CN104004423A - Multifunctional environment-friendly waterproof paint - Google Patents

Multifunctional environment-friendly waterproof paint Download PDF

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Publication number
CN104004423A
CN104004423A CN201410269838.0A CN201410269838A CN104004423A CN 104004423 A CN104004423 A CN 104004423A CN 201410269838 A CN201410269838 A CN 201410269838A CN 104004423 A CN104004423 A CN 104004423A
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China
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parts
waterproof paint
agent
defoamer
functional environment
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CN201410269838.0A
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CN104004423B (en
Inventor
陈久存
李长明
刘茵沁
李文君
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Banger Jianglong Maqu Industrial Co ltd
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Southwest University
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Abstract

The invention discloses multifunctional environment-friendly waterproof paint. The paint comprises, by weight, 25-35 parts of waterborne acrylic emulsion, 10-20 parts of butylbenzene emulsion, 10-20 parts of titanium dioxide, 5-10 parts of light calcium carbonate, 2-5 parts of ceramic fibers, 2-5 parts of molybdenum disulfide, 1-3 parts of dispersants, 0.1-2 parts of adhesion promoters, 0.1-1 part of an ultraviolet absorbent, 0.1-1 part of an antioxidant, 0.1-1 part of a defoamer, 0.5-5 parts of thickeners, 1-2 parts of coalescing agents and 10-25 parts of water. The multifunctional environment-friendly waterproof paint simultaneously has good adhesive force and mechanical properties, is good in ageing resistance, cracking resistance and temperature adaptability, is free of toxin, and is excellent in comprehensive performance.

Description

A kind of multi-functional environment-protection waterproof paint
Technical field
The invention belongs to waterproof paint field, relate to a kind of building coating, particularly a kind of multi-functional environment-protection waterproof paint.
Background technology
Waterproof paint is the material of a kind of liquid state or semi liquid state, at building surface, adopt the operating techniquies such as brush or spraying, by chemical reaction form one continuous, there is certain elasticity and the film of thickness, can resist certain water pressure like this, thereby reach waterproof and moistureproof object.Waterproof paint is a kind of special coating, and its singularity is that coatingsurface can form the Waterproof structural course of a softness, waterproof, cracking resistance, and block water molecule permeates to basic unit from outside.
Buildings and structures in use, all can be subject to the impact of various natural causes, and construction form is different with waterproof position, and suffered influence factor is also different.If building roof waterproof layer long-term exposure is in physical environment, be subject to the erosion of rain, snow, wind, frost, ultraviolet ray and air pollutant; Buildings underground part not only for a long time in water surrounding, but also will bear the repeated action of non-uniform settling; Bridge is the repeated stress effect that will bear frequent traffic load.Therefore, for the material of buildings waterproof, not only need to there is the mechanical property under the effect of opposing complex stress, also need to remain on the lasting stability of over-all properties under various natural cause long-term effect simultaneously.Tradition novel durable waterproof paint is for waterproof outside room, easily causes aging, dry and cracked, the phenomenon such as be out of shape, fracture; And for waterproof such as kitchen, lavatories, for complex-shaped place constructional difficulties, and weather resistance is poor, every several years needs, reprocess, both increased expense, upset again people's orthobiosis.
Summary of the invention
In view of this, the object of the present invention is to provide a kind of novel environment friendly coating simultaneously with excellent mechanical property and weather resistance.
For achieving the above object, the invention provides following technical scheme: a kind of multi-functional environment-protection waterproof paint, described coating contains following component by mass parts: aqueous acrylic emulsion: 25-35 part; Styrene-butadiene emulsion: 10-20 part; Titanium dioxide: 10-20 part; Light calcium carbonate: 5-10 part; Ceramic fiber: 2-5 part; Molybdenumdisulphide: 2-5 part; Dispersion agent: 1-3 part; Adhesion promoter: 0.1-2 part; Uv-absorbing agent: 0.1-1 part; Anti-aging agent: 0.1-1 part; Defoamer: 0.1-1 part; Thickening material: 0.5-5 part; Film coalescence aid: 1-2 part; Water: 10-25 part.
As multi-functional environment-protection waterproof paint of the present invention preferably, described dispersion agent is dispersion agent 5040, described uv-absorbing agent is UV light absorber UV-9; Described anti-aging agent is antioxidant 264; Described defoamer is defoamer NXZ; Described thickening material is inorganic bentonite; Described film coalescence aid is Yi Siman film coalescence aid.
As multi-functional environment-protection waterproof paint of the present invention further preferably, in described waterproof paint, also contain 2-10 part carboxy cellulose.
Another kind as multi-functional environment-protection waterproof paint of the present invention is preferred, and described coating is composed of the following components by mass parts: aqueous acrylic emulsion: 25-35 part; Styrene-butadiene emulsion: 10-15 part; Titanium dioxide: 15-20 part; Light calcium carbonate: 5-10 part; Ceramic fiber: 2-5 part; Molybdenumdisulphide: 2-5 part; Carboxy cellulose: 2-5 part; Dispersion agent: 2-3 part; Adhesion promoter: 0.1-1 part; Uv-absorbing agent: 0.1-0.5 part; Anti-aging agent: 0.1-1 part; Defoamer: 0.5-1 part; Thickening material: 0.5-3 part; Film coalescence aid: 1-2 part; Water: 15-25 part.
Another kind as multi-functional environment-protection waterproof paint of the present invention is preferred, and described coating is composed of the following components by mass parts: aqueous acrylic emulsion: 30 parts; Styrene-butadiene emulsion: 10 parts; Titanium dioxide: 18 parts; Light calcium carbonate: 5 parts; Ceramic fiber: 3 parts; Molybdenumdisulphide: 5 parts; Carboxy cellulose: 5 parts; Dispersion agent: 3 parts; Adhesion promoter: 0.8 part; Uv-absorbing agent: 0.3 part; Anti-aging agent: 0.6 part; Defoamer: 0.8 part; Thickening material: 2 parts; Film coalescence aid: 1 part; Water: 15.5.
The method of preparing described multi-functional environment-protection waterproof paint, comprises the following steps: a) according to described proportioning, select starting material; B) add dispersion machine to be uniformly dispersed in selected titanium dioxide, light calcium carbonate, ceramic fiber, molybdenumdisulphide, carboxy cellulose, dispersion agent, adhesion promoter, uv-absorbing agent, anti-aging agent, defoamer and water; C) slowly add aqueous acrylic emulsion and styrene-butadiene emulsion, stirring at low speed is disperseed; D) add thickening material and film coalescence aid and stir.
As the present invention prepare multi-functional environment-protection waterproof paint method preferably, step b) rotating speed is 1800-2200 rev/min while disperseing, jitter time is 1.5-2.5h.
As the present invention prepare multi-functional environment-protection waterproof paint method further preferably, step c) rotating speed is 350-450 rev/min while disperseing.
Beneficial effect of the present invention is: in waterproof paint of the present invention, added styrene-butadiene emulsion and ceramic fiber, can significantly strengthen the mechanical property of coating and reduce coating cost; The present invention has added appropriate molybdenumdisulphide in coating, not only can play hydrophobic and self-cleaning action, and can significantly strengthen acidproof, the alkaline-resisting and organic solvent-resistant of coating; The present invention has added appropriate several functions auxiliary agent in coating, and various auxiliary agent consistencies are good, can increase sticking power, uvioresistant, the anti-aging and resistance to corrosion of coating simultaneously.The method that the present invention prepares multi-functional environment-protection waterproof paint first adds the abundant dispersion moistening of color stuffing high-speed stirring, then under stirring at low speed, adds emulsion, can effectively avoid high-speed stirring to cause emulsion breaking.
Embodiment
Below the preferred embodiments of the present invention are described in detail.
Following examples will disclose a kind of waterproof coating, and this coating contains following component by mass parts: aqueous acrylic emulsion: 25-35 part; Styrene-butadiene emulsion: 10-20 part; Titanium dioxide: 10-20 part; Light calcium carbonate: 5-10 part; Ceramic fiber: 2-5 part; Molybdenumdisulphide: 2-5 part; Dispersion agent: 1-3 part; Adhesion promoter: 0.1-2 part; Uv-absorbing agent: 0.1-1 part; Anti-aging agent: 0.1-1 part; Defoamer: 0.1-1 part; Thickening material: 0.5-5 part; Film coalescence aid: 1-2 part; Water: 10-25 part; Wherein: described dispersion agent is dispersion agent 5040, described uv-absorbing agent is UV light absorber UV-9; Described anti-aging agent is antioxidant 264; Described defoamer is defoamer NXZ; Described thickening material is inorganic bentonite; Described film coalescence aid is Yi Siman film coalescence aid; In described waterproof paint, also contain in addition 2-10 part carboxy cellulose.
Especially, multi-functional environment-protection waterproof paint of the present invention is composed of the following components by mass parts: aqueous acrylic emulsion: 25-35 part; Styrene-butadiene emulsion: 10-15 part; Titanium dioxide: 15-20 part; Light calcium carbonate: 5-10 part; Ceramic fiber: 2-5 part; Molybdenumdisulphide: 2-5 part; Carboxy cellulose: 2-5 part; Dispersion agent: 2-3 part; Adhesion promoter: 0.1-1 part; Uv-absorbing agent: 0.1-0.5 part; Anti-aging agent: 0.1-1 part; Defoamer: 0.5-1 part; Thickening material: 0.5-3 part; Film coalescence aid: 1-2 part; Water: 15-25 part.
Preferably, described coating is composed of the following components by mass parts: aqueous acrylic emulsion: 30 parts; Styrene-butadiene emulsion: 10 parts; Titanium dioxide: 18 parts; Light calcium carbonate: 5 parts; Ceramic fiber: 3 parts; Molybdenumdisulphide: 5 parts; Carboxy cellulose: 5 parts; Dispersion agent: 3 parts; Adhesion promoter: 0.8 part; Uv-absorbing agent: 0.3 part; Anti-aging agent: 0.6 part; Defoamer: 0.8 part; Thickening material: 2 parts; Film coalescence aid: 1 part; Water: 15.5.
Embodiment 1:
The present embodiment is prepared the method for described multi-functional environment-protection waterproof paint, comprises the following steps:
1), choose starting material:
Wherein: aqueous acrylic emulsion: 35 parts; Styrene-butadiene emulsion: 10 parts; Titanium dioxide: 13 parts; Light calcium carbonate: 5 parts; Ceramic fiber: 3 parts; Molybdenumdisulphide: 5 parts; Carboxy cellulose: 5 parts; Dispersion agent: 3 parts; Adhesion promoter: 0.8 part; Uv-absorbing agent: 0.3 part; Anti-aging agent: 0.6 part; Defoamer: 0.8 part; Thickening material: 2 parts; Film coalescence aid: 1 part; Water: 15.5 parts; Described dispersion agent is dispersion agent 5040, and described uv-absorbing agent is the UV light absorber UV-9 of lark prestige Science and Technology Ltd.; Described anti-aging agent is Lianyun Harbour Ning Kang Chemical Co., Ltd. antioxidant 264; Described defoamer is the defoamer NXZ of BASF Co., Ltd; Described thickening material is inorganic bentonite; Described film coalescence aid is U.S. Yi Siman TEXANOL ester alcohol film coalescence aid.
2), selected titanium dioxide, light calcium carbonate, ceramic fiber, molybdenumdisulphide, carboxy cellulose, dispersion agent, adhesion promoter, uv-absorbing agent, anti-aging agent, defoamer and water are added to dispersion machine 1800-2200 rev/min, dispersion 1.5-2.5h;
3), slowly add aqueous acrylic emulsion and styrene-butadiene emulsion, 350-450 rev/min of dispersed with stirring;
4), add thickening material and film coalescence aid and stir.
Embodiment 2:
The difference of the present embodiment and embodiment 1 is, the selected starting material of the present embodiment and proportioning thereof are as follows:
Aqueous acrylic emulsion: 20 parts; Styrene-butadiene emulsion: 20 parts; Titanium dioxide: 18 parts; Light calcium carbonate: 5 parts; Ceramic fiber: 3 parts; Molybdenumdisulphide: 5 parts; Carboxy cellulose: 5 parts; Dispersion agent: 3 parts; Adhesion promoter: 0.8 part; Uv-absorbing agent: 0.3 part; Anti-aging agent: 0.6 part; Defoamer: 0.8 part; Thickening material: 2 parts; Film coalescence aid: 1 part; Water: 15.5 parts.
Embodiment 3:
The difference of the present embodiment and embodiment 1 is, the selected starting material of the present embodiment and proportioning thereof are as follows:
Aqueous acrylic emulsion: 30 parts; Styrene-butadiene emulsion: 10 parts; Titanium dioxide: 18 parts; Light calcium carbonate: 5 parts; Ceramic fiber: 3 parts; Molybdenumdisulphide: 5 parts; Carboxy cellulose: 5 parts; Dispersion agent: 3 parts; Adhesion promoter: 0.8 part; Uv-absorbing agent: 0.3 part; Anti-aging agent: 0.6 part; Defoamer: 0.8 part; Thickening material: 2 parts; Film coalescence aid: 1 part; Water: 15.5 parts.
Embodiment 4:
The difference of the present embodiment and embodiment 1 is, the selected starting material of the present embodiment and proportioning thereof are as follows:
Aqueous acrylic emulsion: 30 parts; Styrene-butadiene emulsion: 10 parts; Titanium dioxide: 27 parts; Light calcium carbonate: 8 parts; Ceramic fiber: 1 part; Molybdenumdisulphide: 1 part; Carboxy cellulose: 1 part; Dispersion agent: 3 parts; Adhesion promoter: 0.8 part; Uv-absorbing agent: 0.3 part; Anti-aging agent: 0.6 part; Defoamer: 0.8 part; Thickening material: 2 parts; Film coalescence aid: 1 part; Water: 15.5 parts.
Embodiment 5:
The difference of the present embodiment and embodiment 1 is, the selected starting material of the present embodiment and proportioning thereof are as follows:
Aqueous acrylic emulsion: 30 parts; Styrene-butadiene emulsion: 10 parts; Titanium dioxide: 18 parts; Light calcium carbonate: 6.4 parts; Ceramic fiber: 3 parts; Molybdenumdisulphide: 5 parts; Carboxy cellulose: 5 parts; Dispersion agent: 3 parts; Adhesion promoter: 0.2 part; Uv-absorbing agent: 0.1 part; Anti-aging agent: 0.1 part; Defoamer: 0.8 part; Thickening material: 2 parts; Film coalescence aid: 1 part; Water: 15.5 parts.
The performance of above-described embodiment 1-5 gained waterproof paint is as shown in table 1 below:
Table 1 embodiment 1-5 gained waterproof paint performance comparison
Associative list 1 can be found out, above-described embodiment products obtained therefrom had both had excellent sticking power and mechanical property, there is again good ageing resistance, splitting resistance and thermal adaptability, and the toxicological harmless of product own, be a kind of novel environment friendly multifunctional water-proof paint of excellent combination property.
It should be noted that, when coating formula meets aqueous acrylic emulsion: 25-35 part; Styrene-butadiene emulsion: 10-20 part; Titanium dioxide: 10-20 part; Light calcium carbonate: 5-10 part; Ceramic fiber: 2-5 part; Molybdenumdisulphide: 2-5 part; Dispersion agent: 1-3 part; Adhesion promoter: 0.1-2 part; Uv-absorbing agent: 0.1-1 part; Anti-aging agent: 0.1-1 part; Defoamer: 0.1-1 part; Thickening material: 0.5-5 part; Film coalescence aid: 1-2 part; Water: 10-25 part is all to have good result of use.
Finally explanation is, above preferred embodiment is only unrestricted in order to technical scheme of the present invention to be described, although the present invention is described in detail by above preferred embodiment, but those skilled in the art are to be understood that, can to it, make various changes in the form and details, and not depart from the claims in the present invention book limited range.

Claims (8)

1. a multi-functional environment-protection waterproof paint, is characterized in that, described coating contains following component by mass parts: aqueous acrylic emulsion: 25-35 part; Styrene-butadiene emulsion: 10-20 part; Titanium dioxide: 10-20 part; Light calcium carbonate: 5-10 part; Ceramic fiber: 2-5 part; Molybdenumdisulphide: 2-5 part; Dispersion agent: 1-3 part; Adhesion promoter: 0.1-2 part; Uv-absorbing agent: 0.1-1 part; Anti-aging agent: 0.1-1 part; Defoamer: 0.1-1 part; Thickening material: 0.5-5 part; Film coalescence aid: 1-2 part; Water: 10-25 part.
2. multi-functional environment-protection waterproof paint according to claim 1, is characterized in that: described dispersion agent is dispersion agent 5040, and described uv-absorbing agent is UV light absorber UV-9; Described anti-aging agent is antioxidant 264; Described defoamer is defoamer NXZ; Described thickening material is inorganic bentonite; Described film coalescence aid is Yi Siman film coalescence aid.
3. multi-functional environment-protection waterproof paint according to claim 1, is characterized in that: in described waterproof paint, also contain 2-10 part carboxy cellulose.
4. multi-functional environment-protection waterproof paint according to claim 1, is characterized in that, described coating is composed of the following components by mass parts: aqueous acrylic emulsion: 25-35 part; Styrene-butadiene emulsion: 10-15 part; Titanium dioxide: 15-20 part; Light calcium carbonate: 5-10 part; Ceramic fiber: 2-5 part; Molybdenumdisulphide: 2-5 part; Carboxy cellulose: 2-5 part; Dispersion agent: 2-3 part; Adhesion promoter: 0.1-1 part; Uv-absorbing agent: 0.1-0.5 part; Anti-aging agent: 0.1-1 part; Defoamer: 0.5-1 part; Thickening material: 0.5-3 part; Film coalescence aid: 1-2 part; Water: 15-25 part.
5. multi-functional environment-protection waterproof paint according to claim 1, is characterized in that, described coating is composed of the following components by mass parts: aqueous acrylic emulsion: 30 parts; Styrene-butadiene emulsion: 10 parts; Titanium dioxide: 18 parts; Light calcium carbonate: 5 parts; Ceramic fiber: 3 parts; Molybdenumdisulphide: 5 parts; Carboxy cellulose: 5 parts; Dispersion agent: 3 parts; Adhesion promoter: 0.8 part; Uv-absorbing agent: 0.3 part; Anti-aging agent: 0.6 part; Defoamer: 0.8 part; Thickening material: 2 parts; Film coalescence aid: 1 part; Water: 15.5.
6. the method for preparation multi-functional environment-protection waterproof paint as described in claim 1-5 any one, is characterized in that, comprises the following steps: a) according to described proportioning, select starting material; B) add dispersion machine to be uniformly dispersed in selected titanium dioxide, light calcium carbonate, ceramic fiber, molybdenumdisulphide, carboxy cellulose, dispersion agent, adhesion promoter, uv-absorbing agent, anti-aging agent, defoamer and water; C) slowly add aqueous acrylic emulsion and styrene-butadiene emulsion, stirring at low speed is disperseed; D) add thickening material and film coalescence aid and stir.
7. prepare according to claim 6 the method for multi-functional environment-protection waterproof paint, it is characterized in that: while step b) disperseing, rotating speed is 1800-2200 rev/min, and jitter time is 1.5-2.5h.
8. prepare according to claim 6 the method for multi-functional environment-protection waterproof paint, it is characterized in that: while step c) disperseing, rotating speed is 350-450 rev/min.
CN201410269838.0A 2014-06-17 2014-06-17 A kind of multi-functional environment-protection waterproof paint Expired - Fee Related CN104004423B (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105885483A (en) * 2016-06-12 2016-08-24 合肥和安机械制造有限公司 Butylbenzene-emulsion-modified waterborne dacromet coating solution for automobile chassis and preparation method of coating solution
CN106800842A (en) * 2016-12-14 2017-06-06 池州市小康人家科技有限公司 A kind of solar water heater water-repellent paint
CN106957560A (en) * 2017-04-28 2017-07-18 明光市飞洲新材料有限公司 A kind of coating additive using attapulgite as carrier and preparation method thereof
CN107760230A (en) * 2017-11-15 2018-03-06 惠州市永耐宝新材料有限公司 A kind of waterproofing and leakage-stopping adhesive of high-bond and preparation method thereof
CN108570266A (en) * 2018-05-09 2018-09-25 山东七维新材料有限公司 A kind of chemically-resistant type water-based paint compositions and preparation method thereof
CN108587354A (en) * 2018-05-16 2018-09-28 苏州金螳螂建筑装饰股份有限公司 Multifunctional containment hardens primary coat and its preparation method and application
CN108822626A (en) * 2018-07-11 2018-11-16 重庆科顺化工新材料有限公司 A kind of one pack system waterproof coating and preparation method thereof pasted for Ceramic Tiles
CN109096835A (en) * 2018-08-28 2018-12-28 巢湖市兰天大诚门窗幕墙有限公司 Water-repellent paint for composite energy-saving door and window
CN109266071A (en) * 2018-08-07 2019-01-25 山东七维新材料有限公司 A kind of high attached type water-based paint compositions and preparation method thereof

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JPH1176935A (en) * 1997-09-04 1999-03-23 Kansai Paint Co Ltd Formation of waterproof coating film
JP4264146B2 (en) * 1998-08-24 2009-05-13 関西ペイント株式会社 Water-based waterproof coating material, and surface finish method for releasing concrete using the same
CN103666133A (en) * 2013-11-27 2014-03-26 王传福 Stain-resistant waterborne coating
CN103756417A (en) * 2013-12-27 2014-04-30 安徽省美域节能环保技术应用有限公司 Wear-resistant coating for external wall and preparation method thereof

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Publication number Priority date Publication date Assignee Title
JPH1176935A (en) * 1997-09-04 1999-03-23 Kansai Paint Co Ltd Formation of waterproof coating film
JP4264146B2 (en) * 1998-08-24 2009-05-13 関西ペイント株式会社 Water-based waterproof coating material, and surface finish method for releasing concrete using the same
CN103666133A (en) * 2013-11-27 2014-03-26 王传福 Stain-resistant waterborne coating
CN103756417A (en) * 2013-12-27 2014-04-30 安徽省美域节能环保技术应用有限公司 Wear-resistant coating for external wall and preparation method thereof

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105885483A (en) * 2016-06-12 2016-08-24 合肥和安机械制造有限公司 Butylbenzene-emulsion-modified waterborne dacromet coating solution for automobile chassis and preparation method of coating solution
CN106800842A (en) * 2016-12-14 2017-06-06 池州市小康人家科技有限公司 A kind of solar water heater water-repellent paint
CN106957560A (en) * 2017-04-28 2017-07-18 明光市飞洲新材料有限公司 A kind of coating additive using attapulgite as carrier and preparation method thereof
CN107760230A (en) * 2017-11-15 2018-03-06 惠州市永耐宝新材料有限公司 A kind of waterproofing and leakage-stopping adhesive of high-bond and preparation method thereof
CN108570266A (en) * 2018-05-09 2018-09-25 山东七维新材料有限公司 A kind of chemically-resistant type water-based paint compositions and preparation method thereof
CN108587354A (en) * 2018-05-16 2018-09-28 苏州金螳螂建筑装饰股份有限公司 Multifunctional containment hardens primary coat and its preparation method and application
CN108587354B (en) * 2018-05-16 2020-12-22 苏州金螳螂建筑装饰股份有限公司 Multifunctional seal hardening base coat and preparation method and application thereof
CN108822626A (en) * 2018-07-11 2018-11-16 重庆科顺化工新材料有限公司 A kind of one pack system waterproof coating and preparation method thereof pasted for Ceramic Tiles
CN109266071A (en) * 2018-08-07 2019-01-25 山东七维新材料有限公司 A kind of high attached type water-based paint compositions and preparation method thereof
CN109096835A (en) * 2018-08-28 2018-12-28 巢湖市兰天大诚门窗幕墙有限公司 Water-repellent paint for composite energy-saving door and window

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