CN106085036A - A kind of exterior wall functional paint - Google Patents
A kind of exterior wall functional paint Download PDFInfo
- Publication number
- CN106085036A CN106085036A CN201610756300.1A CN201610756300A CN106085036A CN 106085036 A CN106085036 A CN 106085036A CN 201610756300 A CN201610756300 A CN 201610756300A CN 106085036 A CN106085036 A CN 106085036A
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- China
- Prior art keywords
- component
- exterior wall
- parts
- functional paint
- agent
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention belongs to paint field, relate to a kind of exterior wall functional paint, including component A and B component, described component A includes the raw material of following weight portion: substrate emulsion 45 60 parts, glass microballoon 8 12 parts, titanium dioxide 7 10 parts, filler 7 12 parts, 8 13 parts of water, auxiliary agent 10 20 parts；Described substrate emulsion is the copolymer emulsion of fluoroolefins and vinyl acetate；Described filler is one or more in Kaolin, Pulvis Talci, calcium carbonate and one or both the mixture in nano tin dioxide and nanometer antimony oxide；B component includes water-based isocyanate and propylene glycol methyl ether acetate.The coating that the present invention provides uses specific substrate emulsion, and the proportioning of component each to coating is optimized design, obtained coating, having the coating of heat insulating reflecting function, high reflectance, uniformity is good, anti-settling function admirable, good adhesive force, each premium properties is stable, high-weatherability and resistance to water.
Description
Technical field
The invention belongs to paint field, relate to a kind of exterior wall functional paint.
Background technology
Exterior coating can be protected and be in, due to for years on end, the external wall among drenching with rain of exposing to the weather, it is necessary to have enough
Good resistance to water, weatherability, stain resistance and freeze-thaw resistance, guarantee has preferable decorative effect and durability.Not only
So, under the irradiation of the high radiation of the sun, building surface problem raises, and conducts heat to Indoor environment, strengthens
The operating pressure of the cooling systems such as air-conditioning, causes the too much consumption of the energy, and this is also accomplished by coating can heat insulation effect,
In recent years, Coating Market also occurs in that some reflective insulation material and manufacture methods, such as Patent No.
The Chinese invention patent of CN201410847454.2 is in heat-preservation building paint a kind of disclosed in 27 days July in 2016 and preparation side
Method, its composition includes: meerschaum, Qi Mian, periporate quartz, pottery fibre, bentonite, wetting agent, binding agent, distilled water, weight is divided
Number is: meerschaum 0.5-1.5, Qi cotton 3-10, periporate quartz 2-8, the fine 1-3 of pottery, bentonite 0.2-1, wetting agent 0.25-1, viscous
Mixture 5-12, distilled water 50-80；There is insulation, every cold effect, use coating of the present invention can reduce the thickness of wall and same
There is insulation, every cold effect, construction material can be greatly saved, coating heat transfer coefficient is excellent, and comprcssive strength is good, and frost resistance is good,
Not ftractureing indeformable-30 DEG C of freeze thawing, coating is thin, good energy-conserving effect, and component is not so thing, also has the effect of fire-proof sound insulation.
But mainly by controlling conduction of heat, effect of heat insulation is limited, and in use, the uniformity of coating is poor, and tack is paid no attention to
Think.
Summary of the invention
The present invention provides a kind of exterior wall functional paint, solves the drawbacks described above that exterior coating exists, has good
Reflective insulation performance, timeliness is longer, good evenness, and tack is good, and workability is stable.
In order to achieve the above object, the present invention adopts the following technical scheme that: a kind of exterior wall functional paint, including A group
Point and B component, described component A includes the raw material of following weight portion: substrate emulsion 45-60 part, glass microballoon 8-12 part, titanium dioxide
7-10 part, filler 7-12 part, water 8-13 part, auxiliary agent 10-20 part；Described substrate emulsion is the copolymer breast of fluoroolefins and vinyl acetate
Liquid；Described filler is one or more in Kaolin, Pulvis Talci, calcium carbonate and in nano tin dioxide and nanometer antimony oxide
Plant or the mixture of two kinds；B component includes water-based isocyanate and propylene glycol methyl ether acetate.
By implementing technique scheme, two component mating reactions of A, B, the solidification of coating and adhesion property can be had
It is obviously improved, maintains stablizing of heat insulating reflecting performance.Use specific substrate emulsion, under the common effect of filler, it is possible to protect
Holding the most stable effect of heat insulation, single component abandoned by the filler in scheme, is properly added nano tin dioxide, stibium oxide, energy
Enough it is obviously improved effect of heat insulation, moreover it is possible to improving uniformity and the anti-settling of coating, substrate emulsion coordinates with glass microballoon, it is ensured that
The reflecting properties of coating, after adding filler, reflecting properties more useful excellence.
As preferably, the weight ratio that described component A mixes with described B component is 5-8:1.
As preferably, the fluorinated volume of described substrate emulsion is 20-25%, and fluorinated volume is low, it is impossible to meet needs high temperature resistant with
Weather resistance, too high if, and inhibited between filler, instead effect of heat insulation reduces, the fluorinated volume model in the program
Enclose, compared with extraneous coating, there is more excellent high temperature resistant, chemical mediator and weather resistance, and this coating is in phase
Relatively low temperature and relatively short period of time be can be achieved with solidification, simplify execution conditions and technique, so that the painting of large area outdoor
Dress is possibly realized, and has significantly expanded the range of application of coating.
As preferably, the solid content of described substrate emulsion is 45-55%.
As preferably, described glass microballoon is hollow borosilicate glass microballon, and the particle diameter of described glass microballoon is 1-
25μm。
As preferably, described auxiliary agent include coalescents, levelling agent, thickening agent, wetting agent, dispersant and defoamer and
PH adjusting agent, described thickening agent is alkali swelling type thickening agent, and described coalescents is 3-ethoxyl ethyl propionate, described pH regulator
Agent is dimethylethanolamine.
Although the various auxiliary agents in such scheme are all the auxiliary agents can used in prior art, in order to ensure the comprehensive of coating
Performance, from various thickening agents, coalescents and pH adjusting agent, preferably alkali swelling type thickening agent, 3-ethoxyl ethyl propionate
And dimethylethanolamine, the performance of other component effect in scheme will not be had an inhibitory action, and with the substrate in scheme
Can there is more preferable facilitation between emulsion and filler, be conducive to improving further reflective insulation performance and the tack of coating
Energy.
As preferably, described dispersant is polycarboxylate sodium.
As preferably, described filler be Pulvis Talci, nano tin dioxide be the mixing that 1:3-5 is mixed to get according to weight ratio
Thing, this combination, obtained coating combination property is more stable.
As preferably, component A also includes Nano titanium dioxide 0.5-1 weight portion and nano zine oxide 0.5-1 weight
Part.
As preferably, component A also includes the propylene that solid content is 40-60% accounting for the 2-5% of described substrate emulsion weight
Acid resin solution.Add a small amount of acrylic resin, the stability of coating can be improved, also help promotion dispersion, improve and be coated with
The uniformity of material, improves the adhesion property of coating.
By implementing technique scheme, the coating that the present invention provides uses specific substrate emulsion, and to each group of coating
The proportioning divided is optimized design, obtained coating, has the coating of heat insulating reflecting function, high reflectance, and uniformity is good, anti-
Settling property is excellent, good adhesive force, and each premium properties is stable, high-weatherability and resistance to water.
Detailed description of the invention
Below by specific embodiment, the present invention is described in further detail.
Embodiment 1:
A kind of exterior wall functional paint, component A includes the raw material of following weight portion: substrate emulsion 45 parts, glass microballoon 12 parts, titanium
7 parts of white lead, filler 10 parts, 10 parts of water, auxiliary agent 10 parts (coalescents 7 parts, levelling agent 0.1 part, thickening agent 1.4 parts, wetting agent
0.5 part, dispersant 0.4 part and defoamer 0.1 part and pH adjusting agent 0.5 part)；Described substrate emulsion is fluoroolefins and vinyl acetate
Copolymer emulsion, fluorinated volume is 22%, and solid content is 45%；Described coalescents is 3-ethoxyl ethyl propionate；Levelling agent is
Silicone levelling agent；Dispersant is polycarboxylate sodium, and described thickening agent is alkali swelling type thickening agent, and described pH adjusting agent is two
Methylethanolamine.
B component includes 65 weight portion water-based isocyanates and 35 parts by weight of propylene glycol methyl ether acetates.
In component A, described filler is calcium carbonate and nanometer antimony oxide.
Embodiment 2:
A kind of exterior wall functional paint, including component A and B component, when coating uses, is used in mixed way with weight ratio for 5:1.
Component A includes the raw material of following weight portion: substrate emulsion 55 parts, glass microballoon 10 parts, titanium dioxide 8 parts, filler 7
Part, 8 parts of water, auxiliary agent 15 parts (coalescents 12.2 parts, levelling agent 0.3 part, thickening agent 0.5 part, wetting agent 0.7 part, dispersant
0.8 part and defoamer 0.2 part and pH adjusting agent 0.3 part), Nano titanium dioxide 0.5 part, nano zine oxide 0.5 part；Described
Substrate emulsion is the copolymer emulsion of fluoroolefins and vinyl acetate, and fluorinated volume is 20%, and solid content is 55%.
B component includes 70 weight portion water-based isocyanates and 30 parts by weight of propylene glycol methyl ether acetates.
In component A, filler be Pulvis Talci, nano tin dioxide be the mixture that 1:3 is mixed to get according to weight ratio；Described glass
Glass microballon is hollow borosilicate glass microballon, and the particle diameter of described glass microballoon is 1-15 μm；Described coalescents is 3-ethoxy
Base ethyl propionate；Levelling agent is silicone levelling agent；Dispersant is polycarboxylate sodium, and described thickening agent is alkali swelling type thickening
Agent, described pH adjusting agent is dimethylethanolamine.
Embodiment 3:
A kind of exterior wall functional paint, including component A and B component, when coating uses, is used in mixed way with weight ratio for 8:1.
Component A includes the raw material of following weight portion: substrate emulsion 45 parts, glass microballoon 12 parts, titanium dioxide 7 parts, filler 12
Part, 13 parts of water, auxiliary agent 20 parts (coalescents 15 parts, levelling agent 0.5 part, thickening agent 2.0 parts, wetting agent 1.0 parts, dispersant 0.5
Part and defoamer 0.2 part and pH adjusting agent 0.8 part), Nano titanium dioxide 1 part, nano zine oxide 1 part；Described substrate breast
Liquid is the copolymer emulsion of fluoroolefins and vinyl acetate, and fluorinated volume is 25%；Described coalescents is 3-ethoxyl ethyl propionate；Stream
Flat agent is silicone levelling agent；Dispersant is polycarboxylate sodium, and described thickening agent is alkali swelling type thickening agent, described pH regulator
Agent is dimethylethanolamine.
B component includes 75 weight portion water-based isocyanates and 25 parts by weight of propylene glycol methyl ether acetates.
In component A, described filler is the mass mixings such as calcium carbonate, Pulvis Talci, nanometer antimony oxide and nano tin dioxide.Described
Glass microballoon is hollow borosilicate glass microballon, and the particle diameter of described glass microballoon is 10-20 μm.
Embodiment 4:
A kind of exterior wall functional paint, including component A and B component, when coating uses, is used in mixed way with weight ratio for 8:1.
Component A includes the raw material of following weight portion: substrate emulsion 60 parts, glass microballoon 8 parts, titanium dioxide 10 parts, filler 12
Part, 13 parts of water, auxiliary agent 12 parts (coalescents 9 parts, levelling agent 0.1 part, thickening agent 1.4 parts, wetting agent 0.5 part, dispersant 0.4
Part and defoamer 0.1 part and pH adjusting agent 0.5 part), Nano titanium dioxide 0.8 part, nano zine oxide 1 part；Described substrate
Emulsion is the copolymer emulsion of fluoroolefins and vinyl acetate, and fluorinated volume is 20%, and solid content is 50%；Described coalescents is 3-ethoxy
Base ethyl propionate；Levelling agent is silicone levelling agent；Dispersant is polycarboxylate sodium, and described thickening agent is alkali swelling type thickening
Agent, described pH adjusting agent is dimethylethanolamine.
B component includes 68 weight portion water-based isocyanates and 32 parts by weight of propylene glycol methyl ether acetates.
In component A, described filler is Kaolin and the mass mixing such as calcium carbonate, nano tin dioxide.
Embodiment 5:
Different from embodiment 4 are, also include that the solid content accounting for the 2-5% of described substrate emulsion weight is 40-60% in component A
Acrylic resin soln, in the present embodiment, acrylic resin soln solid content is 55%, accounts for the 3% of substrate emulsion weight.
Claims (10)
1. an exterior wall functional paint, it is characterised in that include that component A and B component, described component A include following weight portion
Raw material: substrate emulsion 45-60 part, glass microballoon 8-12 part, titanium dioxide 7-10 part, filler 7-12 part, water 8-13 part, auxiliary agent
10-20 part；Described substrate emulsion is the copolymer emulsion of fluoroolefins and vinyl acetate；Described filler is Kaolin, Pulvis Talci, carbonic acid
One or more in calcium and one or both the mixture in nano tin dioxide and nanometer antimony oxide；B component includes aqueous
Isocyanates and propylene glycol methyl ether acetate.
A kind of exterior wall functional paint, it is characterised in that described component A mixes with described B component
Weight ratio be 5-8:1.
A kind of exterior wall functional paint, it is characterised in that the fluorinated volume of described substrate emulsion is
20-25%。
A kind of exterior wall functional paint, it is characterised in that the solid content of described substrate emulsion is
45-55%。
A kind of exterior wall functional paint, it is characterised in that described glass microballoon is hollow borosilicate
Silicate glass microballon, the particle diameter of described glass microballoon is 1-25 μm.
A kind of exterior wall functional paint, it is characterised in that described auxiliary agent includes coalescents, stream
Flat agent, thickening agent, wetting agent, dispersant and defoamer and pH adjusting agent, described thickening agent is alkali swelling type thickening agent, described
Coalescents is 3-ethoxyl ethyl propionate, and described pH adjusting agent is dimethylethanolamine.
A kind of exterior wall functional paint, it is characterised in that described dispersant is polycarboxylate sodium.
A kind of exterior wall functional paint, it is characterised in that described filler is Pulvis Talci, nano oxygen
Changing stannum is the mixture that 1:3-5 is mixed to get according to weight ratio.
A kind of exterior wall functional paint, it is characterised in that also include nanoscale dioxy in component A
Change titanium and nano zine oxide.
A kind of exterior wall functional paint, it is characterised in that also include in component A accounting for described substrate
The solid content of the 2-5% of emulsion weight is the acrylic resin soln of 40-60%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610756300.1A CN106085036A (en) | 2016-08-30 | 2016-08-30 | A kind of exterior wall functional paint |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610756300.1A CN106085036A (en) | 2016-08-30 | 2016-08-30 | A kind of exterior wall functional paint |
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| CN106085036A true CN106085036A (en) | 2016-11-09 |
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Family Applications (1)
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| CN201610756300.1A Pending CN106085036A (en) | 2016-08-30 | 2016-08-30 | A kind of exterior wall functional paint |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107345104A (en) * | 2017-07-31 | 2017-11-14 | 合肥泓定科技有限公司 | A kind of house interior wall thermal acoustic insulation coating and preparation method thereof |
| CN107400427A (en) * | 2017-07-31 | 2017-11-28 | 合肥泓定科技有限公司 | A kind of thermal acoustic insulation coating and preparation method thereof |
| CN107903732A (en) * | 2017-12-14 | 2018-04-13 | 莆田市涵江区初日化工有限公司 | A kind of light reflection insulating moulding coating and preparation method thereof |
| CN110003734A (en) * | 2019-03-08 | 2019-07-12 | 嘉宝莉化工集团股份有限公司 | A kind of extra-weather-proof, resistant aqueous double-component fluorine carbon building external paint and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107345104A (en) * | 2017-07-31 | 2017-11-14 | 合肥泓定科技有限公司 | A kind of house interior wall thermal acoustic insulation coating and preparation method thereof |
| CN107400427A (en) * | 2017-07-31 | 2017-11-28 | 合肥泓定科技有限公司 | A kind of thermal acoustic insulation coating and preparation method thereof |
| CN107903732A (en) * | 2017-12-14 | 2018-04-13 | 莆田市涵江区初日化工有限公司 | A kind of light reflection insulating moulding coating and preparation method thereof |
| CN110003734A (en) * | 2019-03-08 | 2019-07-12 | 嘉宝莉化工集团股份有限公司 | A kind of extra-weather-proof, resistant aqueous double-component fluorine carbon building external paint and preparation method thereof |
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Application publication date: 20161109 |