CN103992729A - Reinforcing agent for crisp powder ceramic painted cultural relic - Google Patents
Reinforcing agent for crisp powder ceramic painted cultural relic Download PDFInfo
- Publication number
- CN103992729A CN103992729A CN201410190654.5A CN201410190654A CN103992729A CN 103992729 A CN103992729 A CN 103992729A CN 201410190654 A CN201410190654 A CN 201410190654A CN 103992729 A CN103992729 A CN 103992729A
- Authority
- CN
- China
- Prior art keywords
- crisp powder
- crisp
- ceramic
- painted
- reinforcing agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a reinforcing agent for a crisp powder ceramic painted cultural relic. The reinforcing agent comprises, by mass, 6.0%-10.0% of ADM-Z719 waterborne polyurethane resin, 0.3%-1.0% of ZB-F600 bi-component FEVE waterborne fluroresin, 1.0%-3.0% of water soluble epoxy resin B-63, 1.0%-3.0% of C8-10 fatty alcohol-polyoxyethylene ether JFC-6, 2.0%-5.0% of ethanol, 10.0%-20.0% of distilled water, and 65.0%-75.0% methanol. The reinforcing agent provided by the invention has good thermal stability, not only can reinforce the painted layer of the ceramic painted cultural relic, but also can reinforce the ceramic tire. The reinforced painted layer has a primitively simple appearance, small color difference change, strong water resistance, and simple implementation process, significant strengthening effect, so that it can be used for reinforcing a crisp powder pottery crisp powder layer and makes good basis preparation for subsequent desalination.
Description
Technical field
The invention belongs to ceramic colored drawing Techniques of Relics Protection field, be specifically related to the strengthening agent of the crisp bisque of a kind of ceramic colored drawing historical relic (containing pottery tire and painted layer).
Background technology
Ceramic colored drawing historical relic is precious, is carrying very important artistic value and historical information.In the crisp powder ceramic of salt damage colored drawing historical relic (containing colored drawing pottery, pottery figurine, pottery horse), removing of soluble salt is the difficult problem that historical relic's protection field is outstanding for a long time.The phenomenons such as after the ceramic colored drawing historical relic in the dynasties such as a large amount of precious Han dynastys, the Tang Dynasty is unearthed, owing to himself containing solubility and slightly soluble salt, through the impact of external environment, painted layer occurs serious be full of cracks, comes off, crisp powder; Also there is the phenomenon that crisp powder comes off in severe patient pottery tire more, thereby make the original appearance of precious ceramic colored drawing historical relic be subject to havoc, is on the verge of to destroy, and even forever disappears.Therefore the salinity, removing in ceramic colored drawing historical relic painted layer and pottery tire is extremely urgent.
In order thoroughly to solve crisp powder problem, must consider pottery to carry out desalting treatment.This just requires the strengthening agent not only can closure painted layer, also must have suitable pore texture.Although recorded the reinforcement protection of a lot of reinforcement protecting materials to ceramic colored drawing historical relic on pertinent literature, seldom related to the reinforcing of the ceramic colored drawing historical relic of serious crisp powder and the comprehensive regulation of desalination.Therefore, in complete maintenance ceramic colored drawing cultural artifact surface colored drawing original appearance, particularly keep under the precondition of hollowing, be full of cracks, crisp powder painted layer original appearance, to its crisp bisque reinforce and desalination difficulty very big.If to occurring the direct desalination of ceramic colored drawing historical relic of hollowing, be full of cracks, crisp powder disease, can make the precious information such as colored drawing forever disappear.Therefore, first must solidify the painted layer of the crisp powder of ceramic colored drawing cultural artifact surface and the tire of making pottery by strengthening agent permeable with having, saturating salt functional.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of strengthening agent permeable, saturating salt functional that has, for the reinforcing of the crisp bisque of ceramic colored drawing historical relic.
Solving the problems of the technologies described above adopted technical scheme and be this strengthening agent is comprised of the raw material of following quality per distribution ratio:
Above-mentioned crisp powder ceramic colored drawing historical relic strengthening agent is preferably comprised of the raw material of following quality per distribution ratio:
Above-mentioned ADM-Z719 waterborne polyurethane resin is produced by the U.S. macromolecular material of Shandong Order company limited, the two component FEVE water-based fluororesins of ZB-F600 are sold by Zhenbang Fluorine-coating Co., Ltd., Dalian, water-soluble epoxy resin B-63 is produced by blue star novel material Wuxi resin processing plant, and C8-10 fatty alcohol-polyoxyethylene ether JFC-6 is provided by Linyi, Shandong Lv Sen Chemical Co., Ltd..
The preparation method of above-mentioned crisp powder ceramic colored drawing historical relic strengthening agent is: according to the quality per distribution ratio of above-mentioned raw materials, ADM-Z719 waterborne polyurethane resin, the two component FEVE water-based fluororesins of ZB-F600, water-soluble epoxy resin B-63 are dissolved in distilled water, C8-10 fatty alcohol-polyoxyethylene ether JFC-6 is dissolved in ethanol, then even with methanol mixed, obtain crisp powder ceramic colored drawing historical relic strengthening agent.
The using method of above-mentioned crisp powder ceramic colored drawing historical relic strengthening agent is: strengthening agent is dripped in the ceramic colored drawing cultural artifact surface by methyl alcohol complete wetting, after surface is completely air-dry, at ceramic colored drawing cultural artifact surface, smear the strengthening agent after diluting a times with methyl alcohol again, repeatedly smear 3～5 times, obtain the ceramic colored drawing historical relic of reinforcing.
In strengthening agent of the present invention, contained ADM-Z709 waterborne polyurethane resin has the advantages such as water-fast, good film-forming property, painted layer is had to stronger closure ability, and high temperature resistant, strong adhesion, especially anti-ultraviolet ageing performance is outstanding, non-yellowing after 72 hours at ultraviolet ageing, but ADM-Z709 waterborne polyurethane resin is when as the single use of strengthening agent, perviousness is poor, be difficult to the deep crisp bisque that penetrates into colored drawing pottery pottery tire, and after film forming, do not possess good pore structure, the soluble salt of pottery inside cannot be separated out smoothly.By after ADM-Z709 waterborne polyurethane resin and the two component FEVE water-based fluororesin blend of ZB-F600, not only weathering resistance is strong, but also snappiness, the perviousness of strengthening agent have been improved, strengthening agent is reinforced pottery tire again in the crisp powder painted layer of closure, also improved the aperture after single ADM-Z709 waterborne polyurethane resin film forming simultaneously, can improve the speed that in subsequent technique, soluble salt is separated out from pottery surface to a great extent, for follow-up desalination, carry out basis and prepare.Water-soluble epoxy resin B-63 has improved the snappiness after strengthening agent film forming, permeate agent C8-10 fatty alcohol-polyoxyethylene ether JFC-6 has increased the penetrating power of strengthening agent, make strengthening agent of the present invention not only reinforce the crisp bisque of pottery, painted layer original appearance after its processing is simple and unsophisticated, chromatic aberration is little, and implementing process is simple, and consolidation effect is remarkable, can be used for the reinforcing of the crisp bisque of crisp powder pottery, and carried out basic preparation for follow-up desalination.
Accompanying drawing explanation
Fig. 1 is the thermogravimetric analysis figure after crisp powder analog sample is reinforced.
Fig. 2 is the super depth-of-field microscope photo before crisp powder analog sample is reinforced.
Fig. 3 is the super depth-of-field microscope photo after crisp powder analog sample is reinforced.
Fig. 4 is the reflecting rate graphic representation before and after crisp powder analog sample is reinforced.
Fig. 5 is effect contrast figure before and after crisp powder analog sample is reinforced.
Fig. 6 is the effect contrast figure after the crisp powder analog sample in Fig. 5 soaks in water.
Embodiment
Below in conjunction with drawings and Examples, the present invention is described in more detail, but protection scope of the present invention is not limited only to these embodiment.
Embodiment 1
The crisp powder ceramic of the preparation 1000g colored drawing historical relic strengthening agent of take is example, raw materials used and quality is composed as follows:
Its preparation method is: 85g ADM-Z719 waterborne polyurethane resin, the two component FEVE water-based fluororesins of 5g ZB-F600,20g water-soluble epoxy resin B-63 are dissolved in 145g distilled water, 15g C8-10 fatty alcohol-polyoxyethylene ether JFC-6 is dissolved in 30g ethanol, then two kinds of solution and 700g methanol mixed are even, obtain crisp powder ceramic colored drawing historical relic strengthening agent.
Embodiment 2
The crisp powder ceramic of the preparation 1000g colored drawing historical relic strengthening agent of take is example, raw materials used and quality is composed as follows:
Its preparation method is identical with embodiment 1.
Embodiment 3
The crisp powder ceramic of the preparation 1000g colored drawing historical relic strengthening agent of take is example, raw materials used and quality is composed as follows:
Its preparation method is identical with embodiment 1.
In order to prove beneficial effect of the present invention, contriver has carried out heat stability testing to the strengthening agent of embodiment 1 preparation, and adopt the strengthening agent of embodiment 1 preparation to reinforce the crisp powder analog sample of ceramic colored drawing historical relic, and the sample before and after reinforcing has been carried out to various signs, particular case is as follows:
1, the thermostability of strengthening agent
The paint film that 9.6mg strengthening agent is become is put into Q1000DSC+LNCS+FACSQ600SDT Thermo System tester, carries out the measurement of decomposition temperature.Test result is shown in Fig. 1.By Fig. 1, can clearly be found out, the film becoming at 300 ℃ of left and right strengthening agents starts to decompose, and at 460 ℃, decomposes completely, illustrates that strengthening agent of the present invention has good thermotolerance.
2, the variation of crisp powder analog sample surface topography
Crisp powder analog sample before and after reinforcing is put under the digital super depth-of-field microscope of VHX-600 (Keyemce international trade (Shanghai) Co., Ltd.) successively, and regulating magnification is 100 times, observes surface topography and contrasts.Comparing result by Fig. 2 and Fig. 3 can find out, the crisp powder analog sample surface ratio before reinforcing is more coarse, and crisp powder analog sample surface smoother after reinforcing shows that strengthening agent of the present invention has good filling effect and certain levelling property.
3, crisp powder analog sample is reinforced the variation of front and back optical property
(1) crisp powder analog sample is reinforced front and back color difference analysis
Utilize X-RiteVS-450 spectrophotometer to test respectively four crisp powder analog samples of difference and reinforce the value of chromatism of front and back, and assess according to the visual evaluation > > standard of standards of American society of test materials ASTM D1729-89 < < opaque material aberration.The results are shown in Table 1.
The crisp powder analog sample of table 1 is reinforced front and back chromatic aberration
Chromatic aberration by table 1 can be found out, crisp powder analog sample value of chromatism before and after reinforcing is all less than 5 CIELAB units, the standard that meets the visual evaluation > > of standards of American society of test materials ASTM D1729-89 < < opaque material aberration, shows that strengthening agent of the present invention is less on the color impact of ceramic colored drawing.
(2) crisp powder analog sample is reinforced front and back reflecting rate tracing analysis
Adopt X-RiteVS-450 spectrophotometer to carry out reflecting rate test to the crisp powder analog sample before and after reinforcing, the results are shown in Figure 4.As seen from the figure, the reflecting rate that crisp powder analog sample is reinforced rear surface colored drawing is starkly lower than the reflecting rate that crisp powder analog sample is reinforced front surface colored drawing, the crisp powder analog sample color after reinforcing is deepened to some extent, and the chromatic aberration of crisp powder analog sample reinforcing front and back shows that the colour-change of the crisp powder analog sample in reinforcing front and back is less, therefore illustrate that strengthening agent of the present invention has certain reinforcing to manifest effect.
4, the aging front and back of colored drawing breadboard sticking power changes
Cinnabar is evenly coated on tinplate, a part of model is wherein reinforced with strengthening agent, a part is not done any processing in addition, then carry out weathering test, ultraviolet ageing method: sample is put into ultraviolet light and aging proofing box, ultraviolet lamp power is 60W, and vertical irradiation distance is 5cm, ultraviolet ageing 72 hours; Xeothermic aging method: sample is put into the xeothermic weatherometer of BHO-401A, and 105 ± 5 ℃ xeothermic aging 72 hours; Hydrothermal aging method: sample is put into German Binder growth cabinet KBF series hydrothermal aging instrument, is under 85%RH condition in relative humidity, 100 ± 5 ℃ of hydrothermal agings 72 hours; Freeze thawing aging method: sample is put into freezing and thawing test case, and setting high temperature is 40 ℃, low temperature is-40 ℃, 12 hours is 1 circulation, totally six circulations.
According to the paint film adhesion testing method of standard GB/T/T1720-79 (89) < < paint film adhesion assay method > > regulation, the sticking power of aging front and back sample is tested, be the results are shown in Table 2～5.
Sticking power test result before and after table 2 ultraviolet ageing
The sticking power test result of the xeothermic aging front and back of table 3
Sticking power test result before and after table 4 hydrothermal aging
The sticking power test result of the aging front and back of table 5 freeze thawing
From table 2～5, the sticking power of colored drawing on unguyed model after overaging is all greater than 6 grades, sticking power is the poorest, and the sticking power of the colored drawing on model after overaging is all less than 3 grades after reinforcing, sticking power is better, meets the requirement in standard GB/T/T1720-79 (89) < < paint film adhesion assay method > >.Illustrate that strengthening agent of the present invention has good ageing resistance.
5, crisp powder analog sample is reinforced rear surface hydrophilic and hydrophobic test
Adopt OCA20 type video optics contact angle instrument (German Dataphysics company) to measure the contact angle that crisp powder analog sample is reinforced rear surface, test result shows, the contact angle on the crisp powder analog sample surface after reinforcing is 82.5 °, illustrate that strengthening agent of the present invention is not very strong to the affinity of moisture, this just provides one " buffering " to prepare for the desalinating process of follow-up ceramic colored drawing historical relic, in order to avoid follow-up demineralising process is impacted.
6, crisp powder analog sample is reinforced front and back water tolerance contrast
By crisp powder analog sample, half reinforces (seeing left one side of something in Fig. 5) with strengthening agent, and second half does not do any processing (seeing right one side of something in Fig. 5), then in water, soaks 24 hours, takes out with brush and carries out surface brushing.As seen from Figure 6, after the unconsolidated regions of crisp powder analog sample is soaked in water, crisp powder position comes off completely, and reinforcing area does not change, and illustrates that strengthening agent of the present invention has good penetration reinforcement effect and water resistance to crisp powder position.
Claims (2)
1. a crisp powder ceramic colored drawing historical relic strengthening agent, is characterized in that it is comprised of the raw material of following quality per distribution ratio:
2. crisp powder ceramic colored drawing historical relic strengthening agent according to claim 1, is characterized in that it is comprised of the raw material of following quality per distribution ratio:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410190654.5A CN103992729B (en) | 2014-05-07 | 2014-05-07 | Reinforcing agent for crisp powder ceramic painted cultural relic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410190654.5A CN103992729B (en) | 2014-05-07 | 2014-05-07 | Reinforcing agent for crisp powder ceramic painted cultural relic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103992729A true CN103992729A (en) | 2014-08-20 |
| CN103992729B CN103992729B (en) | 2015-06-17 |
Family
ID=51307079
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410190654.5A Expired - Fee Related CN103992729B (en) | 2014-05-07 | 2014-05-07 | Reinforcing agent for crisp powder ceramic painted cultural relic |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103992729B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104356839A (en) * | 2014-10-23 | 2015-02-18 | 西北大学 | Anti-light-ageing reinforcement material of colored relics and preparation method of reinforcement material |
| CN105647289A (en) * | 2015-07-17 | 2016-06-08 | 苏州吉人高新材料股份有限公司 | Ceramic painted relic reinforcing paint and preparation method thereof |
| CN110157200A (en) * | 2019-05-24 | 2019-08-23 | 陕西师范大学 | A kind of coat of colo(u)r strengthening agent based on Modify bone glue |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101186766A (en) * | 2006-11-16 | 2008-05-28 | 国家纳米技术与工程研究院 | Masking liquid for protecting stone cultural artifact and using method thereof |
| CN101608083A (en) * | 2009-07-30 | 2009-12-23 | 陕西师范大学 | Sizing color painting reattachment restoration agent for ceramic relics |
| CN103570280A (en) * | 2013-01-11 | 2014-02-12 | 中国科学院上海硅酸盐研究所 | Preparation method and reinforcement method of crispy powder ceramic culture relic reinforcement material |
-
2014
- 2014-05-07 CN CN201410190654.5A patent/CN103992729B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101186766A (en) * | 2006-11-16 | 2008-05-28 | 国家纳米技术与工程研究院 | Masking liquid for protecting stone cultural artifact and using method thereof |
| CN101608083A (en) * | 2009-07-30 | 2009-12-23 | 陕西师范大学 | Sizing color painting reattachment restoration agent for ceramic relics |
| CN103570280A (en) * | 2013-01-11 | 2014-02-12 | 中国科学院上海硅酸盐研究所 | Preparation method and reinforcement method of crispy powder ceramic culture relic reinforcement material |
Non-Patent Citations (1)
| Title |
|---|
| 范陶峰: "汉代文物彩绘的保护与回帖修复研究", 《中国优秀硕士学位论文全文数据库》 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104356839A (en) * | 2014-10-23 | 2015-02-18 | 西北大学 | Anti-light-ageing reinforcement material of colored relics and preparation method of reinforcement material |
| CN105647289A (en) * | 2015-07-17 | 2016-06-08 | 苏州吉人高新材料股份有限公司 | Ceramic painted relic reinforcing paint and preparation method thereof |
| CN105647289B (en) * | 2015-07-17 | 2018-08-31 | 苏州吉人高新材料股份有限公司 | A kind of ceramic polychrome cultural relics doped coating and preparation method thereof |
| CN110157200A (en) * | 2019-05-24 | 2019-08-23 | 陕西师范大学 | A kind of coat of colo(u)r strengthening agent based on Modify bone glue |
| CN110157200B (en) * | 2019-05-24 | 2021-04-20 | 陕西师范大学 | Pigment layer reinforcing agent based on modified bone glue |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103992729B (en) | 2015-06-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103992729B (en) | Reinforcing agent for crisp powder ceramic painted cultural relic | |
| CN103992136B (en) | A kind of reinforcing of crisp powder ceramic colored drawing historical relic and desalting method | |
| CN103451700A (en) | Sealing agent for micro-arc oxidation film | |
| CN104404487A (en) | Passivator and preparation method thereof | |
| JPS60501846A (en) | Synthetic preservatives and their manufacturing method | |
| CN104119800A (en) | Special-effect heath indoor wall aqueous paint composition and preparation method thereof | |
| Joniak et al. | Degradation of the recreational functions of urban lake: A preliminary evaluation of water turbidity and light availability (Strzeszyńskie Lake, Western Poland) | |
| CN104277677B (en) | One kind is aqueous to exempt from the golden magnetic oil of glazing and its manufacture craft | |
| CN103360889B (en) | Stone matter colored drawing strengthening agent | |
| CN103204703B (en) | Application of ZB-F600 two-component FEVE aqueous fluororesin in pretreatment of damage-prone pottery decorated with colored drawing before restoration | |
| CN103694896B (en) | A kind of self-drying type illusion-colour variable color raw lacquer coating and modulator approach | |
| Salim | A comparative experimental study of the use of toluene and isopropyl alcohol gel in cleaning wax stains from paper supports | |
| CN106608717A (en) | Thick knife-coated sand-textured building paint and preparation method thereof | |
| Venkatachalapathy et al. | Diatoms community structure in relation to physico-chemical factors in Yercaud Lake, Salem District, Tamil Nadu, India | |
| CN106916272A (en) | Material of fragile organic matter historical relic and its preparation method and application is reinforced under a kind of wet environment | |
| CN103102750B (en) | Application of ZB-F600 two-component FEVE water-based fluororesin in repair of silk and paper cultural relic writings and drawings | |
| Aquino-Cruz et al. | Studies on picophytoplankton in the southern Gulf of Mexico: recognition of picoprokaryotes and abundances of picophytoplankton during" dry season" | |
| CN103669112B (en) | Method for removing back lead of ancient and old paintings | |
| CN105440926A (en) | Children antibacterial anti-scratching furniture and preparation method thereof | |
| CN105647289B (en) | A kind of ceramic polychrome cultural relics doped coating and preparation method thereof | |
| CN111607288A (en) | Casein type water-based pigment yellow ink-jet ink for titanium white paper and preparation method thereof | |
| Silva et al. | New species of the genus Encyonema (Cymbellales, Bacillariophyta) from the Descoberto River Basin, Central-western Brazil | |
| CN105969036B (en) | A kind of erasable metallic paint and preparation method thereof | |
| Banens | Occurrence of hypolimnetic blooms of the purple sulfur bacterium, Thiopedia rosea, and the green sulfur bacterium, Chlorobium limicola, in an australian reservoir | |
| JP6384717B2 (en) | Concrete coloring agent, concrete coloring method, concrete and concrete structure |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150617 |