CN104031492B - A kind of aqueous elastic exterior coating and its preparation method - Google Patents

A kind of aqueous elastic exterior coating and its preparation method Download PDF

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Publication number
CN104031492B
CN104031492B CN201410191911.7A CN201410191911A CN104031492B CN 104031492 B CN104031492 B CN 104031492B CN 201410191911 A CN201410191911 A CN 201410191911A CN 104031492 B CN104031492 B CN 104031492B
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exterior coating
powder
ultrafine
aqueous elastic
elastic exterior
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CN104031492A (en
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郭文录
王超
丹媛媛
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Hebei Chenyang Industry and Trade Group Co Ltd
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Jiangsu University of Science and Technology
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Abstract

The present invention discloses a kind of aqueous elastic exterior coating and its preparation method, this coating by mass percentage by component: water is 0.5��2%, AP-261 pure-acrylic emulsion is 20��25%, A-100 elastic emulsion is 19��22%, propylene glycol frostproofer is 5��8%, film coalescence aid is 4��6%, it is 15��17% that CM-10120.0 joins carbon, superfine titanium white R-930 is 12��17%, ultrafine kaolin is 4��6%, ultrafine mica powder is 4��6%, ultra-fine calcite in powder is 4��6%, wetting agent AD-405 is 0.1��0.3%, thickening material TE-936 is 0.2��1.0%, dispersion agent DP-01 is 0.1��0.5%, Cognis sanitas is 0.1��0.3%, defoamer F-111 is 0.1��0.3% composition. it is good that the coating of the present invention has high-weatherability, high resistance to chemicals corrodibility, water tolerance, scrub resistance and artificial ageing resistance, has expressive force and enriches, and stereoscopic sensation is strong, snappiness, plasticity-is extremely strong, strong adhesion, and acid and alkali-resistance, does not fade, not playing skin, do not ftracture, maintenance is heavily coated with and is easy to advantage, preparation technology is simple, and cost is low, profitable.

Description

A kind of aqueous elastic exterior coating and its preparation method
Technical field
The invention belongs to technical field of paint preparation, it relates to a kind of building coating, more specifically relate to a kind of aqueous elastic exterior coating and its preparation method, be mainly used in building external paint.
Background technology
The most of buildings of current China take cement sand plaster as basic unit. But the natural characteristics due to cement-based material, when being subject to the such environmental effects such as temperature variation, alternation of wetting and drying, freeze-thaw cycle, often can produce crack, if its surface is decorated with common exterior coating, then coating can be caused also to produce cracking along with the crackle generation of basic unit and expansion; Along with gathering of time lengthening and above-mentioned destructive factor, crack can be strengthened further, deepen, and is had a negative impact by buildings and even endangers, and such as, when being subject to moisture attack, moisture can infiltrate in crack and internally permeate further; Except making crack expand further because of alternation of wetting and drying effect, also may cause inside concrete steel bar corrosion, even affect the using function of buildings, for another example, when being subject in air the sour gas such as carbonic acid gas and other corrosive gases corrodes, coating, internal water cement mortar and concrete can be produced corrosion by these corrosive gasess, make concrete carbonization, it is also possible to have influence on inside configuration reinforcing bar. At present, building surface crack is considered as the common fault of buildings and be caused extensive concern on building circle. Therefore, develop a kind of for the protection of with the thick-layer flexible paint keeping concrete exterior wall outward appearance, meaning and act on great.
Summary of the invention
It is an object of the invention to for above-mentioned prior art Problems existing and defect, it is provided that a kind of aqueous elastic exterior coating and its preparation method.
The coating of the present invention is except having required decorative effect, moreover it is possible to hides the capillary fracture of body of wall, prevents wall leakage and prevent concrete carbonization. Owing to concrete exterior wall can expand along with the change of envrionment temperature and shrink; the aqueous elastic exterior coating of the present invention also can expand along with this kind of body of wall and shrink and stretch and shrink; thus hide existing and potential distress in concrete; concrete construction can be protected to corrode from wind and rain, acid rain and frost, and the outward appearance of concrete construction and the integrity of internal structure can be protected. Coating is while having excellent unit elongation, it is also possible to repeatedly stretches and restores, covers crackle effectively lastingly.
It is good that the coating of the present invention has high-weatherability, high resistance to chemicals corrodibility, water tolerance, scrub resistance and artificial ageing resistance, has expressive force and enriches, and stereoscopic sensation is strong, snappiness, plasticity-is extremely strong, strong adhesion, acid and alkali-resistance, do not fade, not playing skin, do not ftracture, maintenance is heavily coated with the features such as easy, the favor being more and more subject to user, has good promotional value and development space.
In order to realize above-mentioned purpose, the technical scheme that the present invention takes is:
A kind of aqueous elastic exterior coating, by mass percentage by component: water is 0.5��2%, AP-261 pure-acrylic emulsion is 20��25%, A-100 elastic emulsion is 19��22%, propylene glycol frostproofer is 5��8%, film coalescence aid is 4��6%, it is 15��17% that CM-10120.0 joins carbon, superfine titanium white R-930 is 12��17%, ultrafine kaolin is 4��6%, ultrafine mica powder is 4��6%, ultra-fine calcite in powder is 4��6%, wetting agent AD-405 is 0.1��0.3%, thickening material TE-936 is 0.2��1.0%, dispersion agent DP-01 is 0.1��0.5%, Cognis sanitas is 0.1��0.3%, defoamer F-111 is 0.1��0.3% composition.
Water described above is tap water.
Film coalescence aid described above is TEXANOL alcohol ester 12.
The granularity of superfine titanium white described above, ultrafine kaolin, ultrafine mica powder and ultra-fine calcite in powder is 1250 orders sieves.
In order to realize above-mentioned purpose, another technical scheme that the present invention takes is:
The preparation method of the aqueous elastic exterior coating of the present invention, comprises the following steps:
1. press mass percentage formula, first by the water in component, AP-261 pure-acrylic emulsion, A-100 elastic emulsion, propylene glycol frostproofer, film coalescence aid TEXANOL alcohol ester 12, CM-10120.0 joins carbon and adds respectively in stirred pot, stirs 20��25 minutes with the rotating speed of 800��900r/min;
2. by formula consumption more respectively by superfine titanium white R-930, ultrafine kaolin, ultrafine mica powder, ultra-fine calcite in powder adds in stirred pot, continues stirring 30��35 minutes with the rotating speed of 2500��3000r/min; Adding wetting agent AD-405 more respectively, thickening material TE-936, dispersion agent DP-01, Cognis sanitas, defoamer F-111 continues stirring 20��25 minutes, namely obtains aqueous elastic exterior coating.
The aqueous elastic exterior coating of the present invention and the advantage of its preparation method and useful effect:
1, to have high-weatherability, high resistance to chemicals corrodibility, water tolerance, scrub resistance and artificial ageing resistance good for the coating of the present invention, has expressive force and enriches, and stereoscopic sensation is strong, snappiness, plasticity-is extremely strong, strong adhesion, and acid and alkali-resistance, does not fade, not playing skin, do not ftracture, maintenance is heavily coated with and is easy to advantage.
2, preparation method's technique of the present invention is simple, and cost is low, profitable.
Embodiment
The technical scheme of the present invention is further described below in conjunction with specific examples.
The source of each component: water (local tap water), AP-261 pure-acrylic emulsion (product of permanent profit Chemical Manufacture), A-100 elastic emulsion (product that Shanghai Zhen Zhou chemistry painting industry company limited produces), propylene glycol frostproofer (product that Jinan Ju You Chemical Co., Ltd. produces), film coalescence aid TEXANOL alcohol ester 12 (product that U.S. EASTMAN Yi Shiman produces), CM-10120.0 joins carbon (product that Shenzhen Lian Tan Chemical Co., Ltd. produces), superfine titanium white R-930 (1250 order) (product that Japan produces), ultrafine kaolin (1250 order) (product that Yangzhou Di Lan industrial chemicals company limited produces), ultrafine mica powder (1250 order) (product that Lingshou County, Shijiazhuang, Hebei micacization company limited produces), , ultra-fine calcite in powder (1250 order) (product that Zibo Ling Fei Trade Co., Ltd. produces), wetting agent AD-405 (product that Guangzhou Ang Di Chemical Co., Ltd. produces), thickening material TE-936 (product that Beijing East Chemical Co., Ltd. produces), dispersion agent DP-01 (product that Beijing East Chemical Co., Ltd. produces), Cognis sanitas (product that Ke Ning chemical company of Germany produces), defoamer F-111 (product that Shanghai Bei Qingli industry development company limited produces).
Embodiment 1
One, content formula by mass percentage
Two, preparation method
1. press mass percentage formula, first by the water in component, AP-261 pure-acrylic emulsion, A-100 elastic emulsion, propylene glycol frostproofer, film coalescence aid TEXANOL alcohol ester 12, CM-10120.0 joins carbon and adds respectively in stirred pot, stirs 20��25 minutes with the rotating speed of 800��900r/min;
2. by formula consumption more respectively by superfine titanium white R-930, ultrafine kaolin, ultrafine mica powder, ultra-fine calcite in powder adds in stirred pot, continues stirring 30��35 minutes with the rotating speed of 2500��3000r/min; Adding wetting agent AD-405 more respectively, thickening material TE-936, dispersion agent DP-01, sanitas, defoamer F-111 continues stirring 20��25 minutes, namely obtains aqueous elastic exterior coating.
Three, useful effect
Table 1 is a kind of aqueous elastic exterior coating service check result of embodiment 1
Embodiment 2
One, content formula by mass percentage
Two, preparation method is with embodiment 1
Three, useful effect
Table 2 is embodiment 2 one kinds of aqueous elastic exterior coating service check results
Embodiment 3
One, content formula by mass percentage
Two, preparation method is with embodiment 1
Three, useful effect
Table 3 is embodiment 3 one kinds of aqueous elastic exterior coating service check results
Embodiment 4
One, content formula by mass percentage
Two, preparation method is with embodiment 1
Three, useful effect
Table 4 is embodiment 4 one kinds of aqueous elastic exterior coating service check results
Embodiment 5
One, content formula by mass percentage
Two, preparation method is with embodiment 1
Three, useful effect
Table 5 is embodiment 5 one kinds of aqueous elastic exterior coating service check results
In sum, the present invention prepares the aqueous elastic exterior coating, and has high-weatherability, high resistance to chemicals corrodibility, water tolerance, scrub resistance and artificial ageing resistance good, there is expressive force enrich, stereoscopic sensation is strong, snappiness, and plasticity-is extremely strong, strong adhesion, acid and alkali-resistance, does not fade, and does not play skin, not ftractureing, maintenance is heavily coated with the advantages such as easy. There is certain social benefit, economic benefit and using value, have good development prospect.

Claims (5)

1. an aqueous elastic exterior coating, it is characterized in that, by mass percentage by component: water is 0.5��2%, AP-261 pure-acrylic emulsion is 20��25%, A-100 elastic emulsion is 19��22%, propylene glycol frostproofer is 5��8%, film coalescence aid is 4��6%, it is 15��17% that CM-10120.0 joins carbon, superfine titanium white R-930 is 12��17%, ultrafine kaolin is 4��6%, ultrafine mica powder is 4��6%, ultra-fine calcite in powder is 4��6%, wetting agent AD-405 is 0.1��0.3%, thickening material TE-936 is 0.2��1.0%, dispersion agent DP-01 is 0.1��0.5%, Cognis sanitas is 0.1��0.3%, defoamer F-111 is 0.1��0.3% composition.
2. aqueous elastic exterior coating according to claim 1, it is characterised in that, described water is tap water.
3. aqueous elastic exterior coating according to claim 1, it is characterised in that, described film coalescence aid is TEXANOL alcohol ester 12.
4. aqueous elastic exterior coating according to claim 1, it is characterised in that, the granularity of described superfine titanium white, ultrafine kaolin, ultrafine mica powder and ultra-fine calcite in powder is 1250 orders sieves.
5. the preparation method according to the arbitrary described aqueous elastic exterior coating of Claims 1 to 4, it is characterised in that, comprise the following steps:
(1). by mass percentage formula, first by the water in component, AP-261 pure-acrylic emulsion, A-100 elastic emulsion, propylene glycol frostproofer, film coalescence aid TEXANOL alcohol ester 12, CM-10120.0 joins carbon and adds respectively in stirred pot, stirs 20��25 minutes with the rotating speed of 800��900r/min;
(2). by formula consumption more respectively by superfine titanium white R-930, ultrafine kaolin, ultrafine mica powder, ultra-fine calcite in powder adds in stirred pot, continues stirring 30��35 minutes with the rotating speed of 2500��3000r/min; Adding wetting agent AD-405 more respectively, thickening material TE-936, dispersion agent DP-01, Cognis sanitas, defoamer F-111 continues stirring 20��25 minutes, namely obtains aqueous elastic exterior coating.
CN201410191911.7A 2014-05-07 2014-05-07 A kind of aqueous elastic exterior coating and its preparation method Active CN104031492B (en)

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Publication number Priority date Publication date Assignee Title
CN104761988A (en) * 2015-03-25 2015-07-08 田福东 High-elasticity exterior wall coating
CN106189614A (en) * 2016-07-19 2016-12-07 芜湖昊轩环保新材料有限公司 Elastic exterior coating material and preparation method thereof

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CN1456614A (en) * 2002-05-09 2003-11-19 吉林科龙装饰工程有限公司 Low-temperature resistant coating and preparing method thereof
CN101818012A (en) * 2009-02-26 2010-09-01 北京东方雨虹防水技术股份有限公司 Elastic exterior coating material
CN102888190A (en) * 2012-09-18 2013-01-23 张立功 Pitch angle variable structure of vertical axis wind-driven generating system and control method

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US20060069198A1 (en) * 2003-06-30 2006-03-30 Nissin Chemical Industry Co., Ltd. Building exterior wall-coating emulsion compositions and building exterior walls

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CN1456614A (en) * 2002-05-09 2003-11-19 吉林科龙装饰工程有限公司 Low-temperature resistant coating and preparing method thereof
CN101818012A (en) * 2009-02-26 2010-09-01 北京东方雨虹防水技术股份有限公司 Elastic exterior coating material
CN102888190A (en) * 2012-09-18 2013-01-23 张立功 Pitch angle variable structure of vertical axis wind-driven generating system and control method

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