CN103988845A - Fungicidal mixture - Google Patents
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- CN103988845A CN103988845A CN201410234979.9A CN201410234979A CN103988845A CN 103988845 A CN103988845 A CN 103988845A CN 201410234979 A CN201410234979 A CN 201410234979A CN 103988845 A CN103988845 A CN 103988845A
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Abstract
The invention relates to a fungicidal mixture and also relates to a method for preventing and treating plant diseases. The fungicidal mixture provided by the invention contains the active ingredients, namely bellkute and boscalid, wherein the weight ratio of bellkute to boscalid is (100: 1) to (1: 100), so as to achieve a synergistic effect; the content of the active ingredients, namely bellkute and boscalid, in the mixture is 5-90%. According to the fungicidal mixture, bellkute and boscalid are subjected to binary compounding, are different in mechanism of action and are free from cross-resistance, so that by mixed use, the fungicidal spectrum can be enlarged, a better prevention and treatment effect is exerted, the generation of drug resistance of pathogenic fungi is delayed, and the fungicidal mixture is relatively safe to a variety of crops; the fungicidal mixture can be used for preventing and treating fungi on cereals, fruits, vegetables, cotton, fruit trees and ornamental plants.
Description
Technical field
What the present invention relates to is a kind of Fungicidai mixtures, also relates to a kind of method of preventing and kill off plant disease.
Background technology
Due to the harm of various phytopathogens, many crops are brought about great losses, the lighter's underproduction, severe one can cause total crop failure, directly affects peasant's economic interests, therefore forces peasant to have to prevent and treat disease with bactericide.
The multiple fungal disease of the upper often generation of agricultural crops (Cereal, melon and fruit, vegetables, flowers), as gray mold, powdery mildew, stalk break, stem wilt, climing rot, anthracnose, ring spot, scab, leaf spot, spot defoliation, fruit soft rot, penicilliosis, green mould, rust, peach brown rot, smut, cecospora spot etc.
Hundred can obtain (Bellkute), have another name called biguanides three octyl benzene sulfonates, and its chemical name is: 1 ＇ 1-imino group (octyl group methylene) biguanides 3(alkyl benzene sulfonate), be the antistaling disinfectant of the single molecular structure of biguanides salt, its structural formula is:
n=10～13
Hundred can be produced by Japanese Cao Da company.Hundred can tagging and prevention type bactericide as broad spectrum activity, local permeability is strong, some disease fungus is had to very high growth inhibitory activity, it mainly works to the biosynthesis of Mycophyta ester compounds and cell membrane function, suppress the formation of spore germination, germ tube elongation, appresorium and mycelia, can prevent and treat the fungal disease being caused by most of sac fungis and imperfect fungus.Hundred can obtain the diseases such as gray mold, powdery mildew, stalk break, stem wilt, climing rot, anthracnose, ring spot, scab, leaf spot, spot defoliation, penicilliosis, green mould and fruit soft rot that can be widely used in fungal disease, particularly fruit, vegetables and multiple kinds of crops that control most of sac fungis and imperfect fungus cause.Especially to tomato, grape grey mould, apple tree spot defoliation, powdery mildew of cucumber, the climing rot of watermelon all have good preventive effect.
Boscalid (Boscalid), chemical name is the chloro-N'-of 2-(4 ' one chlordiphenyl one 2-yl) vitamin PP (IUPAC).Chemical constitution is:
Boscalid is a kind of nicotinamide bactericide, by BASF Aktiengesellschaft, researched and developed first successfully, fungicidal spectrum is wider, there is prevention effect, almost all types of fungal diseases are had to activity, very effective to preventing and treating powdery mildew, gray mold, root rot, stalk break and various rots etc., be difficult for producing cross resistance, resistance bacterium to other medicaments is also effective, is mainly used in comprising the control of the diseases such as rape, grape, fruit tree, vegetables and field crop.
Boscalid is a kind of mitochondrial respiratory inhibitor, for succinate dehydrogenase inhibitors (SDHI), it works by suppressing succinic acid ubiquinone reductase (also referred to as Complex II) on mitochondria electron transport chain, and its mechanism of action and other amide-types and benzamide series bactericidal agent are similar.It all has effect to the whole growth link of pathogen, and especially spore-germination inhibitory action is stronger.It also has outstanding preventive effect and good leaf intrinsic permeability.
Boscalid is blade face applying bactericidal agent, can, in the vertical infiltration of leaves of plants portion with to top transmission, have excellent prevention effect, and have certain result for the treatment of.It can suppress spore germination, germ tube elongation, hapteron formation, also effective in the every other vegetative period of fungi, presents remarkable resistance of rainwater washing against and lasting effect.
Boscalid is wide spectrum, systemic fungicide, and it can effectively prevent and treat the disease that sterol inhibitor, double imide class, benzimidazole, aniline pyrimidine class, phenylamide and methoxy acrylic bactericide is produced to resistance.This product can transfer to by xylem blade tip and the leaf margin of plant to top; It also has vertical osmosis, can organize by leaf portion, is delivered to the back side of leaf; But, this product is very little in vapor phase reallocation effect.Boscalid is mainly sprayed by cauline leaf, for preventing and treating powdery mildew (Powdery mildew), brown rot (Monilinia spp), the leaf spot (Mycosphaerella spp) on grape, lawn, fruit tree, vegetables and ornamental plants and the disease being caused by alternaric bacteria (Alternaria spp), botrytis cinerea (Botrytis spp), sclerotium germ (Sclerotinia spp).Also can farming thing for cereal, grape, peanut and potato etc. with complex preparation.
Summary of the invention
The object of the invention is to provide a kind of Fungicidai mixtures, with regard to reduce rate of application and improve known compound hundred can with the activity profile of Boscalid with regard to, the present invention uses under total amount at the reactive compound reducing, and harmful fungoid is had and improves active mixture (Synergistic mixture).
We find, meanwhile, associating or separate administration hundred can and Boscalid, or use successively hundred and can make to prevent and treat better harmful fungoid than using separately each compound with Boscalid.
The invention provides a kind of Fungicidai mixtures, this mixture, by carrying out binary built with Boscalid by hundred, makes the mixture obtaining in control efficiency, have gain effect, and has expanded fungicidal spectrum, played the multiplex effect of a medicine, effectively slowed down or avoid germ to develop immunity to drugs.Astoundingly, the bactericidal activity of Fungicidai mixtures of the present invention is than active the adding with obviously higher of each reactive compound.In other words, there is synergistic effect unpredictable, necessary being, and be not only active augmenting.
Invention is through various further investigations, found that contain hundred can with the Fungicidai mixtures of Boscalid, can prevent and treat the fungal disease of various vegetables, fruit tree and cereal crop.Containing hundred can be with the mixture of Boscalid not only for common phytopathogen, and the pathogen that those have been produced to drug resistance is also very effective, recurs and under condition, also has good control efficiency, thereby completed the present invention in disease.
When reactive compound is present in Fungicidai mixtures of the present invention with specific weight ratio, synergistic effect is obvious especially.But the weight ratio of the reactive compound in Fungicidai mixtures can change within the specific limits.
A kind of Fungicidai mixtures of the present invention is to take following technical scheme to realize:
A Fungicidai mixtures, comprising hundred can be with Boscalid as active component, and described hundred can be 100:1-1:100 with the weight ratio of Boscalid.
Hundred can be simultaneously with Boscalid, together or separate administration, or uses successively; Order in separate administration situation conventionally on the result of prophylactico-therapeutic measures without any impact.
Compound hundred can be with Boscalid conventionally with 100:1-1:100, preferred 50:1-1:50, and more preferably 25:1-1:25, more preferably 10:1-1:10, more preferably the weight ratio of 5:1-1:5 is used.
A Fungicidai mixtures, comprise hundred can with Boscalid active component, filler and/or surfactant.
Described Fungicidai mixtures formulation is wetting powder, missible oil, suspending agent, suspension emulsion, microcapsules, seed coat agent, microemulsion, aqueous emulsion, water dispersible granules, foaming agent, paste, aerosol, ultra low volume spraying liquid.
Described Fungicidai mixtures, wherein can account for the content of Boscalid active component the 5%-90% of Fungicidai mixtures containing hundred.
Described Fungicidai mixtures, wherein can account for the content of Boscalid active component the 10%-80% of Fungicidai mixtures containing hundred.
Described Fungicidai mixtures, wherein can account for the content of Boscalid active component the 20%-60% of Fungicidai mixtures containing hundred.
Prevent and kill off a method for plant disease, described Fungicidai mixtures is applied to plant, plant propagation material and the organ growing subsequently, environment.
The propagating materials of the plant that described mixture process needs protection.
The plant propagation material of described mixture process.
The purposes of described Fungicidai mixtures for preventing and treating fungi.
The purposes of described Fungicidai mixtures for preventing and treating fungi on Cereal, fruit, vegetables, cotton, fruit tree, ornamental plants.
Described Fungicidai mixtures is used for preventing and treating gray mold, stalk break, brown rot, leaf spot, banded sclerotial blight, full rot, rust, anthracnose, early blight, powdery mildew, scab, black spot, climing rot, spot defoliation, stem wilt etc.
Described Fungicidai mixtures is for preventing and treating the purposes of fruit vegetables storing period disease.
Described hundred can use simultaneously or use respectively or sequential application with Boscalid compound.
According to the character of these mixtures and use object and the ambient conditions that mixture will reach, can select mixture with dressing, spraying, immersion, dense fog, the mode such as broadcast sowing or pour and use.
Detailed Description Of The Invention
Hundred can with the synergy of Boscalid, the weight ratio of reactive compound can be selected in larger scope.Hundred can be 100:1-1:100 with the weight ratio of Boscalid, or 50:1-1:50, or 20:1-1:20, preferably 10:1-1:10, more preferably 5:1-1:5.
Fungicidai mixtures of the present invention, the content of active component depends on dosage when sterilization is used separately, also depends on mixed ratio and the synergistic effect degree of a kind of bactericide and another kind of bactericide.
In described Fungicidai mixtures, hundred can account for the content of Boscalid active component the 5%-90% of Fungicidai mixtures, preferably 10%-80%, more preferably 20%-60%.
In described Fungicidai mixtures, active component can be only comprised, also filler and/or surfactant can be comprised.
Fungicidai mixtures of the present invention, can be prepared into various formulations, for example wetting powder, missible oil, suspending agent, suspension emulsion, microcapsules, seed coat agent, microemulsion, aqueous emulsion, water dispersible granules, foaming agent, paste, aerosol, ultra low volume spraying liquid.
According to the present invention, term " filler " refers to can be combined with reactive compound or for example combine, so that it is easier to be administered to the natural or synthetic organic or inorganic compound of object (plant, crop or careless class).Therefore, described filler is preferably inertia, at least should be agricultural acceptable.Described filler can be solid or liquid.
Liquid filling agent is generally: water, alcohol type (methyl alcohol for example, ethanol, isopropyl alcohol, butanols, ethylene glycol etc.), ketone (acetone for example, methyl ethyl ketone, isobutyrone, cyclohexanone etc.), ethers (ether for example, dioxanes, methylcellulose, oxolane etc.), aliphatic hydrocarbon class (kerosene for example, mineral wet goods), aromatic hydrocarbons class (benzene for example, toluene, dimethylbenzene, solvent naphtha, Fluhyzon, chlorinated aromatic hydrocarbons, chlorinated aliphatic hydrocarbon, chlorobenzene, Deng), halogenated hydrocarbon class, amide-type, sulfone class, dimethyl sulfoxide (DMSO), mineral and vegetable oil, animal wet goods.
Solid-filling agent is generally: the phyteral powdery type (particle of soybean meal, starch, grain dust, wood powder, bark powder, sawdust, walnut shell powder, wheat bran, cellulose powder, coconut husk, corncob and tobacco stem for example, extract residue after plant essence etc.), paper, sawdust, pulverize synthesized polymer body, clay class (such as kaolin, bentonite, acid china clay etc.), the talcum powder class of synthetic resin etc.Silica (for example diatomite, silica sand, mica, moisture silicic acid, calcium silicates), chemical fertilizer, the clay fertilizer of active carbon, natural mineral matter class (float stone, attapulgite and zeolite etc.), the inorganic mineral powder of firing diatomite, sand, plastics medium etc. (such as polyethylene, polypropylene, polyvinylidene chloride etc.), potassium chloride, calcium carbonate, calcium phosphate etc., ammonium sulfate, ammonium phosphate, urea, greening ammonium etc., these materials can be used separately or two or more is mixed.
For making the emulsification of active ingredient compound, disperse, solubilization, and/or wetting can use surfactant for example can enumerate fatty alcohol-polyoxyethylene ether, polyoxyethylene alkylaryl ether, polyoxyethylene high-grade aliphatic ester, the phosphate of polyoxyethylene alcohol or phenol, the fatty acid ester of polyalcohol, alkyl aryl sulphonic acid, naphthalene sulfonic acids polymer, lignosulfonates, a shape copolymer of macromolecule comb shape, butyl naphthalene sulfonate, alkylaryl sulfonates, alkyl sodium sulfosuccinate, grease, fatty alcohol and ethylene oxide condensate, the polyacrylates such as alkyltaurate, protein hydrolysate.Suitable oligosaccharide thing or polymer, for example combination of the vinyl monomer based on independent, acrylic acid, polyoxyethylene and/or polyoxypropylene or itself and for example (polynary) alcohol or (polynary) amine.
In preparation, also can use for example carboxymethyl cellulose of tackifier, and the natural and synthetic polymer of powder, particle or latex form, for example gum Arabic, polyvinyl alcohol and polyvinyl acetate or natural phospholipid, for example cephalin and lecithin, and synthetic phospholipid.Other additive is mineral oil and vegetable oil.
The colouring agent that may use is as inorganic pigment, for example, iron oxide, titanium oxide and Prussian blue, and organic dyestuff, as alizarin dyes, azo dyes or metal phthalein mountain valley with clumps of trees and bamboo dyestuff, and trace nutrient, as iron, manganese, boron, ketone, cobalt, molybdenum and zinc salt.
The disintegrant that may use is selected from: one or more in bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, sodium bicarbonate.
The stabilizing agent that may use is selected from: a kind of in sodium citrate, resorcinol.
The antifreezing agent that may use is selected from: one or more in ethylene glycol, propane diols, glycerine, urea.
Described defoamer is selected from: silicone oil, silicone compound, C
10-20saturated fat acid compounds, C
8-10one or more in aliphatic alcohols compound.
Optionally, also can comprise other annexing ingredient, for example protecting colloid, adhesive, thickener, thixotropic agent, bleeding agent, stabilizing agent, screening agent.
Described preparation of the present invention can be mixed described active component to prepare with filler and/or surfactant by known way, also can add other conventional additives, as drier and colouring agent, stabilizing agent, pigment, defoamer, preservative, thickener etc.
Fungicidai mixtures of the present invention can also have with other medicament of weeding, desinsection or bactericidal property, particularly mixes use with protective fungicide, also can mix use with insecticide, protective agent, growth regulator, nutrient for plants or soil conditioner.
Fungicidai mixtures of the present invention has extraordinary fungicide performance, and can be used to prevent and treat phytopathogenic fungi, described fungi is especially selected from Ascomycetes (Ascomycetes), Basidiomycetes (Basidiomycetes), Phycomycetes (Phycomycetes) and deuteromycetes (Deuteromycetes) fungi.
Fungicidai mixtures of the present invention is particularly suited for preventing and treating following plant disease:
Chain lattice spore (AIternaria) on-vegetables, oilseed rape, sugar beet, fruit and rice belongs to,
Silk capsule mould (Aphanomyces) on-sugar beet and vegetables belongs to,
Bipolaris in-corn, Cereal, rice and lawn (Bipolaris) belongs to and interior navel is wriggled, and spore (Drechslera) belongs to,
Standing grain powdery mildew on-Cereal (Blumeria graminis) (powdery mildew),
Botrytis cinerea on-strawberry, vegetables, flowers and grape vine (Botrytis cinerea) (gray mold),
Lettuce dish stalk mould (Bremia lactucae) on-lettuce,
Tail spore (Cercospora) on corn, soybean, rice and sugar beet belongs to,
(for example the standing grain on Cereal revolves spore to cochliobolus on-corn, Cereal, rice (Cochliobolus) genus
Chamber bacterium (Cochliobolus sativus), the palace portion cochliobolus (Cochliobolus miyabeanus) on rice),
Thorn dish spore (Colletotricum) on-soybean and cotton belongs to,
Interior navel on-Cereal and the corn spore (Drechslera) of wriggling belongs to,
The prominent navel on-corn spore (Exserohilum) of wriggling belongs to,
. two spore powdery mildews (Erysiphe cichoracearum) and monofilament shell powdery mildew on cucumber
(Sphaerotheca fuliginea) ,
Fusarium (Fusarium) on-each Plants belongs to and wheel branch spore (Verticillium) belongs to,
Gaeumannomyce on-Cereal (Gaeumanomyces graminis) belongs to,
Red mould (Gibberella) on-Cereal and rice belongs to the (gibberella fujikuroi (Gibberella on rice for example
fujikuroi)) ,
Gram’s staining complex on-rice (Grain staining complex),
Length on-corn and the rice spore (Helminthosporium) of wriggling belongs to,
Michrodochium nivale on-Cereal,
Ball chamber bacterium (Mycosphaerella) on-Cereal, banana and peanut belongs to,
Yam bean layer rest fungus (Phakopsora pachyrhizi) on-soybean and mountain horse sulphur layer rest fungus
(Phakopsara meibomiae) ,
Phomopsis on-soybean and sunflower (Phomopsis) belongs to,
Phytophthora infestans on-potato and tomato (Phytophthora infestans),
The raw single shaft mould (Plasmopara viticola) of grape on-grape vine,
Apple mildew bacterium on-apple (Podosphaera leucotricha),
Wheat-based maize ear rot bacterium (Pseudocercosporella herpotrichoides) on-Cereal,
False downy mildew (Pseudoperonospora) on-lupulus and cucurbit belongs to,
Handle rest fungus (Puccinia) on-Cereal and corn belongs to,
Nuclear cavity bacteria on-Cereal (Pyrenophora) belongs to,
Pyricularia oryzae on-rice (Pyricularia 0 η zae), Bamboo grass wood photovoltaicing leather bacteria (Corticium sasakii), broom stalk Cylindrocarpon (Sarocladium oryzae), sheath rot of rice plant (S.attenuatum), rice leaf smut (Entyloma oryzae)
Piricularia oryzae on-lawn and Cereal (Pyricularia grisea),
-lawn, rice, corn, cotton, oilseed rape, sunflower, sugar beet, vegetables and other are planted
Corruption mould (Pythium) on thing belongs to,
-cotton, rice, potato, lawn, corn, oilseed rape, potato, sugar beet, vegetables and its
Rhizoctonia on his plant (Rhizoctonia) belongs to,
Sclerotinite on-oilseed rape and sunflower (Sclerotinia) belongs to,
Wheat septoria on-wheat (Septoria tritici) and the many spore (Stagonospora of clever withered shell
nodorum) ,
Grape snag shell (Erysiphe) on-grape vine,
Setospaeria on-corn and lawn belongs to,
Silk axle smut (Sphacelotheca reilinia) on-corn,
Thielaviopsis sp on-soybean and cotton (Thievaliopsis) belongs to,
Tilletia foetida on-Cereal (Tilletia) belongs to,
Smut on-Cereal, corn and sugar beet (Ustilago) belongs to,
Black star bacterium (Venturia) on-apple and pears belongs to (scab).
Fungicidai mixtures of the present invention is even more important to preventing and treating a large amount of fungies various crops for example, as cotton, vegetable variety (cucumber, beans, tomato, potato and cucurbitaceous plant), barley, dogstail, oat, banana, coffee, corn, fruit variety, rice, rye, soybean, grape vine, wheat, ornamental plants, peanut, rape, sugarcane and various crop seed in.
Fungicidai mixtures of the present invention is particularly suitable for preventing and treating following plants pathogenic epiphyte: the standing grain powdery mildew in Cereal (Blumeria graminis) (powdery mildew), two spore powdery mildews (Erysiphe cichoracearum) in cucurbitaceous plant and monofilament shell (Sphaerotheca fuliginea), apple mildew bacterium in apple (Podosphaera leucotricha), grape snag shell (Uncinula necator) in grape vine, handle rest fungus (Puccinia) in Cereal belongs to, cotton, rhizoctonia in rice and lawn (Rhizoctonia) belongs to, smut in Cereal and sugarcane (Ustilago) belongs to, venturia inaequalis in apple (Venturia inaequalis) (scab), length in the Cereal spore (Helminthosporium) of wriggling belongs to, wheat glume blight bacterium (Septoria nodorum) in wheat, strawberry, vegetables, Botrytis cinerea in ornamental plants and grape vine (Botrytis cinerea) (gray mold), peanut tail spore (Cercospora arachidicola) in peanut, eye spot bacterium (PseudocercosporellaHerpotrichoides) in Wheat and barley, Pyricularia oryzae in rice (Pyricularia oryzae), phytophthora infestans in potato and tomato (Phytophthora infestans), grape single shaft mould (Plasmopara viticola) in grape vine, false downy mildew (Pseudoperonospora) in lupulus and cucumber belongs to, stalk break in rape (sclerotiose), chain lattice spore (Alternaria) in vegetables and fruit belongs to, ball chamber bacterium (Mycosphaerella) in banana belongs to and Neurospora (Fusarium) and wheel branch spore (Verticillium) genus.
Preferably, Fungicidai mixtures of the present invention can be used for preventing and treating gray mold on Cereal, fruit, vegetables, cotton, fruit tree, ornamental plants, stalk break, brown rot, leaf spot, banded sclerotial blight, full rot, rust, anthracnose, early blight, powdery mildew, scab, black spot, climing rot, spot defoliation, stem wilt etc.
Fungicidai mixtures of the present invention also can be used for preventing and treating fruit vegetables storing period disease.The fruit rot for example being caused by following pathogene:
Aspergillus bacterium, for example aspergillus flavus;
Botrytis (Botrytis) bacterial classification, for example Botrytis cinerea (Botrytis cinerea);
Penicillium (Penicillium) bacterial classification, for example penicillium expansum (Penicillium expansum) and P.purpurogenum;
Sclerotinia (Sclerotinia) bacterial classification, for example sclerotinite (Sclerotinia sclerotiorum);
Verticillium (Verticilium) bacterial classification, for example black and white wheel branch spore (Verticilium alboatrum).
Fungicidai mixtures of the present invention also can be used for control kind and passes and soil-borne disease.The kind for example being caused by following pathogene passes and soil passes rotten and wilting disease and seedling disease:
Alternaria belongs to plants, for example the raw chain lattice spores (Alternaria brassicicola) of rape;
Aphanomyces (Aphanomyce) belongs to plants, for example mould (the Aphanomyces of Kidney bean silk capsule
euteiches) ;
Ascochyta (Ascochyta) belongs to be planted, for example Ascochyta lentis;
Aspergillus, for example aspergillus flavus;
Cladosporium belongs to plants, for example draft branch spore (Cladosporium herbarum);
Cochliobolus belongs to plants, for example standing grain cochliobolus;
(conidial form: Drechslera, Syn: the long spore bacterium that wriggles);
Colletotrichum belongs to be planted, for example hair core anthrax-bacilus (Colletotrichum coccodes);
Fusarium belongs to plants, for example yellow sickle spore;
Gibberella belongs to plants, and for example beautiful another name for Sichuan Province multitude is red mould;
Shell ball spore belongs to (Macrophomina) genus kind, for example Kidney bean shell ball spore (Macrophomina
phaseolina) ;
Little setting-out shell belongs to bacterial classification, for example, avenge rotten little setting-out shell;
Penicillium belongs to plants, for example penicillium expansum;
Phaeosphaeria bacterial classification, for example Phaeosphaeria nodorum;
Phoma (Phoma) belongs to plants, for example black blastema point mould (Phoma lingam);
Phomopsis (Phomopsis), for example soybean Phomopsis (Phomopsis sojae);
Phytophthora belongs to plants, for example Phytophthora cactorum (Phytophthora cactorum);
Nuclear cavity Pseudomonas belongs to be planted, for example wheat class nuclear cavity bacteria (Pyrenophora graminea);
Pyricularia Sacc. (Pyricularia) belongs to plants, for example Magnaporthe grisea (Pyricularia oryzae);
Pythium kind, for example Pythium ultimum;
Rhizoctonia belongs to plants, for example Rhizoctonia solani Kuhn;
Rhizopus (Rhizopus) belongs to plants, for example Rhizopus oryzae (Rhizopus oryzae);
Bulbil belongs to (Sclerotium) genus kind, for example Sclerotium rolfsii (Sclerotium rolfsii);
Core coral Pseudomonas (Typhula) belongs to be planted, for example meat spore core coral bacterium (Typhula incarnata);
Verticillium (Verticillium) belongs to plants, for example verticillium dahliae (Verticillium dahliae);
Fungicidai mixtures of the present invention, under control phytopathogenic fungi desired concn, the compatibility having had with plant.Therefore, can be applied to plant, plant propagation material and the plant organ growing subsequently, environment, habitat or storage areas during Fungicidai mixtures of the present invention.
Term " plant propagation material " is interpreted as referring to all plant parts that have fertility, seed for example, and it can be for breeding the latter, and vegetable matter for example cuttage bar or stem tuber (for example potato).Therefore, plant part used herein comprises plant propagation material.What can mention is seed (narrowly) for example, root, fruit, stem tuber, bulb, rhizome and plant part.Until after germinateing soil or the germination plant suppressing after emerging and effectively plant also can mention.Immature plant can before transplanting, by dipping, be undertaken all or Local treatment is protected.
The plant organ growing is subsequently any part by the plant propagation material plant that for example seed produces.Plant part, plant organ and plant also can be benefited from by active agent combinations or mixture are applied to plant propagation material protective plant and avoid plant disease.Certain plants part and some plant organ growing subsequently also can be regarded plant propagation material as, himself can use with Fungicidai mixtures (or processing); Thereby the plant, other plant part and other the plant organ that by treated plant part and treated plant organ, are produced also can be benefited from by Fungicidai mixtures being applied to certain plants part and certain plants Organoprotective plant and avoid plant disease.
The environment of plant growth, habitat refer to the supporter that can make crops take root, grow, for example: soil, water etc., concrete raw material can be used such as sand, float stone, vermiculite, diatomite, agar-agar, gelling material, polymer substance, asbestos, wood chip, bark etc.Preferred soil.
According to the present invention, use the processing that Fungicidai mixtures of the present invention carries out plant directly to carry out according to conventional treatment method, or realize by processing its environment of living in, habitat or storage space, for example immersion liquid of described conventional treatment method, spraying, evaporation, atomizing, broadcast sowing, smear; For plant propagation material or the plant organ, the especially seed that grow subsequently, also can carry out one or more layers dressing.Type of service depends on the object being intended to; Under any circumstance all should guarantee that mixture of the present invention is meticulous as far as possible and distribute equably.Preferred application process is to be administered to plant shoot to divide, especially foliage applying; Application times and use biology and the weather life condition that ratio depends on objective microbe.Active component also can reach in plant corpus by root system via soil or water, and available liquid preparation waters location or this material is mixed in soil with solid form thus.Fungicidai mixtures of the present invention also can be administered on seed-grain in seed treatment, and stem tuber or cereal can soak successively with the liquid preparation of every kind of active component thus, or wraps up with the wet or dry preparation having mixed.
Active ingredient is mixed environment or the habitat at plant place, for example, with the form of particle, mix (soil application) in soil, and active ingredient also can enter inside plants by root system.To the method for using medicament in soil, for example liquid preparation is diluted in water or does not dilute and be directly applied to the root of plant corpus or the medium method in rice seedling bed that seedling is used, by granule be disseminated to method in the root of plant corpus or the rice seedling bed of seedling have prior to seeding pulvis, water dispersible granules etc. is sprayed in soil and with the whole method of mixing of soil, before sowing or before serike body, will after pulvis, water-dispersible grain dilution agent, be sprayed in implantation hole, seed furrow, then the method for sowing etc.
For the protection of plant propagation material or the plant organ that grows subsequently, for example seed, fruit, stem tuber or kernel or plant cutting are not subject to infecting of plant disease to Fungicidai mixtures of the present invention; can be before using for example, with this propagating materials of mixture process or the plant organ that grows subsequently, seed dressing prior to seeding.Also can be by soaking kernel or with the coated kernel of solid mixture, active component is applied in kind of benevolence and (is coated with) in liquid mixture.When propagating materials being applied to for example seed is broadcast in ditch in seeding process, also this mixture can be applied to application site.These plant propagation materials to the processing method of plant propagation material and so processing are all the further themes of the present invention.
In the control of plant disease, hundred can with Boscalid separately co-administered or hundred can with the mixture of Boscalid use by before or after plant seeding or plant seed, plant or soil spraying or dusting are carried out before or after emerging.Mixture of the present invention can be used before or after plant or plant propagation material are by infection process.
Product of the present invention can finished product preparation form provide, and in Fungicidai mixtures, each material mixes, and the composition of Fungicidai mixtures also can single dose form provide, and before use, directly in bucket or in tank, directly mixes, and is then diluted to required concentration.The frequency of administration of Fungicidai mixtures of the present invention and amount of application, according to the mixing ratio of active ingredient, meteorological condition, medicament form, use period, application process, use place, prevent and kill off target pest, the difference of target crops etc. and variant:
-concentration for leaf portion processing active substance is conventionally: 10-600g/ha, preferably 30-500g/ha, more preferably 50-300g/ha; For dipping or for instiling and using, described dosage even can also reduce, particularly when using inert base as asbestos or pearl rock;
-for seed treatment: 10-6000g active substance/100kg seed, preferably 50-5000g active substance/100kg seed;
-for soil treatment: 10-6000 g/ha, preferably 50-3000 g/ha;
-for fruits and vegetables impregnation process: dilute with water 200-2000 times liquid, soaks fruit one minute.
Above-mentioned dosage is only general exemplary dose, and during actual using, those skilled in the art can, according to actual conditions and needs, especially adjust rate of application according to the seriousness of the character of pending plant or fruits and vegetables and germ.
Fungicidai mixtures of the present invention can be used by common method, and amount of application is with weather or crop state variation, use optimum period and be crop susceptible before or the susceptible initial stage.Its lasting period is conventionally relevant with the content in Fungicidai mixtures, also relevant to extraneous factor.
Fungicidai mixtures of the present invention has the following advantages:
1, hundred can be complementary with the two mechanism of action of Boscalid, can bring into play better protection and therapeutic action;
2, hundred can have an obvious synergistic function with Boscalid is composite, reduce single every mu of using dosage of planting medicament, thereby both can reduce influence degree, and can significantly reduce agricultural cost again, the effect of even preventing and treating some disease surpasses existing other bactericide;
3, fungicidal spectrum is more extensive, to the disease being caused by sac fungi, basidiomycetes, imperfect fungus, Phycomycetes in various crop, has good control efficiency.
In order to make object of the present invention, technical scheme and advantage clearer, the present invention describes with following specific embodiment, but the present invention is limited to absolutely not these examples.It should be pointed out that all any modifications of making within the spirit and principles in the present invention, be equal to replacement and improvement etc., within all should being included in protection scope of the present invention.
Embodiment
Below with reference to embodiment, the invention will be further described:
fORMULATION EXAMPLE:
Can obtain+10% Boscalid wetting powder of embodiment 1 2,%00
Hundred can obtain 2%
Boscalid 10%
Lauryl sodium sulfate 10%
Sodium lignin sulfonate 5%
White carbon 10%
Kaolin complements to 100%
Reactive compound, various auxiliary agent and filler etc. are mixed in the ratio composition of formula, after ultra-fine pulverizer disintegrating, obtain 2,%00 can obtain+10% Boscalid wetting powder.
Can obtain+1% Boscalid wetting powder of embodiment 2 50,%00
Hundred can obtain 50%
Boscalid 1%
Calcium dodecyl benzene sulfonate 1%
Sodium lignin sulfonate 2%
Sucrose complements to 100%
Reactive compound, various auxiliary agent and filler etc. are mixed in the ratio composition of formula, after ultra-fine pulverizer disintegrating, obtain 50,%00 can obtain+1% Boscalid wetting powder.
Can obtain+4% Boscalid missible oil of embodiment 3 1,%00
Hundred can obtain 1%
Boscalid 4%
Ethoxylated castor oil 5%
Calcium dodecyl benzene sulfonate 3%
Dimethyl sulfoxide (DMSO) complements to 100%
Mentioned component is proportionally prepared, stirred and obtain the phase of homogeneous.
Can obtain+5% Boscalid wetting powder of embodiment 4 50,%00
Hundred can obtain 50%
Boscalid 5%
Lauryl sodium sulfate 10%
Sodium lignin sulfonate 5%
White carbon 10%
Kaolin complements to 100%
Said components is mixed in proportion, and grind, pulverize, be prepared into wetting powder.
Can obtain+50% Boscalid water dispersible granules of embodiment 5 2,%00
Hundred can obtain 2%
Boscalid 50%
MODIFIED LIGNOSULPHONATE 5%
Lauryl sodium sulfate 5%
Urea 5%
Kaolin complements to 100%
By hundred can obtaining, Boscalid, dispersant, wetting agent, disintegrant and filler mix in the ratio of formula, through air-flow crushing, becomes wetting powder; Add again a certain amount of water to mix extruding and make material.After drying screening, obtain 2,%00 can obtain+50% Boscalid water dispersible granules.
Can obtain+50% Boscalid suspension emulsion of embodiment 6 0.5% hundred
Oil phase:
Hundred can obtain 0.5%
Methyl oleate 10%
Ethoxylated castor oil 5%
Water:
Boscalid 50%
The sodium salt 1% of the naphthalene sulfonic acids-formaldehyde condensation products of sulfonation
Water complements to 100%
Can be dissolved in methyl oleate hundred, add ethoxylated castor oil to obtain oil phase; According to formula, the sodium salt of the naphthalene sulfonic acids-formaldehyde condensation products of Boscalid, sulfonation, water are obtained to the suspending agent of water Boscalid after grinding and/or high speed shear; Under agitation add water to obtain suspension emulsion oil phase.
Can obtain+10% Boscalid wetting powder of embodiment 7 10,%00
Hundred can obtain 10%
Boscalid 10%
Sodium lignin sulfonate 1%
NaLS 2%
The silicic acid 1% of high degree of dispersion
Kaolin complements to 100%
Said components is mixed in proportion, and grind, pulverize, be prepared into wetting powder.
Can obtain+50% Boscalid coated granule of embodiment 8 40,%00
Hundred can obtain 40%
Boscalid 50%
Polyethylene glycol 3%
The silicic acid 1% of high degree of dispersion
Calcium carbonate complements to 100%
In blender, levigate Fungicidal active compound is evenly applied on the carrier being soaked by polyethylene glycol.Can obtain dustless coated granule in this way.
Can obtain+10% Boscalid wetting powder of embodiment 9 50,%00
Hundred can obtain 50%
Boscalid 10%
Lauryl sodium sulfate 1%
Sodium lignin sulfonate 1%
Kaolin complements to 100%
Said components is mixed in proportion, and grind, pulverize, be prepared into wetting powder.
Can obtain+60% Boscalid granule of embodiment 10 20,%00
Hundred can obtain 20%
Boscalid 60%
Sodium lignin sulfonate 4%
Carboxymethyl cellulose 2%
Kaolin complements to 100%
Reactive compound is mixed with auxiliary agent and grind, with water-wet, granulation, then dry in air stream.
Can obtain+2% Boscalid seed coat agent of embodiment 11 50,%00
Hundred can obtain 50%
Boscalid 2%
Fatty alcohol-polyoxyethylene ether sulfosuccinic acid monoesters disodium 10%
MODIFIED LIGNOSULPHONATE 5%
Xanthans 1%
Bentonite 1%
Glycerine 5%
PVP-K30 1%
Water complements to 100%
Above-mentioned each component is mixed in proportion after grinding and/or high speed shear and obtained seed coat agent.
Can obtain+50% Boscalid microcapsule suspension-suspending agent of embodiment 12 5,%00
ATLOX
TM4913 4%
Citric acid 0.05%
Catalyzer 0.1%
Water 8%
Boscalid 50%
PAPI
TM 1.35%
SOLVESSO
TM200 5%
ATLOX
TM4913 16%
Dispersant LFH 0.3%
Defoamer 0.16%
Urea 4.4%
Hundred can obtain 5%
Water complements to 100%
By PAPI
tM, hundred can obtain, SOLVESSO
tM200 oil phases that form add containing ATLOX
tMin 4913 the aqueous solution, form emulsion.Then heat and be incubated 50
ounder C, add catalyst reaction 2 hours.After cooling, obtain hundred available microcapsuless.
ATLOX
tM4913, dispersant LFH, defoamer, urea, Boscalid and water mix in proportion, after grinding and/or high speed shear, obtain suspending agent.
By hundred can obtaining in the suspending agent that microcapsules adds Boscalid of obtaining, stir and obtain 5,%00 can obtain+50% Boscalid microcapsule suspension-suspending agent.
Can obtain+50% Boscalid suspension emulsion of embodiment 13 1,%00
Hundred can obtain 1%
Boscalid 50%
SOLVESSO
TM200 10%
Ethoxylated castor oil 4%
Fatty alcohol-polyoxyethylene ether sulfosuccinic acid monoesters disodium 5%
MODIFIED LIGNOSULPHONATE 5%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%
By hundred, can be dissolved in SOLVESSO
tMin 200, add ethoxylated castor oil, obtain hundred available oil phases;
Fatty alcohol-polyoxyethylene ether sulfosuccinic acid monoesters disodium, MODIFIED LIGNOSULPHONATE, Boscalid and water are mixed in proportion, after grinding and/or high speed shear, obtain the suspending agent of Boscalid.
By joining the aqueous suspension agent containing Boscalid containing hundred available oil phases, obtain suspension emulsion.
Can obtain+0.5% Boscalid water dispersible granules of embodiment 14 50,%00
Hundred can obtain 50%
Boscalid 0.5%
MODIFIED LIGNOSULPHONATE 5%
Lauryl sodium sulfate 5%
Urea 5%
Kaolin complements to 100%
By hundred can obtaining, Boscalid, dispersant, wetting agent, disintegrant and filler mix in the ratio of formula, through air-flow crushing, becomes wetting powder; Add again a certain amount of water to mix extruding and make material.After drying screening, obtain 50,%00 can obtain+0.5% Boscalid water dispersible granules.
Can obtain+30% Boscalid water dispersible granules of embodiment 15 20,%00
Hundred can obtain 20%
Boscalid 30%
MODIFIED LIGNOSULPHONATE 5%
Lauryl sodium sulfate 5%
Urea 5%
Kaolin complements to 100%
By hundred can obtaining, Boscalid, dispersant, wetting agent, disintegrant and filler mix in the ratio of formula, through air-flow crushing, becomes wetting powder; Add again a certain amount of water to mix extruding and make material.After drying screening, obtain 20,%00 can obtain+30% Boscalid water dispersible granules.
Can obtain+5% Boscalid wetting powder of embodiment 16 5,%00
Hundred can obtain 5%
Boscalid 5%
Lauryl sodium sulfate 1%
Sodium lignin sulfonate 1%
Kaolin complements to 100%
Said components is mixed in proportion, and grind, pulverize, be prepared into wetting powder.
Can obtain+50% Boscalid bond of embodiment 17 50,%00
Hundred can obtain 50%
Boscalid 50%
Proportioning in above embodiment is weight per distribution ratio.
Biological test example
The combination of active principles of different agricultural chemicals is made to agricultural chemicals, is a kind of effectively and efficiently mode of the upper resistance germ of current development novel pesticide and control agricultural.The agricultural chemicals of different cultivars shows three kinds of type of action: summation action, synergistic effect and antagonism after mixing conventionally.But be specially which kind of effect, unpredictable, only have by great many of experiments and just can know.Compound synergic is well filled a prescription, and owing to obviously having improved actual control efficiency, has reduced the usage amount of agricultural chemicals, thereby has delayed widely the drug-fast generation speed of germ, is the important means of integrated control disease.
The present invention can carry out effect analysis by the abundant method of Sun Yun, Colby formula with the combination of Boscalid to hundred, finds that resulting Fungicidai mixtures has gain effect, and is not only the simple addition of two kinds of medicaments in certain ratio range.
Toxicity Determination
Test 1: the toxicity test to graw mold of tomato
Adopt spore germination test method(s).Choose the tomato seedling that growing way is consistent, each processing selects 3 basins for examination tomato seedling, with potter spray tower, under 50PSI pressure, spray, and the about 5mL of every basin, each medicament arranges 12 concentration gradients.After chemicals treatment, 24h connects bacterium, the graw mold of tomato leaf that picks up from field is evenly shaken off to conidium above tomato seedling and inoculate, and then tomato seedling is put into greenhouse and cultivates.After 7d, according to the morbidity grade scale complete stool of graw mold of tomato, investigate disease index, and calculate control efficiency, then by method of least squares, calculate concentration EC in inhibition
50, then calculate co-toxicity coefficient (CTC) according to the abundant method of Sun Yun.
Computational methods:
Actual measurement toxicity index (ATI)=(standard medicament EC
50/ reagent agent EC
50) * 100
The percentage composition of B in percentage composition+B medicament toxicity index * mixture of A in theoretical toxicity index (TTI)=A medicament toxicity index * mixture
Co-toxicity coefficient (CTC)=[mixture actual measurement theoretical toxicity index of toxicity index (ATI)/mixture (TTI) * 100
CTC<80 is antagonism, and 80≤CTC≤120 are summation action, and CTC > 120 is synergistic effect,
Table 1: the virulence test result to graw mold of tomato
As known from Table 1, hundred can be when the combination control graw mold of tomato of Boscalid be in the scope of proportioning 100:1-1:100, and co-toxicity coefficient is all greater than 120, illustrates that both all show as gain effect at being mixed within the scope of this.
Test 2: the toxicity test of powdery mildew of cucumber
Adopt spore germination test method(s): choose the cucumber seedling that growing way is consistent, each processing selects 3 basins for examination leaf seedling, with potter spray tower, under 50PSI pressure, spray, the about 5mL of every basin, each medicament arranges 12 concentration gradients.After chemicals treatment, 24h connects bacterium, the powdery mildew of cucumber leaf that picks up from field is evenly shaken off to conidium above cucumber seedling and inoculate, and then cucumber seedling is put into greenhouse and cultivates.After 7d, according to the morbidity grade scale complete stool of powdery mildew of cucumber, investigate disease index, and calculate control efficiency, then by method of least squares, calculate concentration EC in inhibition
50, then calculate co-toxicity coefficient (CTC) according to the abundant method of Sun Yun.
Table 2: the virulence test result to powdery mildew of cucumber
As known from Table 2, hundred can prevent and treat with the combination of Boscalid powdery mildew of cucumber in the scope of proportioning 100:1-1:100 time, and co-toxicity coefficient is all greater than 120, illustrates that both all show as gain effect at being mixed within the scope of this.
Test 3: the toxicity test of sclerotinia rot of colza
Adopt spore germination test method(s): choose the Brassica campestris L seedling that growing way is consistent, each processing selects 3 basins for examination seedling, with potter spray tower, under 50PSI pressure, spray, the about 5mL of every basin, each medicament arranges 12 concentration gradients.After chemicals treatment, 24h connects bacterium, the sclerotinia rot of colza leaf that picks up from field is evenly shaken off to conidium above Brassica campestris L seedling and inoculate, and then Brassica campestris L seedling is put into greenhouse and cultivates.After 7d, according to the morbidity grade scale complete stool of sclerotinia rot of colza, investigate disease index, and calculate control efficiency, then by method of least squares, calculate concentration EC in inhibition
50, then calculate co-toxicity coefficient (CTC) according to the abundant method of Sun Yun.
Table 3: the virulence test result to sclerotinia rot of colza
As known from Table 3, hundred can be when the combination control sclerotinia rot of colza of Boscalid be in the scope of proportioning 100:1-1:100, and co-toxicity coefficient is all greater than 120, illustrates that both all show as gain effect at being mixed within the scope of this.
Test 4: the toxicity test of Penicillium italicum
Adopt and suppress mycelial growth rate method: experiment target is designated as Penicillium italicum, test adopts co-toxicity coefficient method to evaluate the co-toxicity effect of complex preparation.
By hundred, can use respectively acetone solution with Boscalid, with 0.1% Tween-80 aqueous solution dilution, be mixed with again the liquid of series concentration, in superclean bench, draw respectively 6mL to the conical flask of sterilizing, potato dextrose agar (PDA) 54mL that adds 50 ℃ of left and right, after shaking up, pour the plate of 4 diameter 9cm into, make the toxic medium of 4 respective concentration; Use the same method and can make toxic medium with Boscalid series concentration compound solution by hundred of different proportionings.Penicillium italicum bacterium by cultivating 2 days, breaks into bacterium piece with the card punch of diameter 5mm at colony edge, with transfer needle, bacterium piece is moved to the toxic PDA medium being mixed with in advance central, is then placed in 25 ℃ of incubators and cultivates, and every processing repeats 4 times.After 3 days, adopt right-angled intersection method to measure and respectively process colony diameter cm with slide calliper rule, obtain correction inhibition percentage.Two diameters are surveyed in each bacterium colony right-angled intersection, with its mean, represent bacterium colony size.Then by following formula, obtain colony growth inhibiting rate:
Then by method of least squares, calculate concentration EC in inhibition
50, then calculate co-toxicity coefficient (CTC) according to the abundant method of Sun Yun.
Table 4: the virulence test result to Penicillium italicum
As known from Table 4, hundred can be when the combination control Penicillium italicum of Boscalid be in the scope of proportioning 100:1-1:100, and co-toxicity coefficient is all greater than 120, illustrates that both all show as gain effect at being mixed within the scope of this.
Biological test example
When the effect of active compound combinations surpasses the summation of the effect when each reactive compound is used separately, there is synergistic function.The predictive role of the particular combination of two kinds of reactive compounds can be used so-called " Colby formula " (referring to S.R. Colby, " Calculating Synergistic and Antagonistic Responses of Herbicide Combinations ", Weeds 1967,15,20-22) calculate as follows: if
X is the activity when using consumption for mg/ha or the concentration reactive compound A that is mppm;
Y is the activity when using consumption for ng/ha or the concentration reactive compound B that is nppm, is expressed as the percentage that accounts for untreated control;
E is the activity when using consumption for m and n g/ha or the concentration reactive compound A that is m and n ppm and B,
So
If the activity of actual observation (O) is greater than expection active (E), so this mixture super add and, there is synergistic effect.
Following biological test example is in order to illustrate the present invention.But the present invention is not limited to these embodiment.
Test 1 powdery mildew of cucumber test
Solvent: the N-methyl-pyrrolidones of 7 parts of weight
Emulsifier: the alkylaryl polyglycol ether of 2 parts of weight
Suitable in order to make, 1 part of reactive compound or the combination of reactive compound and solvent of above-mentioned amount and emulsifier is by weight mixed, and be diluted with water to desired concn.
In order to measure activity, the active agent preparations spraying by seedling with described using dosage.Liquid layer to be painted dusts seedling after becoming dry with the spore of cucumber powdery mildew fungus.Then test plant is placed in to temperature approximately 20
oin the greenhouse of C, air humidity approximately 80% to promote the growth of white powder scab.Inoculate and carry out effect assessment after 7 days, 0% refer to effect with contrast quite, 100% does not refer to and observes and infect.Reactive compound, using dosage and result of the test are listed in the following table:
Result of the test shows, observes the active activity of calculating with " Colby " formula that surpasses, and shows obvious synergistic effect.
Test 2 ash arrhizus bacteria tests (strawberry)
Solvent: the N-methyl-pyrrolidones of 7 parts of weight
Emulsifier: the alkylaryl polyglycol ether of 2 parts of weight
In order to make suitable reactive compound, 1 part of reactive compound or the combination of reactive compound and solvent of above-mentioned amount and emulsifier is by weight mixed, and be diluted with water to desired concn.
In order to test therapeutic activity, seedling is dusted with Botrytis cinerea bacterium spore.Inoculate after 48 hours the active agent preparations spraying by Strawberry seedlings with described using dosage.Then test plant is placed in temperature approximately 20
oin the greenhouse of C, air humidity approximately 80% to promote the growth of grey mold scab.Inoculate and carry out effect assessment after 7 days, 0% refer to effect with contrast quite, 100% does not refer to and observes and infect.Reactive compound, using dosage and result of the test are listed in the following table:
Result of the test shows, observes the active activity of calculating with " Colby " formula that surpasses, and shows obvious synergistic effect.
Test 3 stalk break test (rape)/seed treatment
Reactive compound is used with dry seeds seed dressing.Said preparation can be by mixing the reactive compound of independent reactive compound or combination to prepare with levigate mineral matter, and obtaining can be at the equally distributed finely powdered mixt of the surface of the seed.
During seed seed dressing, by infecting seed and seed seed dressing, in the glass flask of sealing, shake 3 minutes.Rape seed is seeded in 1 centimetre of dark standard soil, in temperature approximately 18
oc, cultivates in the greenhouse of air humidity approximately 95%, and seeds cultivation case is illumination in 15 hours day by day often.
Sow after 3 weeks, evaluate the illness of Brassica campestris L seedling, 0% refer to effect with contrast suitable, 100% does not refer to and observes and infect.Reactive compound, using dosage and result of the test are listed in the following table:
| Reactive compound | Using dosage gA.I/100kg seed | The active % observing | The activity (%) of calculating according to Colby | Synergistic |
| Hundred can obtain | 100 | 0 | - | - |
| Boscalid | 500 | 39.82 | - | - |
| Hundred can obtain+Boscalids | 100+500 | 57.32 | 39.82 | Be |
Result of the test shows, observes the active activity of calculating with " Colby " formula that surpasses, and shows obvious synergistic effect.
Test 4: the antiseptic effect to storage strawberry
Process strawberry and pluck fruit picking time, reject sick fruit and wound fruit, with processing liquid, soak fruit 1min.Contrast clear water dipping.Each dries after processing and soaking fruit, packs the plastic box that surrounding is lined with newspaper next day into, normal temperature laboratory storage.Process and check decayed fruit number and reject decayed fruit for latter 7 days, weigh up fruit weight simultaneously.And calculate preventive effect.
Result of the test shows, observes the active activity of calculating with " Colby " formula that surpasses, and shows obvious synergistic effect.
Test the antiseptic effect of 5 pairs of storage oranges and tangerines
Process in oranges and tangerines and pluck tangerine fruit picking time, reject sick fruit and wound fruit, with processing liquid, soak fruit 1min.Contrast clear water dipping.Each dries after processing and soaking fruit, packs the plastic box that surrounding is lined with newspaper next day into, normal temperature laboratory storage.Process and check decayed fruit number and reject decayed fruit for latter 45 days, weigh up fruit weight simultaneously.And calculate preventive effect.
Result of the test shows, observes the active activity of calculating with " Colby " formula that surpasses, and shows obvious synergistic effect.
Claims (16)
1. a Fungicidai mixtures, is characterized in that: comprise hundred can with Boscalid active component, described hundred can be 100:1-1:100 with the weight ratio of Boscalid.
2. mixture according to claim 1, is characterized in that: described hundred can be 50:1-1:50 with the weight ratio of Boscalid.
3. mixture according to claim 1, is characterized in that: described hundred can be 25:1-1:25 with the weight ratio of Boscalid.
4. mixture according to claim 1, is characterized in that: described hundred can be 10:1-1:10 with the weight ratio of Boscalid.
5. mixture according to claim 1, is characterized in that: comprise the active component described in claim 1, filler and/or surfactant.
6. mixture according to claim 1, is characterized in that: hundred can account for the content of Boscalid active component the 5%-90% of mixture.
7. mixture according to claim 1, is characterized in that: hundred can account for the content of Boscalid active component the 10%-80% of mixture.
8. mixture according to claim 1, is characterized in that: hundred can account for the content of Boscalid active component the 20%-60% of mixture.
9. mixture according to claim 1, it is characterized in that, the formulation of described mixture is wetting powder, missible oil, suspending agent, suspension emulsion, microcapsules, seed coat agent, microemulsion, aqueous emulsion, water dispersible granules, foaming agent, paste, aerosol, ultra low volume spraying liquid.
10. the mixture described in claim 1 is used for the purposes of preventing and treating fungi.
The purposes of 11. mixtures according to claim 10 for preventing and treating fungi on Cereal, fruit, vegetables, cotton, fruit tree, ornamental plants.
12. 1 kinds of methods of preventing and kill off plant disease, are applied to plant, plant propagation material and the organ growing subsequently, environment by Fungicidai mixtures claimed in claim 1.
13. methods according to claim 12, is characterized in that: the propagating materials of the plant needing protection by mixture process claimed in claim 1.
The plant propagation material of 14. mixture process claimed in claim 1.
15. methods according to claim 12, is characterized in that: hundred of claim 1 can be used simultaneously or use respectively or sequential application with Boscalid compound.
16. mixtures claimed in claim 1 are for preventing and treating the purposes of fruit vegetables storing period disease.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106417346A (en) * | 2016-09-20 | 2017-02-22 | 佛山市盈辉作物科学有限公司 | Sterilizing composition containing biguanide trioctyl alkylbenzene sulfonate and fluopyram |
| CN106922730A (en) * | 2015-12-30 | 2017-07-07 | 江苏龙灯化学有限公司 | A kind of bactericidal composition |
| CN106982855A (en) * | 2016-01-20 | 2017-07-28 | 江苏龙灯化学有限公司 | A kind of bactericidal composition |
| CN109526978A (en) * | 2017-08-07 | 2019-03-29 | 江苏龙灯化学有限公司 | A kind of bactericidal composition |
| CN109566642A (en) * | 2017-09-29 | 2019-04-05 | 江苏龙灯化学有限公司 | A kind of bactericidal composition |
| CN111869672A (en) * | 2018-05-18 | 2020-11-03 | 河北省农林科学院植物保护研究所 | Bactericidal composition and application thereof |
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| CN106922730A (en) * | 2015-12-30 | 2017-07-07 | 江苏龙灯化学有限公司 | A kind of bactericidal composition |
| CN106982855A (en) * | 2016-01-20 | 2017-07-28 | 江苏龙灯化学有限公司 | A kind of bactericidal composition |
| CN111771899A (en) * | 2016-01-20 | 2020-10-16 | 江苏龙灯化学有限公司 | Bactericidal composition |
| CN106417346A (en) * | 2016-09-20 | 2017-02-22 | 佛山市盈辉作物科学有限公司 | Sterilizing composition containing biguanide trioctyl alkylbenzene sulfonate and fluopyram |
| CN106417346B (en) * | 2016-09-20 | 2019-02-05 | 佛山市盈辉作物科学有限公司 | A kind of bactericidal composition containing three octyl benzene sulfonate and fluopyram of biguanides |
| CN109526978A (en) * | 2017-08-07 | 2019-03-29 | 江苏龙灯化学有限公司 | A kind of bactericidal composition |
| CN109566642A (en) * | 2017-09-29 | 2019-04-05 | 江苏龙灯化学有限公司 | A kind of bactericidal composition |
| CN111869672A (en) * | 2018-05-18 | 2020-11-03 | 河北省农林科学院植物保护研究所 | Bactericidal composition and application thereof |
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