CN103992729B - Reinforcing agent for crisp powder ceramic painted cultural relic - Google Patents
Reinforcing agent for crisp powder ceramic painted cultural relic Download PDFInfo
- Publication number
- CN103992729B CN103992729B CN201410190654.5A CN201410190654A CN103992729B CN 103992729 B CN103992729 B CN 103992729B CN 201410190654 A CN201410190654 A CN 201410190654A CN 103992729 B CN103992729 B CN 103992729B
- Authority
- CN
- China
- Prior art keywords
- crisp powder
- crisp
- painted
- reinforcing agent
- ceramic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a reinforcing agent for a crisp powder ceramic painted cultural relic. The reinforcing agent comprises, by mass, 6.0%-10.0% of ADM-Z719 waterborne polyurethane resin, 0.3%-1.0% of ZB-F600 bi-component FEVE waterborne fluroresin, 1.0%-3.0% of water soluble epoxy resin B-63, 1.0%-3.0% of C8-10 fatty alcohol-polyoxyethylene ether JFC-6, 2.0%-5.0% of ethanol, 10.0%-20.0% of distilled water, and 65.0%-75.0% methanol. The reinforcing agent provided by the invention has good thermal stability, not only can reinforce the painted layer of the ceramic painted cultural relic, but also can reinforce the ceramic tire. The reinforced painted layer has a primitively simple appearance, small color difference change, strong water resistance, and simple implementation process, significant strengthening effect, so that it can be used for reinforcing a crisp powder pottery crisp powder layer and makes good basis preparation for subsequent desalination.
Description
Technical field
The invention belongs to ceramic colored drawing Techniques of Relics Protection field, be specifically related to the strengthening agent of the crisp bisque of a kind of ceramic colored drawing historical relic (containing pottery tire and painted layer).
Background technology
Ceramic colored drawing historical relic is precious, carries very important artistic value and historical information.In crisp powder ceramic colored drawing historical relic (containing colored drawing pottery, pottery figurine, pottery horse) of salt damage, removing of soluble salt is the difficult problem that historical relic's protection field is outstanding for a long time.After the ceramic colored drawing historical relic in the dynasty such as Han dynasty, the Tang Dynasty of a large amount of preciousness is unearthed, owing to himself containing solubility and slightly soluble salt, through the impact of external environment, the phenomenons such as painted layer occurs serious be full of cracks, comes off, crisp powder; More also there is the phenomenon that crisp powder comes off in severe patient pottery tire, thus make the original appearance of precious ceramic colored drawing historical relic be subject to havoc, is on the verge of to destroy, even forever disappears.Therefore, the salinity removed in ceramic colored drawing historical relic painted layer and pottery tire is extremely urgent.
In order to thoroughly solve crisp powder problem, must consider to carry out desalting treatment to pottery.This just requires that strengthening agent not only can closure painted layer, also must have suitable pore texture.Although pertinent literature describes the reinforcement protection of a lot of reinforcement protecting material to ceramic colored drawing historical relic, seldom relate to the reinforcing of ceramic colored drawing historical relic to serious crisp powder and the comprehensive regulation of desalination.Therefore, in complete maintenance ceramic colored drawing cultural artifact surface colored drawing original appearance, under particularly keeping the precondition of hollowing, be full of cracks, crisp powder painted layer original appearance, its crisp bisque is reinforced and desalination difficulty very big.If to the direct desalination of ceramic colored drawing historical relic occurring hollowing, be full of cracks, crisp powder disease, the information such as precious colored drawing can be made forever to disappear.Therefore, the strengthening agent with permeable, saturating salt functional first must be used to solidify painted layer and the pottery tire of the crisp powder of ceramic colored drawing cultural artifact surface.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of strengthening agent with permeable, saturating salt functional, for the reinforcing of the crisp bisque of ceramic colored drawing historical relic.
Solving the problems of the technologies described above adopted technical scheme is that this strengthening agent is made up of the raw material of following percent mass proportioning:
Above-mentioned crisp powder ceramic colored drawing historical relic strengthening agent is preferably made up of the raw material of following percent mass proportioning:
Above-mentioned ADM-Z719 waterborne polyurethane resin is produced by the U.S. macromolecular material company limited of Shandong Order, the two component FEVE water-based fluororesin of ZB-F600 is sold by Zhenbang Fluorine-coating Co., Ltd., Dalian, water-soluble epoxy resin B-63 is produced by blue star novel material Wuxi resin processing plant, and C8-10 fatty alcohol-polyoxyethylene ether JFC-6 is provided by Linyi, Shandong Lv Sen Chemical Co., Ltd..
The preparation method of above-mentioned crisp powder ceramic colored drawing historical relic strengthening agent is: according to the percent mass proportioning of above-mentioned raw materials, ADM-Z719 waterborne polyurethane resin, the two component FEVE water-based fluororesin of ZB-F600, water-soluble epoxy resin B-63 are dissolved in distilled water, C8-10 fatty alcohol-polyoxyethylene ether JFC-6 is dissolved in ethanol, then even with methanol mixed, obtain crisp powder ceramic colored drawing historical relic strengthening agent.
The using method of above-mentioned crisp powder ceramic colored drawing historical relic strengthening agent is: dripped by strengthening agent in the ceramic colored drawing cultural artifact surface by methyl alcohol complete wetting, after surface is completely air-dry, smear with the strengthening agent after methanol dilution one times at ceramic colored drawing cultural artifact surface again, repeatedly smear 3 ~ 5 times, obtain the ceramic colored drawing historical relic reinforced.
ADM-Z709 waterborne polyurethane resin contained in strengthening agent of the present invention has the advantages such as water-fast, good film-forming property, stronger closure ability is had to painted layer, and high temperature resistant, strong adhesion, especially resistance to UV aging is given prominence to, non-yellowing after 72 hours at ultraviolet ageing, but ADM-Z709 waterborne polyurethane resin is when use single as strengthening agent, perviousness is poor, be difficult to the deep crisp bisque penetrating into colored drawing pottery pottery tire, and not possessing good pore structure after film forming, the soluble salt of pottery inside cannot be separated out smoothly.After blended for two to ADM-Z709 waterborne polyurethane resin and ZB-F600 component FEVE water-based fluororesin, not only weathering resistance is strong, but also improve snappiness, the perviousness of strengthening agent, strengthening agent is reinforced pottery tire again while the crisp powder painted layer of closure, further improve the aperture after single ADM-Z709 waterborne polyurethane resin film forming simultaneously, the speed that in subsequent technique, soluble salt is separated out from ceramic surface can be improved to a great extent, carry out basis for follow-up desalination and prepare.Water-soluble epoxy resin B-63 improves the snappiness after strengthening agent film forming, permeate agent C8-10 fatty alcohol-polyoxyethylene ether JFC-6 adds the penetrating power of strengthening agent, strengthening agent of the present invention is made not only to strengthen the crisp bisque of pottery, painted layer original appearance after its process is simple and unsophisticated, chromatic aberration is little, and implementing process is simple, and consolidation effect is remarkable, can be used for the reinforcing of the crisp bisque of crisp powder pottery, and carry out basic preparation for follow-up desalination.
Accompanying drawing explanation
Fig. 1 is the thermogravimetric analysis figure after crisp powder analog sample is reinforced.
Fig. 2 is the super depth-of-field microscope photo before crisp powder analog sample is reinforced.
Fig. 3 is the super depth-of-field microscope photo after crisp powder analog sample is reinforced.
Fig. 4 is the reflecting rate graphic representation before and after crisp powder analog sample is reinforced.
Fig. 5 is effect contrast figure before and after crisp powder analog sample is reinforced.
Fig. 6 is the effect contrast figure after the crisp powder analog sample in Fig. 5 soaks in water.
Embodiment
Below in conjunction with drawings and Examples, the present invention is described in more detail, but protection scope of the present invention is not limited only to these embodiments.
Embodiment 1
To prepare 1000g crisp powder ceramic colored drawing historical relic strengthening agent, raw materials used and quality is composed as follows:
Its preparation method is: be dissolved in 145g distilled water by 85g ADM-Z719 waterborne polyurethane resin, the two component FEVE water-based fluororesin of 5g ZB-F600,20g water-soluble epoxy resin B-63,15g C8-10 fatty alcohol-polyoxyethylene ether JFC-6 is dissolved in 30g ethanol, then two kinds of solution and 700g methanol mixed is even, obtain crisp powder ceramic colored drawing historical relic strengthening agent.
Embodiment 2
To prepare 1000g crisp powder ceramic colored drawing historical relic strengthening agent, raw materials used and quality is composed as follows:
Its preparation method is identical with embodiment 1.
Embodiment 3
To prepare 1000g crisp powder ceramic colored drawing historical relic strengthening agent, raw materials used and quality is composed as follows:
Its preparation method is identical with embodiment 1.
In order to prove beneficial effect of the present invention, contriver has carried out heat stability testing to strengthening agent prepared by embodiment 1, and the crisp powder analog sample of the strengthening agent adopting embodiment 1 to prepare to ceramic colored drawing historical relic is reinforced, and various sign has been carried out to the sample before and after reinforcing, particular case is as follows:
1, the thermostability of strengthening agent
Paint film formed by 9.6mg strengthening agent is put into Q1000DSC+LNCS+FACSQ600SDT Thermo System tester, carries out the measurement of decomposition temperature.Test result is shown in Fig. 1.Can clearly be found out by Fig. 1, formed by about 300 DEG C strengthening agents, film starts to decompose, and decomposes completely, illustrate that strengthening agent of the present invention has excellent thermotolerance at 460 DEG C.
2, the change of crisp powder analog sample surface topography
Under the crisp powder analog sample reinforcing front and back being put in successively the digital super depth-of-field microscope (Keyemce international trade (Shanghai) Co., Ltd.) of VHX-600, regulate magnification to be 100 times, observe surface topography and also contrast.As can be seen from the comparing result of Fig. 2 and Fig. 3, the crisp powder analog sample surface ratio before reinforcing is more coarse, and the crisp powder analog sample surface smoother after reinforcing, show that strengthening agent of the present invention has good filling effect and certain levelling property.
3, crisp powder analog sample reinforces the change of front and back optical property
(1) crisp powder analog sample reinforces front and back color difference analysis
Utilize X-RiteVS-450 spectrophotometer to test the value of chromatism of four pieces of difference crisp powder analog samples reinforcing front and back respectively, and assess according to standards of American society of test materials ASTM D1729-89 " visual evaluation of opaque material aberration " standard.The results are shown in Table 1.
The crisp powder analog sample of table 1 reinforces front and back chromatic aberration
As can be seen from the chromatic aberration of table 1, crisp powder analog sample value of chromatism before and after reinforcing all is less than 5 CIELAB units, meet the standard of standards of American society of test materials ASTM D1729-89 " visual evaluation of opaque material aberration ", show that the Color influences of strengthening agent of the present invention to ceramic colored drawing is less.
(2) crisp powder analog sample reinforces front and back reflecting rate tracing analysis
Adopt X-RiteVS-450 spectrophotometer to carry out reflecting rate test to the crisp powder analog sample before and after reinforcing, the results are shown in Figure 4.As seen from the figure, the reflecting rate that crisp powder analog sample reinforces rear surface colored drawing is starkly lower than the reflecting rate that crisp powder analog sample reinforces front surface colored drawing, namely the crisp powder analog sample color after reinforcing is deepened to some extent, and the chromatic aberration that crisp powder analog sample reinforces front and back shows that the colour-change of reinforcing the crisp powder analog sample in front and back is less, therefore illustrate that strengthening agent of the present invention has certain reinforcing to manifest effect.
4, colored drawing breadboard aging front and back sticking power change
Cinnabar is evenly coated on tinplate, a part of model strengthening agent is wherein reinforced, a part does not do any process in addition, then weathering test is carried out, ultraviolet ageing method: sample is put into ultraviolet light and aging proofing box, ultraviolet lamp power is 60W, and vertical irradiation distance is 5cm, ultraviolet ageing 72 hours; Xeothermic aging method: sample is put into the xeothermic weatherometer of BHO-401A, 105 ± 5 DEG C are xeothermic aging 72 hours; Hydrothermal aging method: sample is put into German Binder growth cabinet KBF series hydrothermal aging instrument, under relative humidity is 85%RH condition, 100 ± 5 DEG C of hydrothermal agings 72 hours; Freeze thawing aging method: sample is put into freezing and thawing test case, set that high temperature is 40 DEG C, low temperature as-40 DEG C, within 12 hours, be 1 circulation, totally six circulations.
Test according to the sticking power of paint film adhesion testing method to aging front and back sample that standard GB/T/T1720-79 (89) " paint film adhesion assay method " specifies, the results are shown in Table 2 ~ 5.
Sticking power test result before and after table 2 ultraviolet ageing
The sticking power test result of the xeothermic aging front and back of table 3
Sticking power test result before and after table 4 hydrothermal aging
The sticking power test result of the aging front and back of table 5 freeze thawing
From table 2 ~ 5, the sticking power of colored drawing on unguyed model after overaging is all greater than 6 grades, sticking power is the poorest, and the sticking power of colored drawing after overaging after reinforcing on model is all less than 3 grades, sticking power is better, meets the requirement in standard GB/T/T1720-79 (89) " paint film adhesion assay method ".Illustrate that strengthening agent of the present invention has good ageing resistance.
5, crisp powder analog sample reinforces rear surface hydrophilic and hydrophobic test
OCA20 type video optics contact angle instrument (German Dataphysics company) is adopted to measure the contact angle of crisp powder analog sample reinforcing rear surface, test result shows, the contact angle on the crisp powder analog sample surface after reinforcing is 82.5 °, illustrate that strengthening agent of the present invention is not very strong to the affinity of moisture, this is just for the desalinating process of follow-up ceramic colored drawing historical relic provides one " buffering " preparation, in order to avoid impact follow-up demineralising process.
6, crisp powder analog sample reinforces front and back water tolerance contrast
Carried out reinforcing (see one side of something left in Fig. 5) by crisp powder analog sample half strengthening agent, second half does not do any process (see one side of something right in Fig. 5), then soaks 24 hours in water, and taking-up brush carries out surface and brushes.As seen from Figure 6, after the unconsolidated regions of crisp powder analog sample is soaked in water, crisp powder position comes off completely, and reinforcing area does not change, and illustrates that strengthening agent of the present invention has good penetration reinforcement effect and water resistance to crisp powder position.
Claims (2)
1. a crisp powder ceramic colored drawing historical relic strengthening agent, is characterized in that it is made up of the raw material of following percent mass proportioning:
2. crisp powder ceramic colored drawing historical relic strengthening agent according to claim 1, is characterized in that it is made up of the raw material of following percent mass proportioning:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410190654.5A CN103992729B (en) | 2014-05-07 | 2014-05-07 | Reinforcing agent for crisp powder ceramic painted cultural relic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410190654.5A CN103992729B (en) | 2014-05-07 | 2014-05-07 | Reinforcing agent for crisp powder ceramic painted cultural relic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103992729A CN103992729A (en) | 2014-08-20 |
| CN103992729B true CN103992729B (en) | 2015-06-17 |
Family
ID=51307079
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410190654.5A Expired - Fee Related CN103992729B (en) | 2014-05-07 | 2014-05-07 | Reinforcing agent for crisp powder ceramic painted cultural relic |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103992729B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104356839A (en) * | 2014-10-23 | 2015-02-18 | 西北大学 | Anti-light-ageing reinforcement material of colored relics and preparation method of reinforcement material |
| CN105647289B (en) * | 2015-07-17 | 2018-08-31 | 苏州吉人高新材料股份有限公司 | A kind of ceramic polychrome cultural relics doped coating and preparation method thereof |
| CN110157200B (en) * | 2019-05-24 | 2021-04-20 | 陕西师范大学 | Pigment layer reinforcing agent based on modified bone glue |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101186766A (en) * | 2006-11-16 | 2008-05-28 | 国家纳米技术与工程研究院 | Masking liquid for protecting stone cultural artifact and using method thereof |
| CN101608083A (en) * | 2009-07-30 | 2009-12-23 | 陕西师范大学 | Sizing color painting reattachment restoration agent for ceramic relics |
| CN103570280A (en) * | 2013-01-11 | 2014-02-12 | 中国科学院上海硅酸盐研究所 | Preparation method and reinforcement method of crispy powder ceramic culture relic reinforcement material |
-
2014
- 2014-05-07 CN CN201410190654.5A patent/CN103992729B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101186766A (en) * | 2006-11-16 | 2008-05-28 | 国家纳米技术与工程研究院 | Masking liquid for protecting stone cultural artifact and using method thereof |
| CN101608083A (en) * | 2009-07-30 | 2009-12-23 | 陕西师范大学 | Sizing color painting reattachment restoration agent for ceramic relics |
| CN103570280A (en) * | 2013-01-11 | 2014-02-12 | 中国科学院上海硅酸盐研究所 | Preparation method and reinforcement method of crispy powder ceramic culture relic reinforcement material |
Non-Patent Citations (1)
| Title |
|---|
| 汉代文物彩绘的保护与回帖修复研究;范陶峰;《中国优秀硕士学位论文全文数据库》;20060901;第15和17页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103992729A (en) | 2014-08-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Stuart | Analytical techniques in materials conservation | |
| CN103992729B (en) | Reinforcing agent for crisp powder ceramic painted cultural relic | |
| CN103992136B (en) | A kind of reinforcing of crisp powder ceramic colored drawing historical relic and desalting method | |
| JPS60501846A (en) | Synthetic preservatives and their manufacturing method | |
| González‐Campelo et al. | Extraordinary Protective Efficacy of Graphene Oxide over the Stone‐Based Cultural Heritage | |
| CN103360889B (en) | Stone matter colored drawing strengthening agent | |
| CN105568715A (en) | Real-leather dyeing process | |
| CN103204703B (en) | Application of ZB-F600 two-component FEVE aqueous fluororesin in pretreatment of damage-prone pottery decorated with colored drawing before restoration | |
| Venkatachalapathy et al. | Diatoms community structure in relation to physico-chemical factors in Yercaud Lake, Salem District, Tamil Nadu, India | |
| Aquino-Cruz et al. | Studies on picophytoplankton in the southern Gulf of Mexico: recognition of picoprokaryotes and abundances of picophytoplankton during" dry season" | |
| Chung et al. | Environmentally benign methods for producing green culms of ma bamboo (Dendrocalamus latiflorus) and moso bamboo (Phyllostachys pubescens) | |
| CN105647289B (en) | A kind of ceramic polychrome cultural relics doped coating and preparation method thereof | |
| CN111732879A (en) | Antiviral healthy plant water-based enamel-like paint and preparation method thereof | |
| CN111607288A (en) | Casein type water-based pigment yellow ink-jet ink for titanium white paper and preparation method thereof | |
| JP5666093B2 (en) | Waterborne wood paint | |
| CN105440926A (en) | Children antibacterial anti-scratching furniture and preparation method thereof | |
| JP6384717B2 (en) | Concrete coloring agent, concrete coloring method, concrete and concrete structure | |
| JP6296284B2 (en) | Concrete member and manufacturing method thereof | |
| CN105969036B (en) | A kind of erasable metallic paint and preparation method thereof | |
| CN114479590B (en) | Ceramic DIY colored drawing pigment and manufacturing method thereof | |
| CN111040629B (en) | Wooden furniture coating and preparation method thereof | |
| JP6296285B2 (en) | How to protect concrete | |
| Banens | Occurrence of hypolimnetic blooms of the purple sulfur bacterium, Thiopedia rosea, and the green sulfur bacterium, Chlorobium limicola, in an australian reservoir | |
| CN112266658B (en) | Permeable colorant | |
| CN108978343B (en) | Rubbing ink mark reinforcing agent and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150617 |