20 part, endoxan 12-15 part, 2-[2-[4-[(4-chloro-phenyl-)-phenmethyl] piperazine-1-base] oxyethyl group] ethanol 10-12 part, hexichol hydroxy methyl acetate 6-8 part, (R)-4-[2-(methylamino-)-1-hydroxyethyl]-1, 2-dihydroxy-benzene hydrochloride 2-4 part, 3-[[(4, 5-dihydro-1H-imidazoles-2-base) methyl] (4-tolyl) amino] phenol 1-2 part.
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| CN104312234B (en) * | 2014-09-29 | 2016-03-23 | 滁州斯迈特复合材料有限公司 | Computer main board fire retardant |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101602682A (en) * | 2009-07-20 | 2009-12-16 | 北京化工大学 | Light-initiated/halogen-free flame retardants and its production and application |
| CN103772740A (en) * | 2014-01-16 | 2014-05-07 | 寿光卫东化工有限公司 | Phosphorus-containing flame retardant and preparation method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004224960A (en) * | 2003-01-24 | 2004-08-12 | Dainippon Ink & Chem Inc | Flame retardant paint composition and flame retardant base material having coating film of the composition |
| CN101818069B (en) * | 2010-04-02 | 2014-01-01 | 南京师范大学 | Method for preparing monophosphonate and biphosphonate mixed fire retardant |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101602682A (en) * | 2009-07-20 | 2009-12-16 | 北京化工大学 | Light-initiated/halogen-free flame retardants and its production and application |
| CN103772740A (en) * | 2014-01-16 | 2014-05-07 | 寿光卫东化工有限公司 | Phosphorus-containing flame retardant and preparation method thereof |
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Address after: 239000 Weier Road, Zone C, Lai'an Industrial Park, Chuzhou City, Anhui Province Patentee after: Anhui smart new material Co.,Ltd. Address before: 239000 Weier Road, Zone C, Lai'an Industrial Park, Chuzhou City, Anhui Province Patentee before: Anhui simaite new materials Co.,Ltd. Address after: 239000 Weier Road, Zone C, Lai'an Industrial Park, Chuzhou City, Anhui Province Patentee after: Anhui simaite new materials Co.,Ltd. Address before: 239000 Weier Road, Zone C, Lai'an Industrial Park, Chuzhou City, Anhui Province Patentee before: CHUZHOU SMET COMPOUND MATERIALS Co.,Ltd. |
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